Conforms to Regulation (EC) No.
1907/2006 (REACH), Annex II (including amendments) - United Kingdom (UK)
SAFETY DATA SHEET
BARITE
SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.1 Product identifier
Product name : BARITE
Product code : 7402DF
Product type : Powder.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Weighting Agent
1.3 Details of the supplier of the safety data sheet
Baker Hughes Indonesia
The garden Center, 6th Floor, Suite 07
Cilandak Commercial Estate
Jl Cilandak KKO
Jakarta
Jakarta Raya 12560
Indonesia
Tel: +62 (0) 21 780 0737
Fax: +62 (0) 21 780 1682
e-mail address of person :
[email protected] responsible for this SDS
1.4 Emergency telephone number
Supplier
Telephone number : CHEMTREC Emergency Telephone Numbers (Indonesia Geomarket):
- Indonesia: 001-803-017-9114 (Bahasa Indonesian) *
-----------------------------------------------------------------
- UK: +(44) 870-820-0418
- USA: +(1) 703-527-3887 (CHEMTREC International 24 hour)
* Number can only be dialled in-country
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Directive 1999/45/EC [DPD]
The product is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Not classified.
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Carc. 1A, H350
STOT RE 2, H373
See Section 16 for the full text of the R phrases or H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms :
Signal word : Danger
Date of issue/Date of revision : 7 March 2016 1/9
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
BARITE
SECTION 2: Hazards identification
Hazard statements : May cause cancer if inhaled.
May cause damage to organs through prolonged or repeated exposure if inhaled.
(lungs)
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Use personal protective equipment as required.
Do not breathe dust or mist.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention.
Storage : Store locked up.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazardous ingredients : Quartz (SiO2)
Supplemental label : Not applicable.
elements
2.3 Other hazards
Substance meets the Not applicable.
criteria for PBT according P: Not available. B: Not available. T: Not available.
to Regulation (EC) No.
1907/2006, Annex XIII
Substance meets the Not applicable.
criteria for vPvB according vP: Not available. vB: Not available.
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : Fine dust clouds may form explosive mixtures with air. Handling and/or processing
not result in classification of this material may generate a dust which can cause mechanical irritation of the
eyes, skin, nose and throat.
SECTION 3: Composition/information on ingredients
Substance/mixture : Mixture
Classification
Product/ingredient Identifiers % 67/548/EEC Regulation (EC) No. Type
name 1272/2008 [CLP]
barium sulfate EC: 231-784-4 60 - Not classified. Not classified. [2]
CAS: 7727-43-7 100
crystalline silica, EC: 238-878-4 5 - 10 Xn; R48/20 STOT RE 1, H372 [1] [2]
respirable powder CAS: 14808-60-7
Mica-group minerals CAS: 12001-26-2 1-5 Not classified. Not classified. [2]
See Section 16 for See Section 16 for the
the full text of the R- full text of the H
phrases declared statements declared
above. above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this
section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Occupational exposure limits, if available, are listed in Section 8.
Date of issue/Date of revision : 7 March 2016 2/9
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
BARITE
SECTION 4: First aid measures
4.1 Description of first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention.
Continue to rinse for at least 15 minutes.
Inhalation : Move exposed person to fresh air. Keep person warm and at rest. If not breathing,
if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 15 minutes. Get medical attention following
exposure or if feeling unwell. Wash clothing before reuse. Clean shoes thoroughly
before reuse.
Ingestion : Wash out mouth with water. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. If vomiting occurs, the
head should be kept low so that vomit does not enter the lungs. Get medical
attention. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Exposure to airborne concentrations above statutory or recommended exposure
limits may cause irritation of the eyes.
Inhalation : Exposure to airborne concentrations above statutory or recommended exposure
limits may cause irritation of the nose, throat and lungs.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
irritation
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : No specific data.
Ingestion : No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to medical doctor : No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
Specific treatments : Not available.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable : Use dry chemical powder.
Not suitable : Do not use water jet.
5.2 Special hazards arising from the substance or mixture
Special exposure hazards : Fine dust clouds may form explosive mixtures with air.
