15-06-2025

1402CJA101021250035 JA

PHYSICS

1) The given circuit shows a uniform straight wire AB of 40 cm length fixed at both ends. In order to
get zero reading in the galvanometer G, the free end of J is to be placed from B at :

(A) 32 cm
(B) 8 cm
(C) 16 cm
(D) 24 cm

2) A uniform metal wire of length ℓ has 10 Ω resistance. Now this wire is stretched to a length 2ℓ
and then bent to form a perfect circle. The equivalent resistance across any arbitrary diameter of
that circle is:

(A) 10Ω
(B) 5Ω
(C) 40Ω
(D) 20Ω

3) A uniform wire of diameter d carries a current of 100 mA when the mean drift velocity of

electrons in the wire is v. For a wire of diameter of the same material to carry a current of 200 mA,
the mean drift velocity of electrons in the wire is:

(A) 4 v
(B) 8 v
(C) v
(D) 2 v

4) Two heaters A and B have power rating of 1 kW and 2 kW, respectively. Those two are first
connected in series and then in parallel to a fixed power source. The ratio of power outputs for these
two cases is :

(A) 1 :1
(B) 2 : 9
(C) 1 : 2
(D) 2 : 3

5) The terminal voltage of the battery, whose emf is 10V and internal resistance 1Ω, when

connected through an external resistance of 4Ω as shown in the figure.

(A) 4V
(B) 6V
(C) 8V
(D) 10V

6) Choose the most appropriate combination of emf(E) and internal resistance(r) of a battery from
the options given below, if terminal voltage of the battery is 8V, when connected through an external
resistance of 4 as shown in the figure.

(A) 10V, 5
(B) 10V, 1
(C) 8V, 1
(D) 8V, 5

7) Equivalent resistance of the following network is _____ Ω.

(A) 1
(B) 2
(C) 3
(D) 4

8) A voltmeter has resistance of 2000Ω and it can measure upto 2V. If we want to increase its range
to 10V than the required resistance in series will be :

(A) 2000Ω
(B) 9000Ω
(C) 6000Ω
(D) 8000Ω

9) In given circuit power generated in resistance will be maximum for x equal to :

(A) 1Ω
(B) 2Ω
(C) 2/3Ω
(D) 0Ω

10) The value of current in the 60Ω resistance in the adjoining circuit diagram will be :

(A) 0.1 A
(B) 0.5 A
(C) 0.05 A
(D) 0.01 A

11) Five identical resistors, each of value 1100Ω are connected to a 220V battery as shown. The

reading of the ideal ammeter A is :

(A) 1/5 A
(B) 2/5 A
(C) 3/5 A
(D) 4/5 A

12) The equivalent resistance of a group of resistance is R. If another resistance is connected in

parallel to the group, its new equivalent becomes R1 & If it is connected in series to the group, its
new equivalent becomes R2 we have :

(A) R1 > R
(B) R1 < R
(C) R2 = R
(D) R2 < R
13) The length of a given cylindrical wire is increased by 100%.Due to the consequent decrease in
diameter the change in the resistance of the wire will be :

(A) 300%
(B) 200%
(C) 100%
(D) 50%

14)

(A) R/4
(B) R/2
(C) R
(D) 2R

15) The equivalent resistance between points X and Y in the following diagram will be :

(A) 10.6Ω
(B) 20Ω
(C) 16Ω
(D) 8Ω

16) Across a metallic conductor of non-uniform cross section a constant potential difference is
applied. The quantity which remains constant along the conductor is :

(A) Current
(B) Drift velocity
(C) Electric field
(D) Current density

17) The equivalent resistance of the arrangement of resistances shown in adjoining figure between
the points A and B is :

(A) 6 ohm
(B) 8 ohm
(C) 16 ohm
(D) 24 ohm

18) If two bulbs of wattage 60 W and 100 W respectively each rated at 110 V are connected in series
with the supply of 220 V, which bulb will fuse ?

(A) 60 W bulb
(B) 100 W bulb
(C) Both the bulbs
(D) Bulbs will not fuse

19) Find the equlvelent resistance between A and B of the network extending off to the inifinity

shown in the figure for R1 = 1Ω, R2 = 4Ω :-

(A) 4 Ω
(B) 1 Ω
(C) 2 Ω
(D) 8 Ω

20) The capacitance of a capacitor with charge q and a potential difference V depends on:

(A) both q and V

(B) the geometry of the capacitor
(C) q only
(D) V only

21) In the following circuit, the equivalent capacitance between terminal A and terminal B is :
(A) 2μF
(B) 1μF
(C) 0.5μF
(D) 4μF

22) Find the equivalent capacitance between A and B. (A : Area of each plate, d : separation between

adjacent plates)

(A)

(B)

(C)

(D)

23) The space between plates of a parallel plate capacitor is filled by a dielectric and it is charged
and then battery is removed. Now dielectric slab is slowly out of the capacitor parallel to the plates.
the variation of the potential of capacitor with respect to the length of the dielectric plate drawn out
is-

(A)
(B)

(C)

(D)

24) A 3μF capacitor is charged as shown in figure. The percentage of it's stored energy dissipated

after the switch S is turned to position 2 is :

(A) 30%
(B) 70%
(C) 50%
(D) 0%

25) A capacitor is charged by connecting a battery across it's plates. It stores energy . Now the
battery is disconnected and another identical capacitor is connected parallel to it, then the energy
stored by both capacitor of the system will be-

(A)

(B)

(C) 3u

(D)
26) Consider the following diagram: Statement-1 : Charge on C1 =
charge on C2 + charge on C3.
Statement-2 : Potential difference across C1 is equal to 5 times the potential difference across C3.

