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 The Effect Of Temperature And Reactant Concentration On...
This experiment aimed to investigate the relationship between temperature and reactant
concentration on the rate of reaction for the hydrolysis of tert Butyl Chloride, and to determine the
validity of the proposed mechanism for the reaction. It was hypothesised that measuring the kinetics
of this unimolecular substitution reaction would demonstrate the reaction ratefor the hydrolysis of
tert Butyl Chloride utilising acetone as the solventwhich should increase with both its increased
concentration and temperature, to produce the product tert Butyl alcohol.

When the solution of tert butyl chloride in acetone is added to water in the presence of a base
and a universal indicator, its reaction to form tert butyl alcohol is indicated by dramatic color
change. Bromothymol blue is an acid base indicator which appears blue in an alkaline medium and
yellow in an acidic solution (Artxy, 2011). The solvolysis of tert butyl chloride is revealed by the
indicator change from blue to yellow as hydrogen halide is produced during the reaction (Mostafa,
2009). The solution is initially blue because of its Sodium Hydroxide (NaOH) content (alkaline), and
the colour change results as aqueous chlorine removes a proton from the transition state, while the
generated hydrogen ions neutralise the hydroxide ions of the NaOH, causing the change in the pH of
the system (Riley, 1977). This qualitatively determines that the rate of reaction is dependent on the
concentration of tert butyl chloride.
 Sub-Population Analysis Paper
growth rate of 35.8% over the fourteen year span or an average rate of 2.6% (United States Census
Bureau [U.S. Census Bureau], 2000).
Composition
The median age in 2010 was 38.5 years with an age group breakdown as follows in Figure 1 (U.S.
Census Bureau, 2010). This figure also shows that the number of people in the age range of 20 to
29 is much lower than the surrounding age ranges and this appears to be mostly due to college
attendance during these years. Since most four year degree programs are

located farther away from Hendersonville and most of them require traditional college freshmen to
live on campus for the first year, this sub population is moving away from the area for those years.
More information about education is discussed below and can be seen in Figures 4 and 5. Females
make up the majority of the population at 26,567 compared to 24,805 for males. Based upon ... Show
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These statistics reflect only those in the population who are 15 years and older. Subcategories within
management, business, science, and arts include business and financial, computers and engineering,
life and physical sciences, education and legal, community services and entertainment, and
healthcare professionals. The services profession includes healthcare support services, fire and law
enforcement services, food service and

