WORKSHEET

SUB: CHEMISTRY
Class: XII
SOLUTION
1. The amount of solute that must be added to
of water so that the vapour pressure of water is lowered by is

a) b) c) d)

2. solution of urea is isotonic with solution of non-volatile solute , what is

the molecular mass of solute x?
a) b) c) d)

3. Which of the following statement is correct?

a) A saturated solution will remain saturated at all temperatures

b) A plant cell swells when placed in hypertonic solution
c) The depression in freezing point is directly proportional to molality of the
solution.
d) None of these.

4. A solution has higher osmotic pressure than its standard solution. Which of the
following term used

a) Isotonic b) Hupertonic c) Dilute d) Hypotonic

5. If of solute is dissolved in of solvent and the

elevation in boiling point is . The molal elevation constant of the solvent is

a) 2 b) 3 c) 2.5 d) 5

6. A non-ideal solution was preparedby mixing 30 ml chloroform and 50ml acetone.

The volume of mixture will be:

a) b) c) d)

7. The unit ebullioscopic constant is:

a) b)
 c) d)

8. Which one of the following is a colligative property?

a) Boiling Point b) Vapour pressure c) Osmotic pressure d) Vapour pressure

9. At a given temperature osmotic pressure of a Concentrated solution of a substance

a) is higher than that of dilute solution b) is lower than that of dilute solution
c) it gains water due to reverse osmosis d)it loses water due to osmosis

10. Boiling point of aqueous solution of a non-volatile solute A is equal to the

boiling point of aqueous solution of non-volatile solute B. The relation
between molecular weights of A and B is

a) b) c) d)

11. If molality of the dilute solution is doubled, the value of molal depression
Constant will be:
a) halved b) tripled c) unchanged d) doubled

12. Maximum amount of a solid solute that can be dissolved in a specified amount of
a given liquid solvent does not depend upon

a) temperature b) nature of solute c) pressure d) nature of solvent

13. Match:
Column-I Column-II
A) Mass percentage (p) Medicine and pharmacy
B) Mass by Volume (q) Concentration of pollutants in water
C) ppm (r) Industrial chemical application
D) Volume Percentage (s) Liquid solutions

a) A-(q) B-(p) C-(s) D-(r)

b) A-(s) B-(r) C-(p) D-(q)
c) A-(r) B-(q) C-(s) D-(p)
d) A-(r) B-(p) C-(q) D-(s)
14. Assertion (A): When 𝑁𝑎𝑐𝑙 is added to a water depression in freezing point is
observed.

Reason(R): The lowering of vapour pressure of a solution causes depression in the

freezing point.
a) Both A and R are true and R is correct explanation of A
b) Both A and R are true but R is not correct explanation of A
c) A is true but R is false
d) A is false but R is true

15. Assertion (A): When a solution is separated from the pure solvent by a
semipermeable membrane, the solvent molecules pass through it from pure solvent
to the solution side.

Reason(R): Diffusion of solvent occurs from a region of high concentration

solution to a region of low concentration solution
a) Both A and R are true and R is correct explanation of A
b) Both A and R are true but R is not correct explanation of A
c) A is true but R is false
d) A is false but R is true

READ THE FOLLOWING PASSAGE AND ANSWER THE QUESTIONS (5X1=5M)

Colligative properties of a solution depend upon the number of moles of the solute
dissolved and do not depend upon the nature of the solute. However, they are applicable
only to dilute solutions in which the solutes do not undergo any association or dissociation.
For solutes undergoing such changes, van’t Hoff introduced a factor, called van;t Hoff
factor(i). This has helped not only to explain the abnormal molecular masses of such solutes
in the solution but has also helped to calculate the degree of association or dissociation

1. Name the colligative property in which universal gas constant is

involved?

2. What is the value of van’t Hoff factor when the given electrolyte
undergoes tetramerisation?
3. Why boiling point of water is increased on addition of sodium chloride
into it?
4. What do you mean by isotonic solutions?
5. What is the value of I for Al2(SO4)3(very dilute)?
 (MULTIPLE CHOICE QUESTION)MCQ
11. The unit of ebulioscopic constant is .
–1
(i) K kg /mol or K (molality)
(ii) mol kg/ K or K–1(molality)
(iii) kg mol–1 K–1 or K–1(molality)–1
(iv) K mol kg–1 or K (molality)
12. An unripe mango placed in a concentrated salt solution to prepare
pickle, shrivels because
.
(i) it gains water due to osmosis.
(ii) it loses water due to reverse osmosis.
(iii) it gains water due to reverse osmosis. (iv) it loses water due to
osmosis.
13. The values of Van’t Hoff factors for KCl, NaCl and K2SO4, respectively,
are .
(i) 2, 2 and 2
(ii) 2, 2 and 3
(iii) 1, 1 and 2
(iv) 1, 1 and 1
14. The value of Henry’s constant KH is .
(i) greater for gases with higher solubility.
(ii) greater for gases with lower solubility.
(iii) constant for all gases.
(iv) not related to the solubility of gases.
15. We have three aqueous solutions of NaCl labeled as ‘A’,
‘B’ and ‘C’ with concentrations
0.1M, 0.01M and 0.001M, respectively. The value of van’t Hoff factor for
these solutions will be in the order .

(i) iA < iB < iC

(ii) iA > iB > iC
(iii) iA = iB = iC
(iv) iA < iB > ic
 Q2.How is that measurement of osmotic pressure is more widely used for
determining molar masses of macromolecules than the elevation in boiling point
or depression in freezing point of their solutions?
. Q3. Suggest the most important type of intermolecular interaction in the
following pairs:

Q4. Calculate the mass percentage of aspirin (C9H8O4) in acetonitrile (CH3CN)

when 6.5 g of C9H8O4 is dissolved in 450 g of CH3CN .

3 MARK QUESTIONS
Q1. Non-ideal solution exhibit either positive or negative deviations from
Raoult's law. What are these deviation and why are they caused? Explain with
one example for each type.
Q2 .a) Why is an increase in temperature observed on mixing chloroform and
acetone?
b) Why does sodium chloride solution freeze at a lower temperature than water?
Q3. A solution of glycerol (C3H8O3) in water was prepared by dissolving some
glycerol in 500g of water. This solution has a boiling point of 100.42C while pure
water boils at 100-C. What mass of glycerol was dissolved to make the solution ?
(Kb of water=0.512Kkg/mol)

5 MARKSQUESTION

Q1.a) State Raoult's Law for a solution containing volatile components. How does Raoult's law
become a special case of Henry's Law?
b) 1.00 g of a non‐electrolyte solute dissolved in 50 g of benzene lowered the freezing point of a
benzene by 0.40K.Findthemolar mass of the solute.(Kf for benzene=5.12K kg mol–1)
.a)Calculate the molarity of a sulphuricacid solution in which the mole fraction of water is 0.85.
b)The graphical representation of vapour pressure of two component system as a function of
compositionis given alongside.