CPP FIITJEE Atomic Structure

JEE – Main

1. The ionization energy of He+ is 19.6 × 1018 J per atom. The energy of the first stationary
state of Li2+ is
(A) 19.6 × 1018 J (B) 5 × 1018 J
17
(C) 4.41 × 10 J (D) 4.41 × 1018 J

2. Which set of quantum numbers (n, l, m, s) represents the outermost electron in a gaseous
aluminium atom?
1 1
(A) 2, 1, 0, + (B) 2, 1, 1, +
2 2
1 1
(C) 3, 0, 0, + (D) 3, 1, 1, +
2 2

3. The ratio of energy of photon  = 2000 Å to that of  = 4000 Å is

1 1
(A) 2 (B) (C) 4 (D)
2 4

4. Consider the ground state of Cu atom (z = 29). The number of electrons with the azimuthal
quantum numbers l = 1 and 2 are respectively
(A) 16 and 6 (B) 12 and 10
(C) 12 and 9 (D) 16 and 5

5. In which of the following sets of orbits, electrons have equal orbital angular momentum?
(A) 1s and 2s (B) 3d and 4d (C) 2p and 5p (D)All of the above
6. Which of the following statements is correct?
(A) (n  1) d subshell has lower energy than ns subshell.
(B) (n  1) d subshell has higher energy than ns subshell.
(C) (n + 1) d subshell has lower energy than nf subshell
(D) nf subshell has lower energy than (n + 2)s subshell.

7. Radius of 3rd orbit in He+ is _______ times the radius of first orbit of hydrogen atom.
(A) 9 (B) 4.5 (C) 3 (D) 2.25

8. The frequency in Hertz of a radiation of wavelength 500 nm is

(A) 6 Hz (B) 1014 Hz (C) 6 × 1014 Hz (D) 0.6 × 1014 Hz

9. The wave number of first line of Balmer series of hydrogen is 15200 cm–1. The wave number
of the first line of Li2+ ion is
(A) 15200 cm–1 (B) 60800 cm–1
(C) 76000 cm–1 (D) 136800 cm–1

10. The maximum number of electrons with spin value +1/2 in the orbital with azimuthal
quantum number value, l = 2 and magnetic quantum number, m = +2 is
(A) 5 (B) 10 (C) 3 (D) 1

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11. The electronic configuration of the element which is just above the element with atomic
number 43 in the same periodic group is
(A) 1s22s22p63s23p63d54s2 (B) 1s22s22p63s23p63d104s24p5
(C) 1s22s22p63s23p63d64s1 (D) 1s22s22p63s23p63d104s14p6

12. Which of the following transition between energy levels in the hydrogen atom produces the
fourth line of the second series in the Hydrogen spectrum?
(A) n 2  5  n1  1 (B) n 2  4  n1  1
(C) n 2  6  n1  2 (D) n 2  5  n1  2

13. If the electron of Hydrogen atom is excited to 4th excited state, then the total spectral lines
falling in Paschen series are equal to:
(A) 2 (B) 10
(C) 3 (D) 4

14. Splitting of spectral lines when atoms are subjected to strong electric field is called:
(A) Zeeman effect (B) Stark effect
(C) Decay (D) Disintegration
15. 242 nm is just sufficient to ionise sodium atom. Ionisation energy of sodium atom will be :
(A) 494 kJ mol 1 (B) 24.7 kJ mol 1
(C) 988 kJ mol 1 (D) 247 kJ mol 1

16. Which of the following quantum numbers represent impossible arrangements?

(A) n = 2, l = 1, m = 0, s = –1/2 (B) n = 4, l = 3, m = 2, s = +1/2
(C) n = 3, l = 2, m = 3, s = +1/2 (D) n = 4, l = 3, m = 3, s = +1/2

17. The electronic configuration [Ar] 3d6 can be attributed to

(A) Co3+ (B) Zn2+
2+
(C) Mn (D) Ni+4

18. The diagram below illustrates a possible electronic configuration of which of following
species?
              
1s 2s 2p 3s 3p 4s 3d
(A) Sc (B) Cr2+
(C) Mo (D) Cr

19. The first emission line of hydrogen atomic spectrum in Balmer series appears at
(R = Rydberg constant)
5R 3R
(A) cm 1 (B) cm 1
36 4
7R 9R
(C) cm 1 (D) cm 1
144 400
20. In which of the following one electron system, the radius of first Bohr orbit is minimum?
(A) H-atom (B) Deuterium ion
(C) He+ ion (D) Li2+ ion

