Material Safety Data Sheet
Version 1.8 MSDS Number 300000000110
Revision Date 08/22/2004 Print Date 10/07/2007
1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Oxygen
Chemical formula : O2
Synonyms : Oxygen, Oxygen gas, Gaseous Oxygen, GOX
Product Use Description : General Industrial
Company : Air Products and Chemicals,Inc
7201 Hamilton Blvd.
Allentown, PA 18195-1501
Telephone : 1-800-345-3148 Chemicals
1-800-752-1597 Gases and Electronic Chemicals
Emergency telephone number : 800-523-9374 USA
01-610-481-7711 International
2. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS Number Concentration
(Volume)
Oxygen 7782-44-7 100 %
Concentration is nominal. For the exact product composition, please refer to Air Products technical
specifications.
3. HAZARDS IDENTIFICATION
Emergency Overview
High pressure, oxidizing gas.
Vigorously accelerates combustion.
Keep oil, grease, and combustibles away.
May react violently with combustible materials.
Potential Health Effects
Inhalation : Breathing 75% or more oxygen at atmospheric pressure for more than a few
hours may cause nasal stuffiness, cough, sore throat, chest pain and breathing
difficulty. Breathing pure oxygen under pressure may cause lung damage and
also central nervous system effects.
Eye contact : No adverse effect.
Skin contact : No adverse effect.
Ingestion : Ingestion is not considered a potential route of exposure.
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Air Products and Chemicals,Inc Oxygen
Material Safety Data Sheet
Version 1.8 MSDS Number 300000000110
Revision Date 08/22/2004 Print Date 10/07/2007
Exposure Guidelines
Primary Routes of Entry : Inhalation
Target Organs : None known.
Aggravated Medical Condition
If oxygen is administered to persons with chronic obstructive pulmonary disease, raising the oxygen
concentration in the blood depresses their breathing and raises their retained carbon dioxide to a dangerous
level.
4. FIRST AID MEASURES
General advice : Remove victim to uncontaminated area wearing self contained breathing
apparatus. Keep victim warm and rested. Call a doctor. Apply artificial
respiration if breathing stopped.
Eye contact : Seek medical advice.
Skin contact : W ash with water and soap as a precaution.
Ingestion : Ingestion is not considered a potential route of exposure.
Inhalation : Consult a physician after significant exposure. Move to fresh air. If breathing
has stopped or is labored, give assisted respirations. Supplemental oxygen
may be indicated. If the heart has stopped, trained personnel should begin
cardiopulmonary resuscitation immediately.
5. FIRE
- FIGHTING MEASURES
Suitable extinguishing media : All known extinguishing media can be used.
Specific hazards : Most cylinders are designed to vent contents when exposed to elevated
temperatures.
Further information : Some materials that are noncombustible in air will burn in the presence of an
oxygen enriched atmosphere (greater than 23%). Fire resistant clothing may
burn and offer no protection in oxygen rich atmospheres.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Clothing exposed to high concentrations may retain oxygen 30 minutes or
longer and become a potential fire hazard. Stay away from ignition sources.
Evacuate personnel to safe areas. W ear self-contained breathing apparatus
when entering area unless atmosphere is proved to be safe. Ventilate the area.
Environmental precautions : Do not discharge into any place where its accumulation could be dangerous.
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up : Ventilate the area.
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Air Products and Chemicals,Inc Oxygen
Material Safety Data Sheet
Version 1.8 MSDS Number 300000000110
Revision Date 08/22/2004 Print Date 10/07/2007
Additional advice : If possible, stop flow of product. Increase ventilation to the release area and
monitor concentrations. If leak is from cylinder or cylinder valve, call the Air
Products emergency telephone number. If the leak is in the user's system,
close the cylinder valve, safely vent the pressure, and purge with an inert gas
before attempting repairs.
7. HANDLING AND STORAGE
Handling
All gauges, valves, regulators, piping and equipment to be used in oxygen service must be cleaned for oxygen
service. Oxygen is not to be used as a substitute for compressed air. Never use an oxygen jet for cleaning
purposes of any sort, especially clothing, as it increases the likelihood of an engulfing fire. Only experienced and
properly instructed persons should handle compressed gases. Protect cylinders from physical damage; do not
drag, roll, slide or drop. Do not allow storage area temperature to exceed 50°C (122°F). Before using the
product, determine its identity by reading the label. Know and understand the properties and hazards of the
product before use. W hen doubt exists as to the correct handling procedure for a particular gas, contact the
supplier. Do not remove or deface labels provided by the supplier for the identification of the cylinder contents.