cleaning/maintenance, and personal care services. The sales and office category includes sales
occupations and administrative services. Natural resources, construction, and maintenance includes
professions such as construction and repair, and farming, forestry, and fishing occupations. The
production, transportation, and material moving occupations are self defining in their included
professions (U.S. Census Bureau, 2013b). The educational level for the 18 to 24 year old age range
is represented in Figure 4
 Using Conditional Copula to Estimate Value Risk
Review: Using Conditional Copula to Estimate Value at Risk
ActSc 991 Project
Changwu (Allen) Chen April 14, 2014
1
1 Introduction
Value at Risk (VaR) plays a central role in risk management. By definition, VaR is the maximum
expected loss of a portfolio over a given time horizon with a certain confidence level. VaR can be
seen as a quantile on the lower tail of the distribution of portfolio returns. Although VaR is a simple
measure, it is not easily estimated.
There are several approaches for the estimation of VaR, such as historical simulations, the variance
covariance, and the Monte Carlo approaches. The first approach does not assume any underlying
distribution, whereas the last two approaches demand the joint distribution to be known, which
frequently assumed to be normal distribution. However, the deviation from normality could lead to
an inadequate VaR estimate. In this case, the portfolio could be either riskier than desired or
unnecessarily conservative.
The theory of copula is a powerful tool in modelling multivariate distributions be cause it does not
require the assumption of joint normality and it is a marginal free model. Copula have been broadly
used in the statistical literature. And due to its simplicity and convenience, one may be interested in
its application in the financial area.
In this paper I will first give a brief summary of the paper written by Helder Parra Palaro and Luiz
Koodi Hotta [1]. Then I will discuss the key results presented in the paper
 Assembling And Calibration Of A Robotic Arm Essay
Assembling And Calibration Of a Robotic Arm Asad Ashraf Malik Department of Electronics
Engineering Hamdard University, Karachi [email protected] ABSTRACT A robotic
arm assembly includes a support arm, a rotatable lower arm connected to the support arm, an
upper rotatable arm connected to the lower arm, a first driver for driving the lower arm, a first
transmission transferring power from the first driver to the lower arm, a second driver for
driving the upper arm, and a second transmission transferring power from the second driver to the
upper arm. The first and second drivers are mounted on the support arm. The second transmission
includes a belt assembly, a beveled gear assembly driven by the belt assembly, and a speed
reducer coupled to the upper arm. . I. INTRODUCTION In the past, robotic arms have been
constructed and designed for the use of either an expensive, complex or heavy duty arms for heavy
industrial use, or inexpensive, light duty arms for educational and robotic research purposes. With
respect to the industrial robot arms, closed loop control systems are typically utilized with motors
drive and shaft encoders often located at each of the joints. Unimation Corporation and Cincinnati
Milacron Corporation. The closed loop configuration, as well as the use of shaft encoders and
drives at each joint will permit an arm in which a precise control can be realized. However, due to
the added weight at every joint, the structural components should be
 The Cost Of Playing Hockey At The Elite Level
The cost of playing in hockey at the elite level is simply just too expensive for a typical middle
class Canadian family to be able to afford. Hockey Academies are private schools, which are a
luxury where you go to school and practice and perfect your skills as a hockey player at the same
time. Personal Training and Hockey Schools are tools that could be used to become a better
hockey player by getting stronger, faster and more practice time during the off season. The raise
in prices for ice time, leagues and Equipment has crippled families earnings every season. The
middle class family simply cannot afford these luxuries to help their kids become better hockey
players. The middle class families are looking for other ways of getting money to support their
child throughout sport. These factors are making hockey less competitive at the younger ages as
there is an income discrimination within the sport of hockey, the numbers of participants are
lower, less players are keeping with the sport, and kids are joining other cheaper sports. Well,
Violence is the reason why the are moving away from the sport. Violence is an issue, but there
was more violence in the sport in the earlier days. We still have the best hockey team nationally in
the world and the best players in the National Hockey League, so why worry? Canadian Families
are still going into debt as they are chasing their kid s dream of joining the 0.1% of Canadian
hockey players that make the NHL. Simply, playing hockey
 On Nuclear Disarmament Rhetorical Analysis
The world is a dangerous place to be but is also the only way to live. With the nuclear bombs
being made since 1863 the world is a bomb zone. Does this world feel safe with all the bombs in
the world at a fingertip of one person per country? Every bomb is controlled by their own button.
In Carl Sagan s speech about On Nuclear Disarmament he explains how the world has not been
safer since the first nuclear bomb has been used in 1863. In On Nuclear Disarmament Carl Sagan
expresses that the nuclear bombs have advanced more dramatically since 1863 and will continue to
advance to kill more with one nuke. It is hard to realize that the nuclears in one country is controlled
by the government with one push of a button away. Carl explains to
 Chem 1211K Lab Report Essay
Chemistry 1211K Lab Report
Briana Limage
Drawer #D20
Tuesday December 2, 2014
Lab Day and Time: Tuesday 2 5
Unknown # 4224034 DF14

Introduction
The purpose of this semester long experiment was to determine an unknown organic acid. An
organic acid is an organic compound with acidic properties. A base reacts with acids to form salts.
Titrations are used to determine the concentration of unknown substances. The purpose of the KHP
experiment was to determine the molarity of NaOH. HCl titrations are mainly to check technique
and used to verify the molarity of NaOH solution. The hypothesis is that this acid is C4H3OCOOH.
Experimental
Procedure for melting point:
The identification of the melting point of the organic acid was ... Show more content on
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pH was recorded every time 1.00 mL of NaOH was added to beaker. When the amount of NaOH
added to the beaker was about 5.00 mL away from the expected end point, NaOH was added very
slowly. Approximately 0.20 mL of NaOH was added until the pH made a jump. The pH was
recorded until it reached ~12. This was repeated two more times. The pKa of each trial are
determined using the graphs made on excel.
Results and Discussion
Melting Point:

Starting (°C)
Final (°C)
Rough Melting Point
139
159
Melting Point
131
133
Standard Melting Point
138
140

No correction had to be made to the melting points because the standard melted in the range labeled
on the bottle. The melted point observed is the correct melting point.
KHP:

Table 1
Trial
Mass KHP (g)
Mol KHP / mol NaOH
Initial Volume (mL)
Final Volume (mL)
Total Volume (mL)
1
0.3113
0.001524
5.62
22.70
17.08
2
0.3017
0.001477
9.98
26.40
16.42
3
0.3178
0.001556
14.39
31.85
17.46
Table 2
Trial
Mol NaOH (mol)
Corrected Vol. (L)
Molarity NaOH (M)
Average Molarity (M)
Molarity Deviation (M)
Average Deviation (M)
1
0.001524
0.01708
0.08923
0.08943
0.0002
0.0003
2
0.001477
0.01642
0.08995
0.08943
0.00052
0.0003
3
0.001556
0.01746
0.08912
0.08943
0.00031
0.0003