21. The total spin and magnetic moment for oxygen atom are
(A) ±1, 8 BM (B) ±2, 6.93 BM
(C) ±1, 15 BM (D) ±2, 48 BM

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22. Number of nodal planes (planes of zero electron density) in the dxy orbital is
(A) 1 (B) 2
(C) 0 (D) 0

23. The ionization energy of hydrogen atom in the ground state is x kJ. The energy required for
an electron to jump for 2nd orbit to 3rd orbit is
5x
(A) (B) 5x
36
x
(C) 7.2x (D)
6

24. Which one of the orbitals has zero probability of finding electrons in xz plane?
(A) px (B) py
(C) pz (D) dxz

25. Orbital angular momentum for 3d orbital electron is

h h
(A) 3 (B) 2
2 2
h
(C) 6 (D) 0
2
26. The number of spherical nodes for 2p orbital is
(A) 1 (B) 0 (C) 2 (D) 3

27. The momentum of a particle which has a de Broglie wavelength of 0.1 nm is (in kg ms–1)
(A) 7.08 × 10–21 (B) 6.64 × 10–24
–14
(C) 6.58 × 10 (D) 5.89 × 10–9

28. The de Broglie wavelength associated with a material particle is

(A) directly proportional to its energy (B) directly proportional to its momentum
(C) inversely proportional to its energy (D) inversely proportional to its momentum

2h
29. The angular momentum of an electron in a Bohr’s orbit of hydrogen atom is .

The wavelength of spectral line emitted when the electron falls from this level to next lower
level is
9 RH 16  25 7 RH 144
(A) Å (B) Å (C) Å (D) Å
16  25 9 RH 144 7 RH

30. Which of the following transitions of an electron in a H–atom would emit a photon of
minimum wavelength?
(A) 8 to 3 (B) 6 to 1 (C) 2 to 1 (D) 7 to 5

kn2
31. Rydberg given the equation for all visible radiation in the hydrogen spectrum as   .
n2  4
The value of k in terms of Rydberg constant is
R 4
(A) 4R (B) (C) (D) R
4 R

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32. Three atomic states of a hydrogen like atom are shown
in the figure. The transition from C to B yields a
photon of wavelength 364.6 nm and the transition
from B to A yields a photon of wavelength 121.5 nm,
Then the transition from C to A will yield a photon of
wavelength.

(A) 91.2 nm (B) 243.1 nm (C) 486.1 (D) None of these

33. In a discharge tube, there are only two hydrogen atoms. If the electrons in both atoms are de-
exciting from 4th orbit, the minimum and maximum number of spectral lines should
respectively be
(A) 1,4 (B) 4, 1 (C) 3, 4 (D) 1, 6

34. When electrons are de-exciting from nth orbit of hydrogen atoms, 15 spectral lines are
formed. The shortest wavelength among these will be
11 900 35 36
(A) R (B) (C) (D)
900 11R 36R 35R

35. If the number of orbitals of a particular type were (3l + 1), but spin quantum numbers only +
½ and -½, then a d-type orbital will contain a maximum of _ electrons.
(A) 10 (B) 14 (C) 2 (D) 5

36. The difference in angular momentum associated with the electron in two successive orbits of
hydrogen atom is
(A) h/ (B) h/2 (C) h/2 (D) (n 1) h/2

37. The missing fission product in the reaction 92U235 + 0n1  57La146 + ….. + 3 0n1
(A) 35Br86 (B) 35Br87 (C) 35Fe89 (D) 32Ge89

38. A 3p orbital has

(A) 2 non-spherical nodes
(B) 2 spherical nodes
(C) one spherical and one non-spherical node
(D) one spherical and 2 non-spherical nodes

39. Non - directional orbital is

(A) 3s (B) 4f (C) 4d (D) 4p

4E
40. The energy of a I, II and III energy levels of a certain atom are E ,
and 2E respectively. A
3
photon of wavelength  is emitted during a transition from III to I. What will be the
wavelength of emission for transition II to I?

