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Boiler: 1 mol (g) 500 degree celsius 0.08 CO 0.92 〖 𝐶 𝑂 〗 - 2

1. The document presents an energy balance calculation for a boiler that operates at 500 degrees Celsius. 2. Gaseous reactants of 0.08 mol CO and 0.92 mol CO2 enter the boiler along with 0.2 mol of liquid water at 25 degrees Celsius and 5 bar pressure. 3. The energy balance equates the enthalpy of the gaseous products leaving the boiler to the enthalpy of the reactants entering, using specific enthalpy values that are functions of temperature.

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Mahad Qazi
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33 views3 pages

Boiler: 1 mol (g) 500 degree celsius 0.08 CO 0.92 〖 𝐶 𝑂 〗 - 2

1. The document presents an energy balance calculation for a boiler that operates at 500 degrees Celsius. 2. Gaseous reactants of 0.08 mol CO and 0.92 mol CO2 enter the boiler along with 0.2 mol of liquid water at 25 degrees Celsius and 5 bar pressure. 3. The energy balance equates the enthalpy of the gaseous products leaving the boiler to the enthalpy of the reactants entering, using specific enthalpy values that are functions of temperature.

Uploaded by

Mahad Qazi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
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1 mol (g) 500 degree celsius

0.08 CO
0.92 〖
𝐶
𝑂

Boiler
〗
_2

0.2 mol
𝐻_2O

𝐻_2 O (l,25 degree celsius, 5 bar)

1 mol gas

0.08 CO
Energy balance 0.92 〖𝐶
Λ𝐻=∑8_𝑂𝑢𝑡▒ 〖𝑛 _𝑖 𝐻 ̂_𝑖 〗 -∑8_𝑖𝑛▒ 〖𝑛 _𝑖 𝑂
𝐻 ̂_𝑖 〗 〗_
2
specific enthaplies are
(𝐻=∫24_500^𝑇▒(𝐶𝑝
)𝑐𝑜) ̂ dT
∫24_500^𝑇▒ 〖 (0.02895+0.4110∗10^−5 〗 𝑇 +0.3548∗ 〖 10 〗 ^(−8)
𝑇^2−2.220∗10^−12T^3

0.2
(𝐻_2=∫24_500^𝑇▒
〖 (𝐶𝑝) 〖𝐶 0 〗 _2
𝐻_2O 〗 ) ̂dT
∫24_500^𝑇▒ 〖 0.03611+4.223∗106−5 〗 𝑇− 2.887∗ 〖 10 〗 ^(−8)
T^2+7.464∗10^−12T^3

𝐻 ̂_3=𝐻 ̂(𝐻_2 𝑂(𝑙,25 𝑑𝑒𝑔𝑟𝑒𝑒 𝑐𝑒𝑙𝑠𝑖𝑢𝑠,5 𝑏𝑎𝑟)


105 kJ/kg
(𝐻_3=𝐻 ̂() ̂𝐻_2 𝑂(𝑣,5 𝑏𝑎𝑟, 𝑠𝑎𝑡𝑢𝑟𝑎𝑡𝑒𝑑)
2747.5 kJ/kg

T degree celsius
inetgrating the expression for specific enthaplies of CO and CO2
and putting values of specific enthalpies of water (l and g) we get

299.065
-1.59E-05
〖 10 〗 ^(−8)

0 〗 ^(−8)

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