a.

SECTION-A

1 Which one will have maximum numbers of water molecules?(A)18molecules of 1

water

B. 1.8grams of water

B. 18grams of water (D)18moles of water

2 ……………. is the mass percentage of carbon in carbodioxide? 1

3 The second ionization enthalpies of Na,Mg,Al and Si are in the order:……………. 1

4 Consider the following species: 1

N3-, O2-,F–, Na+, Mg2+,Al3+What is common in them?

(a)Radius(b)No.of protons(c)No.of nucleons(d)No.of electrons

5 Azimuthal quantum number determines the………………………………… 1

6 The electronic configuration of Co2+ ion is……………. 1

7 Transition metals belongs to 1

a. Group number1to2

b. Group number13to18

c. Group number3to12

d. Group number1to8

8 A certain orbital has no angular nodes and two radial nodes. The orbital is- 1
 (a) 2p (b) 3p (c) 3s (d) 2s

9 The volume of gas is reduced to 1/8 from its original volume. The specificheatwill 1
be……………………………………………

10 In the reaction, 2SO3 2SO2 + O2 The unit of equlibrium 1

constant Kc is :

a. mole-2 lit.-1

b. mole2. lit.

c. mole. lit.

d. mole. lit.-1

11 A measured temperature on Fahrenheit scale is 200F. What will this reading be on 1

the Celsius Scale?

(a)40 ℃

(b)94 ℃

(c)93.3℃

(d)30℃
12 The correct bond order in the following species is—————. 1

(a)O2+<O2–<O22+

(b)O2–<O2+<O22+

(c) O2+ < O+ < O–2 2 2

(d)O22+<O2–<O2+

Forquestions13-16

a. Both A and R are the true and R is the correct explanation of A.

b. Both A and R are true but R is not the correct explanation of A.

c. A is true but R is false.

d. Both A andR are false.

13 Assertion (A): One atomic mass unit is defined as one-twelfth of the mass of 1
onecarbon-12atom.

Reason (R): Carbon-12 isotope is the most abundant isotope of carbon and has
been chosen as standard.

14 Assertion(A):Atoms with completely filled and half-filled subshells are stable. 1

Reason (R) : Completely filled and un-filled subshells have the symmetrical
distribution of electrons and have maximum exchange energy.

15 Assertion:BF3 molecule has zero dipole moment.Reason :B is electronegative and 1

B–F bonds are polar in nature.

16 Assertion(A):If two systems are in thermal equilibrium with the third then all the 1
three systems will be in thermal equilibrium with one another.
 Reason(R):Zeroth Law of thermodynamics was given before first Law.

SECTION-B

17 What is the molar concentration of sugar C12H22O11 if it’s 2gm are dissolved in 2
enoughwatertomakefinalvolume2L

18i.In O-2.and F-, which one would have larger size? 1+1

ii.Among alkali metals which element do you expect to be least electronegative?

19 The enthalpy of the atomisation for the reaction CH4(g) C(g) + 4H(g) is 1
1665 K.J. mole-1 what is the bond of energy of the C-Hbond?
1

20 In a process, 700 J of heat is absorbed by a system and 390 J of work is done by 2

the system.What is the change in internal energy for the process?

OR

Calculate the number of kj of heat necessary to raise the temperature of60g of

aluminium from35°Cto55°C.Molar heat capacity of Al is

24Jmol-1K-1.

21 What is Kc for the following equilibrium when the equilibrium concentration of

each substance is: [SO2] = 0.6 M, [O2] = 0.82M, and [SO3] = 1.9 M ?
1
2SO2 + O2 2SO3
1

SECTION-C

22 (i) An atomic orbital has n = 3. What are the possible values of l and ml ? 1+1+1
(ii) List the quantum numbers ml and l of electron in 3rd orbital.
(iii) Which of the following orbitals are possible ?
1py, 2s, 2px ,3f,5g,4f,1f and 2dX2-Y2

23 4 liters of water are added to 2 lt. of 6 molar Hcl solutions. what is the molarity of 1
resulting solution?
1

24i.Define adiabatic system. 1

ii.What are the values of work done, internal energy and heat for isothermal free 1
expansion of an ideal gas?
1
iii.Explain state and path functions with an example of each.
25 Draw enrgy level diagram of O2. Also calculate bond order and explain magnetic 3
character in O2.

26 Kp = 0.04 atm at 899 k for the equilibrium shown below. what is the equilibrium 3
concentration of C2H6 when it is placed in a flask at 4 atm. pressure and allowed to
come to equilibrium?

