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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
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SDS # : 31157
MULTIS EP 2
Date of the previous version: 2016-11-21 Revision Date: 2016-11-29 Version 13.01
Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1. Product identifier
Product name MULTIS EP 2
Number 626
Substance/mixture Mixture
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Lubricating grease.
1.3. Details of the supplier of the safety data sheet
Supplier A - TOTAL UK LIMITED
One Euston Square
40 Melton Street. London. NW1 2FD
UNITED KINGDOM
Tel: +44 (0)20 7339 8000
Fax: +44 (0)20 7339 8033
B - TOTAL LUBRIFIANTS
562 Avenue du Parc de L'ile
92029 Nanterre Cedex
FRANCE
Tél: +33 (0)1 41 35 40 00
Fax: +33 (0)1 41 35 84 71***
For further information, please contact:
Contact Point A - HSE
B - HSE***
E-mail Address A - [email protected]
B - [email protected]***
1.4. Emergency telephone number
Emergency telephone: +44 1235 239670
TOTAL UK ltd: + 44 (0) 20 7339 8000
For Lubricants only: TOTAL Lubricants - +44 (0)1977 636200
For bitumen only: Total Bitumen -+44 (0) 17 7272 9302
UK: National Poisons Information Service (NPIS): NHS111 or a doctor
Section 2: HAZARDS IDENTIFICATION
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2.1. Classification of the substance or mixture
REGULATION (EC) No 1272/2008
For the full text of the H-Statements mentioned in this Section, see Section 2.2.
Classification
The product is classified as dangerous in accordance with Regulation (EC) No. 1272/2008
Chronic aquatic toxicity - Category 3 - (H412)
2.2. Label elements
Labelled according to REGULATION (EC) No 1272/2008
Signal Word
None
Hazard Statements
H412 - Harmful to aquatic life with long lasting effects
Precautionary statements
P501 - Dispose of contents/ container to an approved waste disposal plant
2.3. Other hazards
Physical-Chemical Properties Contaminated surfaces will be extremely slippery.
Environmental properties Should not be released into the environment.
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixture
Hazardous components
Chemical Name EC-No REACH CAS-No Weight % GHS Classification
Registration
Number
Phosphorodithioic acid, 270-478-5 no data available 68442-22-8 1-<2.5 Eye Irrit. 2 (H319)
mixed O,O-bis(2-ethylhexyl Aquatic Chronic 2 (H411)
and iso-Bu) esters, zinc salts
Fatty acids, vegetable-oil, 276-337-4 - 72102-30-8 1-<2.5 Aquatic Chronic 2 (H411)
Me esters, sulfurized
Additional information Product containing mineral oil with less than 3% DMSO extract as measured by IP 346.
For the full text of the H-Statements mentioned in this Section, see Section 16.
Section 4: FIRST AID MEASURES
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4.1. Description of first aid measures
General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR
EMERGENCY MEDICAL CARE.
Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes.
Skin contact Remove contaminated clothing and shoes. Wash skin with soap and water. Wash
contaminated clothing before reuse. High pressure jets may cause skin damage. Take
victim immediately to hospital.
Inhalation Move to fresh air.
Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a
physician or poison control centre immediately.
4.2. Most important symptoms and effects, both acute and delayed
Eye contact Not classified.
Skin contact Not classified. High pressure injection of the products under the skin may have very
serious consequences even though no symptom or injury may be apparent.
Inhalation Not classified. Inhalation of vapours in high concentration may cause irritation of respiratory
system.
Ingestion Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhoea.
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
Section 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Suitable extinguishing media Carbon dioxide (CO 2). ABC powder. Foam. Water spray or fog.
Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.
5.2. Special hazards arising from the substance or mixture
Special hazard Incomplete combustion and thermolysis may produce gases of varying toxicity such as
carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may
be highly dangerous if inhaled in confined spaces or at high concentration.
5.3. Precautions for fire-fighters
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Special protective equipment for Wear self-contained breathing apparatus and protective suit.
fire-fighters
Other information Cool containers / tanks with water spray. Fire residues and contaminated fire extinguishing
water must be disposed of in accordance with local regulations.
Section 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
General Information Do not touch or walk through spilled material. Contaminated surfaces will be extremely
slippery. Use personal protective equipment. Ensure adequate ventilation. Remove all
sources of ignition.
6.2. Environmental precautions
General Information Do not allow material to contaminate ground water system. Try to prevent the material from
entering drains or water courses. Local authorities should be advised if significant spillages
cannot be contained. See Section 12 for additional Ecological Information.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Dam up. Contain spillage, and then collect with non-combustable absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according
to local / national regulations (see section 13). Collect free product with suitable mechanical
means. Keep in suitable, closed containers for disposal.
6.4. Reference to other sections
Personal protective equipment See Section 8 for more detail.
