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Exercise - II: (One or More Than One Option Correct)

The document discusses ionic equilibrium and contains 5 multiple choice questions related to concepts like pH, pKa, titration curves, and buffer solutions. Question 1 contains statements about the pH of a dilute HCl solution, conjugate base of H2PO4-, and how the autoprotolysis constant of water changes with temperature. Question 2 provides data about the titration of a weak base and asks which statements are correct. Question 3 asks which statement about indicators, titration curves, and calculations is incorrect. Question 4 asks which statement is true about the pH and pOH of alkaline solutions. Question 5 asks which mixture can be used to prepare a buffer solution.

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45 views1 page

Exercise - II: (One or More Than One Option Correct)

The document discusses ionic equilibrium and contains 5 multiple choice questions related to concepts like pH, pKa, titration curves, and buffer solutions. Question 1 contains statements about the pH of a dilute HCl solution, conjugate base of H2PO4-, and how the autoprotolysis constant of water changes with temperature. Question 2 provides data about the titration of a weak base and asks which statements are correct. Question 3 asks which statement about indicators, titration curves, and calculations is incorrect. Question 4 asks which statement is true about the pH and pOH of alkaline solutions. Question 5 asks which mixture can be used to prepare a buffer solution.

Uploaded by

Bhushan
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Page # 24 IONIC EQUILIBRIUM

Exercise - II (One or more than one option correct)


1. Which of the following statement(s) is/are correct?
(A) the pH of 1.0 × 10–8 M solution of HCl is 8
(B) the conjugate base of H2PO4– is HPO42–
(C) autoprotolysis constant of water increases with
temperature
(D) When a soltion of a weak monoprotic acid is titrated
again a strong base, at half -neutralization point pH =
(1/2) pKa.

2. A 2.5 gm impure sample containing weak monoacidic


base (Mol. wt. = 45) is dissolved in 100 ml water and
th
1
titrated with 0.5 M HCl when   of the base was
5
neutralised the pH was found to be 9 and at equivalent
point pH of solution is 4.5. Given : All data at 25º C &
log 2 = 0.3.
Select correct statement(s).
(A) Kb of base is less than 10–6
(B) Concentration of salt (C) at equivalent point is 0.25 M
(C) Volume of HCl is used at equavalent point is 100 ml
(D) Weight percentage of base in given sample is 80%

3. Select incorrect statement(s).


(A) Phenolphthalein is suitable indicator for the
titraction of HCl(aq) with NH4OH (aq).
(B) An acid-base indicator in a buffer solution of pH =
pKln + 1 is ionized to the extent of 90%
(C) In the titration of a monoacidic weak base with a
strong acid, the pH at equivalent point is always
1
calculated by pH = [pKw – pKb – logC]
2
(D) When Na3PO4(aq) is titrated with HCl (aq.), the
pH of solution at second equivalent point is calculated
1
by [pKa + pKa ]
2 1 2

4. Which of the following is true for alkaline aqueous


solution?
pk w pk w
(A) pH > (B) pH > pOH (C) pOH < (D) pH < pOH
2 2

5. A buffer solution can be prepared from a mixture of


(A) sodium acetate and acetic acid in water
(B) sodium acetate and hydrochloric acid in water
(C) ammonia and ammonium chloride in water
(D) ammonia and sodium hydroxide in water.

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