C2H6 C2H4+H2

27 An element X with atomic number 112 has been recently predicted. Its electronic
configurationis:

[Rn] 5f146d107s2 .Predict 1

i.itsgroup 1

ii.block in which this element would be placed 1

iii.IUPAC name and symbol.

28 In a reaction 3

A +2 B → AB2

Identify the limiting reagent in the following reaction mixtures.

(i) 300 atoms of A + 200 molecules of B

(ii) 2 mol of A + 3 mol of B

(iii) 100 atoms of A + 100 molecules of B

(iv) 5 mol of A + 2.5 mol of B

(v)2.5 mol of A + 5 mol of B

(vi)3gm of A +5 gm of B

SECTION-D

29 Read the passage given below and answer the following questions: 1

Hybridisation helps us to understand the geometry of molecules.This is because

hybridized orbital sare directed in space in some preferred direction to have stable
1
arrangement , which determine the geometry.The presence of lone pairs in addition to
bond pairs distortthe geometry due to repulsion.

a. What is the hybridization of Sulphur inSF4 1

 b. Give example of molecule having trigonal planer geometry.

c. Give shape of the molecule having four bond pairs and one lonepair. 1

d. Distinguish coaxial and collateral overlapping with example.

30 Read the passage given below and answer the following questions: In the periodic
table electronegativity increases from left to right in a

period and decreases from top to bottom in a group. The non-metallic character of an
element is directly related to the electronegativity while the metallic character is
inversely related to it.

a.The element with maximum electronegativity belongs to(a)Period-1,Group-18

1
(b)Period-2,Group-17(c)Period-3,Group-17 (d)Period-2, Group-1.

b.Which of the following groups contains metals, non-metals as well as

metalloids?(a)Group-1
1
(b) Group-17(c) Group-14(d)Group-2.

c.The least, metallic element of group-13 is(a)Aluminium 1

b. Boron

b. Gallium

b. Indium.
1
d.The electronegativity decreases with (a)decrease in nuclear charge (b)increase in
atomic mass

(c)decrease in atomic size (d)increase in atomic number.

SECTION-E
31 a.The bromine atom possesses 35 electrons that contain 6 electrons in 2p orbital, 6 1
electrons in 3p orbital and 5 electrons in 4p orbital. Which of these electrons
experiences the lowest effective nuclear charge?

b.The arrangement of the orbitals is based upon the energy based on the (n+l ) value.
1
The lower the value of the (n+l ), the lower energy found. For orbitals with equal
values of (n+l), the orbital with the lower value of n will have the lower energy.

1. Based upon the above-given information, arrange the following orbitals in the
increasing order of their energy
1
(a) 1s, 2s, 3s, 2p

(b) 4s, 3s, 3p, 4d

(c) 5p, 4d, 5d, 4f, 6s

(d) 5f, 6d, 7s, 7p

c. Wavelengths of the following different radiations have given below :

λ(A) = 300 nm

λ(B) = 300 μm

λ(c) = 3 nm 1
λ (D) 30 A°

Arrange the following radiations in the increasing order of their energies.

d. The Balmer series in the hydrogen spectrum corresponds to the transition from n1 =
2 to n2 = 3,4,………. This series lies in the visible region. Calculate the wave number of
lines associated by the transition in the Balmer series if the electron moves to n = 4
orbit. (RH= 109677 cm-1)

32 1. The net enthalpy change for the reaction is the amount of energy needed to 2
break all the bonds from the reactant molecules minus the amount of energy
needed to form all the bonds in the product molecules. What will be the
enthalpy change for the given reaction? 2

H2(g) + Br2(g) → 2HBr(g)

Given that the Bond energy of the H2, Br2 and HBr is 435 kJ mol-1, 192 kJ mol-1,
as well as 368 kJ mol-1, respectively.
 2. Expansion of the gas in the vacuum is called free expansion. Calculate the work
done as well as the change in the internal energy if 1 litre of the ideal gas expands
isothermally into a vacuum until the total volume is 5 litres?
1
3. Entropy on boiling of egg ………………whereas curding of milk…………….

33 (i) Structures of molecules of two compounds are given below:

2
a. Which of the two compounds will have intermolecular hydrogen bonding and
which compound is expected to show intramolecular hydrogen bonding.

b. Which of the above two compounds will show lower melting point. Why? 1

c. Solubility of compounds in water depends on power to form hydrogen bonds

with water.Which of the above compounds will form hydrogen bond with water as 2
easily and be more soluble in it