Chapter 3
Conduction and Breakdown of
Solid
Solid as Insulators
Solid dielectric materials are used in all kinds of
electrical circuits and devices to insulate one current
carrying part from another when they operate at
different voltages.
The solid materials provide the mechanical support for
conducting parts and at the same time insulate the
conductors from one another.
A good dielectric should have low dielectric loss, high
mechanical strength, should be free from gaseous
inclusions, and moisture, and be resistant to thermal
and chemical deterioration.
Solid dielectrics have higher breakdown strength
compared to liquids and gases.
The
mechanism of breakdown is a complex
phenomena in the case of solids.
The various breakdown mechanisms can be
classified as follows:
intrinsic or ionic breakdown,
electromechanical breakdown,
failure due to treeing and tracking,
thermal breakdown,
electrochemical breakdown, and
breakdown due to internal discharges.
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INTRINSIC BREAKDOWN
When voltages are applied only for short durations of the order of 10 -8 S,
the dielectric strength of a solid dielectric increases very rapidly to an
upper limit called the intrinsic electric strength.
Intrinsic breakdown depends upon the presence of free electrons which
are capable of migration through the lattice of the dielectric.
Usually, a small number of conduction elections are present in solid
dielectrics, along with some structural imperfections and small amounts of
impurities.
The impurity atoms, or molecules or both act as traps for the conduction
electrons up to certain ranges of electric fields and temperatures.
When these ranges are exceeded, additional electrons in addition to
trapped electrons are released, and these electrons participate in the
conduction process.
Based on this principle, two types of intrinsic breakdown mechanisms
have been proposed.
Electronic Breakdown
Avalanche or Streamer Breakdown
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Electronic Breakdown
The initial density of conduction (free)
electrons is also assumed to be large, and
electron-electron collisions occur.
When an electric field is applied, electrons
gain energy from the electric field and cross
the forbidden energy gap from the valency to
the conduction band.
When this process is repeated, more and
more electrons become available in the
conduction band, eventually leading to
breakdown.
Avalanche or Streamer Breakdown
Conduction
electrons gain sufficient energy above
a certain critical electric field and cause liberation
of electrons from the lattice atoms by collisions.
Under uniform field conditions, if the electrodes
are embedded in the specimen, breakdown will
occur when an electron avalanche bridges the
electrode gap.
An electron within the dielectric, starting from the
cathode will drift towards the anode and during
this motion gains energy from the field and loses it
during collisions.
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When
the energy gained by an electron
exceeds the lattice ionization potential, an
additional electron will be liberated due to
collision of the first electron.
This process repeats itself resulting in the
formation of an electron avalanche.
Breakdown will occur, when the avalanche
exceeds a certain critical size.
ELECTROMECHANICAL BREAKDOWN
When
solid dielectrics are subject to high
electric fields, failure occurs due to
electrostatic compressive forces which can
exceed the mechanical compressive
strength.
If the thickness of the specimen is d and is
compressed to a thickness d0 under an
applied voltage V, then the electrically
developed compressive stress is in
equilibrium if
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THERMAL BREAKDOWN
When an electric field is applied to a dielectric, conduction current, however
small it may be, flows through the material. The current heats up the
specimen and the temperature rises. The heat generated is transferred to
the surrounding medium by conduction through the solid dielectric and by
radiation from its outer surfaces.
Equilibrium is reached when the heat used to raise the temperature of the
dielectric, plus the heat radiated out, equals the heat generated. The heat
generated under d.c. stress E is given as
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Chemical and Electrochemical
Deterioration
In the presenceand
of airBreakdown
and other gases some
dielectric materials undergo chemical
changes when subjected to continuous
electrical stresses.
Oxidation: In the presence of air or oxygen, materials such as
rubber and polyethylene undergo oxidation giving rise to surface
cracks
Hydrolysis: When moisture or water vapour is present on the
surface of a solid dielectric, hydrolysis occurs and the materials
lose their electrical and mechanical properties. Electrical
properties of materials such as paper, cotton tape, and other
cellulose materials deteriorate very rapidly due to hydrolysis.
Plastics like polyethylene undergo changes, and their service life
considerably reduces.
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Chemical Action: Even in the absence of electric fields, progressive
chemical degradation of insulating materials can occur due to a
variety of processes such as chemical instability at high
temperatures, oxidation and cracking in the presence of air and
ozone, and hydrolysis due to moisture and heat. Since different
insulating materials come into contact with each other in any
practical apparatus, chemical reactions occur between these
various materials leading to reduction in electrical and mechanical
strengths resulting in failure.
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Tracking
Tracking is the formation of a permanent conducting
path, usually carbon, a surface of insulation and in
most cases the conduction path results from
degradation of the insulation. For tracking to happen,
the insulator must contain some organic substance on
the surface.
