Routine Test – 4
AS : chemistry Date : 20/06/2025
Time : 20 Min.
1. Last line of the Lyman series of H-atom has frequency v1 , last line of Lyman series of He+ ion has
frequency v2 and 1st line of Lyman series of He+ ion has frequency v3. Then
(A) 4v1 = v 2 + v 3 (B) v1 = 4v 2 + v 3 (C) v 2 = v3 − v1 (D) v 2 = v1 + v3
2. If 1 and 2 are respectively the wavelengths of the series limit of Lyman and Balmer series of
Hydrogen atom, then the wavelength of the first line of the Lyman series of the H-atom is :
− 1 12
(A) 1 − 2 (B) 1 2 (C) 2 (D)
12 2 − 1
3. If numerical value of mass and velocity are equal for a particle, then its de-Broglie wavelength in terms
of K.E. is
mh h
(A) (B) (C) both are correct (D) none is correct
2K.E. 2mK.E.
4. A wavelength of 400 nm of electromagnetic radiation corresponds to :
(A) frequency ( ) = 7.5 1014 Hz
(B) wave number ( ) = 2.5 106 m−1
(C) momentum of photon = 1.66 10−27 kgms−1
(D) all are correct values
5. In one experiment, a proton having initial kinetic energy of 1 eV is accelerated through a potential
difference of 3 V. In another experiment, an -particle having initial kinetic energy 20 eV is retarded
by a potential difference of 2 V. The ratio of de-Broglie wavelengths of proton and -particle is :
(A) 2 6 :1 (B) 8 : 1 (C) 4 : 1 (D) 2 2 :1
6. When photons of energy 4.25 eV strike the surface of a metal A, the ejected photoelectrons have
maximum kinetic energy (K.E)A and de-Broglie wavelength is A . The maximum kinetic energy of
photoelectrons liberated from another metal B by photons of energy 4.7 eV is (KE) B, where
(KE )B = (KE )A − 1.5 eV. If the de-Broglie wavelength of these photoelectrons is B ( = 2 A ) , then :
(A) The work function of metal A is 2.25 eV (B) The work function of metal B is 4.20 eV
(C) (KE)A = 2 eV (D) (KE)B = 2.75 eV
7. The ionisation energy of He+ ion is 19.6 × 10–18 J per ion. Calculate the energy of the first stationary
state of Li2+ ion.
8. Match the following :
Column – I Column – II
th 2+
(A) Binding energy of 5 excited state of Li sample (p) 10.2 V
(B) 1st excitation potential of H-atom (q) 3.4 eV
nd +
(C) 2 excitation potential of He ion (r) 13.6 eV
(D) I.E. of H-atom (s) 48.4 V
9. The IP of H-atom is 13.6 V. It is exposed to electromagnetic waves of wavelength 1026 Å and then,
it gives out induced radiations. Find the wavelength of all possible induced radiations.
10. The ionization energy of a Hydrogen like species is 4 Rydberg. What is the radius of the first orbit of
this atom ? (Given : Bohr radius of hydrogen = 5.3 × 10–11 m; 1 Rydberg = 2.2 × 10–18 J)
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Key & Hints
1. (D)
hv1 = 13.6eV
hv 2 = 13.6 22 eV
3
hv 3 = 13.6 22 eV
4
hv2 = hv1 + hv3
v 2 = v1 + v3
2. (D)
3. (A)
h h h
= = = 2
p mv v
2KE hm
but v 2 = therefore =
m 2KE
4. (D)
1
Use C = u=
5. (C)
K.E.proton = 1 + (1)( 3 ) = 4eV
h
p = & K.E.−particle = 20 − ( 2)( 2) = 16 eV
2mp (K.E.)p
h
=
2m (K.E.)
p m (K.E.) 4 16 4
= = =
mp (K.E.)p 1 4 1
6. (ABC)
4.25 = (W0)A + (K.E.)A
4.70 = (W0)B + (K.E.)A – 1.5
So, (W0)B – (W0)A = 0.45 + 1.5 = 1.95
Now, B = 2A
h 2h
=
2m (K.E.)B 2m (K.E.)A
So (K.E)A = 4 (K.E)B
4.25 – (W0)A = 4 [ 4.7 – (W0)B]
4(W0)B – (W0)A = 14.55
So (W0)B = 4.2eV
So (W0)A = 2.25 eV
(K.E.)A = 2eV
(K.E)B = 0.5eV
136, New Civic Centre, Bhilai, Ph. No. 0788 - 4901500 / 9039014505
Website: kcseducate.in | Email: [email protected]
7. – 4.41 × 10–17 J.
The ionisation energy of He+ is 19.6 × 10–18 J.
Energy of the first orbit of He+ (Z = 2) = 19.6 × 10–18 J.
19.6 10−18
Energy of the first orbit of Li2+ ( Z = 3 ) = 9 = 4.41 10−17 J
4
8. (A – q), (B – p), (C – s), (D – r)
9. I induced = 1026 Å , II induced = 1216 Å, III induced = 6568 Å
So, E = E3 − E1
Hence, induced radiations will be correspond to following energy transition
E3 → E1,E3 → E2 and E2 → E1
10. 2.65 × 10–11 m.
Z2
−13.6 = 4R = 4 2.2 10−18 J
n2
4 2.2 10−18 J
Z2 = = 4; Z = 2
13.6 1.6 10−19
n2
r = 0.529 10−10 m
Z
1
r = 0.529 10−10
2
= 2.645 10−11m
136, New Civic Centre, Bhilai, Ph. No. 0788 - 4901500 / 9039014505
Website: kcseducate.in | Email: [email protected]