Percent deviation= (Average deviation/average molarity) X 100

Percent deviation= (0.0003/0.08943) X 100 = 0.38%
Calculations for the molarity of NaOH were:

The results showed the molarity of the NaOH solution. This experiment was completed twice and a
new average molarity
 Women s Conditions In The Victorian Age
For many years, women have been considered inferior to men and, as a consequence, they have been
subservient to men and to their own families. For instance, they had to be chaste, obedient,
sympathetic, powerless, they could not go out when they wanted or dressed as they liked, but they
were expected to stay at home and dedicated themselves to the education of children and to the
domestic cleaning.

In the history of the United Kingdom, an important period that contributed to the subsequent
independence of women was the Victorian Age. During this era, we can identify three types of
women:
Women who belonged to the nobility class; they were educated and they had the opportunity to
enjoy a luxurious life.
Middle class women; one of their main goals was to marry a noble man in order ... Show more
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The history of the main character, Jane, can be seen as a symbolical pilgrimage towards maturity
and fulfillment (Newman 1996:475) which began in Gateshead where she lived with her evil,
wealthy aunt Mrs. Reed who sent Jane to Lowood Institution, a school for poor and orphaned
girls. Time passed and after eight years, Jane left Lowood and found a job as a governess at
Thornfield Hall where she fell in love with the master of the house, Edward Rochester, who
proposed to her; however, the day of the marriage Jane found out that Mr. Rochester was already
married to Bertha, who was mad and locked up in the attic of Thornfield. After that
disillusionment, Jane s trip continued to Moor House, where she was said that her dead uncle left
her a great inheritance, and she also decided to give a second opportunity to Mr. Rochester after
hearing his voice in the wind. The history ended in Ferndean with the marriage between Jane and
Mr. Rochester, who after losing his eyesight in a fire, progressively recovered it just in time to see
their firstborn
 The Dual Party Bill
Criminal Justice reform has dramatically increased lately, and has become a current issue amongst
all states and more than enough voters mandating a response from Congress.
On October 1st, 2015, Charles Grassley whom is from Iowa and is the Republican Senate Judiciary
Committee Chairman led the proposal Sentencing Reform and Corrections Act of 2015. The dual
party bill was also supported and sponsored by Richard Durbin (Democrat from Illinois), Cory
Booker (Democrat from New Jersey), Patrick Leahy (Democrat from Vermont), Mike Lee
(Republican from Utah), Sheldon Whitehouse (Democrat from Rhode Island), John Cornyn
(Republican from Texas), Lindsey Graham (Republican from South Carolina), and Chuck Schumer
(Democrat from New York). The purpose of the dual party bill is to diminish the amount of federal
mandated conditions that are in relation to drug and gun sentencing provisions. This also includes
arranging to make the new provisions subsequent; raise the release exemption to the drug mandated
sentence minimums; due to the Fair Sentencing Act of 2010 to develop to be subsequently
operational, and reward incarcerated prisoners the capability to save credits for the time they have
served already when attending rehabilitation programs.
The bill was endorsed by a divided vote of the Judiciary Committee on an election poll of 15 to 5 on
October 22, 2015. For the bill to become an active law, there were a number of things that they
would need to undergo for it to be. The
 Clean Water Act Protects Water
A Priceless Natural Resource Clean Water Water is necessary to sustain life. Water not only
sustains life, but it is the very foundation for life. Where does the water we drink come from? Our
water comes from many different sources such as groundwater, lakes, rivers, reservoirs, aquifers,
springs and streams. In order for this water to sustain our life, it must be clean. Water is needed to
meet the demands of people in their everyday life. This includes the need for water in homes,
agriculture, industry, medicine and recreation. For health and prosperity people must have
access to clean, safe water. Water is regulated at the federal, state and local level. The Clean Water
Act protects water at the federal level. The Environmental Protection Agency regulates the
standards for contaminants in water. In order for our water to be clean, we must protect our
water sources from pollution and contaminants. This is why we need to care for the water that we
have. Humans need water in order to survive. Our bodies are about 60 percent water, the brain is
about 70 percent water, and the lungs are made of 90 percent water. Water is more important for
you to survive than food is. When you become dehydrated, it reduces the amount of blood flow in
your body, and causes your heart to work harder, and pump the blood faster. If you go long enough
without water you ll eventually enter into coma and die. You can also drink too much water. When
you drink too much water you can