SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 1(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Trade name
CORRTREAT 3747
Material number: 250014
Chemical nature: Mixture of quaternary amines and ethoxylated imidazolines in
water.

1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industry sector : Oilfield
Type of use : Corrosion inhibitor
Exposure scenarios: see annex

1.3. Details of the supplier of the safety data sheet

Identification of the company
Clariant Gulf FZ-LLC
Dubai Science Park North Tower, Office No: 1601
Dubai – U.A.E
Information about the substance/mixture
BU Care Chemicals
Product Stewardship
e-mail: [email protected]

1.4. Emergency telephone number

00800-5121 5121 (24 h)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)
Acute toxicity, Category 4 H302: Harmful if swallowed.

Skin irritation, Category 2 H315: Causes skin irritation.

Serious eye damage, Category 1 H318: Causes serious eye damage.

Skin sensitisation, Category 1 H317: May cause an allergic skin reaction.

Long-term (chronic) aquatic hazard, H411: Toxic to aquatic life with long lasting effects.
Category 2

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
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Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

Hazard pictograms :

Signal word : Danger

Hazard statements : H302 Harmful if swallowed.

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H411 Toxic to aquatic life with long lasting effects.

Prevention:
Precautionary statements :
P261 Avoid breathing mist or vapours.
P264 Wash skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a
POISON CENTER/ doctor.
P391 Collect spillage.

Hazardous components which must be listed on the label:

Reaction product of tallow fatty propylene diamine, formaldehyde and ethylene oxide
Fatty acids, tall-oil, reaction products with polyethylenepolyamines
Alkylpyridine benzyl chloride quaternary
Mercaptoacetic acid
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

Ecological information: The substance/mixture does not contain components considered to have
endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated
regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

Toxicological information: The substance/mixture does not contain components considered to

have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated
regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

No additional hazards are known except those derived from the labelling.

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Components
Chemical name CAS-No. Classification Concentration
EC-No. (% w/w)
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Index-No.
Registration number
Reaction product of tallow fatty 283149-88-2 Acute Tox. 4; H302 >= 3 - < 10
propylene diamine, formaldehyde Skin Irrit. 2; H315
and ethylene oxide Eye Dam. 1; H318
Aquatic Chronic 1;
H410
Aquatic Acute 1;
H400
Ethanediol 107-21-1 Acute Tox. 4; H302 >= 1 - < 10
203-473-3 STOT RE 2; H373
603-027-00-1 (Kidney)
01-2119456816-28
01-2119456816-28-
0000
01-2119456816-28-
0003
01-2119456816-28-
0038
01-2119456816-28-
0117
UK-20-5549617523-
7-0000
UK-20-7511478711-
4-0000
UK-20-8044687532-
2-0000
Fatty acids, tall-oil, reaction 68910-93-0 Skin Irrit. 2; H315 >= 3 - < 10
products with 272-756-1 Eye Dam. 1; H318
polyethylenepolyamines Aquatic Chronic 1;
H410
Aquatic Acute 1;
H400
Alkylpyridine benzyl chloride 100765-57-9 Acute Tox. 4; H302 >= 3 - < 10
quaternary Acute Tox. 3; H331
Acute Tox. 3; H311
Skin Irrit. 2; H315
Eye Dam. 1; H318
Skin Sens. 1B; H317
STOT SE 3; H335
(Respiratory system)
STOT RE 2; H373
Aquatic Chronic 2;
H411
Mercaptoacetic acid 68-11-1 Acute Tox. 3; H301 >= 1 - < 3
200-677-4 Acute Tox. 3; H331
607-090-00-6 Acute Tox. 3; H311
01-2119494933-24 Skin Corr. 1B; H314
DUIN-UK-20- Eye Dam. 1; H318
1442979995-1-0000
Acute toxicity
estimate

Acute oral toxicity: 73

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mg/kg
Acute dermal toxicity:
848 mg/kg
Methanol 67-56-1 Flam. Liq. 2; H225 >= 1 - < 3
200-659-6 Acute Tox. 3; H301
603-001-00-X Acute Tox. 3; H331
01-2119433307-44 Acute Tox. 3; H311
01-2119433307-44- STOT SE 1; H370
0000 (Eyes, Central
01-2119433307-44- nervous system)
0024
01-2119433307-44- specific concentration
0061 limit
01-2119433307-44- STOT SE 1; H370
0066 >= 10 %
01-2119433307-44- STOT SE 2; H371
0071 3 - < 10 %
01-2119433307-44- STOT SE 1; H370
0091 >= 10 %
01-2119433307-44- STOT SE 2; H371
0128 3 - < 10 %
01-2119433307-44-
0142
01-2119433307-44-
0176
01-2119433307-44-
XXXX
For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice : Remove/ Take off immediately all contaminated clothing.
Get medical advice/ attention if you feel unwell.

If inhaled : If inhaled, remove to fresh air.

Get medical advice/ attention.

In case of skin contact : Wash off immediately with plenty of water.

Consult a physician.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
Consult a physician.

If swallowed : Rinse mouth with water.

If conscious, give the victim plenty of water to drink.
Do NOT induce vomiting.
In case of unconsciousness do not induce vomiting or give
anything by mouth.
Take victim immediately to hospital.
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Substance key: 000000473131 Revision Date: 14.03.2023
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4.2 Most important symptoms and effects, both acute and delayed
Symptoms : irritant effects

corrosive effects

sensitising effects

Risks : Causes skin irritation.

Causes serious eye damage.

May cause an allergic skin reaction.

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : Dry powder
Alcohol-resistant foam
Carbon dioxide (CO2)

5.2 Special hazards arising from the substance or mixture

Specific hazards during : Carbon oxides
firefighting Sulphur oxides
Hydrogen sulfide (H2S)

5.3 Advice for firefighters

Special protective equipment : Full protective suit In case of fire: Wear respiratory protection.
for firefighters

Further information : Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Ensure adequate ventilation.
Wear suitable protective equipment.
Wear respiratory protection.
Do not let the liquid drain into rivers, ponds or sewer systems.

6.2 Environmental precautions

Environmental precautions : The product should not be allowed to enter drains, water
courses or the soil.
If the product contaminates rivers and lakes or drains inform
respective authorities.
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Substance key: 000000473131 Revision Date: 14.03.2023
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6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Soak up with inert absorbent material.
Dispose of absorbed material in accordance with the
regulations.
Rinse away rest with plenty of water

6.4 Reference to other sections

Information regarding Safe handling, see chapter 7., For personal protection see section 8., For
disposal considerations see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : Avoid spilling, spraying or splashing
Provide adequate ventilation.
In case of insufficient ventilation, wear suitable respiratory
equipment.
Have eyewash bottle in readiness.

Advice on protection against : Observe the general rules of industrial fire protection
fire and explosion

Hygiene measures : Do not eat, drink or smoke when using this product. Wash
hands before breaks and at the end of workday. Take off
immediately all contaminated clothing.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Keep container tightly closed in a cool, well-ventilated place.
areas and containers Keep only in the original container.

Further information on : Keep containers tightly closed in a cool, well-ventilated place.

storage conditions Handle and open container with care.

7.3 Specific end use(s)

Specific use(s) : No further recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name End Use Exposure routes Potential health Value
effects
Ethanediol Workers Inhalation Long-term local 35 mg/m3
CAS-No.: 107-21-1 effects
Remarks:DNEL
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Workers Dermal Long-term systemic 106 mg/kg

effects bw/day
Remarks:DNEL
Consumers Inhalation Long-term local 7 mg/m3
effects
Remarks:DNEL
Consumers Dermal Long-term systemic 53 mg/kg
effects bw/day
Remarks:DNEL
Mercaptoacetic acid Workers Inhalation Long-term systemic 1,13 mg/m3
CAS-No.: 68-11-1 effects
Remarks:DNEL
Workers Inhalation Acute systemic 4,5 mg/m3
effects
Remarks:DNEL
Workers Inhalation Acute local effects 4,5 mg/m3
Remarks:DNEL
Workers Dermal Long-term systemic 1,6 mg/kg
effects bw/day
Remarks:DNEL
Consumers Oral Long-term systemic 0,08 mg/kg
effects bw/day
Remarks:DNEL
Methanol Workers Inhalation Long-term systemic 130 mg/m3
CAS-No.: 67-56-1 effects
Remarks:DNEL
Workers Inhalation Acute systemic 130 mg/m3
effects
Remarks:DNEL
Workers Inhalation Long-term local 130 mg/m3
effects
Remarks:DNEL
Workers Inhalation Acute local effects 130 mg/m3
Remarks:DNEL
Workers Dermal Long-term systemic 20 mg/kg
effects bw/day
Remarks:DNEL
Workers Dermal Acute systemic 20 mg/kg
effects bw/day
Remarks:DNEL
Consumers Inhalation Long-term systemic 26 mg/m3
effects
Remarks:DNEL
Consumers Inhalation Acute systemic 26 mg/m3
effects
Remarks:DNEL
Consumers Inhalation Long-term local 26 mg/m3
effects
Remarks:DNEL
Consumers Inhalation Acute local effects 26 mg/m3
Remarks:DNEL
Consumers Dermal Long-term systemic 4 mg/kg
effects bw/day
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Remarks:DNEL
Consumers Dermal Acute systemic 4 mg/kg
effects bw/day
Remarks:DNEL
Consumers Oral Long-term systemic 4 mg/kg
effects bw/day
Remarks:DNEL
Consumers Oral Acute systemic 4 mg/kg
effects bw/day
Remarks:DNEL
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name Environmental Compartment Value
Mercaptoacetic acid Fresh water 0,027 mg/l
CAS-No.: 68-11-1
Intermittent use/release 0,27 mg/l
Marine water 0,003 mg/l
Sewage treatment plant 0,5 mg/l
Fresh water sediment 0,009 mg/kg dry
weight (d.w.)
Marine sediment 0,001 mg/kg dry
weight (d.w.)
Soil 0,005 mg/kg dry
weight (d.w.)
8.2 Exposure controls
Engineering measures
Provide adequate ventilation.
Personal protective equipment
Eye/face protection : Tightly fitting safety goggles
Face-shield

Hand protection
Remarks : Neoprene gloves Nitrile rubber gloves. PVC or PE gloves

Skin and body protection : Wear suitable protective clothing.

Respiratory protection : Use only in well-ventilated areas.

