13000

FT XS 1.raw
PDF 01-072-1474 Co O Cobalt Oxide
PDF 01-078-1970 Co3 O4 tricobalt tetraoxide | Cobalt Oxide
12000 PDF 03-065-2992 K2 O Potassium Oxide
PDF 00-001-1307 Al2 O3 γ-Al2 O3 | Aluminum Oxide

11000

10000

9000

8000
Counts

7000

6000

5000

4000

3000

2000

1000

0
10 20 30 40 50 60 70 80 90

2Theta (Coupled TwoTheta/Theta) WL=1.54060

Yes 0 PDF 01-072-1474 Pattern List #9 FT XS 1.raw #1 PDF 01-072-1474 Cobalt Oxide Co O Indexed 28.8555 %
tricobalt tetraoxide | Cobalt
Yes 1 PDF 01-078-1970 Pattern List #9 FT XS 1.raw #1 PDF 01-078-1970 Co3 O4 Blank 88.8113 %
Oxide
Yes 2 PDF 03-065-2992 Pattern List #9 FT XS 1.raw #1 PDF 03-065-2992 Potassium Oxide K2 O Indexed 7.6572 %
Yes 3 PDF 00-001-1307 Pattern List #9 FT XS 1.raw #1 PDF 00-001-1307 γ-Al2 O3 | Aluminum Oxide Al2 O3 Low precision 32.4702 %

3.160 15.27 % 1.0000 Yes 1.54060 Monoclinic C2/m (12) 5.18000 3.01500 3.01700 125.550
5.290 28.07 % 1.0000 Yes 1.54060 Cubic Fd-3m (227) 8.08500
5.390 2.38 % 1.0000 Yes 1.54060 Cubic Fm-3m (225) 6.44900
(1) 54.29 % 1.0000 Yes 1.54060

2 38.34 6.491 No F26= 27.6(0.0185, 51)

8 528.49 6.053 No F30= 999.9(0.0002, 30)
4 268.21 2.333 No F22= 999.9(0.0004, 22)
0.00 3.380 No
 Co O
Cobalt Oxide 2.45213 36.617 858 -2 0 1
2.45213 36.617 858 1 1 0
2.13263 42.347 999 -1 1 1
2.10725 42.883 481 2 0 0
1.50850 61.413 187 0 2 0
1.50850 61.413 187 -2 0 2
1.49961 61.817 308 1 1 1
1.49828 61.878 308 -3 1 1
Monoclinic 74.93 1.28526 73.644 131 -2 2 1
C2/m (12) 38.34 1.28526 73.644 131 -1 1 2
6.49 1.27338 74.447 61 -4 0 1
1.27338 74.447 61 3 1 0
3.160
1.22606 77.846 127 -4 0 2
5.18000 1.22606 77.846 127 2 2 0
3.01500 125.55 1.06632 92.504 41 -2 2 2
3.01700 0
1.05362 93.957 19 4 0 0
1.71808
2 0.97759 103.990 17 1 3 0
1.00066
0.97759 103.990 17 -4 0 3
0.97312 104.666 28 -5 1 2
0.97312 104.666 28 2 2 1
0.95399 107.694 37 -1 3 1
0.95399 107.694 37 -3 1 3
0.95178 108.061 33 0 2 2
ANX: AX
Analysis: Co1 O1 0.95110 108.173 32 -4 2 2
Formula from original source: Co O 0.94496 109.208 31 3 1 1
ICSD Collection Code: 17013
0.94429 109.321 30 -5 1 1
Calculated Pattern Original Remarks: Probably tetragonal, pseudo-cubic,
cf. 28505 0.86947 124.735 26 -1 1 3
Cell in I12/m1-setting: a`=4.214, beta`=90.07 0.86857 124.963 55 -3 3 1
Minor Warning: No e.s.d reported/abstracted on the cell dimension. No R
factors reported/abstracted 0.86857 124.963 55 -5 1 3
Wyckoff Sequence: d a(C12/M1) 0.86430 126.061 13 2 0 2
Unit Cell Data Source: Single Crystal
0.86360 126.242 25 -6 0 2
0.86360 126.242 25 4 2 0
0.82027 139.794 23 -3 3 2
0.82027 139.794 23 -4 2 3
0.81822 140.588 5 0 0 3
0.81738 140.919 11 -6 0 3
0.81738 140.919 11 3 3 0
0.81177 143.213 11 -6 0 1
0.81177 143.213 11 5 1 0
Structure
Publication: J. Phys. Soc. Jpn.
Detail: volume 21, page 850 (1966)
Authors: Saito, S., Nakahigashi, K., Shimomura, Y.
Primary Reference
Publication: Calculated from ICSD using POWD-12++