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Date of issue/Date of revision : 7 March 2016 3/9
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
BARITE
SECTION 5: Firefighting measures
Hazardous thermal : Decomposition products may include the following materials:
decomposition products sulfur oxides
metal oxide/oxides
5.3 Advice for fire-fighters
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Additional information : Not available.
SECTION 6: Accidental release measures
6.1 Personal precautions, : If specialised clothing is required to deal with the spillage, take note of any
protective equipment and information in Section 8 on suitable and unsuitable materials.
emergency procedures
6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
6.3 Methods and materials for containment and cleaning up
Small spill : Move containers from spill area. Vacuum or sweep up material and place in a
designated, labelled waste container. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor.
Large spill : Move containers from spill area. Approach the release from upwind. Prevent entry
into sewers, water courses, basements or confined areas. Vacuum or sweep up
material and place in a designated, labelled waste container. Avoid creating dusty
conditions and prevent wind dispersal. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor. Note: see Section
1 for emergency contact information and Section 13 for waste disposal.
6.4 Reference to other : Note: see section 8 for personal protective equipment and section 13 for waste
sections disposal.
SECTION 7: Handling and storage
7.1 Precautions for safe : Put on appropriate personal protective equipment (see Section 8). Eating, drinking
handling and smoking should be prohibited in areas where this material is handled, stored
and processed. Workers should wash hands and face before eating, drinking and
smoking. Avoid breathing dust. Avoid the creation of dust when handling and avoid
all possible sources of ignition (spark or flame). Prevent dust accumulation. Use
only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Electrical equipment and lighting should be protected to appropriate
standards to prevent dust coming into contact with hot surfaces, sparks or other
ignition sources. Take precautionary measures against electrostatic discharges. To
avoid fire or explosion, dissipate static electricity during transfer by earthing and
bonding containers and equipment before transferring material.
7.2 Conditions for safe storage, including any incompatibilities
Storage : Store in accordance with local regulations. Store in a segregated and approved
area. Store in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10). Eliminate all ignition sources. Separate from oxidizing materials.
Keep container tightly closed and sealed until ready for use. Containers that have
been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabelled containers. Use appropriate containment to avoid
environmental contamination.
Recommended Packaging : Use original container.
materials
7.3 Specific end use(s) : Weighting Agent
Not available.
Date of issue/Date of revision : 7 March 2016 4/9
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
BARITE
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
barium sulfate EH40/2005 WELs (United Kingdom (UK), 12/2011).
TWA: 10 mg/m³ 8 hours. Form: inhalable dust
TWA: 4 mg/m³ 8 hours. Form: respirable dust
crystalline silica, respirable powder EH40/2005 WELs (United Kingdom (UK), 12/2011).
TWA: 0.1 mg/m³ 8 hours. Form: respirable dust
Mica-group minerals EH40/2005 WELs (United Kingdom (UK), 12/2011).
TWA: 10 mg/m³ 8 hours. Form: Inhalable fraction
TWA: 0.8 mg/m³ 8 hours. Form: Respirable fraction
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for
methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous
substances.
8.2 Exposure controls
Occupational exposure : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. Use explosion-proof
ventilation equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and
the safe working limits of the selected respirator.
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Wear suitable gloves tested to EN374.
Eye protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If operating conditions cause high dust concentrations to be
produced, use dust goggles.
Skin protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state : Solid. [Powder.]
Colour : Tan. to Grey.
Odour : Odourless.
Odour threshold : Not available.
pH : Not available.
Boiling point : Not available.
Melting point/freezing : 1580°C (2876°F)
point
Date of issue/Date of revision : 7 March 2016 5/9
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
BARITE
SECTION 9: Physical and chemical properties
Flammability (solid, gas) : May be combustible at high temperature.
Flash point : Closed cup: Not applicable.
Explosive properties : Not available.
Explosion limits : Not available.
Oxidising properties : Not available.
Vapour pressure : Not available.
Density : Not available.
Relative density : 3.8 to 3.95 (20°C)
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Viscosity : Not available.
Vapour density : Not available.
Evaporation rate (butyl : Not available.
acetate = 1)
Decomposition : Not available.
temperature
Auto-ignition temperature : Not available.
