Spark 26 01 Mid Phase Test 4
Spark 26 01 Mid Phase Test 4
(iii) Section–B: This section contains 6 multiple choice questions which have one or more correct answer(s). Each
question carries +4 marks for correct answer and –2 marks for wrong answer. Partial +1mark is given for
darkening a bubble corresponding to each correct option, provided no incorrect option is darkened
(iv) Section–C: This section contains 2 paragraph type questions each paragraph contains 2 multiple choice
questions and only one correct answer. Each question carries +3 marks for correct answer and –1 mark
for wrong answer.
(v) Section–D: This section contains 4 questions. The answer to each question is a NON-NEGATIVE INTEGER.
Each question carries +3 marks for correct answer and there is no negative marking.
Useful Data
PHYSICS CHEMISTRY Atomic No.: H=1, He=2, Li=3, Be=4, B=5, C=6,
Acceleration due to gravity g = 10 m/s2 Gas Constant R=8.314 J K1 mol1 N=7, O=8, F=9, Na=11, Mg=12, Al=13, Si=14,
Planck constant h = 6.6 × 10–34 J-s = 0.0821 Lit atm K1 mol1 P=15, S=16, Cl=17, Ar=18, K=19, Ca=20, Cr=24,
Charge of electron e = 1.6 × 10–19C = 1.987 2 Cal K1 mol1 Mn=25, Fe=26, Co=27, Ni=28, Cu=29, Zn=30,
Mass of electron me = 9.1 × 10–31 kg Avogadro's Number Na=6.023 1023 As=33, Br=35, Ag=47, Si=21, Sn=50, Ti=22, I=53,
Permittivity of free space Planck’s Constant h=6.626 10–34 Js Xe = 54, Ba = 56, Pb=82, U=92, V = 50.
0 = 8.85 × 10–12 C2/N-m2 =6.25 x 10-27 erg.s Atomic masses: H=1, He=4, Li=7, Be=9, B=11,
Density of water water = 103 kg/m3 1 Faraday=96500 Coulomb C=12, N=14, O=16, F=19, Na=23, Mg=24, Al=27,
Atmospheric pressure Pa = 105 N/m2 1 calorie=4.2 Joule Si=28, P=31, S=32, Cl=35.5, K=39, Ca=40, Cr=52,
Gas constant R = 8.314 J K–1 mol–1 1 amu =1.66 x 10-27 kg Mn=55, Fe=56, Co=59, Ni=58.7, Cu=63.5,
1 eV =1.6 x 10-19 J Zn=65.4, As=75, Br=80, Ag=108, Sn=118.7,
I=127, Xe=131, Ba=137, Pb=207,U=238.
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PART–I: PHYSICS
SECTION–A (Single Option Correct Type) (+3, –1)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE option is correct.
1. An infinite imaginary plane divides the space containing two point
charges +q and –q into two parts as shown in the figure. The flux
of electric line of forces crossing the plane will be q / k0 . Find the
value of K.
(A) 1 (B) 2
(C) 3 (D) 4
3Q 3Q Q
(A) (B) (C) (D) Data insufficient.
8 0 4 0 4 0
4. The switch S is open for a long time and then closed. Find loss of
energy in steady state
1 1
(A) CV 2 (B) CV 2
2 4
1
(C) CV 2 (D) CV 2
6
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6. A large parallel plate capacitor has a dielectric slab of dielectric constant K
of the area of its plates, as shown in the 1
1 E1
between its plates that covers
4
figure. The total capacitance of the capacitor is C while that of the portion
with dielectric in between is C1. When the capacitor is charged, the plate 2 E2
area covered by the dielectric gets uniform surface charge density as 1,
and the rest of the area gets uniform surface charge density as 2 . Choose
the correct option, ignoring edge effects.