(A) Statement-1 is correct and Statement-2 is incorrect.

(B) Statement-1 is incorrect and Statement-2 is correct.
(C) Both Statement-1 and Statement-2 is correct.
(D) Both Statement-1 and Statement-2 is incorrect.

27) In the given circuit, potential of point A is 3000 V and of C is 1000 V. Then potential of point B is

(A) 2000 V
(B) 1600 V
(C) 1500 V
(D) 1400 V

28) In the circuit (shown in figure) The charge stored in the capacitor of capacity C is

(A) Zero
(B)
(C)
(D)

29) In the given circuit, charge stored on capacitor will be

(A)
(B)
(C)
(D)

30) The energy of a charged capacitor resides in

(A) The electric field only

(B) The magnetic field only
(C) Both the electric and magnetic field
(D) Neither in electric nor magnetic field

31) Which of the following expressions represents a farad ?

(A) Joule/volt
(B) Volt / coulomb
(C) Coulomb/volt
(D) Coulomb/joule

32) Find common potential if plates of same polarities are connected with each other

(A)

(B)

(C)

(D)

33) Meaning of “fringing of the field” term in reference of capacitors is

(A) bending of field lines from the centre of plates of capacitors

(B) bending of field lines from the edges of plates of capacitors
(C) bending of field lines from the centre & edges of plates of capacitors
(D) bending of field lines from only above of centre of plates of capacitors

34) A capacitor is connected with a cell if distance between plates is halved then force of attraction
between the plates :-

(A) Remains same

(B) Becomes 8 times
(C) Becomes 4 times
(D) Becomes 2 times

35) A 2μF condenser is charged upto 200V and then battery is removed. On combining this with
another uncharged condenser in parallel, the potential differences between two plates are found to
be 40V. The capacity of second condenser is:-

(A) 2μF
(B) 4μF
(C) 8μF
(D) 16μF

36) Three condensers C1, C2 and C3 are connected to a 100 volt D.C. source as shown in the figure
(Fig.). If the charges stored on the plates of C1, C2 and C3 are qa, qb and qc, qd and qe, qf respectively,

then :-

(A)
qb + qd + qf = coulomb
(B) qb + qd + qf = 0
(C) qb = qd = qf
(D) qa + qc + qe = 50 Coulomb

37) Two identical capacitors have the same capacitance C. One of them is charged to potential V1
and the other to V2. The negative ends of the capacitors are connected together. When the positive
ends are also connected, the decreases in energy of the combine system is :-

(A)

(B)

(C)

(D)

38) Two identical capacitors are joined in parallel, charged to a potential V, separated and then
connected in series, the positive plate of one is connected to the negative of the other. Which of the
following is true ?

(A) The charges on the free plated connected together are destroyed.
(B) The energy stored in the system increases.
(C) The potential difference between the free plates is 2 V.
(D) The potential difference remains constant.

39) A capacitor of capacitance C1 is charged to a potential V and then connected in parallel to an

uncharged capacitor of capacitance C2. The final potential difference across each capacitor will be :-

(A)

(B)

(C)

(D)

40) If galvanometer resistance is 1Ω then select correct statement/statements ?

(1) No current flows in (G)

(2) 0.2 A current flows in (G)
(3) Potential difference across 4µf is 1 volt
(4) Potential difference across 5µf is 1.2 volt.

(A) 1,2,3
(B) 2,3,4
(C) 1 only
(D) All

CHEMISTRY

1) For the zero order reaction : A → P , K = 10–2 (mol/litre) sec–1 If initial concentration of A is 0.3M
, then find concentration of A left at 10 sec.

(A) 0 M
(B) 0.2 M
(C) 0.1 M
(D) 0.15 M

2)

For a zero order reaction

A → B ; K = 0.025 Ms–1
If 2M of A is taken initially the concentration of A after 40 sec is -

(A) 0.5M
(B) 1 M
(C) 0.25 M
(D) 2M

3)

At 100ºC gaseous reaction

A(g) → 3B(g) + C(g)

follows Ist order kinetics. After 10 mins total pressure of system is 325 mm Hg and after a long time
total pressure is 400 mm Hg. Then half life of reaction is-
(A) 5 min.
(B) 10 min.
(C) 20 min.
(D) 2.5 min.

4) For a second order reaction R → P, time taken to reduce the concentration of R up to one fourth of
initial value, is how many times the half life

(A) one
(B) two
(C) three
(D) four

5)

For the reaction : 2O3(g) → 3O2(g)

Mechanism :

Step - I O3(g) O2(g) + O(g)

Step - II O(g) + O3(g) 2O2(g)
overall order of reaction based on mechanism is

(A) 1
(B) 2
(C) 3
(D) 1.5

6)
For the reaction : 2O3(g) → 3O2(g)
Mechanism :

Step - I : O3(g) O2(g) + O(g)

Step - II : O(g) + O3(g) 2O2(g)

overall order of reaction based on the given mechanism is :

(A) 1
(B) 2
(C) 3
(D) 1.5

7) For a zero order reaction, the plot of conc. (a – x) vs time is linear with :-

(A) +ve slope and zero intercept

(B) –ve slope and zero intercept
(C) +ve slope and non-zero intercept
(D) –ve slope and non-zero intercept

8)

Which of the following statements is incorrect :

(A) Rate of reaction can not be negative

(B) A bimolecular elementry reaction must be second order reaction
(C) Average rate and instantaneous rate can never be equal
(D) Rate depends upon surface area of the reactants

9) The first order rate constant k is related to temp. as log k = 15.0 – (106 / T) which of the
following pair of value is correct ?

