examtimepdfs.blogspot.

com

FIITJEE MOCK TEST-9

IIT – JEE, 2019
Paper Code
PAPER-II 100401.1
ANSWERS
Physics [PART-I]
1. C 2. C 3. B 4. B
5. D 6. A 7. D 8. B
9. A 10. A 11. B 12. C
1. A  (s) B  (r) C  (q) D  (p)
2. A  (r) B  (p, q) C  (r, s) D  (q, r, s)
1. 3 2. 2 3. 2 4. 1
5. 3
Chemistry [PART-II]
1. C 2. A 3. C 4. B
5. B 6. D 7. C 8. C
9. B 10. A 11. D 12. B
1. A → (p, q, s) B → (p, q, r, s) C → (q, t) D → (p, q, s)
2. A → (p, q, s) B → (r, s, t) C → (p, q, r, s) D → (q, r, s, t)
1. 7 2. 1 3. 1 4. 2
5. 7
Mathematics [PART-III]
1. A 2. B 3. A 4. A
5. D 6. B 7. C 8. A
9. B 10. B 11. A 12. A
1. A  (q) B  (r) C  (t) D  (p)
2. A  (t) B  (t) C  (q) D  (p)
1. 2 2. 6 3. 1 4. 2
5. 0

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Mock Test-9–Paper-2 (100401.1)-PCM-IITJEE-2

Physics PART – I

SECTION – A
1. In endoergic reactions,
Total rest mass energy of the products is greater than total rest mass energy of the reactants
To compensate for this difference, energy is needed to be supplied to make the reaction happen.
By definition,
KE(Y) + KE(Z)  KE(n) = Q, since
KE(x) = 0
As Q < 0, we can write: Q = |Q|
Substituting, we finally get:
KE(n) = KE(y) + KE(z) + |Q|
Y and Z cannot both be at rest, as momentum is conserved
Hence, KE(n) > |Q|

2. Initial pressure at the bottom = g  2H + 2   g  H = 4 gH.

Final density of the homogenous mixture:
  A  2H  2  2A  H 3
  
A  2H  2A  H 2
3 9
Final pressure    g  3H  gH.
2 2

V 2 4  104
3. Heat lost per second in the circuit =  = 80 J
R eq 500
Ratio of heat produced in bulbs = I12R1 : I22R 2
4I2R
 =4:1
I2R
V12 / R1 R
Ratio of heat produced in branch AB to CD = 2
= 2 =2:1
V2 / R 2 R1
V
Current drawn from the cell = = 0.4 A.
Re q

1 1 1
4.   ...(i)
f f2 f2
1 1  1 1   1 1  1 2
Now,    ' v  ' r       2v  2r   2  1  = 
fv fR R
 1 R 2 
R
 1 R 2  f1 f2
This must be zero for achromatic combination
 
i.e., 1  2 = 0 ...(ii)
f1 f2
Solving (i) and (ii)
  
f1  1  1  f
 2 
  
f2   1  2  f
 1 

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Mock Test-9–Paper-2 (100401.1)-PCM-IITJEE-3

5. At any time t, the distance travelled by the ant along the rod is ut. The angle made by the rod at time t
with the x axis is t.
Thus.

r  ut[cos t ˆi  sin tj]
ˆ

 dr
 v  u[cos t ˆi  sin tj]
ˆ  ut[  sin t ˆi   cos tj]
ˆ
dt
= u[(cos t  t sin t)iˆ  (sin t  t cos t)j] ˆ

 v  u cos2 t  2 t 2 sin 2 t  sin2 t  2 t 2 cos 2 t
Now tangential acceleration:

dv 2 tu
at   .
dt 1  2 t 2

mv 2 mv 2
6. N fmax  N 
R R
f v 2 dv v 2
 Retardation a  max   
m R dt R
v t
dv   v t 
  2
 dt v  v 0 1  0 
v R  R 
v0 0

2GM mc 2R s GMm
7. Rs    F
c2 2r 2 r2

2a3 / 2 42 a3
8. By Kepler’s law: T   mx 
Gm x GT 2
D D
Now a  and T = , Substituting we get
2 v
Dv 2
mx   4.25  1037 kg.
2G

2GM 2  6.67  1011  4.3  1037

9. Rs    6.4  1010
c2 (3  108 )2

10. JR=I
JR
 I

1Ns  2  10 2 m 10 2
=  kgm2
2 rad / s 

M(a2  b2 )
11. I
12
12I 102 1 1200 48
 M 2 = 12     kg.
a b 2
 25  10 4 25 

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Mock Test-9–Paper-2 (100401.1)-PCM-IITJEE-4

2
12. JR = I = I 
T
2I
 T
JR
Now I becomes 32 times and JR becomes twice: T becomes 16 times.