E C 3 K C 2K
(A) 1 4 (B) (C) 1 K (D)
E2 C1 K 2 C1 K
q
(B) Total flux through the Gaussian surface is
0
q
(C) Flux crossing through the curved surface is
0 2R2 2
2q
(D) Total flux through the Gaussian surface is
0
8. The electrostatic potential V at any point (x, y, z) in space is given by V=4x2 + 3xy + 6z
(A) The y – and z – components of the electrostatic field at any point are zero
(B) the x component at a point is given – (8x + 3y) î
(C) The x component at a point (1, 0, 2) is 8iˆ
(D) There is no potential drop along y and z axis
9. Two plates, each of one side area ‘A’ are kept at a separation ‘d’. Q1 Q2
They have charge Q1 and Q2 and uniform electric field E exist in
the region as shown. Then
Q Q2 E
(A) Charge on surface (1) is 1 A 0 E
2
Q Q2
(B) Field inside the gap is E 1
2 A 0
(C) Field outside the gap is E 1 2 3 4
d
(D) Field on either side of the plates is identical
10. In the circuit shown, each capacitor has a capacitance C. The emf of
the cell is E. If the switch S is closed
(A) positive charge will flow out of the positive terminal of the cell
(B) positive charge will enter the positive terminal of the cell
(C) The amount of charge flowing through the cell will be CE.
(D) The amount of charge flowing through the cell will be 4/3 CE.
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SECTION–C: Comprehension Type (Single Option Correct Type) (+3, –1)
This section contains 2 paragraphs, type questions. Each paragraph describes an experiment, a
situation or a problem. Two multiple choice questions will be asked based on this paragraph.
Paragraph for Question Nos. 11 to 12
Two rods of length and 2 are placed in xy plane such that their y
+q
mid-point are at origin and they are free to rotate in xy plane about –q
z-axis. Two +q charges are fixed at two ends of bigger rod and two
–q charges are fixed at two ends of smaller rods. x
11. What is electric dipole moment of system?
1 1
(A) 3q (B) 5q –q
2 2 +q
(C) q (D) Zero
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SECTION–D (Numerical Type) (+3, 0)
This section contains 4 questions. The answer to each question is a single/double numerical /
decimal type answer.
15. Two identical capacitors 1 and 2 are connected in series to a battery
as shown in figure. Capacitor 2 contains a dielectric slab of dielectric
constant k as shown E1 and E 2 are the energies stored in the
capacitors. Now the dielectric slab is removed and another dielectric
which can completely fill capacitor 1 (having dielectric constant 2K)
is placed inside it and the corresponding energies are E '1 and E'2
E1 n2
[K=2].The ratio . The value of n is
E'1 9
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PART–II: CHEMISTRY
SECTION–A (Single Option Correct Type) (+3, –1)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE option is correct.
1. Which is correct?
KOH/ Cl
(A) (B) R OH R Cl + OH
OH
Cl
CH3 CH3 CH3 CH3
+
NaBr H3C C Br + NaOH NaBr/H H3C C Br
(C) H3C C OH (D) H3C C OH
2. O CH3
O
H3C
(i) CH3MgBr(1 equivalent )
(ii) H O
Pr oduct :
3
O
OH CH3
O
H3C O CH3
(A) (B)
CH3 H3C
O O
CH3
H3C
O HO CH3
(C) H3C O (D)
CH3 OH
CH3
3. CH3
O O
X Y. X and Y are
H3O
CH3 COOH
CH3 O
H3C
O
(C) O O (D) CH3
, H3C CHO
OH
CH3 O
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4. O
HI
products
Which of the following is not a product of above reaction?
OH I I
(A) CH2(Cl)–CH2–CH2–CH=CH2
BH3 / THF
H2O2 / OH
NaOH
(B) CH2(Cl)–CH2–CH2–CH=CH2
Hg ( OAc )2
NaBH 4
NaOH
H2O O
H O Ph
Ph
OCH3
(D) C6H5–Br + (CH3)3CONa (CH3)3CO–C6H5 + NaBr
6. (X) + Mg ( Y )
dry
CH3CH2CH2OH.
(i) ( Z )
ether ( ii ) H3O
7. Which of the following statements are correct when an alkaline solution of phenol is refluxed
with chloroform at 60°C?
(A) Dichloro carbene is formed as an intermediate.
(B) Ortho isomer is the major product.
(C) Intramolecular proton transfer takes place.
(D) Intramolecular hydride transfer takes place.
8. CH3–L + CH3–ONa CH3OCH3 + L Na
where L is a leaving group.
Which of the following statement(s) is/are true regarding the leaving tendency of the leaving
group (L)?
(A) p–CH3–C6H4–SO3 > CF3SO3 (B) p–CH3–C6H4–SO3 > I
(C) p–CH3–C6H4–SO3 < CF3SO3 (D) p–CH3–C6H4–SO3 < I
9. Which of the following reagents can be used to distinguish between CH2=CH–CH2Cl and
CH3CH2CH2Cl?