(A) (B)  (C) 2  (D) 3 
2

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 JEE - ADVANCED (SINGLE OPTION CORRECT )

1. What is the series limit for Paschen series of the He+ ion in Å?
(A) 2502 (B) 2520 (C) 2250 (D) 2052

2. The time taken by an electron for one complete revolution in the nth Bohr orbit of the
hydrogen atom is
(A) inversely proportional to n 2 (B)directly proportional to n3
(C) directly proportional to n (D) directly proportional to (n/h)2

3. The ionization potential difference is 2.55eV for two of the Bohr orbits of the atomic
hydrogen of quantum numbers n1 and n2, [n1<n2]. What are the values of n1 and n2?
(A) 2, 3 (B) 3, 4 (C) 2, 4 (D) 3, 5

4. Which of the following statements is correct?

(A) The 4p orbital has three nodes
(B) 3s orbital has no node
(C) Orbital angular momentum of the electron in the 1s orbital of the hydrogen atom is h/2π
(D) The Rydberg constant has the same value for all hydrogen like species

5. An electron in a hydrogen atom in its ground state absorbs 1.5 times as much energy as the
minimum required escape from the atom. What is the wavelength of the emitted electron?
(A) 4.7 Å (B) 4.7nm (C) 9.4 Å (D) 9.4nm

6. A one dimensional electron trap has an extension of 1nm. What is the uncertainty in its
momentum in kgm/s?
(A) 1.551×10−24 (B) 1.055×10−25 (C) 1.115×10−23 (D) 5.2×10−26

7. Calculate the mass of the photon with a wavelength corresponding to the series limit of
Balmer transitions of the He+ ion in kg?
(A) 4.22×10−36 (B) 2.24×10−34 (C) 2.42×10-35 (D) 4.22×10−36

8. The wavelength of a certain electron transition in the hydrogen spectrum is 4864Å. Identify
the Transition;
(A) 3rd line Balmer (B) 1st line Lyman
st
(C) 1 line Paschen (D) 2nd line Balmer

9. What according to the Bohr model would be the radius of the electron orbit in the first
excited state of the Li+2 ion??
(A) 0.751Å (B) 0.705Å (C) 0.925Å (D) 0.952Å

10. Photo-electrons are ejected from a metal surface using photons of energy 4×10-20J .The de
Broglie wavelength of the electron emitted with maximum K.E. =59Å . What is the
photoelectric threshold in joules.
(A) 3.313×10−20 (B) 1.131×10−20 (C) 1.331×10−20 (D) 1.673×10−20
11. The series limit values are 8208Å and 22800 Å for the quantum numbers n1 and n2 in the
atomic spectrum of the hydrogen .What is the wavelength for the radiation emitted for the
transition n2→n1 in Å?
(A) 15282 (B) 12258 (C) 12825 (D) 15822

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12. An electron, practically at rest is initially accelerated through a potential difference of 100V
.It then has a de Broglie wavelength = λ1 Å .It then get retarded through 19 V and then has a
wavelength λ2 Å. A further retardation through 32 V changes the wavelength to λ3Å.What is
(λ3― λ2 ) / λ1?
(A) 20/41 (B) 10/63 (C) 20/63 (D) 10/41

13. Wave function vs distance from nucleus graph of an orbital is shown.

The number of nodal sphere of this orbital is

(A) 1 (B) 2 (C) 3 (D) 4

14. For an electron in a hydrogen atom the wave function ψ is proportional to e− (r/(a) where a is
Bohr`s radius . What is the ratio of probability of finding the electron at the nucleus to the
probability of finding the electron at a
(A) e (B) e2 (C) 1/ e2 (D) Zero

15. What transition in He+ ion shall have the same wave number as the first line in Balmer series
of H-atom?
(A) 3→2 (B) 6→4 (C) 5→2 (D) 7→5

16. The potential energy of the electron in an orbit of H-atom would be

(A) −mv2 (B) −e2/r (C) –mv2/2 (D) −e2/2r

17. An electron is moving with a KE of 4.55×10−25J .What will be the de Broglie wavelength for
this electron
(A) 5.28×10−7m (B) 7.27×10−7m (C) 2×10−10m (D) 3×10−5m

18. If each orbital can hold a maximum of 3 electrons. The number of elements in 4th period of
periodic table is
(A) 48 (B) 57 (C) 27 (D) 36

