Estimation of measurement uncertainty
for the determination of
in
using
for the concentration range:
on the basis of
DEV-Guide for the estimation of measurement uncertainty from validation data
(NORDTEST-Handbook for the estimation of measurement uncertainty in environm. laboratories)
calculated by:
Date: Signature:
Reproducibility within Laboratory uRw
standard combined
No. contribution uncertainty uncertainty
1
2
3
4
5
6
7
8
Combined uncertainty component uRw
Method and Laboratory Bias ubias
standard combined
No. contribution uncertainty uncertainty
1
2
3
4
5
6
7
8
Combined uncertainty component ubias
Total Combined Standard uncertainty u
Expanded Uncertainty U k-Factor 2
© Dr. M. Koch, Institute for Sanitary Engineering, Universität Stuttgart
The use of this EXCEL-Sheet is free, as long as the copyright statement is not removed.
(c) ISWA Univ. Stuttgart, Kontakt: Dr. Michael Koch, 0711 685 5446, [email protected]
Reproducibility within laboratory uRw
A) Control sample, covering the whole analytical process
Standard deviation:
at concentration:
rel standard deviation: transfer to sheet "Total"
B) Control sample, not covering the whole analytical process
B.1 result from the control sample
Standard deviation:
at concentration:
rel standard deviation:
B.2 component from changing matrices and concentrations (from range)
Mean rel. range:
Number of measurements for the range (2, 3, 4 or 5) 22
rel. standard deviation:
Combination: transfer to sheet "Total"
C) Unstable control samples for calculation see sheet
C.1 Repeatability "s from range"
Mean range: cell M2
Number of measurements for the range (2, 3, 4 or 5) 22
Standard deviation: cell H4
C.2 "Long term" component
Estimation for standard deviation
based on
Combination: transfer to sheet "Total"
(c) ISWA Univ. Stuttgart, Kontakt: Dr. Michael Koch, 0711 685 5446, [email protected]
Method and Laboratory Bias ubias
A) Multiple Analysis of one certified reference material
Certified value Unit:
Confidence interval +/-
Confidence level 95%
95%
Relative Standard uncertainty:
Mean of CRM-analysis:
Mean deviation:
Mean deviation in %
Std.-deviation of CRM-analysis:
rel. std.-deviation of CRM-analysis:
Number of measurements:
Standard uncertainty transfer to sheet "Total"
B) Multiple analysis of several certified reference materials
cert. value confid. interval confid. level mean
CRM 1 95%
95%
CRM 2 95%
95%
CRM 3 95%
95%
CRM 4 95%
95%
u(cref) deviation squared dev.
CRM 1
CRM 2
CRM 3
CRM 4
mean RMSbias
Standard uncertainty transfer to sheet "Total"
C) Proficiency tests
Assigned val. result deviation squared dev. sR (%) number u(cref)
Sample 1
Sample 2
Sample 3
Sample 4
Sample 5
Sample 6
Sample 7
Sample 8
Sample 9
Sample 10
Sample 11
Sample 12
RMSbias u(cref)
Standard uncertainty transfer to sheet "Total"
D) Recovery Experiment
Uncertainty of the concentration of the spike solution:
Concentration of the spike solution:
Confidence interval +/-
Confidence level: 95%
95%
uconc
Uncertainty of the added volume:
max. deviation [%] (rectangular distribution) std-dev.:
Repeatability [%] (as standard deviation)
(c) ISWA Univ. Stuttgart, Kontakt: Dr. Michael Koch, 0711 685 5446, [email protected]
uvol
Uncertainty of the spike: uAufst
Recovery:
spike abs.deviation recovery rel. deviation squared rel .deviation
1
2
3
4
5
6
7
8
9
10
11
12
RMSbias
Standard uncertainty transfer to sheet "Total"
(c) ISWA Univ. Stuttgart, Kontakt: Dr. Michael Koch, 0711 685 5446, [email protected]
1st value 2nd value 3rd value 4th value 5th value
1 number of measurem.
2 s (absolute)
3 s (relative)
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
mean range rel. range
total mean
mean range
mean rel. range
Data
1 mean:
2 standard deviation
3 rel. standard deviation
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