In an outdoor environment insulation will in time
become covered with contaminant which may be of
industrial or coastal origin. In the presence of moisture
the contamination layer gives rise to leakage current
which heats the surface and causes interruption in the
moisture film; small sparks are drawn between the
separating moisture films.
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This process acts effectively as an extension to the
electrodes. The heat resulting from the small sparks
causes carbonization leads to formation of permanent
carbon track on the surface.
The spreading of carbon track in the form of the
branches of a tree is called treeing
Treeing occurs due to the erosion of material at the tips
of the spark.
Erosion results in the roughening of the surfaces, and
hence becomes a source of dirt and contamination. This
causes increased conductivity resulting either in the
formation of a conducting path bridging the electrodes
or in a mechanical failure of the dielectric.
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System for study of treeing phenomena. 1 and 2 are electrodes
The voltage V1 across the air gap is given as
Since 2 > 1, most of the voltage appears across the air
gap
Sparking will occur in the air gap and, charge
accumulation takes place on the surface of the insulation.
Sometimes the spark erodes the surface of the insulation
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Treeing
can be prevented by having clean,
dry, and undamaged surfaces and a clean
environment. The materials chosen should be
resistant to tracking. Sometimes moisture
repellant greases are used. But this needs
frequent cleaning and regreasing.
Increasing creepage distances should
prevent tracking, but in practice the presence
of moisture films defeat the purpose.
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Breakdown Due to Internal Discharges
Solid insulating materials contain voids or
cavities within the medium or at the
boundaries between the dielectric and the
electrodes.
The permittivity of the filling medium is
frequently lower than that of the solid
insulation, which causes the field intensity in
the cavity to be higher than in the dielectric.
Therefore, even under normal working
voltages, the field in the voids may exceed
their breakdown value.
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When the applied voltage is V, the voltage across the void, F1 is given
Where t and d are the thickness of the void and the dielectric, respectively,
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Under an applied
voltage Va when Vc
reaches breakdown
value Vc of the gap t,
the cavity may break
down.
The dotted curve shows qualitatively the voltage that would appear across the
cavity if it did not break down. As Vc reaches the value V+, a discharge takes place,
the voltage Vc collapses and the gap extinguishes.
The voltage across the cavity then starts increasing again until it reaches VC,
when a new discharge occurs.
On decreasing the applied voltage the cavity discharges as the voltage across it
reaches V-.
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When
the breakdown occurs in the voids, electrons and
positive ions are formed. They will have sufficient energy
When they reach the void surfaces, they may break the
chemical bonds.
Also, in each discharge there will be some heat
dissipated in the cavities, and this will carbonize the
surface of the voids and will cause erosion of the
material.
Channels and pits formed on the cavity surfaces
increase the conduction.
The net effect is a slow erosion of the material and a
consequent reduction of the breakdown strength of the
solid insulation.
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SOLID DIELECTRICS USED IN PRACTICE
They
can be broadly classified into three
groups:
Organic materials,
Inorganic materials
Synthetic polymers.
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Organic materials
Organic
materials are made from vegetable
or animal matter and all of them have similar
characteristics.
They are good insulators and can be easily
used for many practical applications.
Their mechanical and electrical properties
always deteriorate rapidly when the
temperature exceeds 100 0C.
Examples, paper and press board used in
cables, capacitors and transformers.
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Inorganic materials
Inorganic
materials are most stable in their
electrical and mechanical properties when
the temperature is almost up to 250 0C.
Important inorganic materials used for electric
applications are glasses and ceramics.
They are widely used because of their
resistance to atmospheric pollutants and their
excellent performance under varying
conditions of temperature and pressure.
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Synthetic polymers
Synthetic
polymers possess excellent insulating
properties and can be easily fabricated and
applied to the apparatus
These are generally divided into two groups,
Thermoplastic
Thermosetting plastic
They
are very flexible and can be moulded and
extruded at temperatures below their melting
points
They are widely used in bushings, insulators
etc.
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Paper
Kraft
paper is the type of paper used for
insulation purposes.
Low-density paper (0.8 gms/cm3) is preferred in
high frequency capacitors and cables, while
medium density paper is used in power
High-density papers are preferable in d.c. and
energy storage capacitors and for the insulation
of d.c. machines.
Paper is hygroscopic. It has to be dried and
impregnated with impregnants, such as mineral
oil, chlorinated diphenyl and vegetable oils.
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The
relative dielectric constant of
impregnated paper depends upon the
permittivity of cellulose of which the paper is
made, and permittivity of the impregnant and
the density of the paper
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Fibres
Fibres
when used for electrical purposes will
have the ability to combine strength and
durability with extreme fineness and flexibility.
Example, cotton, jute, flax, wool, silk (natural
fibres), rayon, nylon, terylene, teflon and
fibreglass.
Cotton
Bundles of jute
Flax
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Most of the perfectly-dried fibres have a dielectric constant between 3 and 8.