19. The number of orbitals in a sub shell is equal to

(A) n2 (B) 2l (C) 2l +1 (D) m

20. The ratio of the energy of the electron in ground state of hydrogen atom to that of the
electron in the first excited state of Be3+ is
(A) 1:4 (B) 1:8 (C) 1:16 (D) 16:1

21. The electronic transition from n=2 to n=1 will produce the shortest wavelength in
(A) H-atom (B) D-atom (C) He+ ion (D) Be3+ ion

22. The wave number of the first line of Balmer series of Hydrogen is 152000/cm. The wave
number of the first Balmer line of Li2+ ion is?
(A) 15200/cm (B) 60800/cm (C) 76000/cm (D) 1368000/cm

23. Photoelectric emission is observed from a surface for frequencies v1 & v2 of the incident
radiation (where v1>v2) . If the maximum KE of the photoelectrons in two cases are in the
ratio of 1:k ,then the threshold frequency v0 is given by
(A) (v1−v2)/k-1 (B) (kv1−v2)/k-1
(C) (kv2−v1)/k-1 (D) (v1−v2)/k

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24. The difference of nth and (n+1)th Bohr`s radius of H-atom is equal to its (n -1)th Bohr`s
radius. The value of n is
(A) 1 (B) 2 (C) 3 (D) 4

25. The electron in a hydrogen atom makes transition from M shell to L, the ratio of magnitude
of initial to final acceleration is
(A) 9:4 (B) 81:16 (C) 4:9 (D) 16:81

26. The nucleus of an atom is located at x = y = z = 0 .If the probability of finding an s-orbital
electron in a tiny volume assumed x = a, y = 0 = z is 10−5, what is the probability of finding
the electron in the same sized volume around x = z = 0, y = a?
(A) 10−5 (B) 10−5a (C) 10−5a2 (D) 10−5a−1

27. Suppose it is taken as a working hypothesis that an electron finds itself inside a typical
nucleus with an uncertainty in momentum, Δp≈10-20kgm/s, what is an approximate estimate
of the size of the nucleus?
(A) 1.058×10−13m (B) 8.53×10−15 m (C) 3.58×10−16m (D) 5.27×10−15m

28. Energy will be absorbed for the process of separating

(A) a proton from a proton (B) an electron from proton
(C) an electron from an electron (D) a neutron from a neutron

29. Number of waves in third Bohr orbit of Hydrogen will be

(A) 3 (B) 6 (C)9 (D)12

30. Principal, azimuthal and magnetic quantum numbers are respectively related to
(A) size, orientation and shape (B) size, shape and orientation
(C) shape, size and orientation (D) none of these

31. In the hydrogen atoms, the electrons are excited to the 5th energy level. The number of the
lines that may appear in the emission spectrum will be
(A) 4 (B) 8 (C) 10 (D) 12

32. Light of wavelength λ shines on a metal surface with intensity x and the metal emits y
electrons per second of average energy Z , what will happen to y and Z if x is doubled
(A) y will be doubled and Z will become half
(B) y will remain same and Z will be doubled
(C) Both y and Z will be doubled
(D) y will be increased but Z will remain same

33. The ratio of potential energy and total energy of an electron in a Bohr orbit of hydrogen like
species
(A) 2 (B) −2 (C) 1 (D) −1

34. If λ1 and λ2 denotes the de Broglie wavelength of two particles with same masses but charges
in the ratio of 1:2 after they are accelerated from rest through the same potential difference
then
(A) λ1 > λ2 (B) λ1 = λ2 (C) λ1 < λ2 (D) None

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 MORE THAN ONE OPTION CORRECT
1. When α-particle are sent through a thin metal foil, most of them go straight through the foil,
because:
(A) α-particle are much heavier than electrons (B) α-particle are positively charged
(C) most part of the atom is empty space (D) α-particle move with high velocity

2. Rutherford`s α-scattering experiment led to the following conclusions

(A) Atom has largely empty space
(B) The centre of the atom has positively charged nucleus
(C) The size of the nucleus is very small as compared to the size of the atom
(D) The electrons revolve around the nucleus

3. The probability of finding the electron in Px orbital is

(A) Maximum at two opposite sides of the nucleus along the x-axis
(B) Zero at nucleus
(C) Maximum at nucleus
(D) Along the x-axis