SECTION - B
2. The problem is based on Moseley’s law. K photon of any element is more energetic than K photon.

SECTION –C

1. As shown in the figure, let the centre of the ring coincide with the Y
origin and the ring lies in x-y plane. Now z axis is the normal to the
plane, thus the axis about which we have to find moment of inertia R d

makes an angle  = 45 with the Z axis and lies in the z-x plane.
X
Consider an element of the ring at an angular position  and angular 
thickness d. The position vector of this element is

r  R(cos ˆi  sin ˆj) axis
Z
unit vector along the axis of rotation is
â  (cos kˆ  sin ˆi)
Now, perpendicular distance of the element from the axis,

p  r  aˆ
ˆi ˆj kˆ
  ˆ
p  r  aˆ  R cos  sin  0 = [i(sin  cos )  ˆj(cos  cos )  k(sin
ˆ  sin )]  R
sin  0 cos 
 p2  R 2 (sin2  cos 2   cos 2  cos 2   sin 2  sin2 ) = R 2 (cos2   sin2  sin2 )
Now moment of Inertia I =  (dm)p 2
MR2 2
  (cos2   sin2  sin2 )d
2 0

2
MR2  2 1 2 1 2 

2 cos   2 sin   4 sin  sin 2 
 0
MR2 MR2
 [2 cos2    sin2 ]  [2 cos2   sin2 ]
2 2
MR2
 [1  cos 2 ]
2
Putting M = 4 kg, R = 1 m,  = 45,
4  1  1
  1    3 kg m2
2  2

examtimepdfs.blogspot.com
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Mock Test-9–Paper-2 (100401.1)-PCM-IITJEE-5

2. Consider a situation when the bob A has fallen through an angle .

Loss in PE = Gain in KE 
1 2
 I = mg sin  
2
2mg sin  2mg sin 
 A = 
I m 2
2gsin   /2 d
A =

; tA =  0 A (
In the similar position, for B
4gsin  /2 d
B =

; tA =
0 B (
A tB 1
  
B t A 2
tA
  2
tB

d dB
3. Induced EMF in the loop ABD or BDC  A
dt dt A 
1 5 cm
  8  6  10 4  0.263  12  0.263  104
4 6 cm D
I1
Say the resistance per cm of wire is R. 5 cm
Now applying KVL to loops ADB and BDC. I2
  B C
5I1  5(I1  I2 )  6I1  or 16I1  5I2   8 cm
R R
 
Similarly 13I2  5(I1  I2 ) or 18I2  5I1 
R R
23  21 
Solving this we get, i1  , i2 
263 R 263 R
2 
 i1  i2 
263 R
= 10 mA

3 3
H  cosi  9  1 
4. Happ        1m
  cosr  3  3

5. For equilibrium, the system must be in a local minima of potential energy. This is possible only if the
centre of mass of the system lies below O i.e. the centre of the hemisphere. In the critical case, the
centre of mass of the system can coincide with O.
Now taking O as the origin, say H is the maximum principle height of the cone then:
 3R  2 3  H  1 2
  8   3 R   4   3 R H = 0
   
R2 H2
   0 or H  3R
4 12

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Mock Test-9–Paper-2 (100401.1)-PCM-IITJEE-6

Chemistry PART – II

SECTION – A
1. C
Ferrocynide test:
2ZnSO 4  K 4 Fe  CN6   Zn2 Fe  CN6   2K 2SO 4
 White ppt.

Zn2 Fe  CN 6   K 4 Fe  CN 6   2Zn3K 2 Fe CN  6 

2
More solub le 

2. A
H
+
O O O


C COOH   H3C

H
H3C  C C O H  H3C C O H  CO2  H
 Z
 X

O H


C H 
 H3C
H
H3C C O H
Y
CO2 can’t oxidized by oxidizing agent like K2Cr2O7 or KMnO4.

3. C
Compound (IV) is anti aromation and compound I, II and III are aromatic using Huckel rule.

4. B
O O

CH2 NH2
NH2 NH2
NH LiAlH4
O  1 mol

NH
CH2 NH2
 X O Y  Z
O
O

O
Lactons are cyclic ester i.e.

5. B
Hydrolysis of NF3 is not possible at room temperature and this reaction required at least 200oC, as
vacant orbital is not present in this case.

6. D
(I) Compound AlF3 AlCl3 AlBr3 Al2O3
Lattice energy kilo joule 5215 5492 5361 5916
per mole
(II) Charge density and size of cation and anion.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Mock Test-9–Paper-2 (100401.1)-PCM-IITJEE-7

(III) Hg+2, Cd+2 having pseudo inert configuration.