In the case of vapour formation use a respirator with an
approved filter.
Equipment should conform to EN 14387
If the occupational exposure limits cannot be met, in
exceptional cases suitable respiratory equipment should be
worn only for a short period of time.
ABEK-P3-filter

Protective measures : Do not inhale vapours

Avoid contact with skin and eyes.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

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CORRTREAT 3747 Page 9(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

Physical state : Liquid

Colour : yellow to amber

Odour : pungent

Odour Threshold : not determined

Melting point : < 0 °C

Boiling point : > 100 °C

Upper explosion limit / upper : Not applicable

flammability limit

Lower explosion limit / Lower : Not applicable

flammability limit

Flash point : > 61 °C

Auto-ignition temperature : not available

Decomposition temperature : > 100 °C

pH : 5,17 (25 °C)

Concentration: 100 %

Viscosity
Viscosity, dynamic : ca. 3,3 mPa.s (23 °C)

Viscosity, kinematic : no data available

Solubility(ies)
Water solubility : soluble

Partition coefficient: n- : Not applicable

octanol/water

Vapour pressure : approx. 3 kPa (20 °C)

Density : ca. 1,02 g/cm3 (25 °C)

Relative vapour density : no data available

Particle characteristics
Particle size : Not applicable

9.2 Other information

Self-ignition : no data available

Metal corrosion rate : Not applicable

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Evaporation rate : Not applicable

SECTION 10: Stability and reactivity

10.1 Reactivity
See section 10.3. "Possibility of hazardous reactions"
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : With acids hydrogen sulphide is produced.

10.4 Conditions to avoid

Conditions to avoid : Keep away from heat.
Keep away from flames and sparks.

10.5 Incompatible materials

Materials to avoid : not known

10.6 Hazardous decomposition products

Carbon oxides
Sulphur oxides
Hydrogen sulfide (H2S)

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate: 1.351 mg/kg
Method: Calculation method

Acute inhalation toxicity : Acute toxicity estimate: > 20 mg/l

Exposure time: 4 h
Test atmosphere: vapour
Method: Calculation method

Acute dermal toxicity : Acute toxicity estimate: > 2.000 mg/kg

Method: Calculation method

Components:
Reaction product of tallow fatty propylene diamine, formaldehyde and ethylene oxide:
Acute oral toxicity : Assessment: The component/mixture is moderately toxic after
single ingestion.

Ethanediol:
Acute oral toxicity : LD50 (Rat, male and female): Method: Other
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GLP: no
Assessment: The component/mixture is moderately toxic after
single ingestion.

Acute inhalation toxicity : LC50 (Rat, male and female): > 2,5 mg/l
Exposure time: 6 h
Test atmosphere: dust/mist
Method: Other
GLP: yes
Assessment: The substance or mixture has no acute
inhalation toxicity

Acute dermal toxicity : LD50 (Mouse, male and female): > 3.500 mg/kg
Method: Other
GLP: yes
Assessment: The substance or mixture has no acute dermal
toxicity

Alkylpyridine benzyl chloride quaternary:

Acute oral toxicity : Assessment: The component/mixture is moderately toxic after
single ingestion.

Acute inhalation toxicity : Assessment: The component/mixture is toxic after short term
inhalation.

Acute dermal toxicity : Assessment: The component/mixture is toxic after single

contact with skin.

Mercaptoacetic acid:
Acute oral toxicity : LD50 (Rat, male and female): 73 mg/kg
Method: OECD Test Guideline 401

Acute inhalation toxicity : Assessment: The component/mixture is toxic after short term
inhalation.

Acute dermal toxicity : LD50 (Rabbit, male and female): 848 mg/kg
Method: OECD Test Guideline 402
GLP: no

Methanol:
Acute oral toxicity : LD50 (Rat, male and female): 1.187 - 2.769 mg/kg
Method: Other
GLP: no
Assessment: The component/mixture is toxic after single
ingestion.

Acute inhalation toxicity : LC50 (Rat, male and female): 87,5 mg/l
Exposure time: 6 h
Test atmosphere: vapour
Method: Other
GLP: no
Assessment: The component/mixture is toxic after short term
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inhalation.

Acute dermal toxicity : Assessment: The component/mixture is toxic after single

contact with skin.

Skin corrosion/irritation
Product:
Remarks : no data available

Components:
Reaction product of tallow fatty propylene diamine, formaldehyde and ethylene oxide:
Result : Irritating to skin.

Ethanediol:
Species : Rabbit
Exposure time : 20 h
Method : Other
Result : No skin irritation
GLP : no

Fatty acids, tall-oil, reaction products with polyethylenepolyamines:

Result : Irritating to skin.

Alkylpyridine benzyl chloride quaternary:

Result : Irritating to skin.

Mercaptoacetic acid:
Method : Other
Result : Causes burns.
GLP : yes

Methanol:
Species : Rabbit
Exposure time : <= 20 h
Method : Other
Result : No skin irritation
GLP : no

Serious eye damage/eye irritation

Product:
Remarks : no data available

Components:
Reaction product of tallow fatty propylene diamine, formaldehyde and ethylene oxide:
Result : Risk of serious damage to eyes.
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Ethanediol:
Species : Rabbit
Exposure time : 24 h
Method : Other
Result : No eye irritation
GLP : no

Fatty acids, tall-oil, reaction products with polyethylenepolyamines:

Result : Risk of serious damage to eyes.

Alkylpyridine benzyl chloride quaternary:

Result : Risk of serious damage to eyes.

Mercaptoacetic acid:
Species : Rabbit
Method : Directive 67/548/EEC, Annex V, B.5.
Result : Risk of serious damage to eyes.

Methanol:
Species : Rabbit
Method : Other
Result : No eye irritation
GLP : no

Respiratory or skin sensitisation

Product:
Remarks : no data available

Components:
Ethanediol:
Test Type : Maximisation Test
Exposure routes : Dermal
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Not a skin sensitizer.
GLP : yes

Assessment : Harmful if swallowed.

Alkylpyridine benzyl chloride quaternary:

Result : The product is a skin sensitiser, sub-category 1B.

Mercaptoacetic acid:
Remarks : no data available
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Methanol:
Test Type : Maximisation Test
Exposure routes : Dermal
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Not a skin sensitizer.
GLP : no

Assessment : Toxic if swallowed, in contact with skin or if inhaled.

Germ cell mutagenicity

Product:
Germ cell mutagenicity- : No information available.
Assessment

Components:
Ethanediol:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Concentration: 33 - 5000 μg/plate
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: yes

Test Type: Ames test

Test system: Escherichia coli
Concentration: 33 - 5000 μg/plate
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: yes

Test Type: Chromosome aberration test in vitro

Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation
Method: Other
Result: negative
GLP: yes

Test Type: In vitro mammalian cell gene mutation test

Test system: mouse lymphoma cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
GLP: yes

Genotoxicity in vivo : Test Type: Dominant lethal assay

Species: Rat (male and female)
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Strain: Fischer F344

Application Route: oral (feed)
Exposure time: 3 generation
Dose: 40 - 200 - 1000 mg/kg
Method: Other
Result: negative
GLP: no

Germ cell mutagenicity- : It is concluded that the product is not mutagenic based on
Assessment evaluation of several mutagenicity tests.

Mercaptoacetic acid:
Genotoxicity in vitro : Test Type: In vitro gene mutation study in bacteria
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative

Test Type: In vitro gene mutation study in mammalian cells

Test system: mouse lymphoma cells
Metabolic activation: with and without metabolic activation
Method: Regulation (EC) No. 440/2008, Annex, B.17
Result: negative
GLP: yes
Remarks: By analogy with a product of similar composition

Test Type: Chromosome aberration test in vitro

Test system: Human lymphocytes
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 473
Result: negative
GLP: yes

Genotoxicity in vivo : Test Type: Micronucleus test

Species: Mouse (male)
Strain: Switzerland
Application Route: Dermal
Dose: 1000, 500, 250 mg/kg
Method: OECD Test Guideline 474
Result: negative
GLP: yes

Test Type: Micronucleus test

Species: Mouse (female)
Strain: Switzerland
Application Route: Dermal
Dose: 500, 250, 125 mg/kg
Method: OECD Test Guideline 474
Result: negative
GLP: yes

Germ cell mutagenicity- : In vitro tests did not show mutagenic effects, In vivo tests did
Assessment not show mutagenic effects
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Methanol:
Genotoxicity in vitro : Test Type: Micronucleus test
Test system: Chinese hamster lung cells
Concentration: 40 mg/ml
Method: Other
Result: negative
GLP: No information available.

Test Type: HGPRT assay

Test system: Chinese hamster lung cells
Concentration: 15,8 - 63,3 mg/ml
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
GLP: No information available.

Test Type: In vitro gene mutation study in bacteria

Test system: Salmonella typhimurium
Concentration: 5 - 5000 μg/plate
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: No information available.

Genotoxicity in vivo : Test Type: Chromosome Aberration Test

Species: Mouse (male)
Strain: C57BL/6 x DBA/2
Application Route: Inhalation
Exposure time: 5 d, 6 h/day
Dose: 1,04 - 5,3 mg/l
Method: Other
Result: negative
GLP: No information available.

Germ cell mutagenicity- : It is concluded that the product is not mutagenic based on
Assessment evaluation of several mutagenicity tests.

Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment

Components:
Ethanediol:
Species : Mouse, male and female
Application Route : oral (feed)
Exposure time : 2a
Dose : 6250-12500-25000-50000 ppm
Control Group : yes
Frequency of Treatment : daily
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NOAEL : 1.500 mg/kg bw/day

Method : Other
GLP : yes

Carcinogenicity - : Not classifiable as a human carcinogen.

Assessment

Mercaptoacetic acid:
Species : Mouse, female
Application Route : Dermal
Dose : 1% and 2% in acetone
Method : Other
Result : negative
GLP : no
Remarks : By analogy with a product of similar composition

Carcinogenicity - : Not classifiable as a human carcinogen.

Assessment

Methanol:
Species : Rat, male and female
Application Route : Inhalation
Exposure time : 24
Dose : 0,013 - 0,13 - 1,3 mg/l
Control Group : yes
Frequency of Treatment : 20 h/day
NOAEL : >= 1,3 mg/l
Method : OECD Test Guideline 453
GLP : No information available.

Carcinogenicity - : Not classifiable as a human carcinogen.

Assessment

Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment No information available.

Components:
Ethanediol:
Effects on fertility : Test Type: Three-generation study
Species: Rat, male and female
Strain: Fischer F344
Application Route: oral (feed)
Dose: 40 - 200 - 1000
General Toxicity - Parent: NOAEL: > 1.000 mg/kg body weight
General Toxicity F1: NOAEL: > 1.000 mg/kg body weight
General Toxicity F2: NOAEL: > 1.000 mg/kg body weight
Method: Other
GLP: no
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Effects on foetal : Test Type: reproductive and developmental toxicity study

development Species: Rat, female
Strain: Sprague-Dawley
Application Route: oral (gavage)
Dose: 150 - 500 - 1000 - 2500 mg/kg
Duration of Single Treatment: 9 d
General Toxicity Maternal: NOEL: 1.500 mg/kg body weight
Teratogenicity: NOEL: 150 mg/kg body weight
Method: Other
GLP: yes

Reproductive toxicity - : No reproductive toxicity to be expected.

