Algorithm For Solving Thermochemistry Problems
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ScribdTranslationsAlgorithm For Solving Thermochemistry Problems
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ScribdTranslationsHOW TO SOLVE THIS TYPE OF PROBLEMS?
1.
Q = 3116.6 kJ is the heat released in this reaction. Using the "simple rule of three," we deduce:
M C2H6= 2 * AC+6*AH= 2*12+6*1= 30 units
2* 30 g C2H6................. releases 3115.6 KJ
60 g C2H6..............................x
X= 3115.6 KJ
2. What we need to know:From physics (the chapter on thermodynamics) it is known that the heat released during the burning of a
substanceQ = m * csubstance* T received = Q yielded
because for example,i=200C shitf=800C thenTi=200C + 273 = 293K and Tf=800C + 273 = 353K
T = 353K - 293K = 60 t = 800C - 200C= 60 T = t
............................................................................................................................
Solution: Q=m*cwater* T
3115.6 KJ = 10 Kg * 4.18 KJ/Kg*K * t t = 3115.6 KJ t =3115,6 K = 74,53
10 Kg * 4.18 kJ/Kg*K 41.8
3.
This similar problem solved in class
4.Solution:
The heat of combustion is the thermal effect associated with the complete combustion reaction of one mole of
substance at a pressure of 1 atm and given temperature. The heat of combustion is tabulated and expressed in
kcal/mol.
5.Based on the values of ΔfThe0 stability of substances under standard conditions can be assessed.
calculate other thermodynamic quantities and write thermochemical equations.
0
As much as ΔfThe smaller H is, the more stable the chemical species is.
Solution:
With and
- 393.5 kJ/mol -285.8 kJ/mol CO2this is more stable H2O CO2
IMPORTANT:
A chemical reaction is written in the form:
C2H6(g)+ 7/2 O2(g) 4 CO2(g)+ 6H2O(l) + 3116.6 KJ
sauce
C2H6(g)+ 7/2 O2(g) 4 CO2(g)+ 6H2O(l) r H = - 3116, KJ
So, we conclude that the reaction enthalpy is equal, but of opposite sign to the amount of heat.
what accompanies a thermochemical reaction.
Q=- H
r
1. the reaction is exothermic A+B C+ D + Q
Q 0
rH 0
1. a reaction is endothermic A+B + Q C+ D
Q 0
rH 0