(A) A = 1015 and E = 1.9 × 104 KJ

(B) A= 10–15 and E = 40 KJ
(C) A = 1015 & E = 40 KJ
(D) A = 10–15 & E = 1.9 × 104 KJ

10) From the figure, the activation energy for the reverse reaction would be: (Given Ea = 1640 KJ/
mole, Er = –120KJ/mole):

(A) – 120 KJ/mole

(B) + 152 KJ/mole
(C) + 120 KJ/mole
(D) 1760 KJ/mole

11) A reaction 2N2O5(g) 4NO2(g) + O2(g), the value of rate constant k is 2 × 10–4 min–1. The
rate of the reaction when [N2O5] = 0.2 mol/l

(A) 4 × 10–5 mol/l –sec

(B) 8 × 10–6 mol/l –min
(C) 6.67 × 10–7 mol/l –sec
(D) 1.33 × 10–6 mol/l –sec

12) Mathematical representation for t1/4 life for first order reaction is over is given by:

(A) t1/4 = [(2.303)/(K)] log 4

(B) t1/4 = [(2.303)/(K)] log 3
(C) t1/4 = [(2.303)/(K)] log (4/3)
(D) t1/4 = [(2.303)/(K)] log (3/4)

13) For 2A B, the expression of net rate of formation of B is, assuming forward reaction is
first order while backward reaction is zero order :

2
(A) K1 [A] – K2[B]
(B) 2K1 [A] – K2
(C) (1/2) K1 [A] – K2 [B]
(D) K1 [A] – K2

14) For a given reaction of first order it takes 20 min. for the conc. to drop from 1.0 M to 0.60 M The
time required for the conc. to drop from 0.60 M to 0.36 M will be :

(A) more than 20 min

(B) 20 min
(C) less than 20 min
(D) can not tell

15) The velocity of a reaction is doubled for every 10°C rise in temp. If the temp. is raised to 50°C,
the reaction velocity increases by about :

(A) 12 times
(B) 16 times
(C) 32 times
(D) 50 times
16) A2 + 2 B → 2 AB

[A2] [B] {–d[A2]/dt}

0.1 0.2 1 × 10–2 Ms–1
0.2 0.2 2 × 10–2 Ms–1
0.2 0.4 8 × 10–2 Ms–1
Order of reaction w.r.t. A2 and B are respectively :
(A) 1, 2
(B) 2, 1
(C) 1, 1
(D) 2, 2

17) What will be the order of reaction and rate constant for a chemical change having log (t50%) vs
log conc (A) curves as

(A) 0, 1/2
(B) 1, 1
(C) 2, 2
(D) 3, 1

18) For a reaction, the possible mechanism is

What is the rate law and order of the reaction ?

(A) Rate order = 1

(B) Rate order = 2
(C) Rate order = 2
(D) Rate order = 3

19) The slope of the line for the graph of log k versus for the reaction, N2O5 → 2NO2 + O2 is –
5000. Calculate the energy of activation of the reaction - (kJ K–1 mol–1)

(A) 95.7
(B) 9.57
(C) 957
(D) None

20) In a reaction carried out at 400 K, 0.0001% of the total number of molecules are in activated
state. The energy of activation of reaction is -

(A) 0
(B) 7.37 Kcal/mol
(C) 9.21 Kcal/mol
(D) 11.05 Kcal/mol

21) Following data are obtained for the reaction A + B → product

[A] (mole L–1) [B] (mole L–1) Rate (mole L–1 s–1)

4 × 10–2 4 × 10–2 2 × 10–2

4 × 10–2 8 × 10–2 4 × 10–2

2 × 10–2 8 × 10–2 2 × 10–2

The reaction confirms the rate law

(A)
– = k [A]

(B)
– = k [A] [B]2

(C)
– = k [A] [B]

(D)
– = k [B]

22) For any reaction A(g) → P(s) following observation is made :

Partial pressure of A (in

Time (min)
bar)

0 20

20 10

60 5
Order of the reaction may be -
(A) –1
(B) 0
(C) 1
(D) 2

23) The rate law for the reaction : 2 C + D → A + E is

If C is present in large excess, the order of the reaction will be -

(A) Zero
(B) First
(C) Second
(D) Third

24) For any fist order reaction following observation is made

If at temperature (T) half life of the reaction is 6930 sec. & at temperature (T') half life of the

reaction is 0.693 msec. Then calculate

(A) 2
(B) 4
(C) 6
(D) 8

25) Half lives for a zero order (A → B) & 1st order reaction (A → P) are same. Then starting with same
initial concentration of 'A' the ratio of initial rate of first order & zero order will be -

(A) 0.693

(B)

(C) 0.693 × 2

(D)

26) The reaction A(g) + 2B(g) → C(g), the rate of reaction = k [A]2 [B] = 8 × 10–2 M/min, when
concentrations of each A and B are 1.0 M. Now rate of reaction when half of the B has reacted
should be:

