25072025 Revision Assignment Foundation Batch
ORGANIC CHEMISTRY
(Topic : ISOMERISM)
(for JEE-Mains & Advanced 2027)
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01. Which of the following compounds will show geometrical isomerism :
(a) Cholorocylopropane (b) 1, 1, 2 –Trichlorocycloprapane
(c) Hexachlorocyclopropane (d) 1,2-Dichlorocyclopropane
02. Geometrical isomerism is possible in :
(a) (b) (c) (d)
03. Which of the following can show geometrical isomerism :
(a) (b) (c) (d)
04. and are :
(a) Enantiomers (b) Geometrical isomers (c) conformers (d) Homologs
05. Which will not show geometrical isomerism :
(a) (b) (c) (d)
06. Which of the following compounds will exhibit geometrical isomerism :
(a) 1-Phenyl-2-butene (b) 3-Phenyl-1-butene
(c) 2-Phenyl-1-butene (d) 1, 1-Diphenyl-1-propene
07. Which of the following is correct :
[a] A meso isomer contains at least two chiral carbon and can rotate the plane of
plane polarized light (PPL).
[b] A racemic mixture is equimolar mixture of diastereomers and the mixture can
not rotate the plane of PPL.
[c] A meso isomer cannot rotate the plane of PPL due to absence of chiral centres.
[d] A meso isomer is achiral due to plane of symmetry or centre of symmetry or both.
page no # 1
08. Which of the following will not show geometrical isomerism :
(a) (b) (c) (d)
09. Write correct relation between following molecules :
CH2COOH
(A) (B)
CH2COOH
(a) Position isomers (b) Chain isomers
(c) Homologus (d) Geometrical isomers
10. Consider the following four statements
S1 : Geometrical isomers are not mirror image isomer.
S2 : A compound having double bond (restricted bond) always show geometrical
isomerism.
S3 : Acyclic compound having single bond does not show geometrical isomerism.
S4 : Cyclodecene can exist in cis & trans form.
(a) T F F T (b) T T F T (c) F F F T (d) T F T T
11. Which of the following is Incorrect :
Me Me
H OH H F H OH
H OH
(a) HO H is chiral (b) C=C is NOTchiral (c) HO H
is chiral
Cl Br
Me Et
(d) Me (CHOH)7 Me contains only real chiral carbons but not psuedo chiral carbon
12. Which of the following is optically active :
(a) (b) (c) (d)
13. Which of the following compound posses plane of symmetry ?
(a) (b) (c) (d)
Me
Me
14. H Incorrect statement about this compound is :
H
(a) it shows geometrical isomerism (b) it posses centre of symmetry
(c) it posses plane of symmetry (d) it shows optical isomerism
15. Cis-trans isomerism is shown by :
(a) (b) (c) (d)
page no # 2
16. Examine the relation between the following pairs of compounds :
Cl
Cl HO OH
Cl
(I) and (II) OH and
Cl OH
COOH
COOH
(III) and
HOOC COOH
(a) All I, II, III are identical (b) All I, II, III are isomers
(c) I, II are identical, III is isomer (d) I is identical and II, III are isomer
17. Column – I Column – II
F Br
(A) (P) Cis
CH3O F
F Br
(B) (Q) Trans
F OCH3
H
(C) (R) E
OCH 3
OCH3
(D) (S) Z
OCH3
(a) (A P,R), (B R,S), (C Q,S), (D P,S)
(b) (A Q,S), (B R,S), (C P,R), (D P,S)
(c) (A Q,S), (B P,R), (C P,R), (D P,S)
(d) (A P,S), (B P,R), (C Q,S), (D P,Q)
18. The no. of optically active isomers of
and are :
Cl Br Cl Cl
(a) 4, 3 (b) 2, 2 (c) 2, 0 (d) 4, 2
19. Which of the following have same configuration :
(I) (II) (III)
(a) I & II (b) II & III (c) I & III (d) all
20. In the following structure, the double bonds are marked as I II, III and IV
Geometrical isomerism is not possible at site (s) :
(a) I (b) III (c) I and III (d) I and IV
page no # 3
Integer Type #
21. Chiral centres present in the given structure (Tetracycline) will be :
22. Calculate the number of chiral centre in the molecule Ethyl 2,2-dibromo-4-ethyl-6-
methoxy cyclohexane carboxylate.
23. The number of isomers for the compound with molecular formula C2BrClFI is.
24. How many structural isomers of C5H10 will show geometrical isomerism .
25. Number of the following compounds which can show geometrical isomerism is:
(i) (ii) (iii) (iv)
(v) (vi) (vii)
26. How many geometrical isomers are possible for the given compound ?
Ph – CH = CH – CH = CH – COOH
27. How many geometrical isomers of CH3 CH = CH – CH = NOH exist ?
28. Find out the total number of stereocentres in the given compound.
29. How many different planes of symmetry are present in the following compound.
Cl
Cl Cl
Cl Cl
Cl
30. Minimum MW of a (CxHy) containing minimum number of C-atom to show optical isomerism
31. Number of meso isomer of the given compound is.
Br Br
C
C
Br Br
page no # 4