4. Which of the statements is(are) correct?

(A) Electrons in motion behave as if they are waves
(B) s-orbital is non directional
(C) An orbital can accommodate a maximum of the two electrons with parallel spins
(D) The energies of the various sub-levels in the same shell are in order s>p>d>f
5. Which concerning Bohr`s model are true?
(A) Predicts that probability of electron near the nucleus is more
(B) Angular momentum of electron in H-atom =nh/2π
(C) Introduces the idea of stationary states
(D) Explains line spectrum of hydrogen

6. Which sets of quantum no. are consistent with the theory

n l m s
(A) 2 1 0 -1/2
(B) 4 3 -2 -1/2
(C) 3 2 -3 1/2
(D) 4 3 -3 1/2

7. Heisenberg uncertainty principal is not significant for

(A) Moving electrons (B) Motor car
(C) Stationary particles (D) All of the above

8. Consider the electronic configuration for neutral atoms

1) 1s22s22p63s1 2) 1s22s22p64s1. Which of the following statements is/are false?
(A) Energy is required to change 1 to 2
(B) 1 represents Na atom
(C) 1 and 2 represent different elements
(D) More energy is required to remove one electron from 1 than 2
9. For the energy levels in an atom which one of the following statements is/are correct?
(A) 4f subshell has maximum 14 electrons.
(B) The 2nd principal energy level can have 4 sub energy levels and contains a maximum of 8
electrons
(C) The M energy level can have a maximum of 32 electrons
(D) The 4s sub energy level is at lower energy than the 3d sub energy level
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10. Which of the following statements are correct for an electron that has n = 4 and m =−2?
(A) The electron may be in a d orbital
(B) The electron is in the fourth principal electronic shell
(C) The electron may be in a p-orbital
(D) The electron may have the spin quantum number =0.5

11. Which of the following statement is/are correct??

(A) There is no probability of finding a p –electron exactly at the nucleus.
(B) The orbital d2z has two lobes of electron density directed along the z-axis and a ring of
electron density (called dough nut) centered in the xy-plane
(C) The orientation of p-orbitals and d-orbitals minimize electron-electron repulsion in
many electron atoms
(D) None is correct
12. Which of the following is/are correct?
(A) For all values of n the p-orbitals have the same shape but the overall size increases as n
increases, for a given atom
(B) The fact that there is a particular direction, along which each p-orbital has maximum
electron density, plays an important role in determining molecular geometries
(C) The charge cloud of a single electron in 2px atomic orbital consists of two lobes of
electron density
(D) None is correct

13. Which of the following is the correct set of four quantum numbers for each of the electrons
in the 3d sub shell when it is fully occupied?
(A) n=3;  =2; m=0,1,─1,2, ─2 and s = ±0.5, ±0.5, ±0.5, ±0.5 and ±0.5
(B) n=3;  =1; m=0,1,─1,2,─2 and s = ±0.5, ±0.5, ±0.5, ±0.5 and ±0.5
(C) n=4;  =2; m=0,1,─1,2,─2 and s=±0.5, ±0.5, ±0.5, ±0.5 and ±0.5
(D) None is correct.

14. Which of the following statements is/are correct??

(A) The energy of an electron in a many electron atom generally increases with an increase
in the value of n, but for a given (n+l), the lower the value of l, the lower is the energy.
(B) An electron close to the nucleus experiences a large electrostatic attraction
(C) For a given value of n, an s-electron penetrates the nucleus more than a p-electron which
penetrates more than a d-electron and so on
(D) None is correct

15. Which of the following statements is/are correct??

(A) All substances have magnetic properties
(B) There are substances in which all electron spins are paired
(C) There are substances in which one or more electrons have unpaired spins
(D) The greater the number of unpaired electrons, the greater is Paramagnetism per mole of
substance

16. The mathematical expression for the uncertainty principal is

(A) Δ x Δp ≥ h/4π (B) Δ EΔt ≥ h/4π (C) Δ x Δp ≥ h/p (D) ΔEΔt ≥ h/p

17. Choose the correct relations on the basis of Bohr`s theory

(A) Velocity of electron α1/n (B) Frequency of revolution α 1/n3
2
(C) Radius of orbit α n Z (D) Force on electron α 1/n4

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18. Which of the following statements is/are correct?
(A) A photon is a positively charged nuclear particle
(B) A photon is a particle of light energy
(C) A photon is a quantum of light
(D) A photon is a bundle of energy of definite magnitude.