(A) sodium fusion; HNO3 + AgNO3 (B) Tollen’s reagent
(C) AgNO3 + C2H5–OH (D) cold aq. KMnO4
10. In which of the following reactions, meta isomer is the major product?
(A) o-chlorotoluene + NaNH2 + NH3(l) (B) o-chloroanisole + NaNH2 + NH3 (l)
(C) m-chlorotoluene + NaNH2 + NH3(l) (D) m-chloroanisole + NaNH2 + NH3 (l)
Aakash INVICTUS Advanced JEE Prep. Program (IIT-JEE), East Delhi Centre
SECTION–A: Comprehension Type (Single Option Correct Type) (+3, –1)
This section contains 2 paragraphs, type questions. Each paragraph describes an experiment, a
situation or a problem. Two multiple choice questions will be asked based on this paragraph.
Paragraph for Question Nos. 11 to 12
There are number of organic compounds including esters, xanthate esters, amine oxides ect.,
that undergo pyrolytic elimination with heat in the absence of added reagent, either in inert
solvent or in the absence of solvent. In general these elimination follow the rate law.
Rate (substrate)
However reaction is different from E1 elimination by the degree of syn-stereoselectivity that
they exhibit. These reactions are also known as Ei elimination and the degree of
synstereoselectivity reflect the extent to which they proceed via cyclic transition state.
H
Ph H CH3 H3 C Me
H Me Ph CH3 Me
H N
+
T 100C
HO N
H N Me Ph H O
H H Me
O Me
(A) (B)
Ph
Ph
CH3
+
N
(C) CH2 (D) None of these
Ph
12. Pyrolysis of
Me O CH3
Me CD3
would give
(A) Mixture of CH2=CHCD3 and CH3CH=CD2
(B) CH3CH=CD2
(C) Me2 N C CD3 CH3
(D) CH2=CHCD3
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13. Compound (B) in the above passage is
(A) anisole (B) O-cresol (C) m-cresol (D) p-cresol
OH
Ph
No of double bond in product P is
16. Identify numbers of alcohol those will show rearrangement during dehydration with
concentration H2SO4
OH
CH3 CH3 OH H3C CH3
H3C H3C
OH
OH CH3 CH3
, , CH3 , ,
CH3 OH H3C OH
HO
Ph
Aakash INVICTUS Advanced JEE Prep. Program (IIT-JEE), East Delhi Centre
17. Find out number of reactions those mainly proceed with retention of configuration
CH CH3
3
SOCl
(a) H (b) KCN
2
D Cl
DMSO
Ph Br H
aq.KOH
OCH 3 H OCH 3 Br aq.KOH
(c) (d)
CH3 Br CH3 H
CH3 Ph
SOCl
OH
2
NaI KSH
(e) H Cl
acetone
(f) D Pyridne
Ph CH3
18. Examine the ten structures shown below. How many compounds will give mainly SN2
reaction on treatment with NaSH in presence of DMSO?
Br CH3 I
Br
(a) (b) H3C Cl (c) (d) H3C I (e)
CH3
Cl
H3C CH3
Cl CH3 Br
CH3
(f) (g) H3C (h) H2C (i) (j)
Cl CH3
CH3 CH3
Cl
Aakash INVICTUS Advanced JEE Prep. Program (IIT-JEE), East Delhi Centre
PART–III: MATHEMATICS
SECTION–A (Single Option Correct Type) (+3, –1)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE option is correct.
1. Let f(x) = xx, x(0, ) and let g(x) be inverse of f(x), then g(x) must be
1
(A) x(1+logx) (B) x(1+logg(x)) (C) (D) non-existent.
x(1 logg(x))
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x 2 2x y 1 2
6. Consider, P ,Q 2 and R 2 where x, y, z R.
x2 x 1 y y 1 z z 1
If k = [P + Q + R] ([P] + [Q] + [R]) then the possible value(s) of k is(are):
(A) 0 (B) 1 (C) 2 (D) 3
x 3 if x [4, 2)
x6 x 0
7. Let f x 1 if x [ 2,2) , g(x) = then
3 x if 2x 6 x 0
x 2,4
(A) gof(x) = k will have one atleast solution if k [5, 8]
(B) Range of fog(x) is [1, 1]
(C) lim fog x 1
x 2
8. Let f(x) = |x – 4| + |x – 5| + |x – 6| and g(x) = f(x + k). Find k, so that g(x) is an even function.
Then k is greater than
(A) 2 (B) 3 (C) 4 (D) 5
1
9. The function g defined by g(x) = sin + cos – 1; sin {x}, where {.} denotes the
fractional part function, is
(A) an even function (B) periodic function (C) odd function (D) neither even not odd
10. Let f:RR defined by f(x) = cos–1(–{–x}), where {x} denotes fractional part of x. then, which of
the following is/are correct?