Waste treatment See section 13.
Section 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Advice on safe handling When using, do not eat, drink or smoke. For personal protection see section 8. Use only in
well-ventilated areas. Do not breathe vapours or spray mist. Avoid contact with skin, eyes
and clothing.
Prevention of fire and explosion Take precautionary measures against static discharges. Ground/bond containers, tanks
and transfer/receiving equipment.
Hygiene measures Ensure the application of strict rules of hygiene by the personnel exposed to the risk of
contact with the product. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product. Do
not use abrasives, solvents or fuels. Do not dry hands with rags that have been
contaminated with product. Do not put product contaminated rags into workwear pockets.
7.2. Conditions for safe storage, including any incompatibilities
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Technical measures/Storage Keep away from food, drink and animal feedingstuffs. Keep in a bunded area. Keep
conditions container tightly closed. Preferably keep in the original container. Otherwise, reproduce all
the statutory information from the labels onto the new container. Do not remove the hazard
labels of the containers (even if they are empty). Design the installations in order to avoid
accidental emissions of product (due to seal breakage, for example) onto hot casings or
electrical contacts. Protect from frost, heat and sunlight. Protect from moisture.
Materials to avoid Strong oxidising agents.
7.3. Specific use(s)
Specific use(s) No information available.
Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Control parametres
Exposure limits Mineral oil mist:
USA: OSHA (PEL) TWA 5 mg/m3, NIOSH (REL) TWA 5 mg/m3, STEL 10 mg/m3, ACGIH
(TLV) TWA 5 mg/m3 (highly refined)
Legend See section 16
8.2. Exposure controls
Occupational Exposure Controls
Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in
confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for
breathing and wear the recommended equipment.
Personal protective equipment
General Information If the product is used in mixtures, it is recommended that you contact the appropriate
protective equipment suppliers. These recommendations apply to the product as supplied.
Respiratory protection None under normal use conditions. When workers are facing concentrations above the
exposure limit they must use appropriate certified respirators. Respirator with combination
filter for vapour/particulate (EN 14387). Type A/P1. The use of breathing apparatus must
comply strictly with the manufacturer's instructions and the regulations governing their
choices and uses.
Eye protection If splashes are likely to occur, wear:. Safety glasses with side-shields.
Skin and body protection Wear suitable protective clothing. Protective shoes or boots. Long sleeved clothing.
Hand protection Hydrocarbon-proof gloves: Fluorinated rubber, Nitrile rubber. In case of prolonged contact
with the product, it is recommended to wear gloves complying with EN 420 and EN 374
standards, protecting at least for 480 minutes and having a thickness of 0,38 mm at least.
These values are indicative only. The level of protection is provided by the material of the
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glove, its technical characteristics, its resistance to the chemicals to be handled, the
appropriateness of its use and its replacement frequency.
Environmental exposure controls
General Information The product should not be allowed to enter drains, water courses or the soil.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Colour light brown to dark brown
Physical state @20°C solid
Odour characteristic
Odour Threshold No information available
Property Values Remarks Method
pH Not applicable
Melting point/range Not applicable
Boiling point/boiling range No information available
Flash point > 200 °C Cleveland Open Cup (COC)
> 392 °F Cleveland Open Cup (COC)
Evapouration rate Not applicable
Flammability Limits in Air No information available
Upper No information available
Lower No information available
Vapour pressure Not applicable
Vapour density Not applicable
Relative density 0.87 @ 20 °C
Density 870 kg/m3 @ 20 °C
Water solubility Insoluble
Solubility in other solvents No information available
logPow No information available
Autoignition temperature No information available
Decomposition temperature No information available
Viscosity, kinematic Not applicable
Explosive properties Not explosive
Oxidising properties Not applicable
Possibility of hazardous reactions No information available
9.2. Other information
Penetration index 265 - 295 (1/10mm) @ 25 °C ASTM D 217
Freezing point No information available
Drop point > 185 °C ISO 2176
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Section 10: STABILITY AND REACTIVITY
10.1. Reactivity
General Information No information available.
10.2. Chemical stability
Stability Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions None under normal processing.
10.4. Conditions to Avoid
Conditions to Avoid Heat (temperatures above flash point), sparks, ignition points, flames, static electricity.
10.5. Incompatible materials
Materials to avoid Strong oxidising agents.
10.6. Hazardous Decomposition Products
Hazardous Decomposition Products None under normal use. Incomplete combustion and thermolysis may produce gases of
varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes
and soot.
Section 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Acute toxicity Local effects Product Information
Skin contact . Not classified. High pressure injection of the products under the skin may have very
serious consequences even though no symptom or injury may be apparent.
Eye contact . Not classified.
Inhalation . Not classified. Inhalation of vapours in high concentration may cause irritation of
respiratory system.
Ingestion . Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhoea.