19. Which of the following statements is/are correct?

(A) Stark effect is the splitting lines when source is placed in electric field
(B) Beyond a certain limit a spectrum of an atom there is continuum
(C) The intensities of spectral line in line spectrum decreases with increase in the value of n
(D) Shielding effect is possible in H-atom

20. Which statements is/are true regarding white lights?

(A) It is a form of energy (B) It can be deflected by a magnet
(C) It consists of photons of same energy (D) It is part of electromagnetic spectrum

21. An electron jumps nth level to 1st level , the fact which is/are correct about H atoms is/are
(A) Number of spectral lines =n(n-1)/2 (B) Number of spectral lines =∑(n-1)
(C) If n=4, the number of spectral lines =6 (D) Number of spectral lines =n(n-1)

22. Photoelectric effect supports quantum nature of light because

(A) There is a minimum frequency below which no emission of photoelectron is possible
(B) Maximum KE of photo electrons depends only on frequency of light and not on intensity
(C) Even when the metal surface is faintly illuminated the photoelectron leave the surface
immediately
(D) Electric charge of the photoelectrons is quantized
23. Which of the following statements is/are correct?
(A) If the value of l=0, the electron distribution is spherical
(B) The shape of the orbital is given by magnetic quantum number
(C) Orbital angular momentum of 1s, 2s, 3s electrons are equal
(D) In an atom, all electrons travel with the same velocity

COMPREHENSION TYPE

Comprehension – 1:
Rutherford proposed the atomic model after his most striking experiment on
  scattering leading to discovery of nucleus. Bohr later on modified the atomic model on
the basis of Planck’s quantum theory of light and proposed the concept of stationery circular
nh
orbit of quantized angular momentum . The collection of the line spectrum led
2
Sommerfeld to give the idea of elliptical orbits. He successfully explained the existence of
subshells and their number in a shell. The orbital angular momentum of subshells was
h
proposed as l  l  1 . . the emission of a spectral line in atomic spectra was supposed to
2
be due to the jump of electron from one energy level to other.

1. The orbital angular momentum of electron in 2p orbital is:

h h h 
(A) (B) (C) (D)
2 2 2 2

2. The volume occupied by the nucleus is about …… times of volume of atom:

(A) 10 – 15 (B) 1015 (C) 10 ─12 (D) 10 – 10
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3. Non – directional orbital is
(A) 3s (B) 4f (C) 4d (D) 4p

4. The total number of fundamental particles in 14

6 C is
(A) 6 (B) 8 (C) 14 (D) 20

5. The minimum energy is given out when an electron jumps from one orbit to other from:
(A) 2 to 1 (B) 3 to 2 (C) 4 to 3 (D) 5 to 4

6. An oil drop has ─6.39 x 10─19 coulomb charge. The number of electrons in this oil drop is:
(A) 4 (B) 3 (C) 2 (D) 1

Comprehension – 2 :

Bohr proposed his atomic model based on Planck’s quantum theory and derived following
relations for one electron system in C.G.S. units :
u1
For H – atom rn  n 2  r1 , E n  E1  Z 2 , u n  ; r1  0.529 A ; u1  2.19  10 8 cm / sec .; E1  13.6eV
n
For 1 electron systems , other than H
n 2  r1H E1H  Z 2 u1 H  Z
rn  ; En  2
; un 
Z n n
Later on de Broglie proposed the dual nature of electron and put forward his wave concept.
The wavelength of electron in an orbit was given by   h / mu .