Assessment No teratogenic effects to be expected.

Mercaptoacetic acid:
Effects on fertility : Test Type: One generation study
Species: Rat, male and female
Strain: Sprague-Dawley
Application Route: oral (gavage)
Dose: 0, 20, 40 or 80 mg/kg/day
General Toxicity - Parent: NOEL: 20 mg/kg body weight
General Toxicity F1: NOEL: 40 mg/kg body weight
Method: OECD Test Guideline 421
GLP: yes
Remarks: By analogy with a product of similar composition

Effects on foetal : Test Type: Pre-natal

development Species: Rat
Strain: wistar
Application Route: oral (gavage)
Dose: 3, 15 and 75 mg/kg
General Toxicity Maternal: NOAEL: 15 mg/kg body weight
Developmental Toxicity: NOAEL: 75 mg/kg body weight
Method: OECD Test Guideline 414
GLP: yes
Remarks: By analogy with a product of similar composition

Test Type: Pre-natal

Species: Rat
Strain: Sprague-Dawley
Application Route: Dermal
Dose: 50, 100 or 200 mg//day
General Toxicity Maternal: NOAEL: < 50 mg/kg body weight
Developmental Toxicity: NOAEL: >= 100 mg/kg body weight
Method: OECD Test Guideline 414
GLP: yes
Remarks: By analogy with a product of similar composition

Test Type: Pre-natal

Species: Rabbit
Strain: New Zealand white
Application Route: Dermal
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Dose: 10, 15, 25 or 65 mg/kg/day

General Toxicity Maternal: NOAEL: >= 65 mg/kg body weight
Developmental Toxicity: NOAEL: >= 65 mg/kg body weight
Method: OECD Test Guideline 414
GLP: yes
Remarks: By analogy with a product of similar composition

Reproductive toxicity - : Weight of evidence does not support classification for

Assessment reproductive toxicity

Methanol:
Effects on fertility : Test Type: Two-generation study
Species: Rat, male and female
Strain: Sprague-Dawley
Application Route: Inhalation
Dose: 0,013 - 0,13 - 1,3 mg/l
Duration of Single Treatment: 20 h
General Toxicity - Parent: NOAEC: 1,3 mg/l
General Toxicity F1: NOAEC: 0,13 mg/l
General Toxicity F2: NOAEC: 0,13 mg/l
Method: OECD Test Guideline 416
GLP: No information available.

Effects on foetal : Test Type: Pre-natal

development Species: Rat, female
Strain: Sprague-Dawley
Application Route: Inhalation
Dose: 0,27 - 1,33 - 6,65 mg/l
Duration of Single Treatment: 22,7 h
General Toxicity Maternal: NOAEC: 1,33 mg/l
Teratogenicity: NOAEC F1: 1,33 mg/l
Method: OECD Test Guideline 414
GLP: No information available.

Test Type: Pre-natal

Species: Rat
Strain: Long-Evans
Application Route: oral (gavage)
Dose: 1027 - 2054 - 4108 mg/kg
Frequency of Treatment: 1
General Toxicity Maternal: LOAEL: 1.027 mg/kg body weight
Teratogenicity: LOAEL F1: 1.027 mg/kg body weight
Method: OECD Test Guideline 414
GLP: No information available.

Reproductive toxicity - : No reproductive toxicity to be expected.

Assessment No teratogenic effects to be expected.

STOT - single exposure

Product:
Remarks : no data available
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Components:
Ethanediol:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, single exposure.

Alkylpyridine benzyl chloride quaternary:

Assessment : May cause respiratory irritation.

Mercaptoacetic acid:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, single exposure.

Methanol:
Target Organs : Eyes, Central nervous system
Assessment : Causes damage to organs.

STOT - repeated exposure

Product:
Remarks : no data available

Components:
Ethanediol:
Exposure routes : Oral
Target Organs : Kidney
Assessment : May cause damage to organs through prolonged or repeated
exposure.

Alkylpyridine benzyl chloride quaternary:

Assessment : May cause damage to organs through prolonged or repeated
exposure.

Mercaptoacetic acid:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.

Methanol:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.

Repeated dose toxicity

Product:
Remarks : no data available
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Components:
Ethanediol:
Species : Rat, male
NOAEL : 150 mg/kg bw/day
Application Route : oral (feed)
Exposure time : 16 w
Number of exposures : daily
Dose : 50 - 150 - 500 - 1000 mg/kg
Control Group : yes
Method : OECD Test Guideline 408
GLP : No information available.

Species : Dog, male

NOAEL : 2.200 - 4.400 mg/kg bw/day
Application Route : Dermal
Exposure time : 4w
Number of exposures : daily
Dose : 2 - 4 mL/kg bw
Control Group : yes
Method : OECD Test Guideline 410
GLP : yes

Species : Rat, male and female

NOAEL : 200 mg/kg bw/day
Application Route : oral (gavage)
Exposure time : 33 d
Number of exposures : daily
Dose : 220, 660, 2000 mg/kg bw/day
Control Group : yes
Method : OECD Test Guideline 407

Species : Rat, male

NOAEL : 150 mg/kg bw/day
Application Route : oral (feed)
Exposure time : 12 months
Number of exposures : daily
Dose : 50, 150, 300, 400 mg/kg bw/day
Control Group : yes
Method : OECD Test Guideline 452

Mercaptoacetic acid:
Species : Rat, male and female
NOEL : 7 mg/kg
NOAEL : 20 mg/kg
LOAEL : 60 mg/kg
Application Route : oral (gavage)
Exposure time : 13 weeks
Number of exposures : 7 days/week
Dose : 7, 20, 60 mg/kg bw/d
Method : OECD Test Guideline 408
GLP : yes
Remarks : By analogy with a product of similar composition
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Species : Rat, male and female

NOAEL : >= 180 mg/kg
LOAEL : 11,25 mg/kg
Application Route : Dermal
Exposure time : 13 weeks
Number of exposures : 5 times/week
Dose : 11.25,22.5,45,90,180mg/kg bw/d
Method : OECD Test Guideline 411
Remarks : By analogy with a product of similar composition

Methanol:
Species : Monkey, male
LOAEL : 2.340 mg/kg
Application Route : oral (gavage)
Exposure time : 3d
Number of exposures : daily
Dose : 2340 mg/kg
Control Group : no data available
Method : Other
GLP : No information available.
Remarks : Significant toxicity observed in testing

Species : Rat, male and female

NOEL : 0,13 mg/l
LOAEL : 1,3 mg/l
Application Route : Inhalation
Test atmosphere : vapour
Exposure time : 12 m
Number of exposures : 20 h/day
Dose : 0,013 - 0,13 - 1,3 mg/l
Control Group : yes
Method : OECD Test Guideline 453
GLP : No information available.

Species : Rat, male and female

NOAEL : 6,66 mg/l
Application Route : Inhalation
Test atmosphere : vapour
Exposure time : 4w
Number of exposures : 6 h/d, 5 d/wk
Dose : 0,663 - 2,65 - 6,63 mg/l
Control Group : yes
Method : OECD Test Guideline 412
GLP : No information available.

Application Route : Skin contact

Remarks : not tested.

Aspiration toxicity
Product:
no data available
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Components:
Ethanediol:
No aspiration toxicity classification

Mercaptoacetic acid:
No aspiration toxicity classification

Methanol:
No aspiration toxicity classification

11.2 Information on other hazards

Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain components
considered to have endocrine disrupting properties according
to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.

SECTION 12: Ecological information

12.1 Toxicity
Product:
Toxicity to fish : Remarks: no data available

Toxicity to daphnia and other : Remarks: no data available

aquatic invertebrates

Toxicity to algae/aquatic : Remarks: no data available

plants

Toxicity to microorganisms :
Remarks: no data available

Components:
Reaction product of tallow fatty propylene diamine, formaldehyde and ethylene oxide:
Ecotoxicology Assessment
Acute aquatic toxicity : Very toxic to aquatic life.

Chronic aquatic toxicity : Very toxic to aquatic life with long lasting effects.

Ethanediol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 72.860 mg/l
Exposure time: 96 h
Test Type: static test
Analytical monitoring: yes
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Method: EPA
GLP: no
Remarks: The details of the toxic effect relate to the nominal
concentration.

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test
Analytical monitoring: yes
Method: OECD Test Guideline 202
GLP: yes

Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (green algae)): 6.500 -

plants 13.000 mg/l
End point: Growth rate
Exposure time: 7 d
Test Type: static test
Analytical monitoring: no data available
Method: EPA
GLP: No information available.

Toxicity to microorganisms : EC20 (activated sludge, domestic): > 1.995 mg/l

End point: Bacteria toxicity (respiration inhibition)
Exposure time: 0,5 h
Analytical monitoring: no
Method: ISO 8192
GLP: no

Toxicity to fish (Chronic : Chronic Toxicity Value: 2.629 mg/l

toxicity) End point: Other
Exposure time: 30 d
Species: Fish
Method: Other
GLP: no
Remarks: The value is given based on a SAR/AAR approach
using OECD Toolbox, DEREK, VEGA QSAR models
(CAESAR models), etc.

Toxicity to daphnia and other : NOEC: 8.590 mg/l

aquatic invertebrates End point: Reproduction rate
(Chronic toxicity) Exposure time: 7 d
Species: Ceriodaphnia spec.
Test Type: semi-static test
Analytical monitoring: yes
Method: Other
GLP: No information available.
Remarks: The details of the toxic effect relate to the nominal
concentration.

Fatty acids, tall-oil, reaction products with polyethylenepolyamines:

Ecotoxicology Assessment
Acute aquatic toxicity : Very toxic to aquatic life.
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Chronic aquatic toxicity : Very toxic to aquatic life with long lasting effects.

Alkylpyridine benzyl chloride quaternary:

Ecotoxicology Assessment
Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects.

Mercaptoacetic acid:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l
End point: mortality
Exposure time: 96 h
Test Type: flow-through test
Method: OECD Test Guideline 203
GLP: yes

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 38 mg/l
aquatic invertebrates End point: Immobilization
Exposure time: 48 h
Test Type: static test
Method: OECD Test Guideline 202
GLP: yes

Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (algae)): 13 mg/l

plants End point: Biomass
Exposure time: 72 h
Test Type: static test
Method: OECD Test Guideline 201
GLP: yes

EC50 (Pseudokirchneriella subcapitata (algae)): 27 mg/l

End point: Growth rate
Exposure time: 72 h
Test Type: static test
Method: OECD Test Guideline 201
GLP: yes

Toxicity to microorganisms : EC50 (activated sludge): 530 mg/l

Exposure time: 3 h
Test Type: static test
Method: OECD Test Guideline 209
GLP: yes
Remarks: By analogy with a product of similar composition

NOEC (activated sludge): 32 mg/l

Exposure time: 3 h
Test Type: static test
Method: OECD Test Guideline 209
GLP: yes
Remarks: By analogy with a product of similar composition

Toxicity to fish (Chronic : Remarks: no data available

toxicity)
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Toxicity to daphnia and other : Remarks: no data available

aquatic invertebrates
(Chronic toxicity)

Methanol:
Toxicity to fish : LC50 (Lepomis macrochirus (Bluegill sunfish)): 15.400 mg/l
End point: mortality
Exposure time: 96 h
Test Type: flow-through test
Analytical monitoring: yes
Method: EPA
GLP: No information available.