(A) 2.25 × 10–2 M/min

(B) 3.00 × 10–2 M/min
(C) 1.00 × 10–2 M/min
(D) 2.5 × 10–3 M/min

27) For reversible elementary reaction :

2R P
Correct option is :

(A)
= 2{k1[R]2 – k–1 [P]}

(B)
= {k1[R] – k–1[P]}

(C)
= 2 {k–1[P] – k1[R]2}

(D)
= {k–1[P] – k1[R]2}

28) Statement-1 : The number of reacting species (atoms, ions or molecules) taking part in an
elementary reaction, which must collide simultaneously in order to bring about a chemical reaction
is called the molecularity of a reaction.
Statement-2 : The molecularity of reaction of both complex and elementary reactions can be
determined.

(A) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for Statement-1
Statement-1 is true, Statement-2 is true and Statement-2 is NOT the correct explanation for
(B)
Statement-1
(C) Statement-1 is true, Statement-2 is false
(D) Statement-1 is false, Statement-2 is true

29) Which of the following expressions correctly describes the relationship between the rates at
which NO2 and Cl2 are consumed in the reaction below ?
2NO2(g) + Cl2(g) —→ 2NO2Cl(g)

(A)

(B)

(C)

(D)

30) Select the incorrect statement among the following :

(A) Unit of frequency factor (A) of second order reaction is M–1 sec–1.
(B) Overall molecularity of a complex reaction is not defined.
(C) Order of an elementary reaction may be zero.
With increase in temperature the steric factor of a reaction following a particular mechanism
(D)
remain unchanged.

31) For a first order reaction A(g) → 2B(g) + C(g) at constant volume and 300 K, the total pressure at
the beginning (t = 0) and at time t are P0 and Pt respectively. Initially, only A is present with
concentration of [A]0.
(Assume that all these gases behave as ideal gases)

(a) (b) (c) (d)

Select the correct plot(s) related to above reaction.

(A) plot a & b

(B) plot a & d
(C) plot b & d
(D) plot c & d

32) A first order reaction is 50% completed in 20 minutes at 27°C and in 5 min at 47°C. The energy
of activation of the reaction is

(A) 100 kJ/mol

(B) 55.14 kJ/mol
(C) 11.97 kJ/mol
(D) 6.65 kJ/mol

33) The rate constant, the activation energy and the Arrhenius parameter (A) of a chemical reaction
at 25°C are 3.0 × 10–4 s–1, 104.4 kJ mol–1 and 6.0 × 1014 s–1 respectively. The value of the rate constant
at T → ∞ is

(A) 2.0 × 1018 s–1

(B) 6.0 × 1014 s–1
(C) infinity
(D) 3.6 × 1030 s–1

34) Which of the following curve represents a Ist order reaction :–

(A)

(B)

(C)

(D) 1 & 3 both

35) A reaction is found to have the rate constant x sec–1. By what factor the rate is increased if initial
conc. of A is tripled ?

(A) 3
(B) 9
(C) x
(D) Remains same

36) If the first order reaction involves gaseous reactants and gaseous products the units of its rate
may be –

(A) atm.
(B) atm - sec.
(C) atm – sec–1
(D) atm2 sec2

37) If the rate of the reaction is equal to the rate constant, the order of the reaction is :-

(A) 0
(B) 1
(C) 2
(D) 3

38) At certain temperature, the half life period for the thermal decomposition of a gaseous substance
depends on the initial partial pressure of the substance as follows :

P (mm Hg) 500 250

t1/2 (in min.) 235 940

Find the order of reaction :
(A) 1
(B) 2
(C) 2.5
(D) 3

39) In an exothermic reaction A(g) ⇌ B(g), the activation energy of reverse reaction is twice that of
forward reaction. If enthalpy of reaction is –90 kJ/mol, the activation energy of the reverse reaction
is :

(A) 60 kJ/mol
(B) 45 kJ/mol
(C) 180 kJ/mol
(D) 90 kJ/mol

40) Which of the following is not correct for first order reaction :

(A)
 –kt
(B) N = N0e

(C)

(D) None of these

MATHEMATICS

1) In the interval ; the function f(x) = + sinx is :

(A) increasing
(B) decreasing
(C) constant
(D) neither increasing nor decreasing

2) If f (x) = 2x3 – 3x2 – 36x + 6 has local maximum and minimum at x = a and x = b respectively, then
ordered pair (a, b) is –

(A) (3, –2)

(B) (2, –3)
(C) (–2, 3)
(D) (–3, 2)

3) For the curve y = xex ;

(A) x = 0 is a point of maxima

(B) x = 0 is a point of minima
(C) x = –1 is a point of minima
(D) x = –1 is a point of maxima

4) The normal to the curve x = a(1 +cosθ), y = a sinθ at 'θ' always passes through the fixed point :

(A) (a, a)
(B) (0, a)
(C) (0, 0)
(D) (a, 0)

5) The line y = x + 1 is a tangent to the curve y2 = 4x at the point :

(A) (1, 2)
(B) (2, 1)
(C) (1, –2)
(D) (–1, 2)

6) If 0 ≤ x ≤ 5, then the minimum distance of the point (0, c) from parabola y = x2 is-
(A)
(B)
(C)
(D) None of these

7) If curve and intersect orthogonally then the value of a is :

(A)

(B)

(C) 2
(D) 3

8) x(1 – x2), 0 ≤ x ≤ 2, is maximum at :

(A) x = 0
(B) x = 1
x=
(C)

(D) No-where

9) In [0, 2π] ; maximum value of x + sin2x is :

(A)
+

(B)
–

(C)
+

(D)
–

10) The slope of tangent at (2, –1) to the curve

x = t2 + 3t – 8 and y = 2t2 – 2t – 5 is :

(A) –6
(B) 0
(C) 6/7
(D) 22/7

11) The displacement 's' of a moving particle at a time 't' is given by s = 5 + 20t – 2t2. Find its
acceleration when the velocity is zero.