(A) f is many one but not even function (B) Range of f contains two prime numbers
(C) f is non-periodic (D) Graph of f does not lie below X-axis.
11. Let P is the number of functions from A to B which are strictly increasing, Q is the number of
functions from a to B which are strictly decreasing and R is the number of functions from A to
B in which f(x1) f(x2 ) f(x3 ) f(x 4 ) f(x5 ) then P + Q + R is equal to
(A) 1420 (B) 1596 (C) 1444 (D) 1820
12. Let S be the number of onto functions from A to B such that at most one element (except x5)
S
in the co-domain set should have unique pre-image in the domain set then the value of
100
is:
(A) 1008 (B) 1387 (C) 1480 (D) 1190
Space for rough work
Aakash INVICTUS Advanced JEE Prep. Program (IIT-JEE), East Delhi Centre
Paragraph for Question 13 to14
Consider the following two binary relations on the set A={a, b, c} :
R1 = {(c, a), (b, b), (a, c), (c, c), (b, c), (a, a)}
and R2={(a, b), (b, a), (c, c), (c, a), (a, a), (b, b), (a, c)}.
13. R1 is
(A) symmetric (B) identity (C) universal (D) transitive
14. R2 is
(A) not symmetric (B) identity (C) universal (D) not transitive
17. f : R R is f(x) ln(x x 2 1), then find the number of solutions to the equation
f 1(x) e |x| .
18. The number of solutions of the equation |cos x| = 2[x], where [.] denotes greatest integer
function, is equal to _______.
Aakash INVICTUS Advanced JEE Prep. Program (IIT-JEE), East Delhi Centre
MID PHASE TEST – IV
JEE ADVANCED (PCM)
BATCH: SPARK 26-01
Time: 3 hrs M.M.: 180
Aakash INVICTUS Advanced JEE Prep. Program (IIT-JEE), East Delhi Centre
Hint & Solutions
SECTION–A
1. A
The no. of lines emerging from q charge will all terminate on –q charge and thus they should
all cross an infinite plane. Therefore the flux linked with infinite plane is q / 0 .
2. A
Consider that charge is placed inside a complete cone. Flux 3R
through the circular face of the cone will be
Q Q Q
1 cos 60 R
20 4 0
So, flux linked with the complete curved surface of the cone
Q Q 3Q
will be .
0 40 40
3. B
UC K C Ue K e .
4. B
CV CV 2
q w b qV
2 2
2
CV
loss of energy .
4
SECTION–B
5. A, B, D
6. B, C
K0 A 30 A
C
4d 4d
K A C 3 K
C1 0 ;
4d C1 K
V E
E1 E2 1 1
d E2
K 0 A K V
Q1 C1V V 1 0
4d d
3 0 A 3A V
Q 2 C2 V V 2 2 0 1 K
4d 4 d 2
7. A, B
R
q q
Flux through curved surface 2 1 cos q
0 20
q q
cos
0 0 4R2 2
8. B, C
V
E
r
9. A, B q Q1 – q Q1 + Q2 – q
For EP = 0
q Q q Q2
E 1 P
2A 0 2 A 0 2A 0
Q Q2
q 1 0 AE – (Q1 – q)
2
Q Q2
E inside the gap = E 1
2 A 0
Aakash INVICTUS Advanced JEE Prep. Program (IIT-JEE), East Delhi Centre
Q1 Q2
E on the left side of plates = E
2 A 0
Q Q2
E on the right side of plates = E 1
2 A 0
10. A, D
SECTION–C
11. D
P P1 P2
12. C
1 qa 1 qa 9 q 2
E . .
40 2 2 3/2
a
40 a2 2 3/2 320 a4
4
13. A
14. D
SECTION–D
15. 5
16. 1
17. 2
P 4 R 2
cm
F macm
f 2RE.
18. 5 Q
kQ
dU VP(ring)dx dx P
R2 x 2
Q
3R
dx dx
40 0 R2 x 2
U x
U
Q
40 0 sec d
Q
40
n(sec tan )0
/3 Q
40
n 2 3
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