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 18.260 mg/l
aquatic invertebrates End point: Immobilization
Exposure time: 96 h
Test Type: semi-static test
Analytical monitoring: no data available
Method: OECD Test Guideline 202
GLP: No information available.
Remarks: The details of the toxic effect relate to the nominal
concentration.

Toxicity to algae/aquatic : ErC50 (Pseudokirchneriella subcapitata (microalgae)): ca.

plants 22.000 mg/l
End point: Growth rate
Exposure time: 96 h
Test Type: static test
Analytical monitoring: no data available
Method: OECD Test Guideline 201
GLP: No information available.

Toxicity to microorganisms : IC50 (activated sludge): > 1.000 mg/l

End point: Bacteria toxicity (growth inhibition)
Exposure time: 3 h
Test Type: aquatic
Analytical monitoring: yes
Method: OECD Test Guideline 209
GLP: No information available.

Toxicity to fish (Chronic : NOEC: 446,7 mg/l

toxicity) Exposure time: 28 d
Species: Pimephales promelas (fathead minnow)
Method: Other
GLP: no
Remarks: The value is given based on a SAR/AAR approach
using OECD Toolbox, DEREK, VEGA QSAR models
(CAESAR models), etc.

Toxicity to daphnia and other : NOEC: 208 mg/l

aquatic invertebrates End point: Reproduction rate
(Chronic toxicity) Exposure time: 21 d
Species: Daphnia magna (Water flea)
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Method: calculated
GLP: no
Remarks: The value is given based on a SAR/AAR approach
using OECD Toolbox, DEREK, VEGA QSAR models
(CAESAR models), etc.

Toxicity to soil dwelling : LC50: > 1 mg/cm2

organisms Exposure time: 48 h
End point: mortality
Species: Eisenia fetida (earthworms)
Method: OECD Test Guideline 207
GLP:No information available.

NOEC:
10000 mg/kg dry weight (d.w.)
Exposure time: 28 d
End point: mortality
Species: Folsomia candida
Method: Other
GLP:No information available.

Plant toxicity : IC50: ca. 41.000 mg/l

Exposure time: 3 d
End point: emergence
Species: Lactuca sativa (lettuce)
Analytical monitoring: no data available
Method: Other
GLP:no

Sediment toxicity : Remarks: Not applicable

12.2 Persistence and degradability

Product:
Biodegradability : Biodegradation: < 20 %
Method: OECD

Components:
Ethanediol:
Biodegradability : Test Type: aerobic
Inoculum: activated sludge
Concentration: 53 mg/l
Result: Readily biodegradable.
Biodegradation: 90 - 100 %
Related to: Dissolved organic carbon (DOC)
Exposure time: 10 d
Method: OECD Test Guideline 301A
GLP: yes

Mercaptoacetic acid:
Biodegradability : Test Type: aerobic
Inoculum: activated sludge
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Result: Readily biodegradable.

Biodegradation: 67 %
Exposure time: 28 d
Method: OECD Test Guideline 301D

Methanol:
Biodegradability : Test Type: aerobic
Inoculum: activated sludge
Concentration: 3 - 10 mg/l
Result: Readily biodegradable.
Biodegradation: 95 %
Related to: Biochemical Oxygen Demand (BOD)
Exposure time: 20 d
Method: Closed Bottle test
GLP: no

Test Type: aerobic

Inoculum: activated sludge
Concentration: 4 - 200 g/l
Result: Readily biodegradable.
Biodegradation: 82,7 %
Related to: Biochemical Oxygen Demand (BOD)
Exposure time: 5 d
Method: Other
GLP: no

Photodegradation : Rate constant: 9,32E-13 cm3/s

Degradation (indirect photolysis): 50 % Degradation half life:
17,2 d
GLP: no

12.3 Bioaccumulative potential

Product:
Bioaccumulation : Remarks: no data available

Components:
Ethanediol:
Bioaccumulation : Remarks: Due to the low logPow bioaccumulation is not
expected

Partition coefficient: n- : log Pow: -1,36

octanol/water Method: estimated
GLP: no

Mercaptoacetic acid:
Bioaccumulation : Remarks: No bioaccumulation is to be expected (log Pow <=
4).

Partition coefficient: n- : log Pow: -2,99 (22 °C)

octanol/water pH: 7
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Method: OECD Test Guideline 107

Methanol:
Bioaccumulation : Species: Leuciscus idus (Golden orfe)
Exposure time: 72 h
Bioconcentration factor (BCF): < 10
Method: Other
GLP: No information available.

Partition coefficient: n- : log Pow: -0,77

octanol/water Method: No information available.
GLP: No information available.

12.4 Mobility in soil

Product:
Distribution among : Remarks: no data available
environmental compartments

Components:
Ethanediol:
Distribution among : Adsorption/Soil
environmental compartments Medium: water - soil
log Koc: 0
Method: other (calculated)

Methanol:
Distribution among : Adsorption/Soil
environmental compartments Medium: water - soil
Koc: 1
Method: other (calculated)

12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

Components:
Ethanediol:
Assessment : This substance is not considered to be persistent,
bioaccumulating and toxic (PBT).

Methanol:
Assessment : This substance is not considered to be persistent,
bioaccumulating and toxic (PBT).
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12.6 Endocrine disrupting properties

Product:
Assessment : The substance/mixture does not contain components
considered to have endocrine disrupting properties according
to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.

12.7 Other adverse effects

Product:
Additional ecological : no data available
information

Components:
Ethanediol:
Environmental fate and : not available
pathways

Additional ecological : Do not allow to enter ground water, waterways or waste water.
information

Methanol:
Environmental fate and : not available
pathways

Additional ecological : Do not allow to enter ground water, waterways or waste water.
information

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : Dispose of in accordance with local regulations.

Contaminated packaging : Packaging that cannot be cleaned should be disposed of as

product waste

SECTION 14: Transport information

Section 14.1. to 14.5.

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ADR
UN no. UN 1760
Proper shipping name: Corrosive liquid, n.o.s.
Hazard inducer(s): Thioglycolic acid
Fatty acids, tall-oil, reaction products with
polyethylenepolyamines
Class: 8
Primary risk: 8
Packing group: II
Hazard no. : 80
Environmental hazards: Special marking provision: environmentally hazardous
Remarks Shipment permitted
ADN
UN no. UN 1760
Proper shipping name: Corrosive liquid, n.o.s.
Hazard inducer(s): Thioglycolic acid
Fatty acids, tall-oil, reaction products with
polyethylenepolyamines
Class: 8
Primary risk: 8
Packing group: II
Environmental hazards: Special marking provision: environmentally hazardous
Remarks Shipment permitted
RID
UN no. UN 1760
Proper shipping name: Corrosive liquid, n.o.s.
Hazard inducer(s): Thioglycolic acid
Fatty acids, tall-oil, reaction products with
polyethylenepolyamines
Class: 8
Primary risk: 8
Packing group: II
Hazard no. : 80
Environmental hazards: Special marking provision: environmentally hazardous
Remarks Shipment permitted
IATA
UN no. UN 1760
Proper shipping name: Corrosive liquid, n.o.s.
Hazard inducer(s): Thioglycolic acid
Fatty acids, tall-oil, reaction products with
polyethylenepolyamines
Class: 8
Primary risk: 8
Packing group: II
Environmental hazards: Special marking provision: environmentally hazardous
Remarks Shipment permitted
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IMDG
UN no. UN 1760
Proper shipping name: Corrosive liquid, n.o.s.
Hazard inducer(s): Thioglycolic acid
Fatty acids, tall-oil, reaction products with
polyethylenepolyamines
Class: 8
Primary risk: 8
Packing group: II
Environmental hazards: Special marking provision: environmentally hazardous
Remarks Shipment permitted
Marine pollutant: Marine Pollutant
Hazard inducer/Marine Fatty acids, tall-oil, reaction products with
pollutant: polyethylenepolyamines
EmS : F-A S-B

14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.

14.7. Maritime transport in bulk according to IMO instruments

No transport as bulk according IBC - Code.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
REACH - Restrictions on the manufacture, placing on : Conditions of restriction for the
the market and use of certain dangerous substances, following entries should be
mixtures and articles (Annex XVII) considered:
Number on list 3
Methanol (Number on list 75, 69)

REACH - Candidate List of Substances of Very High : Not applicable

Concern for Authorisation (Article 59).

Regulation (EC) No 1005/2009 on substances that : Not applicable

deplete the ozone layer

Regulation (EU) 2019/1021 on persistent organic : Not applicable

pollutants (recast)

Council Regulation (EC) No 111/2005 laying down rules : Neither banned nor restricted
for the monitoring of trade between the Community and
third countries in drug precursors

Regulation (EC) No 649/2012 of the European : Not applicable

Parliament and the Council concerning the export and
import of dangerous chemicals

REACH - List of substances subject to authorisation : Not applicable

(Annex XIV)
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Other regulations:
Apart from the data/regulations specified in this chapter, no further information is available
concerning safety, health and environmental protection.

European Regulation (EC) No 1272/2008 on classification, labelling and packaging of

substances and mixtures.

15.2 Chemical safety assessment

Chemical Safety Assessments (CSAs) are available for one or more of the component substances
contained in this product.

SECTION 16: Other information

Full text of H-Statements

H225 : Highly flammable liquid and vapour.
H301 : Toxic if swallowed.
H302 : Harmful if swallowed.
H311 : Toxic in contact with skin.
H314 : Causes severe skin burns and eye damage.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H318 : Causes serious eye damage.
H331 : Toxic if inhaled.
H335 : May cause respiratory irritation.
H370 : Causes damage to organs.
H373 : May cause damage to organs through prolonged or repeated
exposure.
H373 : May cause damage to organs through prolonged or repeated
exposure if swallowed.
H400 : Very toxic to aquatic life.
H410 : Very toxic to aquatic life with long lasting effects.
H411 : Toxic to aquatic life with long lasting effects.
Full text of other abbreviations
Acute Tox. : Acute toxicity
Aquatic Acute : Short-term (acute) aquatic hazard
Aquatic Chronic : Long-term (chronic) aquatic hazard
Eye Dam. : Serious eye damage
Flam. Liq. : Flammable liquids
Skin Corr. : Skin corrosion
Skin Irrit. : Skin irritation
Skin Sens. : Skin sensitisation
STOT RE : Specific target organ toxicity - repeated exposure
STOT SE : Specific target organ toxicity - single exposure

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - Agreement concerning the International Carriage of Dangerous Goods by
Road; AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the
Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation;
Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN -
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Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada);
ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Concentration associated with x% response; ELx - Loading rate associated with x% response;
EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; GHS - Globally Harmonized System;
GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic
Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention;
PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council
concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID -
Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-
Accelerating Decomposition Temperature; SDS - Safety Data Sheet; SVHC - Substance of Very
High Concern; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand Existing Chemicals
Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Substances Control
Act (United States); UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative
Further information
Other information : Observe national and local legal requirements

Classification of the mixture: Classification procedure:

Acute Tox. 4 H302 Calculation method
Skin Irrit. 2 H315 Calculation method
Eye Dam. 1 H318 Calculation method
Skin Sens. 1 H317 Calculation method
Aquatic Chronic 2 H411 Calculation method

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet
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information before handling any of these products. For additional information, please contact
Clariant.

