JEE 2023

Class XI Organic Chemistry #4

DPP NO. (JEE MAIN+ADVANCED)

Max Marks: 44 39 Minutes Test

1. How many of the following molecules/ions show correct direction of

inductive effect.
H3C CH3 vi. Br Mg CH3

]
TB
i. F
vii. HO CH3
– –
ii. H3C CH2
viii. O CH3
CH2 –

iii. Cl
CH2
ix.
[II
HN
H3C
CH3

C
+
CH3
NA
iv. H3C
x. CH3

v. Li CH3
RA

a. eight c. seven
b. ten d. six
2. How many of the following molecules/ ions show correct direction of
IN

inductive effect.
O Na CH3
CH

O
H3C
I. OH
O
H3C
SA

–
II. O +
– N V. NH2
IV. O O

III. NH

Page No. 1
 H2C CH

+
H3C S CH3

+
VIII. X. H3C
N –
– O
VI. O O
CH

IX. NH2

VII.
(a) ten (c) eight
(b) seven (d) six

]
TB
3. Inductive effect involves:
(a) delocalization of sigma electrons
(b) delocalization of π-electrons
(c) displacement of sigma electrons
(d) displacement of π-electrons
[II
NA
4. Which statement is correct regarding Inductive effect?
(a) Electron displacement along a carbon chain and develops
partial charges on atoms.
RA

(b) Complete transfer of one of the shared pair of electrons to

one of the atoms joined by a double bond.
(c) Implies transfer of lone pair of electrons from more
IN

electronegative atom to the less electronegative atom.

(d) I effect increases with increase in the distance.
CH

5. Select the correct statement about Inductive effect:

(a) Inductive effect transfer electrons from one carbon atom
SA

to another.
(b) Inductive effect is the polarization of sigma bond electrons.
(c) Net charge develops in the molecule by inductive effect.
(d) Inductive effect is distance independent.

Page No. 2
6. Which of the following has incorrect direction of Inductive effect?
CH3 O

–
O

(c)
O
(a) CH3
O CH3

OH (d) H3C

(b)

7. Which of the following has correct direction of inductive effect?

]
(a) H3C Li

(b)

TB
H2N CH

(c) H2N CH
NH2

–
[II
A
(d) O
N

8. Which of the following alkyl group has the maximum +I effect?

(a) (CH3)2CH - (c) CH3CH2 -
RA

(b) (CH3)3C - (d) CH3 –

9. Which of the following group shows +I effect?

IN

(a) -F (c) -NH-

(b) -CHO (d) -CN
CH

10. Decreasing -I effect of given groups is:

I. -CN III. -NH2
II. -NO2 IV. -Cl
SA

(a) IV>III>I>II (c) I>III>IV>II

(b) IV>I>III>II (d) I>II>III>IV

Page No. 3
11. Which is the correct order of inductive effect?
(a) -NH2 > -OR > -F (c) -NH2 > -F > -OR
(b) -F > -OR > -NH2 (d) -OR > -F > -NH2

12. Which of the following statement is correct?

(a) +I group stabilizes the carbocation.
(b) +I group stabilizes the carbon free radical.
(c) -I group stabilizes the carbanion.
(d) All of these.

13. Arrange the following compounds in decreasing order of their dipole

moment.

]
I. CH3-CH2-NO2 III. CH3-CH2-Br

TB
II. CH3-CH2-Cl IV. CH3-CH2-I
(a) IV>III>I>II (c) I>III>IV>II
(b) IV.I>III>II (d) I>II>III>IV
[II
N A
RA
IN
CH
SA

Page No. 4
 ANSWERS

1. d
2. a
3. c
4. a
5. b
6. d
7. b
8. b
9. c

]
10. d

TB
11. b
12. d
13. d
14. b [II
NA
RA
IN
CH
SA

Page No. 5
 JEE 2023

Class XI Organic Chemistry #5

DPP NO. (JEE MAIN+ADVANCED)

Max Marks: 15 10 Minutes Test

Q. How many of the following compounds can show resonance?

]
O

TB
4.

[II O

1.
NA
5.
O

O
RA

6.
IN

2. H
CH

H
O
O N
SA

7.

3. NH2
8. NH

Page No. 1
 NH2
9.

NH
10.

11. Cl

NH

12.

]
N

TB
NH

13.

NH2
[II
NA
14.

15.
RA
IN
CH
SA

Page No. 2
 ANSWERS

1. Yes
2. Yes
3. Yes
4. Yes
5. Yes
6. Yes
7. Yes

]
8. Yes

TB
9. No
10. Yes
11. Yes
12. Yes
[II
NA
13. Yes
14. Yes
15. Yes
RA
IN
CH
SA

Page No. 3