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Mica and Its Products
Mica
is the generic name of a class of
crystalline mineral silicates of alumina and
potash.
It can be classified into five main groups: (i)
muscovite, (ii) phlogopite, (iii) fibiolite, (iv)
lipidolite, and (v) Zinnwaldite
Mica sheet
Mica flakes
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Rock with mica
Fibiolite
and lipidolite are not suitable to be insulators
because they are bristle and hard.
It has a unique combination of electrical properties,
High dielectric strength,
Low dielectric losses,
Resistance to high temperatures
Good mechanical strength.
Very
pure mica is used for high frequency
applications.
Spotted mica is used for low voltage insulation, such
as for armature windings, switchgear, in electrical
heating and cooling equipments.
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Glass
Glass is a thermoplastic inorganic material
comprising complex systems of oxides (SiO2).
The dielectric constant of glass varies from 3.7 to 10
The density varies from 2.2 to 6 g/cm 3
At room temperature, the volume resistivity of glass
varies from 1012 to 1020 ohm-cm.
The dielectric loss of glass varies from 0.004 to
0.020 depending on the frequency.
Glass is used as a cover and for internal supports in
electric bulbs, electronic valves, mercury arc
switches, x-ray equipment, and capacitors.
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Ceramics
Ceramics
are inorganic materials produced
by combining minerals into monolithic bodies
by high temperature heat treatment.
Low permittivity ceramics (r< 12) are used as
insulators, while the high permittivity
ceramics (r > 12) are used in capacitors and
transducers.
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Rubber
Rubber
is a natural or synthetic vulcanizable
high polymer having high elastic properties.
General impurities, chemical changes due to
ageing, moisture content and variations in
temperature and frequency have substantial
effects on the electrical properties of rubber.
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Plastics
Plastics
are very widely used as insulating
materials because of their excellent dielectric
properties.
Polyethylene
Fluorocarbon Plastics
Nylon
Polyvinyl Chloride
Polyesters
Polystyrenes
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Polyethylene
Polyethylene
is a thermoplastic material
which combines unusual electrical properties,
high resistance to moisture and chemicals,
easy processability, and low cost.
It has got high resistivity and good dielectric
properties at high frequencies, and therefore,
is widely used for power and coaxial cables,
telephone cables, multi-conductor control
cables, TV lead-in wires, etc.
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Fluorocarbon Plastics
Types of Flourocarbon Plastics are
Polytetrafluoroethylene (P.T.F.E.),
polychlorotrifluoroethylene (P.C.T.F.E.) and
polyvinylidene (P.V.F2) plastics.
P.T.F.E. is the most thermally stable and chemically
resistant of all the three. It is considered as one of
the best plastics used for insulation because of its
excellent electrical and mechanical properties.
P.C.T.F.E. has higher dielectric constant and loss
factor than P.T.F.E., but melts at 1900C.
P.V.F2 can be worked in the temperature range
-300C to 1500C.
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Nylon
Nylon
is a thermoplastic which possesses high
impact, tensile, and flexural strengths over a
wide range of temperature (0 to 3000C).
It also has high dielectric strength and good
surface and volume resistivities even after
lengthy exposure to high humidity.
It is also resistant to chemical action, and can be
easily moulded, extruded and machined.
It is generally recommended for high frequency
low loss applications.
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Polyvinyl Chloride
Polyvinyl chloride or P. V.C. is used commercially in
various forms.
It is available as an unplasticized, tough, and rigid
sheet material and can be easily shaped to any
required form.
It is chemically resistant to strong acids and alkalis and
is insoluble in water, alcohol and organic solvents like
benzene.
The upper temperature limit of operation is about 60 0C.
The dielectric constant and loss tangent are 3.0-3.3
and 0.015-0.02 respectively, at all frequencies up to 1
MHz.
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Polyesters
Polyesters have excellent dielectric properties and
superior surface hardness, and are highly resistant
to most chemicals.
Unsaturated polyesters are used in glass laminates
and glass fibre reinforced mouldings. They are
widely used for making small electrical components
to very large structures.
Saturated polyesters are used in producing fibres
and film. Polyester fibre is used to make paper, mat
and cloth for electrical applications.
The film is used for insulating wires and cables in
motors, capacitors and transformers.
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Polystyrenes
Electrical grade polystyrenes have a dielectric
strength comparable to that of mica, and have low
dielectric losses which are independent of the
frequency.
Their volume resistivity is about I019 ohm-cm and the
dielectric strength is 200-350 kV/cm. The dielectric
constant at 2O0C is 2.55, and the loss tangent is
0.0002 at all frequencies up to 10,000 MHz.
Polystyrene films are extensively used in the
manufacture of low loss capacitors.
Films and drawn threads of polystyrene are also
used for high frequency and cable insulations.
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