CuKα1 Not specified

1.54060
27.6 (0.0185,51)
 Co3 O4
Cobalt Oxide 4.66788 18.997 13 1 1 1
2.85848 31.267 280 2 2 0

tricobalt tetraoxide 2.43772 36.841 999 3 1 1

2.33394 38.543 81 2 2 2
2.02125 44.804 176 4 0 0
1.85483 49.076 30 3 3 1
1.65034 55.647 76 4 2 2
1.55596 59.348 216 5 1 1
Cubic 240.8 1.42924 65.225 314 4 4 0
Fd-3m (227) 528.49 1.36661 68.618 2 5 3 1
6.05 1.34750 69.731 1 4 4 2
1.27835 74.109 23 6 2 0
5.290
1.23295 77.329 65 5 3 3
8.08500 1.21886 78.393 33 6 2 2
1.16697 82.613 17 4 4 4
1.13213 85.750 3 7 1 1
1.00000 8
1.08040 90.955 28 6 4 2
1.00000
1.05258 94.079 113 7 3 1
1.01063 99.317 32 8 0 0
0.98774 102.496 4 7 3 3
0.98045 103.563 1 6 4 4
0.95283 107.887 14 8 2 2
0.93357 111.199 51 7 5 1
ANX: AB2X4
Analysis: Co3 O4 0.92741 112.319 14 6 6 2
Formula from original source: Co3 O4 0.90393 116.896 17 8 4 0
Delete duplicate: Delete: See PDF 01-078-1969; WFM 12/04
0.88744 120.454 2 9 1 1
ICSD Collection Code: 63165
Calculated Pattern Original Remarks: Refinement for short angular range 0.88215 121.668 1 8 4 2
10 - 90 deg 0.86186 126.699 5 6 6 4
Wyckoff Sequence: e c b(FD3-MS)
Unit Cell Data Source: Powder Diffraction 0.84754 130.699 29 9 3 1
0.82517 137.975 76 8 4 4
0.81257 142.875 3 7 7 1

Structure
Publication: J. Appl. Chem.
Detail: volume 20, page 394 (1987)
Authors: Will, G., Masciocchi, N., Parrish, W., Hart, M.
Primary Reference
Publication: Calculated from ICSD using POWD-12++

CuKα1 Not specified

1.54060
999.9 (0.0002,30)
 K2 O
Potassium Oxide 3.72333 23.880 99 1 1 1
3.22450 27.642 686 2 0 0
2.28007 39.491 999 2 2 0
1.94445 46.676 28 3 1 1
1.86167 48.884 141 2 2 2
1.61225 57.081 124 4 0 0
1.47950 62.752 8 3 3 1
1.44204 64.576 150 4 2 0
Cubic 94.2 1.31640 71.628 199 4 2 2
Fm-3m (225) 268.21 1.24111 76.728 4 5 1 1
2.33 1.14003 85.015 54 4 4 0
1.09008 89.925 3 5 3 1
5.390
1.07483 91.561 60 6 0 0
6.44900 1.01968 98.126 73 6 2 0
0.98346 103.119 1 5 3 3
0.97222 104.803 36 6 2 2
1.00000 4
0.93083 111.693 19 4 4 4
1.00000
0.90304 117.080 2 5 5 1
0.89432 118.932 32 6 4 0
0.86178 126.721 105 6 4 2
0.83959 133.119 2 7 3 1
0.80612 145.709 13 8 0 0

Additional Patterns: See PDF 01-077-2151

NIST M&A collection code: N AL3564 5335
Temperature Factor: IB=K,O
Minor Warning: No e.s.d reported/abstracted on the cell dimension. No
Rfactor reported/abstracted

Structure
Publication: Z. Elektrochem. Angew. Phys. Chem.
Detail: volume 40, page 588 (1934)
Authors: E.Zintl
Primary Reference
Publication: Calculated from NIST using POWD-12++

CuKα1 Not specified

1.54060
999.9 (0.0004,22)
 Al2 O3
Aluminum Oxide 2.86000 31.249 6
2.72000 32.902 25

γ-Al2 O3 2.60000 34.467 19

2.45000 36.650 41
2.29000 39.312 31
2.16000 41.786 6
1.99000 45.547 50
1.94000 46.789 19
101.96 1.79000 50.978 6
0 1.60000 57.559 6
1.53000 60.459 9
3.38
1.50000 61.799 13
-1.000
1.44000 64.678 3
1.39000 67.307 100
1.29000 73.330 3
1.24000 76.809 3
1.18000 81.506 3
1.13000 85.950 9
0.99000 102.170 9

Deleted Or Rejected By: Delete: JV Smith, April 2, 1960

General Comments: High temperature

Primary Reference
Publication: Private Communication
Authors: Aluminum Co. of America, New Kensington, PA, USA.

MoKα1 Not specified

1.54060