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Trials Enthalpy of Vaporization Percentage Error: Trial #1 32.46 KJ/mol 8.3083%

This document reports on 4 trials measuring the enthalpy of vaporization and boiling point of an unknown compound. For each trial, the enthalpy of vaporization, boiling point, and percentage error from literature values are reported. Across the 4 trials, the enthalpy of vaporization ranged from 32.3165 to 32.51 kJ/mol. The boiling point ranged from 353.16 to 354.4372 K. The percentage error for both values was generally below 10% for each trial.

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Trisha Anne Aranzaso Bautista
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54 views5 pages

Trials Enthalpy of Vaporization Percentage Error: Trial #1 32.46 KJ/mol 8.3083%

This document reports on 4 trials measuring the enthalpy of vaporization and boiling point of an unknown compound. For each trial, the enthalpy of vaporization, boiling point, and percentage error from literature values are reported. Across the 4 trials, the enthalpy of vaporization ranged from 32.3165 to 32.51 kJ/mol. The boiling point ranged from 353.16 to 354.4372 K. The percentage error for both values was generally below 10% for each trial.

Uploaded by

Trisha Anne Aranzaso Bautista
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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Trials Enthalpy of Vaporization Percentage Error

Trial #1 32.46 KJ/mol 8.3083%

Trial #2 32.45 KJ/mol 8.175%

Trial #3 32.51 KJ/mol 8.48%

Trial #4 32.3165 KJ/mol 7.83%

Trials Boiling Point Percentage Error

Trial #1 353.16 K 0.2091%

Trial #2 353.47 K 0.1215%

Trial #3 353.43 K 0.1328%

Trial #4 354.4372 K 0.15%


COMPOUND MOLAR ENTHALPY OF
VAPORIZATION

Methanol (CH3OH) 35.21 KJ/mol

Ethanol (C2H5OH) 38.56 KJ/mol

Cyclohexane (C6H12) 29.97 KJ/mol

n-Hexane (C6H14) 28.85 KJ/mol

2-methylpentane (C6H14) 27.79 KJ/mol


CALCULATIONS:

Trial 1

B
Tbp =
[ A−ln (760 ) ]

3903.7
Tbp =
[17.678−ln ( 760 )]

Tbp = 353. 16 K

353.16−353.9
Percentage Error = ¿ ∨¿ x 100%
353.9

Percentage Error = 0.2091%

ΔHvap = RB
KJ
ΔHvap = 0.008314 (3903.7 K)
mol . K
ΔHvap = 32.46 KJ/mol

32.46−29.97
Percentage Error = ¿ ∨¿ x 100%
29.97

Percentage Error = 8.3083%

Trial 2

3899.7
Tbp =
[17.666−ln (760 ) ]

Tbp = 353. 47 K

353.47−353.9
Percentage Error = ¿ ∨¿ x 100%
353.9

Percentage Error = 0.1215%

ΔHvap = RB
KJ
ΔHvap = 0.008314 (3899.7 K)
mol . K
ΔHvap = 32.42 KJ/mol

32.4 5−29.97
Percentage Error = ¿ ∨¿ x 100%
29.97

Percentage Error = 8.175%

Trial 3

3910.6
Tbp =
[17.698−ln ( 760 )]

Tbp = 353. 43 K

353.43−353.9
Percentage Error = ¿ ∨¿ x 100%
353.9

Percentage Error = 0.133%

ΔHvap = RB
KJ
ΔHvap = 0.008314 (3910.6 K)
mol . K
ΔHvap = 32.51 KJ/mol

32.51−29.97
Percentage Error = ¿ ∨¿ x 100%
29.97

Percentage Error = 8.48%

Trial 4

3887
Tbp =
[17.6−ln (760 ) ]

Tbp = 354.4372 K
354.4372−353.9
Percentage Error = ¿ ∨¿ x 100%
353.9

Percentage Error = 0.15%

ΔHvap = RB
KJ
ΔHvap = 0.008314 (3887 K)
mol . K
ΔHvap = 32.3165 KJ/mol

32.3165−29.97
Percentage Error = ¿ ∨¿ x 100%
29.97

Percentage Error = 7.83%

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