7. C

8. C

9. B
Solution for Q. No. 7 to 9.
A  FeO.Cr2O3 or FeCr2O4 B  Fe2O3
C  Na2CrO4 D  Fe4[Fe(CN)6]3
E  Na2Cr2O7 F  K2Cr2O7
G  K3[Cr(C2O4)3] H  Fe2(C2O4)3
I  FeC2O4 J  CO2
K  FeO L  CO
M  Fe N  Fe3O4
CO obtained on heating oxlate prevents aerial oxidation of FeO to Fe2O3.
Light
Fe2  C2O 4 3   2Fe  C2O 4   CO 2 used in blue print.
Fe(III) salt containing certain anion having reducing properties like oxlate and citrate are reduced to Fe(II)
salts when exposed to light this fact is made used to making blue prints.

10. A
pKa1  pKa2 2.34  9.60
pI glycine    5.97
2 2
pKa1  pKa2 2.19  4.25
pI glutamic acid    3.22
2 2

11. D
None of these as (7.4) is in pH drop region in both the case.

12. B
(A) Sanger’s reagent (DNFB) 1-fluoro- 2,4-dinitro benzene undergoes nucleophilic aromatic
substitution with N-terminal amino acids.
(B) At (pH = 3) glutamic acid shall be almost in the Zwitter ion form while glycine shall be in cationic
form. Hence resin must have negative charge.
Since amino acids exist in solution as charged molecules they can be separated in a column
containing suitable resin.
(C) From graph it can be clearly analysed in these region, pH is almost constant.
(D) Glutamic acid as pH = 3 is near its (PI)

SECTION – B
1. A → (p, q, s) B → (p, q, r, s) C → (q, t) D → (p, q, s)
O
COOH HO
 CH3  O
   2H2O
OH HOOC O
(A)

O
Three lactones are formed d    ,     and d   

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Mock Test-9–Paper-2 (100401.1)-PCM-IITJEE-8

O O

CH3 CH3

(B)   CO2 
COOH

Two compounds are formed d    and    

OH

(C) 
COOH  COOH  H O
 2

Two compound cis and trans

O
COOH


O
(D) H3C COOH   H2 O

O
Two compounds are formed d    and    
COOH
Compound give NaHCO3 test as well as bromine water.

2. A → (p, q, s) B → (r, s, t) C → (p, q, r, s) D → (q, r, s, t)

(A)  N2H4  IO3  2HCl   ICl  3H2 O  N2 
ICl is red brown in liquid state and black in solid state.
2AgNO3  
 2Ag  s   2NO2  O2
(B) 
Brown colour
NH4 2 Cr2O7 

 Cr2 O3  4H2 O  N2
(C) 
Green residue
 300o C
2FeSO4 .7H2 O 
 Fe2O3  SO2  SO3  7H2 O
(D) 
Re d colour

SECTION – C
1. 7
(i) IF7 - sp 3 dx2  y2 dz2 dxy, - pentagonal bipyramidal or decahedral
(ii) Fe  CO 5  dz2 sp3 - trigonal bipyramidal
(iii) Zeise’s salt - dx2  y2 sp2 K PtCl3  C2H4  

(iv) Wilkinson’s catalyst - dx2  y2 sp2 PPh3 3 RhCl

(v) K 3 Ni  CN5  dx2  y2 sp3 - square pyramidal

(vi) K 2 PtCl4   d x2  y2 sp 2

(vii) NiBr2 PMe3 2  dx2  y2 sp2

(viii) Brown ring complex – Na2[Fe(CN)5NO] – sp 3 dx2  y2 dz2

2. 1


H2S  
 2H  S


FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Mock Test-9–Paper-2 (100401.1)-PCM-IITJEE-9

K a1  K a2 H2S  1022  0.1

S 2   2
 2
H  H 
pS = 23 – 2(pH)
[Zn+2] [S2] = 10–23
1023
S2    10 21
0.01
pS = 21
23  21
pH 
2
pH = 1
In fact if we want to precipitate (ZnS) quantitatively the pH must be raised even higher pH (4 to 5).

3. 1
Let x be the weight (in mg) of iodine which remains in the aqueous phase.
 x
I2 aq.   M
254  20
10  x 
I2 CCl4   M
254  2.25
I2 CCl4 10  x   20
Kd  
I2 aq.  x   2.25
80 
10  x   20
 x 2.25
x = 1.0 mg.