W hen moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport
cylinders. Leave valve protection caps in place until the container has been secured against either a wall or
bench or placed in a container stand and is ready for use. Use an adjustable strap wrench to remove over-tight
or rusted caps. Before connecting the container, check the complete gas system for suitability, particularly for
pressure rating and materials. Before connecting the container for use, ensure that back feed from the system
into the container is prevented. Ensure the complete gas system is compatible for pressure rating and materials
of construction. Ensure the complete gas system has been checked for leaks before use. Employ suitable
pressure regulating devices on all containers when the gas is being emitted to systems with lower pressure
rating than that of the container. Never insert an object (e.g. wrench, screwdriver, pry bar, etc.) into valve cap
openings. Doing so may damage valve, causing a leak to occur. If user experiences any difficulty operating
cylinder valve discontinue use and contact supplier. Close container valve after each use and when empty, even
if still connected to equipment. Never attempt to repair or modify container valves or safety relief devices.
Damaged valves should be reported immediately to the supplier. Do not use containers as rollers or supports or
for any other purpose than to contain the gas as supplied. Never strike an arc on a compressed gas cylinder or
make a cylinder a part of an electrical circuit. Do not smoke while handling product or cylinders. Never re-
compress a gas or a gas mixture without first consulting the supplier. Never attempt to transfer gases from one
cylinder/container to another. Always use backflow protective device in piping. When returning cylinder install
valve outlet cap or plug leak tight. Never permit oil, grease, or other readily combustible substances to come into
contact with valves or containers containing oxygen or other oxidants. Do not use rapidly opening valves (e.g.
ball valves). Open valve slowly to avoid pressure shock. Never pressurize the entire system at once. Use only
with equipment cleaned for oxygen service and rated for cylinder pressure. Never use direct flame or electrical
heating devices to raise the pressure of a container. Containers should not be subjected to temperatures above
50°C (122°F). Prolonged periods of cold temperature below -30°C (-20°F) should be avoided.
Storage
Containers should be stored in a purpose build compound which should be well ventilated, preferably in the
open air. Full containers should be stored so that oldest stock is used first. Stored containers should be
periodically checked for general condition and leakage. Observe all regulations and local requirements
regarding storage of containers. Protect containers stored in the open against rusting and extremes of weather.
Containers should not be stored in conditions likely to encourage corrosion. Containers should be stored in the
vertical position and properly secured to prevent toppling. The container valves should be tightly closed and
where appropriate valve outlets should be capped or plugged. Container valve guards or caps should be in
place. Keep containers tightly closed in a cool, well-ventilated place. Store containers in location free from fire
risk and away from sources of heat and ignition. Full and empty cylinders should be segregated. Do not allow
storage temperature to exceed 50°C (122°F). Display "No Smoking or Open Flames" signs in the storage
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Air Products and Chemicals,Inc Oxygen
Material Safety Data Sheet
Version 1.8 MSDS Number 300000000110
Revision Date 08/22/2004 Print Date 10/07/2007
areas. Return empty containers in a timely manner. Flammable storage areas should be separated from oxygen
and other oxidizers by a minimum distance of 20 ft. (6.1 m.) or by a barrier of non-combustible material at least 5
ft. (1.5 m.) high, having a fire resistance rating of at least 1/2 hour.
Technical measures/Precautions
Containers should be segregated in the storage area according to the various categories (e.g. flammable, toxic,
etc.) and in accordance with local regulations.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protective equipment
Respiratory protection : Users of breathing apparatus must be trained.
Hand protection : Sturdy work gloves are recommended for handling cylinders.
The breakthrough time of the selected glove(s) must be greater than the
intended use period.
Eye protection : Safety glasses recommended when handling cylinders.
Skin and body protection : Safety shoes are recommended when handling cylinders.
Special instructions for : Ensure adequate ventilation, especially in confined areas. Gloves must be
protection and hygiene clean and free of oil and grease.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : Compressed gas.
Color : Colorless gas
Odor : No odor warning properties.