(A) 4 units
(B) –4 units
(C) 2 units
(D) 6 units

12) The function increases in the interval

(A)
(B)
(C)
(D)

13) The function where is

(A) Decreasing for all

(B) Increasing for all
(C) Neither increasing nor decreasing for all
(D) None of these

14) If then y

(A) Has a local minimum

(B) Has a local maximum
(C) Neither have a local maximum or minimum
(D) All of these

15) Find the height of a cylinder, which is open at the top, having fixed surface area & greatest
volume and of radius r.

(A) r
(B) 2r
(C) r/2
(D) 3πr/2

16)

(A)

(B)

(C)

(D)
17)

(A) ex log (sec x) + c

(B) ex log (cosec x) + c
(C) ex log (cos x) + c
(D) ex log (sin x) + c

18) If , then

(A)

(B)

(C)

(D)

19) is equals to

(A)

(B)

(C)

(D) None of these

20) equals

(A)

(B)

(C)

(D)

21) If and , then f (x) =

(A)

(B)
(C)

(D)

22)

(A)

(B)

(C)

(D) None of these

23)

(A) tan x + cot x

(B) cot x – tan x + C
(C) tan x – cot x + C
(D) None of these

24) is

(A)

(B)
(C) 14x + C
(D)

25) The value of is equal to

(A)
(B)
(C) tan(ex) + C
(D) cot(ex) + C

26)

(A)
(B)

(C)

(D) None of these

27)

(A)

(B)

(C)

(D) None of these

28) If and then the value of is

(A)

(B)

(C)

(D)

29) If the integral

where k is an arbitrary constant, then A is equal to

(A)

(B)

(C)

(D)

30)

(A)

(B)
(C)
(D)

31) If

,
then the values of A, B and C are respectively

(A) 5, –7, – 5
(B) 2, –7, –5
(C) 5, –7, 5
(D) 2, –7, 5

32) If , then is equal to :

(A)

(B)

(C)

(D)

33) The integral is equal to

(A)

(B)

(C)

(D)

34)

The value of is

(A)
(B)

(C)

(D)

35) is equal to

(A)
(B)
(C)
(D)

36) The curve y = ax3 + bx2 + cx + 5 touches the x-axis at (–2, 0) and cuts the y-axis at a point Q
where its gradient is 3, then the value of a + b + c is

(A)

(B)

(C)

(D)

37) If y = alogx + bx2 + x has its extreme value at x = –1 and x = 2, then the value of a + b is

(A)

(B)

(C)

(D)

38) If f(x) = x3 + bx2 + cx + d and 0 < b2 < c, then in

(A) f(x) is strictly increasing function

(B) f(x) is bounded
(C) f(x) has a local maxima
(D) f(x) is a strictly decreasing function

39) The maximum value of the function

f(x) = 2x3 – 15x2 + 36x – 48 on the
set A ={x|x2 + 20 9x} is
(A) –16
(B) –7
(C) 16
(D) 7

40) A triangular park is enclosed on two sides by a fence and on the third side a straight river bank.
The two sides having fence are of same length x. The maximum area(in sq. units) enclosed by the
park is

(A)

(B)

(C)

(D)
 ANSWER KEYS

PHYSICS

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D A B B C B A D D C C B A A A A B A A B
Q. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
A. A C D B A C A B B A C D B C C C C C A B

CHEMISTRY

Q. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A. B B A C A A D C A D C C D D C A A D A D
Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. C D B A C A B C D C B B B D A C A D C C

MATHEMATICS

Q. 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
A. A C C D A B B C C C B D A C A A A A B D
Q. 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
A. A C C A B A C D C A D C A D B B A A D C
 SOLUTIONS

PHYSICS

1)
8 (x) = 12(40 – x)
2x = 120 – 3x ⇒ 5x = 120 ⇒ x = 24 cm.

2)

∴ for 2ℓ length R = 40Ω

Now

3) Using i = neAvd

100 × 10–3 = .....(1)

200 × 10–3 = .....(2)

On Solving ; v' = 8v.

4)

⇒ .
5)

I=
VT = E – Ir
=10 – 2 (1)
= 8V.

6)

VT = E – Ir
=10 – 2 (1)
= 8V

7)
6Ω is short circuit

8) Ia = 2 = 10–3 A

V = Ig (G + H)
10 = 10–3 (2000 + H)
H = 104 – 2000 = 8000 Ω
9) For power to be maximum on :
Fixed Resistance, variable resistance is zero.
⇒ Current is maximum.
⇒ Power is maximum.

10)

11)

12) Let Resistance added be R1.

(1)
⇒ R1 < R
R1 < R1

(2)
⇒ R2 < R
R2 < R1

13) % change = 300%

R1 = 4R.

