BAKLIWAL TUTORIALS
GOC Assignment TOPIC: RESONANCE (Basic part)
PART-A OBJECTIVE QUESTIONS
1. The notation for relating two resonating structures is :
(A) (B) (C) (D)
2. Resonance is delocalisation of :
(A) electrons (B) electrons (C) electrons (D) None
3. Resonance effect involves :
(A) Delocalization of –electrons along a conjugated system.
(B) Delocalization of lone pair along a conjugated system.
(C) Delocalization of negative charge along a conjugated system.
(D) All are correct.
4. During delocalization, which statement is incorrect :
(A) Net charge remains same
(B) Number of paired electrons remain same
(C) Number of unpaired electrons remain same
(D) Energy of resonating structures always remains same
5. Which of the following statements is incorrect ?
(A) The energy of resonance hybrid is always less than that of any resonating structure.
(B) The resonance energy is the difference between the enthalpies of formation of the molecule and the
resonating structure having maximum energy.
(C) The resonance structures are hypothetical structure and they do not represent any real molecule.
(D) In delocalized structure of benzene the -charge cloud is spread equally above and below the plane
of molecule.
6. Which of the following statement regarding resonance is NOT correct ?
(A) the different resonating structures of a molecule have fixed arrangement of atomic nuclei.
(B) the different resonating structures differ in the arrangement of electrons.
(C) the hybrid structure has equal contribution from all the resonating structures always.
(D) None of the individual resonating structure explains all characteristics of the molecule.
7. Resonance structure of the molecule does not have
(A) higher energy than their hybrid structure.
(B) identical arrangement of atoms.
(C) the same number of paired electrons.
(D) always equal contribution to the resonance hybrid.
8. Which of the following compounds have delocalized electrons ?
O
||
(P) CH2 CHCCH3 (Q) (R) (S) CH3CH2NHCH = CHCH3
9. Among the given sets, which represents the resonating structure ?
(A) and (B) and
(C) and (D) and
10. In which of the following resonance is not possible?
(A) CH2 = C = CH2 (B) CH2 = C = CH (C) CH2 = C = CH (D) CH2 = C =
11. What is NOT-True for inductive effect but True for Resonance effect (During their functioning)
(Inductive effect) (Resonance effect)
(A) electron pair is delocalised -electron pair delocalized
(B) electron pair is localized -electron pair is localized
(C) Bond angle does not change -electron pair is localized
(D) Hybridisation of atoms changes -electron pair is localized
12. In which delocalisation of positive charge is possible ?
–
NH H H OH O
3 2
N
(A) (B) (C) (D)
13. Resonance stabilized cation is :
(A) (B) (C) (D)
14. The correct number of p-electrons have been mentained in :
(A) ; (4) (B) ; (6)
(C) ; (3) (D) ; (6)
15. Which of the hybrid species are correct?
(A) (B)
(C) (D)
16. Which of the following species can not show resonance?
(A) (B) (C) (D)
17. Resonance is not possible in :
(A) (B) (C) CH2=CH–Cl (D)
18. Which does not have conjugate system ?
(A) CH2 = CHCl (B) CH2 = CHCHO (C) CH3CH = CH 2 (D)
19. The compound which is not resonance stabilised
(A) CH2=CH–Cl (B) (C) CH2=CH–CH2–Cl (D)
20. Which of the following is not acceptable as resonating structure :
(A) (B) (C) (D) None of these
21. Which of the following pair is not pair of resonating structures?
(A) & (B) CH2 = CH – O– & CH2 – CH O
(C) CH2 = CH – O – CH3 & CH2 – CH O– CH3 (D) CH3 – C O & CH3 – C O
22. Which of the following structures constitute resonance structures ?
(A) & CH3 – O – N = O (B) &
(C) (CH3)2 CO & (D) CH3 – CH = CH – CH3 & CH3 – CH2 – CH = CH2
23. Which statement is/are true about resonance ?
(A) It decreases the energy of system.
(B) The hybridisation of atoms do not change due to resonance
(C) Resonance hybrid is more stable than any resonating structure.
(D) Resonanting structures can not be isolated at any temperature
24. Which of the following statement is incorrect about resonance ?
(A) The most stable structure explains all the characteristics of a species.
(B) All resonating structures remain in equilibrium.
(C) Resonance hybrid has maximum similarity with most stable resonating structure.
(D) Resonance hybrid is real.
25. Polarization of electrons in acrolein may be written as :
– –
(A) C H2 CH – C H O (B) C H2 CH – C H O
– – –
(C) C H2 CH – C H O (D) C H2 CH – C H O
26. Which of the following is a conjugated system ?
(A) CH 2=CH–CH=CH2 (B) CH 2=C=CH 2
(C) CH2=CH–CH2–CH=CH2 (D) CH2=CH–CH=O
27. The acceptable resonating structure(s) of the following molecule is/are :
(A) (B)
(C) (D)
28. In which cases delocalisation of charge is possible?
– – –
(A) (B) O — P(CH3)2 (C) O — P (CH3)3 (D) O — B(CH3)2
PART-B SUBJECTIVE QUESTIONS
29. Number of electrons in resonance in the following structure is.
30. Identify the number of compounds in which positive charge will be delocalised ?
31. In how many of the following cases, the negative charge is delocalised?
.. CH3
–
..