REG_EU / EN
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Exposure scenario

Number Title
ES 1 Formulation or re-packing; Formulation & (re)packing of substances and
mixtures
PROC1, PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC15,
PROC28 - ERC2
2-Butoxyethanol
ES 2 Widespread use by professional workers; Use in oil and gas field drilling
and production operations, off-shore
PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC28 - ERC8d
2-Butoxyethanol
ES 3 Widespread use by professional workers; Use in oil and gas field drilling
and production operations, on-shore
PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC28 - ERC8d
2-Butoxyethanol
ES 4 Use at industrial sites; Use in oil and gas field drilling and production
operations, off-shore
PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC28 - ERC4
2-Butoxyethanol
ES 5 Use at industrial sites; Use in oil and gas field drilling and production
operations, on-shore
PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC28 - ERC4
2-Butoxyethanol

1. ES 1: Formulation or re-packing; Formulation &

(re)packing of substances and mixtures
1.1. Title section

Environment
CS1: Formulation or re-packing (Formulation into mixture) ERC2
Workers
CS2: Formulation or re-packing (General measures applicable to all activities) CS135
CS3: Formulation or re-packing (Chemical production or refinery in closed PROC1
process without likelihood of exposure or processes with equivalent
containment conditions)
CS4: Formulation or re-packing (Chemical production or refinery in closed PROC2
continuous process with occasional controlled exposure or processes
with equivalent containment conditions)
CS5: Formulation or re-packing (Manufacture or formulation in the chemical PROC3
industry in closed batch processes with occasional controlled exposure
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or processes with equivalent containment condition)

CS6: Formulation or re-packing (Chemical production where opportunity for PROC4
exposure arises)
CS7: Formulation or re-packing (Transfer of substance or mixture PROC8b
(charging/discharging) at dedicated facilities)
CS8: Formulation or re-packing (Mixing or blending in batch processes) PROC5
CS9: Formulation or re-packing (Transfer of substance or mixture PROC8a
(charging/discharging) at non dedicated-facilities)
CS10: Formulation or re-packing (Manual maintenance (cleaning and repair) of PROC28
machinery)
CS11: Formulation or re-packing (Transfer of substance or mixture into small PROC9
containers (dedicated filling line, including weighing))
CS12: Formulation or re-packing (Use as laboratory reagent) PROC15

1.2. ES 1 Conditions of use affecting exposure

1.2.1 ES 1 - CS 1: Control of environmental exposure: Formulation or re-packing
(Formulation into mixture) (ERC2)

Remarks : ESVOC SPERC 2.2.v1

Product characteristics
Physical Form (at time of use) : Liquid, vapour pressure < 0.5 kPa at Standard Temperature
and Pressure
Remarks : Non-hydrophobic

Amount used
Annual amount per site : 8330 tonnes/year
Daily amount per site : 27800 kg/day
Daily amount per site (Msafe) : 185.000 kg

Environment factors not influenced by risk management

Dilution Factor (River) : 10
Dilution Factor (Coastal Areas) : 100

Other given operational conditions affecting environmental exposure

Number of emission days per year : 300
Remarks : Continuous process, Continuous release

Technical conditions and measures / Organizational measures

Water : Prevent discharge of undissolved substance to or recover
from onsite wastewater.
Remarks : Bund storage facilities to prevent soil and water pollution in
the event of spillage.
Prevent environmental discharge consistent with regulatory
requirements.
A leak prevention plan is needed to prevent low level continual
releases.
Site should have a spill plan to ensure that adequate
safeguards are in place to minimize the impact of episodic
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releases.

Conditions and measures related to sewage treatment plant

Type of Sewage Treatment Plant : Sewage treatment plant
Flow rate of sewage treatment : 2.000 m3/d
plant effluent
Effectiveness (of a measure) : 87 %

Waste management measures

Disposal methods : Incineration (Effectiveness (of a measure): 99,98 %)
Waste treatment : This material and its container must be disposed of as
hazardous., Dispose of waste product or used containers
according to local regulations.

1.2.2 ES 1 - CS 2: Control of worker exposure: Formulation or re-packing (General

measures applicable to all activities) (CS135)

Product characteristics
Concentration of the Substance in : <= 100 %
Mixture/Article

Physical Form (at time of use) : Liquid, vapour pressure < 0.5 kPa at Standard Temperature
and Pressure
Remarks : Assumes use at not more than 20°C above ambient
temperature.

Frequency and duration of use

Exposure duration : 8h
Remarks : Continuous process

Other operational conditions affecting workers exposure

Remarks : Assumes a good basic standard of occupational hygiene is
implemented

Risk Management Measures

Organisational measures to : Ensure that direct skin contact is avoided.
prevent /limit releases, dispersion Identify potential areas for indirect skin contact.
and exposure Clear spills immediately.
Wash off any skin contamination immediately.
Ensure operatives are trained to minimise exposures.
Avoid direct eye contact with product, also via contamination
on hands.
Avoid splashing.

Technical conditions and : Formulate in enclosed or ventilated mixing vessels.

measures

Personal protective measures : Use suitable eye protection.

For further specification, refer to section 8 of the SDS.

Personal protective measures : In case of potential exposure:

Wear suitable gloves tested to EN374.
For further specification, refer to section 8 of the SDS.
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1.2.3 ES 1 - CS 3: Control of worker exposure: Formulation or re-packing (Chemical

production or refinery in closed process without likelihood of exposure or processes
with equivalent containment conditions) (PROC1)

Remarks : General exposures

Closed systems
Continuous process
no sampling

Risk Management Measures

Note : No other specific measures identified.

1.2.4 ES 1 - CS 4: Control of worker exposure: Formulation or re-packing (Chemical

production or refinery in closed continuous process with occasional controlled
exposure or processes with equivalent containment conditions) (PROC2)

Remarks : General exposures

Closed systems
Continuous process
With sample collection
Bulk product storage

Risk Management Measures

Note : No other specific measures identified.

1.2.5 ES 1 - CS 5: Control of worker exposure: Formulation or re-packing

(Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition)
(PROC3)

Remarks : General exposures

Use in contained systems
Batch process
With sample collection
Process sampling

Risk Management Measures

Note : No other specific measures identified.

1.2.6 ES 1 - CS 6: Control of worker exposure: Formulation or re-packing (Chemical

production where opportunity for exposure arises) (PROC4)

Remarks : General exposures

Open systems

Risk Management Measures

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Note : No other specific measures identified.

1.2.7 ES 1 - CS 7: Control of worker exposure: Formulation or re-packing (Transfer of

substance or mixture (charging/discharging) at dedicated facilities) (PROC8b)

Remarks : Bulk transfers

Drum/batch transfers

Risk Management Measures

Note : No other specific measures identified.

1.2.8 ES 1 - CS 8: Control of worker exposure: Formulation or re-packing (Mixing or

blending in batch processes) (PROC5)

Remarks : Mixing operations

Open systems

Risk Management Measures

Note : No other specific measures identified.

1.2.9 ES 1 - CS 9: Control of worker exposure: Formulation or re-packing (Transfer of

substance or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Remarks : Transfer from/pouring from containers

Manual

Risk Management Measures

Note : No other specific measures identified.

1.2.10 ES 1 - CS 10: Control of worker exposure: Formulation or re-packing (Manual

maintenance (cleaning and repair) of machinery) (PROC28)

Remarks : Equipment cleaning and maintenance

Risk Management Measures

Note : No other specific measures identified.

1.2.11 ES 1 - CS 11: Control of worker exposure: Formulation or re-packing (Transfer

of substance or mixture into small containers (dedicated filling line, including
weighing)) (PROC9)

Remarks : Drum and small package filling

Risk Management Measures

Note : No other specific measures identified.
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1.2.12 ES 1 - CS 12: Control of worker exposure: Formulation or re-packing (Use as

laboratory reagent) (PROC15)

Remarks : Laboratory activities

Risk Management Measures

Note : No other specific measures identified.

1.3. ES 1 Exposure estimation and reference to its source

1.3.1 ES 1 - CS 1: Environmental release and exposure: Formulation or re-packing
(Formulation into mixture) (ERC2)

Release route Release rate Release estimation method

Air 0,1 % ESVOC SPERC 2.2.v1, (Initial release
prior to RMM)
Water 0,5 % ESVOC SPERC 2.2.v1, (Initial release
prior to RMM)
Soil 0,01 % ESVOC SPERC 2.2.v1, (Initial release
prior to RMM)

protection target Exposure estimation and reference to its source RCR

(ECETOC TRA)
Sewage treatment plant 69,5 mg/L (Risk from environmental exposure is driven 0,15
by wastewater treatment plant microbes.)
Freshwater 0,885 mg/L 0,10
Freshwater sediment 3,77 mg/kg dry weight 0,11
Marine water 0,0886 mg/L 0,10
Marine sediment 0,377 mg/kg dry weight 0,11
Soil 0,150 mg/kg dry weight 0,06

1.3.3 ES 1 - CS 3: Worker exposure: Formulation or re-packing (Chemical production

or refinery in closed process without likelihood of exposure or processes with
equivalent containment conditions) (PROC1)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 0,01 ppm (ECETOC TRA worker v3, long-term) < 0,01
inhalative 0,04 ppm (ECETOC TRA worker v3, short-term) < 0,01
dermal 0,03 mg/kg bw/day (ECETOC TRA worker v3)

1.3.4 ES 1 - CS 4: Worker exposure: Formulation or re-packing (Chemical production

or refinery in closed continuous process with occasional controlled exposure or
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processes with equivalent containment conditions) (PROC2)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 1 ppm (ECETOC TRA worker v3, long-term) 0,05
inhalative 4 ppm (ECETOC TRA worker v3, short-term) 0,08
dermal 1,4 mg/kg bw/day (ECETOC TRA worker v3)