9.2 Other information
Pour point : Not available.
SECTION 10: Stability and reactivity
10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : The product is stable.
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : Avoid the creation of dust when handling and avoid all possible sources of ignition
(spark or flame). Take precautionary measures against electrostatic discharges.
To avoid fire or explosion, dissipate static electricity during transfer by earthing and
bonding containers and equipment before transferring material. Prevent dust
accumulation.
10.5 Incompatible : Not available.
materials
10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.
SECTION 11: Toxicological information
Potential acute health effects
Inhalation : Exposure to airborne concentrations above statutory or recommended exposure
limits may cause irritation of the nose, throat and lungs.
Ingestion : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Eye contact : Exposure to airborne concentrations above statutory or recommended exposure
limits may cause irritation of the eyes.
Acute toxicity
General : May cause damage to organs through prolonged or repeated exposure if inhaled.
Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Date of issue/Date of revision : 7 March 2016 6/9
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
BARITE
SECTION 11: Toxicological information
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Ingestion : No specific data.
Skin contact : No specific data.
Eye contact : Adverse symptoms may include the following:
irritation
redness
SECTION 12: Ecological information
12.1 Toxicity : No known significant effects or critical hazards.
Conclusion/Summary : No known significant effects or critical hazards.
12.2 Persistence and degradability
Conclusion/Summary : Not available.
12.3 Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Not available.
12.4 Mobility in soil : Not available.
12.5 Results of PBT and vPvB assessment
PBT : Not applicable.
P: Not available. B: Not available. T: Not available.
vPvB : Not applicable.
vP: Not available. vB: Not available.
12.6 Other adverse effects : No known significant effects or critical hazards.
SECTION 13: Disposal considerations
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Empty
containers or liners may retain some product residues. This material and its
container must be disposed of in a safe way. Significant quantities of waste product
residues should not be disposed of via the foul sewer but processed in a suitable
effluent treatment plant. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority
requirements. Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
13.2 Additional information
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers.
Date of issue/Date of revision : 7 March 2016 7/9
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
BARITE
SECTION 14: Transport information
International transport regulations
Regulatory 14.1 UN 14.2 Proper shipping name 14.3 Transport 14.4 PG* Label
information number hazard class(es)
ADR/RID Class Not - - -
regulated.
ADN Class Not - - -
regulated.
IMDG Class Not - - -
regulated.
IATA Class Not - - -
regulated.
PG* : Packing group
Regulatory 14.5 14.6 Special precautions for user Additional
information Environmental information
hazards
ADR/RID Class No. - -
ADN Class No. - -
IMDG Class No. - -
IATA Class No. - -
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Proper shipping name : Not available.
Ship type : Not available.
Pollution category : Not available.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Other EU regulations
Europe inventory : Not determined.
Black List Chemicals : Not listed
Priority List Chemicals : Not listed
15.2 Chemical Safety : This product contains substances for which Chemical Safety Assessments are still
Assessment required.
Date of issue/Date of revision : 7 March 2016 8/9
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
BARITE
SECTION 16: Other information
16.1 Revision comments : Not available.
Indicates information that has changed from previously issued version.
16.2 Abbreviations and : ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
16.3 Key literature : Not available.
references and sources for
data
16.4 Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Carc. 1A, H350
STOT RE 2, H373
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Carc. 1A, H350 Calculation method
STOT RE 2, H373 Calculation method
16.5 Full text of abbreviated : H350 - May cause cancer if inhaled.
H statements H373 - May cause damage to organs through prolonged or repeated
exposure if inhaled. (lungs)
16.5 Full text of abbreviated : R48/20- Harmful: danger of serious damage to health by prolonged exposure
R phrases through inhalation.
Full text of classifications : Xn - Harmful
[DSD/DPD]
16.6 Training advice : Not available.
16.7 Further information
Date of issue/ Date of : 7 March 2016
revision
Version : 1
Notice to reader
This information relates only to the specific material designated and may not be valid for such material used
in combination with any other materials or in any process. Such information is, to the best of the company's
knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or
representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy
himself as to the suitability of such information for his own particular use.