1. The number of waves made by a Bohr electron in H – atom for one complete revolution in its
3rd orbit are:
(A) 1 (B) 2 (C) 3 (D) 4
2. The circumference (in m) of third Bohr orbit in H – atom is :
(A) 3.0 10 7 (B) 3.0 10 8 (C) 3.0 10 6 (D) 3.0 10 9

3. The wavelength (in m ) of moving electron in 3rd orbit of H – atom is :

(A) 1.0 10 9 (B) 2.0 10 9 (C) 1.0 10 7 (D) 1.0 10 8

4. The potential energy of electron in 3rd Bohr orbit of H – atom is:

(A) - 2.42 10 12 erg (B) -4.84 10 12 erg (C) +4.84 10 12 erg (D) 2.42 10 12 erg

5. The momentum of electron in 3rd Bohr orbit of H – atom is :

(A) 6.65 10 25 kg m sec 1 (B) 6.65 10 28 kg m sec 1
(C) 6.65 10 29 kg m sec 1 (D) 6.65 10 20 kg m sec 1

Comprehension – 3:
h
De Broglie proposed dual nature for electron by putting his famous equation   . Later on
mu
 h 
Heisenberg proposed uncertainly principle as x.p      . On the contrary particle
2 2 
nature of electron was established on the basis of photoelectric effect. When a photon strikes
the metal surface, it gives up its energy to the electron. Part of this energy (say W) is used by
the electrons to escape from the metal and the remaining imparts the kinetic energy (1/2 mu2)
to the photoelectron. The potential applied on the surface to reduce the velocity of
photoelectron to zero is known as stopping potential.
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1. With what velocity must an electron travel so that its momentum is equal to that of photon of
wavelength is   5200 A :
(A) 800 m s- 1 (B) 1400 m s- 1 (C) 400 m s- 1 (D) 200 m s-1

2. With what potential should a beam of electron be accelerated so that its wavelength becomes
equal to 1.54 A .
(A) 63.3 V (B) 6.33 V (C) 633 V (D) None of these

3. The binding energy of electron in a metal is 250 kJ mol – 1 . The threshold frequency of metal
is:
(A) 6  10 12 sec 1 (B) 6  1014 sec 1 (C) 6  1010 sec 1 (D) 6  1012 sec 1

4. If uncertainties in position and momentum of an electron are same, then uncertainty in its
velocity can be given by:
h u 
(A)  2
(B)  (C)  (D) All of these
4m 4m 2m 2

5. The metal most commonly used in photoelectric cell is

(A) Na (B) Ba (C) Cs (D) Ni

6. The wavelength of a golf ball weighing 200g and moving at a speed of 5 meter /hr is of the
order:
(A) 10 – 10 m (B) 10 – 20 m (C) 10 – 30 m (D) 10 – 40 m

Comprehension – 4:

The electrons in a poly – electronic atom are filled one by one in order of increasing energy
level. The energy of subshells and orientation of orbitals depends upon the values of three
quantum numbers (i.e. n , l and m respectively) derived from Schrodinger wave equation.
The different orbitals of a subshells however posses same energy level and are called
degenerate orbitals but their energy level changes in presence of magnetic field and the
orbitals are non – degenerate. A spectral line is noticed if an electron jumps from one level to
other. The paramagnetic nature of element is due to the presence of unpaired electron.

1. P3- is isoelectronic with:

(A) N 3- (B) As3+ (C) Cl- (D) F-

2. The number of unpaired electrons in Cr atom is:

(A) 2 (B) 3 (C) 5 (D) 6

3. The element which has as many ‘s’ electrons as ‘p’ electrons but belong to III period is :
(A) O (B) Mg (C) Al (D) C

4. The total magnetic moment of Ni2+ ion is :

(A) 6 BM (B) 8 BM (C) 15 BM (D) 12 BM

5. The number of spherical and angular nodes in 2p orbitals are:

(A) 1, 1 (B) 2, 1 (C) 1, 0 (D) 0, 1

6. The possible number of spectral lines when an electron can jump from 5th shell to 2nd shell is:
(A) 4 (B) 2 (C) 3 (D) 6

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7. In the absence of electric or magnetic field, the correct order for energy levels in H – atom is:
(A) 3s = 3p = 3d > 2s (B) 3d > 3p > 3s > 2s
(C) 3d > 3p = 3s > 2s (D) 3d > 3p > 3s = 2s

8. Total number of valence electrons in NH 4 is:

(A) 9 (B) 8 (C) 6 (D) 11

MATRIX MATCH

Column-I and Column-II contains four entries each. Entries of Column-I are to be matched
with some entries of Column-II. One or more than one entries of Column-I may have the
matching with the same entries of Column-II.