14)
Re-Draw

15)

16) Current remain unchanged in Non-uniform cross section metallic.

Conductor where as,

17) ⇒

18)

So voltage drop across 60 W bulb = 220 ×

= 137.5 V
> 110 V
So 60 W bulb will fuse
Hence option (1) is correct.

19) then

R= ⇒ R=
2
⇒ 4R + R = 4R + 2(4 + R)
⇒ R2 + 4R – 6R – 8 = 0
⇒ R2 – 4R + 2R – 8 = 0
⇒ R = 4 or R = –2
Hence option (1)

20)

Capacitance depends only on

(1) Shape
(2) Size
(3) Medium

21) Balanced wheat stone bridge

Ceq = 2μF

22)

(Ceq)AB =

23)
As slab is drawn out, capacitor decreases & hence potential increases. When slab is completely
drawn out, potential becomes constant.
∴

24) When switch is connected to point 1,

u = (3u) v2
when switch is connected to point 2, energy dissipated across 8 μF will be,

Δu =

∴ % loss of energy =

25) When a capacitor is charged by connecting a battery across it's plates, the initial energy
stored is :

Now, the battery is disconnected, charge remains constant and another identical capacitor
connected in parallel.
∴ Ceq = C + C = 2C

∴ Final stored energy = u' =

26) ≡

∴ V1 = 5V2

27) Explanation :
We need to find the potential at point B, in the given circuit.

Concept :
Potential distribution across capacitor in circuit.

Solution :
Infact, we are given two capacitors of capacitance 20μF each, connected in series, with total
potential difference (P.D.) = (3000 – 1000) = 2000 volt. This (P.D.) will distribute equally (as
capacitance is same) ⇒ P.D. = 1000 volt each.
⇒ VB (1000 + 1000) = 2000 Volt
[Or in other words, VB = 3000 – 1000 = 2000 volt]

Final Answer :
Option (1)

Final Answer :
Option (1)

28)

Question Asking About:

Two capacitor are connected in series. find charge on the c capacitor.

Key Concept:
Charge on series connection of capacitor in same.

Formula
Q = CV

capacitor in series =

Solution/Explanation/Calculation:
Q = 4μf × 10V
Q = 40μC

Conclusion:
Hence, option (2) is correct.

Estimated Time : 1-2 minutes

Level : Easy

29) Concept :
Charged on capacitor.

Formula :
Q = C × Veffective
where:
C = 4μF
Veffective = (20V – 10V) = 10V,
Since both the cells tends to charge oppositely.

Calculation :
Q = 4 × 10 = 40 μC

Final Answer : (2) 40 μC

30) 1. Explanation of Question

The question asks where the energy stored in a charged capacitor resides. We need to identify
whether it's in the electric field, the magnetic field, both, or neither.

2. Concept : Energy Storage in Capacitors.

3. Formula
There are no formula needed for this conceptual question.

4. Mathematical Calculation (if any)

There are no mathematical calculations needed for this conceptual question.

The energy stored in a capacitor is due to separate charge and create and electric field
between the capacitor plates.

5. Correct Answer with Option; 1. (the electric field only.)

6. Estimate Time. Total estimated time:30 sec.

7. Level- Easy

31)

Concept:
• Capacitance C is defined as the charge stored per unit potential difference

• The SI unit of capacitance is farad (F)

Formula:

Calculation :
From the formula, the correct unit of farad is :

Thus, the correct answer is Option 3: Coulomb/Volt

32) Concept:
• Charge is conserved when capacitors are connected.
• The total charge before connection equals the total charge after connection,
Formula:
Total initial charge:
Qinitial = C1V1 + C2V2
Final common potential:

Calculation:
By using the charge conservation equation:

Thus, the correct answer is Option 4

33) Question Asking About:

We need to select best open that explains, "fringing of the field".

Concept :
Fringing of electric field (parallel plate capacitor)

Solution :

Figure :
Note : Fringing of electric field lines is the phenomenon, where the field lines deviate from the
ideal parallel lines between the plates of parallel plate capacitor, bending outwards towards
the edges of the plates.

Final Answer :
 Option (2)

34)

⇒F∝

35)

⇒
⇒ C = 8μF

36) Charge flow in series is same on all three capacitors.

37)

38)

When the two capacitors charged to same potential are connected in series, then total
potential difference
V' = V1 + V2 = V + V = 2V

39) When a charged capacitor of capacitance C1 is connected in parallel to an uncharged

capacitor of capacitance C2, the charge is shared between them till both attain the common
potential which is given by, common potential

40) Capacitor → open ; I = = 0.2 A

Apply KVL to find Potential difference

CHEMISTRY

41)

[A]t = [A]0 – Kt
= 0.3 – 10–2 × 10
= 0.2 M
42) A → B
a 0
a–x x
X = Kt = 0.025 × 40 = 1M
∴ a – x = 2 – 1 = 1M

43)

Incomplete information.

44)

R —→ P
For second order reaction n = 2
For order reaction

For half life At’ =

Conc. reduce to one forth

⇒ 3 times.