1.3.5 ES 1 - CS 5: Worker exposure: Formulation or re-packing (Manufacture or

formulation in the chemical industry in closed batch processes with occasional
controlled exposure or processes with equivalent containment condition) (PROC3)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 3 ppm (ECETOC TRA worker v3, long-term) 0,15
inhalative 12 ppm (ECETOC TRA worker v3, short-term) 0,24
dermal 0,69 mg/kg bw/day (ECETOC TRA worker v3)

1.3.6 ES 1 - CS 6: Worker exposure: Formulation or re-packing (Chemical production

where opportunity for exposure arises) (PROC4)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 5 ppm (ECETOC TRA worker v3, long-term) 0,25
inhalative 20 ppm (ECETOC TRA worker v3, short-term) 0,4
dermal 6,9 mg/kg bw/day (ECETOC TRA worker v3)

1.3.7 ES 1 - CS 7: Worker exposure: Formulation or re-packing (Transfer of

substance or mixture (charging/discharging) at dedicated facilities) (PROC8b)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 5 ppm (ECETOC TRA worker v3, long-term) 0,25
inhalative 20 ppm (ECETOC TRA worker v3, short-term) 0,4
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

1.3.8 ES 1 - CS 8: Worker exposure: Formulation or re-packing (Mixing or blending in

batch processes) (PROC5)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 5 ppm (ECETOC TRA worker v3, long-term) 0,25
inhalative 20 ppm (ECETOC TRA worker v3, short-term) 0,4
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)
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1.3.9 ES 1 - CS 9: Worker exposure: Formulation or re-packing (Transfer of

substance or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 10 ppm (ECETOC TRA worker v3, long-term) 0,5
inhalative 40 ppm (ECETOC TRA worker v3, short-term) 0,8
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

1.3.10 ES 1 - CS 10: Worker exposure: Formulation or re-packing (Manual

maintenance (cleaning and repair) of machinery) (PROC28)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 10 ppm (ECETOC TRA worker v3, long-term) 0,5
inhalative 40 ppm (ECETOC TRA worker v3, short-term) 0,8
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

1.3.11 ES 1 - CS 11: Worker exposure: Formulation or re-packing (Transfer of

substance or mixture into small containers (dedicated filling line, including weighing))
(PROC9)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 5 ppm (ECETOC TRA worker v3, long-term) 0,25
inhalative 20 ppm (ECETOC TRA worker v3, short-term) 0,4
dermal 6,9 mg/kg bw/day (ECETOC TRA worker v3)

1.3.12 ES 1 - CS 12: Worker exposure: Formulation or re-packing (Use as laboratory

reagent) (PROC15)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 5 ppm (ECETOC TRA worker v3, long-term) 0,25
inhalative 20 ppm (ECETOC TRA worker v3, short-term) 0,4
dermal 0,34 mg/kg bw/day (ECETOC TRA worker v3)

1.4. ES 1 Guidance to Downstream User to evaluate whether he

works inside the boundaries set by the Exposure Scenario
Health
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Risk management measures are based on qualitative risk characterisation.
Available hazard data do not enable the derivation of a DNEL for eye irritant effects.
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Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites;
thus, scaling may be necessary to define appropriate site-specific risk management measures.
Further details on scaling and control technologies are provided in SPERC factsheet.

2. ES 2: Widespread use by professional workers; Use in

oil and gas field drilling and production operations, off-
shore
2.1. Title section

Environment
CS1: Widespread use by professional workers (Widespread use of non- ERC8d
reactive processing aid (no inclusion into or onto article, outdoor))
Workers
CS2: Widespread use by professional workers (General measures applicable CS135
to all activities)
CS3: Widespread use by professional workers (Transfer of substance or PROC8b
mixture (charging/discharging) at dedicated facilities)
CS4: Widespread use by professional workers (Manufacture or formulation in PROC3
the chemical industry in closed batch processes with occasional
controlled exposure or processes with equivalent containment condition)
CS5: Widespread use by professional workers (Chemical production where PROC4
opportunity for exposure arises)
CS6: Widespread use by professional workers (Chemical production where PROC4
opportunity for exposure arises)
CS7: Widespread use by professional workers (Transfer of substance or PROC8a
mixture (charging/discharging) at non dedicated-facilities)
CS8: Widespread use by professional workers (Transfer of substance or PROC8a
mixture (charging/discharging) at non dedicated-facilities)
CS9: Widespread use by professional workers (Chemical production or PROC1
refinery in closed process without likelihood of exposure or processes
with equivalent containment conditions)
CS10: Widespread use by professional workers (Transfer of substance or PROC8a
mixture (charging/discharging) at non dedicated-facilities)
CS11: Widespread use by professional workers (Transfer of substance or PROC8a
mixture (charging/discharging) at non dedicated-facilities)
CS12: Widespread use by professional workers (Manual maintenance PROC28
(cleaning and repair) of machinery)
CS13: Widespread use by professional workers (Manual maintenance PROC28
(cleaning and repair) of machinery)
CS14: Widespread use by professional workers (Chemical production or PROC2
refinery in closed continuous process with occasional controlled
exposure or processes with equivalent containment conditions)

2.2. ES 2 Conditions of use affecting exposure

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2.2.1 ES 2 - CS 1: Control of environmental exposure: Widespread use by

professional workers (Widespread use of non-reactive processing aid (no inclusion
into or onto article, outdoor)) (ERC8d)

Product characteristics
Physical Form (at time of use) : Liquid, vapour pressure < 0.5 kPa at Standard Temperature
and Pressure
Remarks : Non-hydrophobic

Amount used
Amounts used (Msafe) : 316.000 kg/day

Other given operational conditions affecting environmental exposure

Number of emission days per year : 365
Remarks : Wide dispersive use, Continuous process

Technical conditions and measures / Organizational measures

Remarks : Prevent environmental discharge consistent with regulatory
requirements.

Waste management measures

Waste treatment : External treatment and disposal of waste should comply with
applicable local and/or national regulations., Dispose of waste
product or used containers according to local regulations.,
This material and its container must be disposed of as
hazardous.

2.2.2 ES 2 - CS 2: Control of worker exposure: Widespread use by professional

workers (General measures applicable to all activities) (CS135)

Product characteristics
Concentration of the Substance in : <= 100 %
Mixture/Article

Physical Form (at time of use) : Liquid, vapour pressure < 0.5 kPa at Standard Temperature
and Pressure
Remarks : Assumes use at not more than 20°C above ambient
temperature.

Frequency and duration of use

Exposure duration : 12 h
Remarks : Continuous process

Other operational conditions affecting workers exposure

Remarks : Assumes a good basic standard of occupational hygiene is
implemented

Risk Management Measures

Organisational measures to : Ensure there is no direct skin contact with product.
prevent /limit releases, dispersion Identify potential areas for indirect skin contact.
and exposure Clear spills immediately.
Wash off any skin contamination immediately.
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Ensure operatives are trained to minimise exposures.

Avoid direct eye contact with product, also via contamination
on hands.
Avoid splashing.

Personal protective measures : Use suitable eye protection.

For further specification, refer to section 8 of the SDS.

Personal protective measures : In case of potential exposure:

Wear suitable gloves tested to EN374.
For further specification, refer to section 8 of the SDS.

2.2.3 ES 2 - CS 3: Control of worker exposure: Widespread use by professional

workers (Transfer of substance or mixture (charging/discharging) at dedicated
facilities) (PROC8b)

Remarks : Bulk transfers from tote tanks and supply vessels

Filling of equipment from drums or containers

Risk Management Measures

Note : No other specific measures identified.

2.2.4 ES 2 - CS 4: Control of worker exposure: Widespread use by professional

workers (Manufacture or formulation in the chemical industry in closed batch
processes with occasional controlled exposure or processes with equivalent
containment condition) (PROC3)

Remarks : Drilling mud (re-)formulation

Treatment and disposal of filtered solids
Process sampling

Risk Management Measures

Note : No other specific measures identified.

2.2.5 ES 2 - CS 5: Control of worker exposure: Widespread use by professional

workers (Chemical production where opportunity for exposure arises) (PROC4)

Remarks : Drill floor operations

Scale squeeze operations

Risk Management Measures

Note : No other specific measures identified.

2.2.6 ES 2 - CS 6: Control of worker exposure: Widespread use by professional

workers (Chemical production where opportunity for exposure arises) (PROC4)

Remarks : Operation of solids filtering equipment

With potential for aerosol generation
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Elevated temperature

Risk Management Measures

Technical conditions and : Provide extract ventilation to points where emissions occur.
measures

2.2.7 ES 2 - CS 7: Control of worker exposure: Widespread use by professional

workers (Transfer of substance or mixture (charging/discharging) at non dedicated-
facilities) (PROC8a)

Remarks : Cleaning of solids filtering equipment

Risk Management Measures

Technical conditions and : Drain down system prior to equipment break-in or
measures maintenance.
Provide a good standard of general ventilation (not less than 3
to 5 air changes per hour).

2.2.8 ES 2 - CS 8: Control of worker exposure: Widespread use by professional

workers (Transfer of substance or mixture (charging/discharging) at non dedicated-
facilities) (PROC8a)

Remarks : Cleaning of solids filtering equipment

Risk Management Measures

Technical conditions and : Drain down system prior to equipment break-in or
measures maintenance.
Ensure operation is undertaken outdoors.

2.2.9 ES 2 - CS 9: Control of worker exposure: Widespread use by professional

workers (Chemical production or refinery in closed process without likelihood of
exposure or processes with equivalent containment conditions) (PROC1)

Remarks : Application by injection

Risk Management Measures

Note : No other specific measures identified.

2.2.10 ES 2 - CS 10: Control of worker exposure: Widespread use by professional

workers (Transfer of substance or mixture (charging/discharging) at non dedicated-
facilities) (PROC8a)

Remarks : Transfer from/pouring from containers

Risk Management Measures

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Technical conditions and : Provide a good standard of general ventilation (not less than 3
measures to 5 air changes per hour).
Use drum pumps or carefully pour from container.

2.2.11 ES 2 - CS 11: Control of worker exposure: Widespread use by professional

workers (Transfer of substance or mixture (charging/discharging) at non dedicated-
facilities) (PROC8a)

Remarks : Transfer from/pouring from containers

Risk Management Measures

Technical conditions and : Ensure operation is undertaken outdoors.
measures Use drum pumps or carefully pour from container.

2.2.12 ES 2 - CS 12: Control of worker exposure: Widespread use by professional

workers (Manual maintenance (cleaning and repair) of machinery) (PROC28)

Remarks : Equipment cleaning and maintenance

Risk Management Measures

Technical conditions and : Drain down system prior to equipment break-in or
measures maintenance.
Provide a good standard of general ventilation (not less than 3
to 5 air changes per hour).

2.2.13 ES 2 - CS 13: Control of worker exposure: Widespread use by professional

workers (Manual maintenance (cleaning and repair) of machinery) (PROC28)

Remarks : Equipment cleaning and maintenance

Risk Management Measures

Technical conditions and : Drain down system prior to equipment break-in or
measures maintenance.
Ensure operation is undertaken outdoors.