4. 2
a a
y ,x where ‘a’ is edge length.
2 2
a
2 2 2  2 2
a
 
2
2

5. 7
x
are 14 
No. of position isomers for
y
 x  7   14
x=7

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Mock Test-9–Paper-2 (100401.1)-PCM-IITJEE-10

Mathematics PART – III

SECTION – A

dI  2 3 
1.      sin   2cos  
d  3 243 
2 2
2. x + y – 6x – 4y + 9 = 0
2  3m  20  R (3, 4)
y = mx, 2  , 4
 12 
1  m2
4 + 9m2 – 12m = 4 + 4m2 C
m = 0 or 5m = 12  m = 12/5 (3, 2)
12
y x and y = 4 are tangents
5 O
 5
Equation of circle is  x  0   x     y  0  y  4   0
 3

3. The plane parallel to 2x + 3y + z = 1 and through (1, 0, 1) is 2(x – 1) + 3(y – 0) + (z – 1) = 0

Any plane through line of intersection (x + y + z – 3) + (2x + y – z – 5) = 0 as it is passing through (1,
0, 1)
1
So, (1 + 0 + 1 – 3) + (2  1 + 0 – 1 – 5) = 0    
4
1
 x  y  z  3    2x  y  z  5   0
4
2x + 3y + 5z – 7 = 0
So, required line is 2x + 3y + z – 3 = 0, 2x + 3y + 5z – 7 = 0

t1  t 2  t 3 acos A  bcosB  c cosC

4.  1
abc abc

5. Let amount of salt present in tank is ‘m’ gm

dm  m 
 10   4
dt  100  t 
dm 4
 m  10
dt 100  t
 5
100  t 4 m  10 100  t  c
5
m(100 + t)4 = 2(100 + t)5 + c
at t = 0, m0 = 50 gm
50  1004 = 2(100)5 + c
c = –150  1004
150  1004
mt = 2(100 + t) –
100  t 4
150  100
m100 = 400 –
16  100

n   2    n  1  
6. S C1  n  1 sin    nC2 n  2  sin    .....  nCn 1  sin  
n  n   n 
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Mock Test-9–Paper-2 (100401.1)-PCM-IITJEE-11

  2   
2S  n  n C1 sin  nC2 sin  .....  n Cn1 sin  n  1  
 n n  n 

7.–9. Length of AD is 6 units

1
cos B = and ED = 10
4

SECTION – B

1. (C) 2 sin x  sin t

 2 cos xdx  cos tdt
/2 /2
1  sin2 t 9 / 2 1 1 10

0
2
cos tdt =
2  cos
0
tdt

 3 1/ 4  1/ 3
2 
(D) lim x  1    1   
x   x  x 
 1 3  1 2 
lim x 1    .....   1    .....  
x   4 x  3 x 
 3 2  
   
  98 1
lim x   4 3    
x   x  12 12

1
2. (A) Put x   t and roots of the t 2  at  2  a  0 should be distinct real
x
1
(B) Put x   t and roots of the t 2  at  2  a  0 should be distinct real
x

1  1 t < –2
(C) x 2   ax   1  0
2
x  x
 1 
x    t
 x
(t2 – 2) + at + 1 = 0
t2 + at – 1 = 0
(1) If both roots less than –2 or
(2) If one root is less than –2
 D – {both roots > –2}
(D) (x2 + x + 2)2 – a{(x2 + 2)2 – x2} = 0
(x2 + x + 2)2 – a{(x2 – x + 2)(x2 + x + 2)} = 0
2 2
(x + x + 2){x (1 – a) + (1 + a)x + 2 – 2a} = 0
2 2
D = (1 + a)2 – 4(1 – a)(2 – 2a) > 0 = (1 + a)2 –  2 2  1  a   0
((1 + a) + 2 2 (1 – a))((1 + a) – 2 2 (1 – a)) > 0
 1  2 2    1  2 2  
  a    a   0
 1 2 2   1 2 2 
2 2 1 1 2 2
a
1 2 2 2 2 1

examtimepdfs.blogspot.com
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Mock Test-9–Paper-2 (100401.1)-PCM-IITJEE-12

SECTION – C
1. ‘7’ should be placed at 4th place
n E  6! 1
 
n  S  7! 7

2. x + 2y + 3z = 15
z=1
x + 2y = 12
10 1
  5 points
 2 5
z=2
x + 2y = 9
7 1
5 2  4 points
1 4 
z=3
4 1
 2 points
2 2
z=4
z + 2y = 3
1 1 1 point
Total number of points = 12
n
Hence is 6
2

z1  z2 1
4.  z3
2 2
 z2  z 3  3
z1      z1  z4 
 2  4

examtimepdfs.blogspot.com

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com