45) r = Knet [O3]2 [O2]–1

46)

Step 1:

.......... (i)

Step 2:
Rate =

Rate =
∴ Order = (2) + (–1) = 1

47) H2O :

K=
K×t = a – (a–x)
(a–x) = a – Kt
y = c + mx
∵ slope = –ve
Intercept = –K

48)

For elementry reaction order and molecularity of reaction will be same

49)

In k = In A –

logk = logA –

logk = 15 –
log A = 15
A = 1015

Ea =

50)

Activation energy of reverse reaction :

(Ea)Reverse = Ea + (–Er)
= 1640 + (120)
= 1640 + 120
= 1760 KJ/mole

51)
= k [N2O5]

52) Explanation:
Need to find t1/4 for first order reaction.

Concept:

for t1/4,

Hence, option (3) is correct.

53)
= k1 [A] – k2

54)

For 1st order reaction

Using condition,

t = 20
55)

56)

Let, m and n is the order of reaction w.r.t. A2 and B respectively.

So,
Now : from given data,
1 × 10–2 M/s = k[0.1]m[0.2]n …(1)
2 × 10–2 M /s = k[0.2]m[0.2]n …(2)
8 × 10–2 M /s = k[0.2]m[0.4]n …(3)
Divide (2) by (1) we get
2m = 2, ⸫ m = 1
Similarly divide (3) by (2) we get
4 = 2n , 22 = 2n
⸫n=2

57)

A. Question Explanation:

We are given a graph of log(t50%) versus log(concentration of reactant A) for a chemical

reaction. We need to determine the order of the reaction and the relationship between the
half-life (t50%) and the initial concentration of the reactant.

B. Given Data:

A. Graph: log(t50%) vs. log(concentration of A)

C. Concept:

A. Order of Reaction

D. Mathematical Calculation:

A. For a zero-order reaction: t50% ∝ [A]₀

A. Taking the logarithm of both sides: log(t50%) = log([A]₀) + constant

B. This results in a linear graph with a slope of 1.

 B. For a first-order reaction: t50% is independent of the initial concentration.

A. Therefore, the graph of log(t50%) vs. log([A]₀) would be a horizontal line (slope =
0).

C. For a second-order reaction: t50% ∝ 1/[A]₀

A. Taking the logarithm of both sides: log(t50%) = –log([A]₀) + constant

B. This results in a linear graph with a slope of –1.

D. For a nth-order reaction: t50% ∝ 1/[A]₀(n–1)

A. The slope of the log(t50%) vs. log([A]₀) graph will be -(n–1).

E. Final Answer:

A. Order of Reaction: Since the graph is linear with a slope of 1, the order of the reaction
is zero.

Relationship between t50% and Rate Constant: For a zero-order reaction, t50% is directly
proportional to the initial concentration of the reactant.
The rate constant (k) is related to t50% by the following equation:

t50% = [A]₀ / 2k

58)
.... (1)

..... slow step (RDS)

From (1)

Order of reaction is 3

59) N2O5 —→2NO2 + O2

log k = log A –

given log k vs have slope, = –5000

60) Fraction of active molecule = = 10–6

= ln10–6 = 2.303 log 10–6

Ea = 6 × 2.303 × 2 × 10–3 × 400 = 11.05 kcal.

61)
r = k[A]m[B]n
Exp-1 ; 2 × 10–2 m/sec = k[4 × 10–2 m]m [4 × 10–2]n ...(i)
Exp-2 ; 4 × 10–2 m/sec = k[4 × 10–2 m]m [8 × 10–2]n ...(ii)
Exp-3 ; 2 × 10–2 m/sec = k[2 × 10–2 m]m [8 × 10–2]n ...(iii)

By

By
So, rate,

r = k[A][B] = –

62) A(g) —→ P(s)

If
⇒ –1= 1 – n
⇒n=2

63) 2C + D → A + E ; rate =
If [C] is very large → act as constant
rate = k’[D] ; k’ = k[C]2
So, it becomes 1st order

64) For 1st order reaction

AT temp T ; ____(1)

At temp T’ ; _____(II)

65) given (t1/2)zero = (t1/2)1st

0
{a Initial concentration}

Initial rate,

66) A + 2B → P
at t1 1.0 M 1.0 M
at t2 1.0 – 0.25 1.0 – 0.5
= 0.75 M = 0.5 M
∴ r2 = 2.25 × 10–2 M/min

67)

68) The concept of molecularity is valid only for elementary reactions.

69)

Hence

70) Theoretical.

71) , rate constant does not depend on concentration of reactant.

, half life does not depend on concentration of reactant for first order reaction.

72)

Ea = 55.14 kJ/mol

73)
at T → ∞
r = A = 6 × 1014s–1

74) for a first order reaction,

n(a – x) = (–k)t + n(a)

⇒
 ⇒ (A) is correct

&
⇒ (C) is correct.

75) from the unit of rate constant, we can infer that the order = 1
⇒ rate ∝ [A]
⇒ rate will get tripled upon tripling the concentration of reactant

76) For a first order reaction = rate = k.pA

⇒ order of rate = atm/sec

77) ⇒ rate = [A]° = k

⇒ zero order reaction

78) P1 = 500, (t1/2)1 = 235

⇒n–1=2⇒

79) ΔH = Eaf – Eab

–90 = Eaf – 2Eaf
Eaf = 90 kJ/mole, Eab = 180 kJ/mol

0
80) ; N = N e(–kt)

∴ is not correct

MATHEMATICS

81)
Given f(x) =

f'(x) = – + cosx

∵ <x< ⇒ < cosx < 1

⇒ 0 < – + cosx <

∴ Function is increasing in the given interval

82)

f(x) = 2x3 – 3x2 – 36x + 6

f'(x) = 6x2 – 6x – 36 & f''(x) = 12x – 6
Now f'(x) = 0 ⇒ 6(x2 – x – 6) = 0
⇒ (x – 3) (x + 2) = 0 ⇒ x = –2, 3
f''(–2) = –30
∴ x = –2 is a point of local maximum
f''(3) = 30
∴ x = 3 is a point of local minimum
Hence, (–2, 3) is the required ordered pair.