Molecular W eight : 32 g/mol
Relative vapor density : 1.1 (air = 1)
Relative density : 1.1 (water = 1)
Density : 0.081 lb/ft3 (0.0013 g/cm3) at 70 °F (21 °C)
Note: (as vapor)
Specific Volume : 12.08 ft3/lb (0.7540 m3/kg) at 70 °F (21 °C)
Boiling point/range : -297 °F (-183 °C)
Critical temperature : -180 °F (-118 °C)
Melting point/range : -362 °F (-219 °C)
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Air Products and Chemicals,Inc Oxygen
Material Safety Data Sheet
Version 1.8 MSDS Number 300000000110
Revision Date 08/22/2004 Print Date 10/07/2007
W ater solubility : 0.039 g/l
10. STABILITY AND REACTIVITY
Stability : Stable under normal conditions.
Materials to avoid : Flammable materials.
Organic materials.
Avoid oil, grease and all other combustible materials.
11. TOXICOLOGICAL INFORMATION
Acute Health Hazard
Ingestion : No data is available on the product itself.
Inhalation : No data is available on the product itself.
Skin. : No data is available on the product itself.
Chronic Health Hazard
Premature infants exposed to high oxygen concentrations may suffer delayed retinal damage that can progress to
retinal detachment and blindness. Retinal damage may also occur in adults exposed to 100% oxygen for extended
periods (24 to 48 hr). At two or more atmospheres central nervous system (CNS) toxicity occurs. Symptoms include
nausea, vomiting, dizziness or vertigo, muscle twitching, vision changes and loss of consciousness and generalized
seizures. At three atmospheres, CNS toxicity occurs in less than two hours and at six atmospheres in only a few
minutes.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Aquatic toxicity : No data is available on the product itself.
Toxicity to other organisms : No data available.
Persistence and degradability
Mobility : No data available.
Bioaccumulation : No data is available on the product itself.
Further information
No ecological damage caused by this product.
13. DISPOSAL CONSIDERATIONS
W aste from residues / unused : Return unused product in orginal cylinder to supplier. Contact supplier if
products guidance is required.
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Air Products and Chemicals,Inc Oxygen
Material Safety Data Sheet
Version 1.8 MSDS Number 300000000110
Revision Date 08/22/2004 Print Date 10/07/2007
Contaminated packaging : Return cylinder to supplier.
14. TRANSPORT INFORMATION
CFR
Proper shipping name : Oxygen, compressed
Class : 2.2 (5.1)
UN/ID No. : UN1072
IATA
Proper shipping name : Oxygen, compressed
Class : 2.2 (5.1)
UN/ID No. : UN1072
IMDG
Proper shipping name : OXYGEN, COMPRESSED
Class : 2.2 (5.1)
UN/ID No. : UN1072
CTC
Proper shipping name : OXYGEN, COMPRESSED
Class : 2.2 (5.1)
UN/ID No. : UN1072
Further Information
Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle
driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an
emergency.
15. REGULATORY INFORMATION
OSHA Hazard Communication Standard (29 CFR 1910.1200) Hazard Class(es)
Oxidizer. Compressed Gas.
Country Regulatory list Notification
USA TSCA Included on Inventory.
EU EINECS Included on Inventory.
Canada DSL Included on Inventory.
Australia AICS Included on Inventory.
South Korea ECL Included on Inventory.
China SEPA Included on Inventory.
Philippines PICCS Included on Inventory.
J apan ENCS Included on Inventory.
EPA SARA Title III Section 312 (40 CFR 370) Hazard Classification:
Fire Hazard. Sudden Release of Pressure Hazard.
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Air Products and Chemicals,Inc Oxygen
Material Safety Data Sheet
Version 1.8 MSDS Number 300000000110
Revision Date 08/22/2004 Print Date 10/07/2007
US. California Safe Drinking W ater & Toxic Enforcement Act (Proposition 65)
This product does not contain any chemicals known to State of California to cause cancer, birth defects or any other
harm.
16. OTHER INFORMATION
NFPA Rating
Health : 0
Fire : 0
Instability : 0
Special : OX
HMIS Rating
Health : 0
Flammability : 0
Physical hazard : 3
Prepared by : Air Products and Chemicals, Inc. Global EH&S Product Safety Department
For additional information, please visit our Product Stewardship web site at
http//www.airproducts.com/productstewardship/
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Air Products and Chemicals,Inc Oxygen