2.2.14 ES 2 - CS 14: Control of worker exposure: Widespread use by professional

workers (Chemical production or refinery in closed continuous process with
occasional controlled exposure or processes with equivalent containment conditions)
(PROC2)

Remarks : General exposures

Closed systems
Storage

Risk Management Measures

Note : No other specific measures identified.
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according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 49(76)

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2.3. ES 2 Exposure estimation and reference to its source

2.3.1 ES 2 - CS 1: Environmental release and exposure: Widespread use by
professional workers (Widespread use of non-reactive processing aid (no inclusion
into or onto article, outdoor)) (ERC8d)

Release route Release rate Release estimation method

Air 0%
Water 100 %
Soil 0%

protection target Exposure estimation and reference to its source RCR

(CHARM model)
Marine water 0,000381 mg/L (Risk from environmental exposure is < 0,01
driven by marine water.)
Marine sediment 0,000924 μg/kg dry weight < 0,01

2.3.3 ES 2 - CS 3: Worker exposure: Widespread use by professional workers

(Transfer of substance or mixture (charging/discharging) at dedicated facilities)
(PROC8b)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 13 ppm (ECETOC TRA worker v3, long-term) 0,67
inhalative 39,9 ppm (ECETOC TRA worker v3, short-term) 0,8
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

2.3.4 ES 2 - CS 4: Worker exposure: Widespread use by professional workers

(Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition)
(PROC3)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4 ppm (ECETOC TRA worker v3, long-term) 0,2
inhalative 12 ppm (ECETOC TRA worker v3, short-term) 0,24
dermal 0,69 mg/kg bw/day (ECETOC TRA worker v3)

2.3.5 ES 2 - CS 5: Worker exposure: Widespread use by professional workers

(Chemical production where opportunity for exposure arises) (PROC4)

Route of exposure and type Exposure estimate RCR

of effects
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inhalative 13 ppm (ECETOC TRA worker v3, long-term) 0,67

inhalative 39,9 ppm (ECETOC TRA worker v3, short-term) 0,8
dermal 6,9 mg/kg bw/day (ECETOC TRA worker v3)

2.3.6 ES 2 - CS 6: Worker exposure: Widespread use by professional workers

(Chemical production where opportunity for exposure arises) (PROC4)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 13 ppm (ECETOC TRA worker v3, long-term) 0,67
inhalative 39,9 ppm (ECETOC TRA worker v3, short-term) 0,8
dermal 6,9 mg/kg bw/day (ECETOC TRA worker v3)

2.3.7 ES 2 - CS 7: Worker exposure: Widespread use by professional workers

(Transfer of substance or mixture (charging/discharging) at non dedicated-facilities)
(PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4,7 ppm (ECETOC TRA worker v3, long-term) 0,23
inhalative 14 ppm (ECETOC TRA worker v3, short-term) 0,28
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

2.3.8 ES 2 - CS 8: Worker exposure: Widespread use by professional workers

(Transfer of substance or mixture (charging/discharging) at non dedicated-facilities)
(PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4,7 ppm (ECETOC TRA worker v3, long-term) 0,23
inhalative 14 ppm (ECETOC TRA worker v3, short-term) 0,28
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

2.3.9 ES 2 - CS 9: Worker exposure: Widespread use by professional workers

(Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions) (PROC1)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 0,013 ppm (ECETOC TRA worker v3, long-term) < 0,01
inhalative 0,0399 ppm (ECETOC TRA worker v3, short-term) < 0,01
dermal 0,03 mg/kg bw/day (ECETOC TRA worker v3)

2.3.10 ES 2 - CS 10: Worker exposure: Widespread use by professional workers

(Transfer of substance or mixture (charging/discharging) at non dedicated-facilities)
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(PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4,7 ppm (ECETOC TRA worker v3, long-term) 0,23
inhalative 14 ppm (ECETOC TRA worker v3, short-term) 0,28
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

2.3.11 ES 2 - CS 11: Worker exposure: Widespread use by professional workers

(Transfer of substance or mixture (charging/discharging) at non dedicated-facilities)
(PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4,7 ppm (ECETOC TRA worker v3, long-term) 0,23
inhalative 14 ppm (ECETOC TRA worker v3, short-term) 0,28
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

2.3.12 ES 2 - CS 12: Worker exposure: Widespread use by professional workers

(Manual maintenance (cleaning and repair) of machinery) (PROC28)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4,7 ppm (ECETOC TRA worker v3, long-term) 0,23
inhalative 14 ppm (ECETOC TRA worker v3, short-term) 0,28
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

2.3.13 ES 2 - CS 13: Worker exposure: Widespread use by professional workers

(Manual maintenance (cleaning and repair) of machinery) (PROC28)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4,7 ppm (ECETOC TRA worker v3, long-term) 0,23
inhalative 14 ppm (ECETOC TRA worker v3, short-term) 0,28
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

2.3.14 ES 2 - CS 14: Worker exposure: Widespread use by professional workers

(Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions) (PROC2)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 6,7 ppm (ECETOC TRA worker v3, long-term) 0,33
inhalative 20 ppm (ECETOC TRA worker v3, short-term) 0,4
dermal 1,4 mg/kg bw/day (ECETOC TRA worker v3)
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according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 52(76)

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Version : 7 - 0 / EU Date of printing : 16.03.2023

2.4. ES 2 Guidance to Downstream User to evaluate whether he

works inside the boundaries set by the Exposure Scenario
Health
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Risk management measures are based on qualitative risk characterisation.
Available hazard data do not enable the derivation of a DNEL for eye irritant effects.

3. ES 3: Widespread use by professional workers; Use in

oil and gas field drilling and production operations, on-
shore
3.1. Title section

Environment
CS1: Widespread use by professional workers (Widespread use of non- ERC8d
reactive processing aid (no inclusion into or onto article, outdoor))
Workers
CS2: Widespread use by professional workers (General measures applicable CS135
to all activities)
CS3: Widespread use by professional workers (Transfer of substance or PROC8b
mixture (charging/discharging) at dedicated facilities)
CS4: Widespread use by professional workers (Manufacture or formulation in PROC3
the chemical industry in closed batch processes with occasional
controlled exposure or processes with equivalent containment condition)
CS5: Widespread use by professional workers (Chemical production where PROC4
opportunity for exposure arises)
CS6: Widespread use by professional workers (Chemical production where PROC4
opportunity for exposure arises)
CS7: Widespread use by professional workers (Transfer of substance or PROC8a
mixture (charging/discharging) at non dedicated-facilities)
CS8: Widespread use by professional workers (Transfer of substance or PROC8a
mixture (charging/discharging) at non dedicated-facilities)
CS9: Widespread use by professional workers (Chemical production or PROC1
refinery in closed process without likelihood of exposure or processes
with equivalent containment conditions)
CS10: Widespread use by professional workers (Transfer of substance or PROC8a
mixture (charging/discharging) at non dedicated-facilities)
CS11: Widespread use by professional workers (Transfer of substance or PROC8a
mixture (charging/discharging) at non dedicated-facilities)
CS12: Widespread use by professional workers (Manual maintenance PROC28
(cleaning and repair) of machinery)
CS13: Widespread use by professional workers (Manual maintenance PROC28
(cleaning and repair) of machinery)
CS14: Widespread use by professional workers (Chemical production or PROC2
refinery in closed continuous process with occasional controlled
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CORRTREAT 3747 Page 53(76)

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exposure or processes with equivalent containment conditions)

3.2. ES 3 Conditions of use affecting exposure

3.2.1 ES 3 - CS 1: Control of environmental exposure: Widespread use by
professional workers (Widespread use of non-reactive processing aid (no inclusion
into or onto article, outdoor)) (ERC8d)

Product characteristics
Physical Form (at time of use) : Liquid, vapour pressure < 0.5 kPa at Standard Temperature
and Pressure
Remarks : Non-hydrophobic

Amount used
Amounts used (Msafe) : 7.930 kg/day

Other given operational conditions affecting environmental exposure

Number of emission days per year : 365
Remarks : Wide dispersive use, Continuous process

Technical conditions and measures / Organizational measures

Remarks : Bund storage facilities to prevent soil and water pollution in
the event of spillage.
Prevent environmental discharge consistent with regulatory
requirements.

Conditions and measures related to sewage treatment plant

Type of Sewage Treatment Plant : Onsite Sewage Treatment Plant
Flow rate of sewage treatment : 2.000 m3/d
plant effluent
Effectiveness (of a measure) : 87 %

Waste management measures

Waste treatment : External treatment and disposal of waste should comply with
applicable local and/or national regulations., Dispose of waste
product or used containers according to local regulations.,
This material and its container must be disposed of as
hazardous.

3.2.2 ES 3 - CS 2: Control of worker exposure: Widespread use by professional

workers (General measures applicable to all activities) (CS135)

Product characteristics
Concentration of the Substance in : <= 100 %
Mixture/Article

Physical Form (at time of use) : Liquid, vapour pressure < 0.5 kPa at Standard Temperature
and Pressure
Remarks : Assumes use at not more than 20°C above ambient
temperature.
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CORRTREAT 3747 Page 54(76)

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Frequency and duration of use

Exposure duration : 12 h
Remarks : Continuous process

Other operational conditions affecting workers exposure

Remarks : Assumes a good basic standard of occupational hygiene is
implemented

Risk Management Measures

Organisational measures to : Ensure there is no direct skin contact with product.
prevent /limit releases, dispersion Identify potential areas for indirect skin contact.
and exposure Clear spills immediately.
Wash off any skin contamination immediately.
Ensure operatives are trained to minimise exposures.
Avoid direct eye contact with product, also via contamination
on hands.
Avoid splashing.

Personal protective measures : Use suitable eye protection.

For further specification, refer to section 8 of the SDS.

Personal protective measures : In case of potential exposure:

Wear suitable gloves tested to EN374.
For further specification, refer to section 8 of the SDS.

3.2.3 ES 3 - CS 3: Control of worker exposure: Widespread use by professional

workers (Transfer of substance or mixture (charging/discharging) at dedicated
facilities) (PROC8b)

Remarks : Bulk transfers from tote tanks and supply vessels

Filling of equipment from drums or containers

Risk Management Measures

Note : No other specific measures identified.

3.2.4 ES 3 - CS 4: Control of worker exposure: Widespread use by professional

workers (Manufacture or formulation in the chemical industry in closed batch
processes with occasional controlled exposure or processes with equivalent
containment condition) (PROC3)

Remarks : Drilling mud (re-)formulation

Treatment and disposal of filtered solids
Process sampling

Risk Management Measures

Note : No other specific measures identified.