ATEmix (inhalation-dust/mist) 390.30 mg/l
ATEmix (inhalation-vapour) 1,538.20 mg/l
Acute toxicity - Component Information
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Fatty acids, vegetable-oil, Me esters, LD50 > 5000 mg/kg (Rat)
sulfurized
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Sensitisation
Sensitisation Not classified as a sensitizer.
Specific effects
Carcinogenicity This product is not classified carcinogenic.
Mutagenicity This product is not classified as mutagenic.
Reproductive toxicity This product does not present any known or suspected reproductive hazards.
Repeated Dose Toxicity
Subchronic Toxicity No information available.
Target Organ Effects (STOT)
Other information
Other adverse effects Characteristic skin lesions (oil blisters) may develop following prolonged and repeated
exposures (contact with contaminated clothing).
Section 12: ECOLOGICAL INFORMATION
12.1. Toxicity
Harmful to aquatic life with long lasting effects.
Acute aquatic toxicity - Product Information
No information available.
Acute aquatic toxicity - Component Information
Chemical Name Toxicity to algae Toxicity to daphnia and Toxicity to fish Toxicity to
other aquatic microorganisms
invertebrates.
Fatty acids, vegetable-oil, EC50 (48h) 8.8 mg/l LC50 (96h) > 8000 mg/l
Me esters, sulfurized (Daphnia magna - Limit test)
72102-30-8
Chronic aquatic toxicity - Product Information
No information available.
Chronic aquatic toxicity - Component Information
.
Effects on terrestrial organisms
No information available.
12.2. Persistence and Degradability
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General Information
No information available.
12.3. Bioaccumulative potential
Product Information No information available.
logPow No information available
Component Information .
Chemical Name log Pow
Fatty acids, vegetable-oil, Me esters, sulfurized - 72102-30-8 14
12.4. Mobility in soil
Soil Given its physical and chemical characteristics, the product has no soil mobility.
Air Loss by evaporation is limited.
Water The product is insoluble and floats on water.
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment No information available.
12.6. Other adverse effects
General Information No information available.
Section 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste from residues / unused Should not be released into the environment. Dispose of in accordance with the European
products Directives on waste and hazardous waste. Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or
disposal.
EWC Waste Disposal No The following Waste Codes are only suggestions:. 12 01 12. According to the European
Waste Catalogue, Waste Codes are not product specific, but application specific. Waste
codes should be assigned by the user based on the application for which the product was
used.
Section 14: TRANSPORT INFORMATION
ADR/RID not regulated
IMDG/IMO not regulated
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ICAO/IATA not regulated
ADN not regulated
Section 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
European Union
Further information
No information available
15.2. Chemical Safety Assessment
Chemical Safety Assessment No information available
15.3. National regulatory information
The United Kingdom
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Section 16: OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3
H335 - May cause respiratory irritation
H315 - Causes skin irritation
H318 - Causes serious eye damage
H319 - Causes serious eye irritation
H411 - Toxic to aquatic life with long lasting effects
Abbreviations, acronyms
ACGIH = American Conference of Governmental Industrial Hygienists
bw = body weight
bw/day = body weight/day
EC x = Effect Concentration associated with x% response
GLP = Good Laboratory Practice
IARC = International Agency for Research of Cancer
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LC50 = 50% Lethal concentration - Concentration of a chemical in air or a chemical in water which causes the death of 50% (one
half) of a group of test animals
LD50 = 50% Lethal Dose - Chemical amount, given at once, which causes the death of 50% (one half) of a group of test animals
LL = Lethal Loading
NIOSH = National Institute of Occupational Safety and Health
NOAEL = No Observed Adverse Effect Level
NOEC = No Observed Effect Concentration
NOEL = No Observed Effect Level
OECD = Organization for Economic Co-operation and Development
OSHA = Occupational Safety and Health Administration
UVCB = Substance of unknown or Variable composition, Complex reaction products or Biological material
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
dw = dry weight
fw = fresh water
mw = marine water
or = occasional release
Legend Section 8
TWA: Time Weight Average
STEL: Short Time Exposure Limit
+ Sensitiser * Skin designation
** Hazard Designation C: Carcinogen
M: Mutagen R: Toxic to reproduction
Revision Date: 2016-11-29
Revision Note *** Indicates updated section.
This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
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This safety data sheet serves to complete but not to replace the technical product sheets. The information contained
herein is given in good faith and is accurate to the best of knowledge at the date indicated above.It is understood by the
user that any use of the product for purposes other than those for which it was designed entails potential risk.The
information given herein in no way dispenses the user from knowing and applying all provisions regulating his
activity.The user bears sole liability for the precautions required when using the product.The regulatory texts indicated
herein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and exhaustive.It is
the user's responsibility to ensure that he is subject to no other obligations than those mentioned.
End of Safety Data Sheet
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