The gases of a mixture exit at a flow of 10. , and⁄ at 285ºC.
composition in percent by volume of the gases is: 75% 5% 8%
air 12%; said mixture passes through an absorber of Where 97% mol is absorbed
of .
Bachelor of Arts10m310000 L
10m 3 kg
h
, 7cm 2
, T =285ºC <> 558 ºK
CO2 n2 (75%)=7500L
CO n2(5%)=500 L
SO2 n3(8%)=800 L
AIR n4(12%) = 1200 L
PV = RTN
1x10000 = 0.082x558 n
ntotal =218.55
97%CO2 158,983 mol
Vp x( =) fm x (.Vtotal
)
fm CO
( 20.75)
fm CO
( 0.05
)
fm SO
( 2=)0.08
from( Air 0.12
)
nx
fmn
total
n CO
( 2=)163,9
( =) 10.9275
in CO
( 2= )17,484
in SO
( =)26,226
in Aire
masa
nx= maamolehither
m CO ( 2=)7211.6g
m CO ( =) 305,97g
I am(SO2=) 1118.976g
in the( air = )1573.56g
Determine:
a) The amount ofCO2that is absorbed in gram 97%CO2
97%(163,9) 158,983 mol
b) The composition of the mixture at the output of the absorber in percent
weight.
m (CO2=) 7211.6g 70.63%
Substance n m=(%weight* PM n= (m/PM) Xi= n/nt PM
100) mt average=xi *
PM
m (CO= ) 305.97g 3%
m ( SO2=) 1118.976g 10.96%
( air=) 1573.56g 15.41%
in the
10210,106g 100%
c) The average molecular weight at the outlet of the absorber.
Pmolesee yoular = PMCO2+ PMCO + PMSO2 +PMAir
Pmolecular = 196mol -g
A coke oven produces 1,000,000 ft3/h of a gas that has the following composition
in percent by volume: C6H6 8%, C3H8 5%, CH4 40%, CO 7%, H2 35% and the rest is CO2.
The gas comes out of the furnace at 20 lb/in2 and 740 ºF. After cooling to 100ºF, the benzene and the
toluene is eliminated by 85% by weight through absorption.
1,000,000 ft³/h = 28,816,000 l
20 lb / in2 = 13.62 atm
T= 740 ºF = 666,4812 ºK
Determine:
The average molecular weight of the mixture at the outlet of the furnace and the absorber.
C6H6 8 8 78 0.103 0.005 0.39
C3H8 5 5 44 0.114 0.006 0.264
CH4 40 40 16 2.5 0.121 1,936
CO 7 7 28 0.25 0.012 0.336
H2 35 35 2 17.5 0.85 1.7
CO2 5 5 44 0.114 0.006 0.264
TOTAL 100 100 20,581 1 4.89
B) The mass of the gas at the outlet of the furnace
Substance n m=(%weight* PM n= (m/PM) Remove 85% of
100) mt benzene and toluene
C6H6 8 8 78 0.103
0.031
C3H8 5 5 44 0.114
CH4 40 40 16 2.5 2.5
CO 7 7 28 0.25 0.25
H2 35 35 2 17.5 17.5
CO2 5 5 44 0.114 0.114
TOTAL 100 100 20,581 20,395
C) The composition at the outlet of the absorption tower in weight percent
Substance m=(%weight* PM n= (m/PM) Xi= n/nt % mol
100) mt
C6H6 8 8 78 0.103 0.005 0.5%
C3H8 5 5 44 0.114 0.006 0.6%
CH4 40 40 16 2.5 0.121 12.1%
CO 7 7 28 0.25 0.012 1.2%
H2 35 35 2 17.5 0.85 85%
CO2 5 5 44 0.114 0.006 0.6%
TOTAL 100 100 20,581 1 100%
d) The mass of separated benzene and toluene in lb
n = 0.184 mol
m = PM * n = 122 * 0.184 = 22.45 g * 1 kg / 1000 g * 2.205 lb / 1 kg = 0.05 lb
28. A mixture that contains 20% mol of CO, 30% mol of CO2, 40% mol of N2, and 10% mol of
O2 is at 600°R and 30 lb/in2 in a 1 ft3 container; it is passed through a
tank where 85% of CO2 is eliminated, with the mixture exiting at 1 atm and 25°C.
Determine:
a) What is the average molecular weight of the mixture at the beginning and at the end of the
process?
Average molecular weight at the beginning:
Pressure: 30 lb/in2x 0.068046 = 2.04138 atm
Volume: 1 ft3x 28, 317 = 28, 32 L
600 °R x 5/9 = 333.33 °K
2438 atm x2832
= = = 21151 mol
0.082 .⁄ 333, 33°
.
Substance % mol X PM PM n = 2, 1151 m = (n x PM)
(average)
(g)
CO 20 0, 20 28 5.6 0.423 02 11.84456
CO2 30 0, 30 44 13.2 0.634 53 27.91932
N2 40 0, 40 28 11.2 0.846 04 23,68912
O2 10 0, 10 32 3.2 0.211 51 6.76832
TOTAL 100 1 33.2 70, 22132
The average molecular weight at the beginning is 33.2 g/mol
Average molecular weight at the end:
85% of CO is eliminated.2
• 27.91932 - (0.85 x 27.91932) = 4.187898; 4.187898 g of CO will remain2
Substance m (g) PM n = m / PM X=n/nt PM (average)
CO 11.84456 28 0.42302 0.27 7.56
CO2 4,187898 44 0.0951795 0.06 2.64
N2 23,68912 28 0.84604 0.54 15,12
O2 6.76832 32 0.21151 0.13 4.16
TOTAL 46.489898 1,5757495 1 29.48
b) What is the partial pressure of each component at the outlet?
Substance X Pressure
P = 1 atm
CO 0.27 0.27 atm
CO2 0.06 0.06 atm
N2 0.54 0.54 atm
O2 0.13 0.13 atm
TOTAL 1 1 atm
c) The density of the mixture at the inlet and outlet of the absorber.
Density at the entrance:
Pressure: 30 lb/in2x 0.068046 = 2.04138 atm
Volume: 1 ft3x 28, 317 = 28, 32 L
600 °R x 5/9 = 333.33 °K
n = P VR T = 2.01438 atm x 28.32 l0.082 atm.lmol.K x 333.33 °K = 2.1151
mol
Substance % mol X PM n = 2, 1151 m = (n x PM)
(g)
CO 20 0, 20 28 0.423 02 11.84456
CO2 30 0, 30 44 0.634 53 27.91932
N2 40 0, 40 28 0.846 04 23,68912
O2 10 0, 10 32 0.211 51 6.76832
TOTAL 100 1 70, 22132
ρ=m/V
ρ=70.22 g/28.32 L= 2.48 g/L
The density at the entrance is 2.48 g/L
Density at the outlet:
Substance m (g) PM n equals m divided
X = by
n / PM
nt PM (average)
CO 11,84456 28 0.42302 0.27 7.56
CO2 4.187898 44 0.0951795 0.06 2.64
N2 23,68912 28 0.84604 0.54 15,12
O2 6.76832 32 0.21151 0.13 4.16
TOTAL 46.489898 1.5757495 1 29.48
Leaving the mixture at 1 atm and 25°C.
V = R x T x n P = 0.082 LatmK mol x 298 K x 1.5757495 mol 1 atm = 38.51 L
density = mass / volume
ρ=46.49 g/38.51 L= 1.21 g/L
The density at the outlet is 1.21 g/L