83)

y = xex ⇒ = xex + ex

and = xex + 2ex

Now, = 0 ⇒ ex(x + 1) = 0
⇒ x = –1 [∵ ex > 0, ∀ x]

and = e–1 (–1 + 2) > 0, at x = – 1

Therefore ; x = –1 is a point of minima

84) x = a (1 + cos θ), y = a sin θ

and

Now,

∴ Slope of normal = = tan θ

Equation of normal at θ is
y – a sinθ = tanθ{x – a(1 + cosθ)}
Clearly the line passes through (a, 0)

85) Equation of the curve is y2 = 4x Differentiating both sides w.r.t. x, we get

Slope of the line y = x + 1 is 1.

Since the line y = x + 1 is a tangent to the curve y2 = 4x,
∴ Slope of the tangent to the curve at (x, y) = slope of the line

Substituting y = 2 in y2 = 4x, we get 22 = 4x

⇒ x=1
Hence, the required point is (1, 2)

86) Let (h, k) be any point on the parabola y = x2.

Let D be the required distance between (h, k) and (0, c). Then

D= …(1)
Since (h, k) lies on the parabola y = x , we have k = h2. So (1) gives
2

D ≡ D(k) =

or D'(k) =
Now D'(k) = 0

gives k =

Observe that when k < , then 2(k – c) + 1 < 0, i.e., D'(k) < 0. Also when k > , then

D'(k) > 0. So, by first derivative test, D(k) is minimum at k = . Hence, the required
shortest distance is given by

87)

Two curves intersect orthogonally if

..... (i)
Now eliminating y from the given equations we have
...... (ii)

Eliminating from (i) and (ii), we get

88)

Let y = x(1 – x2)

⇒ = (1 – x2) – 2x2 = 1 – 3x2

and = – 6x

Now ; =0⇒x=±

Now, at x = ; <0

Therefore ; y is maximum at x =

89)

Let f(x) = x + sin2x

⇒ f'(x) = 1 + 2 cos2x and
f"(x) = – 4sin2x
Now, f'(x) = 0 ⇒ cos2x = –1/2
⇒ 2x = 2π/3, 4π/3, ..........
⇒ x = π/3, 2π/3

But f"(π/3) = –4 <0

∴ f(x) is maximum at x = π/3 and its one maximum value is :

π/3 + sin(2π/3) ⇒ π/3 +

90)

x = t2 + 3t – 8

⇒ = 2t + 3
and y = 2t2 – 2t – 5

⇒ = 4t – 2

∴ = ......(1)
Since (2, –1) is a point on the curve, therefore
2 = t2 + 3t – 8
⇒ t = –5, 2
and –1 = 2t2 – 2t – 5
⇒ t = 2, –1
Thus ; t = 2
Now, slope of tangent at the given point = = from (1))

91) We have s = 5 + 20t – 2t2

Now,
Acceleration

∴ The acceleration is –4 units.

92) We have,

for
∴ f(x) is increasing on

93) We have, ,

Thus, given function is decreasing for all

94) Let
Then,
For a maximum or minimum, we have

But, this equation give imaginary values of x.

So, for any real value of x.
Hence, f(x) does not have a maximum or minimum.

95) Let b be the height of the cylinder of given surface area S. Then,

Let V be the volume of the cylinder. Then,

For maximum or minimum, we have

Also, for all r.
Hence, V is maximum when r = h.

96)

97)

=
=

98)

99)

=
= +C

100)

101)

102)

103)
=

104)

105)
Let

106)
107)

108)

As f(0) = 0,

109)
110)

Let sin x + 8 cos x = K(4 sin x + 6 cos x) + L(4 cos x 6 sin x)

Then, and

+C

111)

112)
Let x3 = t

Then

......... (replacing the value of x3 & dx)

113)

114)

115)
116)

p(-2,0),
Then a+b+c = ?

….(1)
3=c
Put in equation (1)
12 a – 4b + 3 = 0 ….(2)
0 = -8a + 4b – 2c + 5
-8a + 4b = 1 …..(3)
12a – 4b = -3
4a = -2

Put in (2)

4b = -3

117)

Given that the extreme value at

…(1)

….(2)
….(1)
6b = - 3

a=1+1
a=2

a+b
118)

…… [Given]

So,
So, the function is strictly increasing function

119)

Function is increasing in

Maximum value of function is at x = 5

120)

Step 1: Find the relation between angle and side:

Assume the two equal sides AB and AC have length x.
Also, assume
Draw a perpendicular line AD.
So, and
Step 2 : Find the area of the smaller triangle:
Use the area of triangle formula to find the area of

Step 3 : Find the area of the whole triangle:

Use the obtained area to get the area of the bigger triangle.

Find the area of using the above relation.

Step 4: Maximize the area of :

Maximize the area of the triangle by maximizing .
Maximum value of

So, maximum value of

Hence, option (C) is the correct answer