1. If in Bohr’s model, for unielectronic atom following symbols are used rn , z  Radius of n th
orbit with atomic number Z; U n , z  Potential energy of e  ;
K n , z  Kinetic energy of e  : Vn , z  Velocity of e  ;
Tn , z  Time period of revolution
Column-I Column-II
(A) U1,2 : K1,1 (P) 1 : 8
(B) r2,1 : r1,2 (Q) – 8 : 1
(C) V1,2 : V2,4 (R) 1 : 1
(D) T1,2 : T2,2 (S) 8 : 1

2. Column-I Column-II
(A) The number of radial node of 5s atomic orbital is (P) 1
(B) The number of angular node of 3d yz atomic orbital is (Q) 4
(C) The sum of number of angular node and radial (R) 2
node of 4d xy atomic orbital
(D) The number of angular node of 3p atomic orbital is (S) 3

3. Column-I Column-II
h
(A) Orbital angular momentum of an electron (P) s ( s  1)
2
(B) Angular momentum of an electron in an orbit (Q) n(n  2)
nh
(C) Spin angular momentum of an electron (R)
2
h
(D) Magnetic moment of atom (in B.M.) (S) l (l  1)
2

4. Column-I Column-II
(A) No. of orbitals in the nth shell (P) 2(2l + 1)
(B) Max. no. of electrons in a subshell (Q) n
(C) No. of subshells in nth shell (R) 2l + 1
(D) No. of orbitals in a subshell (S) n2

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5. Column-I Column-II
1

(A) (P) 4s
r

4  r 2 2

(B) (Q) 5px

Distance from nucleus

(C) Angular probability is dependent on  and  (R) 3s

(D) No angular node is present (S) 6dxy

6. Column - I Column - II
(A) m= 1 (P) p- subshell
(B) l = 2 (Q) f- subshell
(C) n = 3 (R) d- subshell
(D) Angular nodes (S) s- subshell

7. Column - I Column - II (Bohr’s model)

(A) Total Energy of e− (P)  Z 2
(B) Revolution frequency of e− (Q)  Z 3
(C) Acceleration of e− (R) Decreases as orbit number increases
(D) Radius of orbit (S) Increases as orbit number increases

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 ANSWERS

JEE – Main

1. C 2. D 3. A 4. B 5. D 6. B 7. B

8. C 9. D 10. A 11. A 12. C 13. A 14. B

15. A 16. C 17. A,D 18. D 19. A 20. D 21. A

22. B 23. A 24. B 25. C 26. B 27. B 28. D

29. D 30. B 31. C 32. A 33. A 34. D 35. C

36. B 37. B 38. C 39. A 40. D

JEE – Advanced

ONLY ONE OPTION CORRECT

1. D 2. B 3. C 4. A 5. A 6. D 7. C

8. D 9. B 10. A 11. C 12. C 13. A 14. D

15. B 16. A 17. B 18. C 19. C 20. A 21. D

22. D 23. B 24. D 25. D 26. A 27. D 28. B

29. A 30. B 31. C 32. D 33. A 34. A

MORE THAN ONE OPTION CORRECT

1. A, C, D 2. A, B, C, D 3. A, B, D 4. A, B 5. B, C, D 6. A, B, D 7. B, C

8. C 9. A, D 10. A, B, D 11. A, B, C 12. A, B, C 13. A 14. B, C

15. ABCD 16. A, B 17. A, B, D 18. B, C, D 19. A, B, C 20. A, D 21. ABC

22. A, B, C 23. A, C

COMPREHENSION TYPE; ASSERTION & REASONS

COMPREHENSION -1

1. (B) 2.(A) 3.(A) 4.(D) 5. (D) 6. (A)

COMPREHENSION -2

1. (C) 2. (D) 3. (A) 4. (B) 5. (A)

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COMPREHENSION -3

1. (B) 2. (A) 3. (B) 4. (D) 5. (C) 6. (C)

COMPREHENSION -4

1. (C) 2. (D) 3. (B) 4. (B) 5. (D) 6. (D)

7. (A) 8.(B)
MATRIX MATCH
1. A  Q; B  S; C  R; DP

2. A  Q; B  R; C  S; DP

3. A  S; B  R; C  P; DQ

4. A  S; B  P; C  Q; DR

5. A  P; B  P, Q, S; C  Q, S; D  P, R

6. A  P, Q, R; B  R; C  P, R, S; D  P, Q, R

7. A  P, S; B  P, R; C  Q, R; DS

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