3.2.5 ES 3 - CS 5: Control of worker exposure: Widespread use by professional

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CORRTREAT 3747 Page 55(76)

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workers (Chemical production where opportunity for exposure arises) (PROC4)

Remarks : Drill floor operations

Scale squeeze operations

Risk Management Measures

Note : No other specific measures identified.

3.2.6 ES 3 - CS 6: Control of worker exposure: Widespread use by professional

workers (Chemical production where opportunity for exposure arises) (PROC4)

Remarks : Operation of solids filtering equipment

With potential for aerosol generation
Elevated temperature

Risk Management Measures

Technical conditions and : Provide extract ventilation to points where emissions occur.
measures

3.2.7 ES 3 - CS 7: Control of worker exposure: Widespread use by professional

workers (Transfer of substance or mixture (charging/discharging) at non dedicated-
facilities) (PROC8a)

Remarks : Cleaning of solids filtering equipment

Risk Management Measures

Technical conditions and : Drain down system prior to equipment break-in or
measures maintenance.
Provide a good standard of general ventilation (not less than 3
to 5 air changes per hour).

3.2.8 ES 3 - CS 8: Control of worker exposure: Widespread use by professional

workers (Transfer of substance or mixture (charging/discharging) at non dedicated-
facilities) (PROC8a)

Remarks : Cleaning of solids filtering equipment

Risk Management Measures

Technical conditions and : Drain down system prior to equipment break-in or
measures maintenance.
Ensure operation is undertaken outdoors.

3.2.9 ES 3 - CS 9: Control of worker exposure: Widespread use by professional

workers (Chemical production or refinery in closed process without likelihood of
exposure or processes with equivalent containment conditions) (PROC1)

Remarks : Application by injection

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CORRTREAT 3747 Page 56(76)

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Risk Management Measures

Note : No other specific measures identified.

3.2.10 ES 3 - CS 10: Control of worker exposure: Widespread use by professional

workers (Transfer of substance or mixture (charging/discharging) at non dedicated-
facilities) (PROC8a)

Remarks : Transfer from/pouring from containers

Risk Management Measures

Technical conditions and : Provide a good standard of general ventilation (not less than 3
measures to 5 air changes per hour).
Use drum pumps or carefully pour from container.

3.2.11 ES 3 - CS 11: Control of worker exposure: Widespread use by professional

workers (Transfer of substance or mixture (charging/discharging) at non dedicated-
facilities) (PROC8a)

Remarks : Transfer from/pouring from containers

Risk Management Measures

Technical conditions and : Ensure operation is undertaken outdoors.
measures Use drum pumps or carefully pour from container.

3.2.12 ES 3 - CS 12: Control of worker exposure: Widespread use by professional

workers (Manual maintenance (cleaning and repair) of machinery) (PROC28)

Remarks : Equipment cleaning and maintenance

Risk Management Measures

Technical conditions and : Drain down system prior to equipment break-in or
measures maintenance.
Provide a good standard of general ventilation (not less than 3
to 5 air changes per hour).

3.2.13 ES 3 - CS 13: Control of worker exposure: Widespread use by professional

workers (Manual maintenance (cleaning and repair) of machinery) (PROC28)

Remarks : Equipment cleaning and maintenance

Risk Management Measures

Technical conditions and : Drain down system prior to equipment break-in or
measures maintenance.
Ensure operation is undertaken outdoors.
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according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 57(76)

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Version : 7 - 0 / EU Date of printing : 16.03.2023

3.2.14 ES 3 - CS 14: Control of worker exposure: Widespread use by professional

workers (Chemical production or refinery in closed continuous process with
occasional controlled exposure or processes with equivalent containment conditions)
(PROC2)

Remarks : General exposures

Closed systems
Storage

Risk Management Measures

Note : No other specific measures identified.

3.3. ES 3 Exposure estimation and reference to its source

3.3.1 ES 3 - CS 1: Environmental release and exposure: Widespread use by
professional workers (Widespread use of non-reactive processing aid (no inclusion
into or onto article, outdoor)) (ERC8d)

Release route Release rate Release estimation method

Air 0,5 %
Water 7%
Soil 0%

protection target Exposure estimation and reference to its source RCR

(ECETOC TRA)
Sewage treatment plant 0,623 mg/L < 0,01
Freshwater 0,152 mg/L (Risk from environmental exposure is driven 0,02
by freshwater.)
Freshwater sediment 0,596 mg/kg dry weight (Risk from environmental 0,02
exposure is driven by freshwater sediment.)
Soil 0,0000359 mg/kg dry weight < 0,01

3.3.3 ES 3 - CS 3: Worker exposure: Widespread use by professional workers

(Transfer of substance or mixture (charging/discharging) at dedicated facilities)
(PROC8b)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 13 ppm (ECETOC TRA worker v3, long-term) 0,67
inhalative 39,9 ppm (ECETOC TRA worker v3, short-term) 0,8
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

3.3.4 ES 3 - CS 4: Worker exposure: Widespread use by professional workers

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 58(76)

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(Manufacture or formulation in the chemical industry in closed batch processes with

occasional controlled exposure or processes with equivalent containment condition)
(PROC3)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4 ppm (ECETOC TRA worker v3, long-term) 0,2
inhalative 12 ppm (ECETOC TRA worker v3, short-term) 0,24
dermal 0,69 mg/kg bw/day (ECETOC TRA worker v3)

3.3.5 ES 3 - CS 5: Worker exposure: Widespread use by professional workers

(Chemical production where opportunity for exposure arises) (PROC4)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 13 ppm (ECETOC TRA worker v3, long-term) 0,67
inhalative 39,9 ppm (ECETOC TRA worker v3, short-term) 0,8
dermal 6,9 mg/kg bw/day (ECETOC TRA worker v3)

3.3.6 ES 3 - CS 6: Worker exposure: Widespread use by professional workers

(Chemical production where opportunity for exposure arises) (PROC4)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 13 ppm (ECETOC TRA worker v3, long-term) 0,67
inhalative 39,9 ppm (ECETOC TRA worker v3, short-term) 0,8
dermal 6,9 mg/kg bw/day (ECETOC TRA worker v3)

3.3.7 ES 3 - CS 7: Worker exposure: Widespread use by professional workers

(Transfer of substance or mixture (charging/discharging) at non dedicated-facilities)
(PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4,7 ppm (ECETOC TRA worker v3, long-term) 0,23
inhalative 14 ppm (ECETOC TRA worker v3, short-term) 0,28
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

3.3.8 ES 3 - CS 8: Worker exposure: Widespread use by professional workers

(Transfer of substance or mixture (charging/discharging) at non dedicated-facilities)
(PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4,7 ppm (ECETOC TRA worker v3, long-term) 0,23
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CORRTREAT 3747 Page 59(76)

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inhalative 14 ppm (ECETOC TRA worker v3, short-term) 0,28

dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

3.3.9 ES 3 - CS 9: Worker exposure: Widespread use by professional workers

(Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions) (PROC1)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 0,013 ppm (ECETOC TRA worker v3, long-term) < 0,01
inhalative 0,0399 ppm (ECETOC TRA worker v3, short-term) < 0,01
dermal 0,03 mg/kg bw/day (ECETOC TRA worker v3)

3.3.10 ES 3 - CS 10: Worker exposure: Widespread use by professional workers

(Transfer of substance or mixture (charging/discharging) at non dedicated-facilities)
(PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4,7 ppm (ECETOC TRA worker v3, long-term) 0,23
inhalative 14 ppm (ECETOC TRA worker v3, short-term) 0,28
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

3.3.11 ES 3 - CS 11: Worker exposure: Widespread use by professional workers

(Transfer of substance or mixture (charging/discharging) at non dedicated-facilities)
(PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4,7 ppm (ECETOC TRA worker v3, long-term) 0,23
inhalative 14 ppm (ECETOC TRA worker v3, short-term) 0,28
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

3.3.12 ES 3 - CS 12: Worker exposure: Widespread use by professional workers

(Manual maintenance (cleaning and repair) of machinery) (PROC28)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4,7 ppm (ECETOC TRA worker v3, long-term) 0,23
inhalative 14 ppm (ECETOC TRA worker v3, short-term) 0,28
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

3.3.13 ES 3 - CS 13: Worker exposure: Widespread use by professional workers

(Manual maintenance (cleaning and repair) of machinery) (PROC28)
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according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 60(76)

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Route of exposure and type Exposure estimate RCR

of effects
inhalative 4,7 ppm (ECETOC TRA worker v3, long-term) 0,23
inhalative 14 ppm (ECETOC TRA worker v3, short-term) 0,28
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

3.3.14 ES 3 - CS 14: Worker exposure: Widespread use by professional workers

(Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions) (PROC2)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 6,7 ppm (ECETOC TRA worker v3, long-term) 0,33
inhalative 20 ppm (ECETOC TRA worker v3, short-term) 0,4
dermal 1,4 mg/kg bw/day (ECETOC TRA worker v3)

3.4. ES 3 Guidance to Downstream User to evaluate whether he

works inside the boundaries set by the Exposure Scenario
Health
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Risk management measures are based on qualitative risk characterisation.
Available hazard data do not enable the derivation of a DNEL for eye irritant effects.

4. ES 4: Use at industrial sites; Use in oil and gas field

drilling and production operations, off-shore
4.1. Title section

Environment
CS1: Use at industrial sites (Use of non-reactive processing aid at industrial ERC4
site (no inclusion into or onto article))
Workers
CS2: Use at industrial sites (General measures applicable to all activities) CS135
CS3: Use at industrial sites (Transfer of substance or mixture PROC8b
(charging/discharging) at dedicated facilities)
CS4: Use at industrial sites (Manufacture or formulation in the chemical PROC3
industry in closed batch processes with occasional controlled exposure
or processes with equivalent containment condition)
CS5: Use at industrial sites (Chemical production where opportunity for PROC4
exposure arises)
CS6: Use at industrial sites (Chemical production where opportunity for PROC4
exposure arises)
CS7: Use at industrial sites (Transfer of substance or mixture PROC8a
(charging/discharging) at non dedicated-facilities)
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CORRTREAT 3747 Page 61(76)

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CS8: Use at industrial sites (Transfer of substance or mixture PROC8a

(charging/discharging) at non dedicated-facilities)
CS9: Use at industrial sites (Chemical production or refinery in closed process PROC1
without likelihood of exposure or processes with equivalent containment
conditions)
CS10: Use at industrial sites (Transfer of substance or mixture PROC8a
(charging/discharging) at non dedicated-facilities)
CS11: Use at industrial sites (Transfer of substance or mixture PROC8a
(charging/discharging) at non dedicated-facilities)
CS12: Use at industrial sites (Manual maintenance (cleaning and repair) of PROC28
machinery)
CS13: Use at industrial sites (Manual maintenance (cleaning and repair) of PROC28
machinery)
CS14: Use at industrial sites (Chemical production or refinery in closed PROC2
continuous process with occasional controlled exposure or processes
with equivalent containment conditions)

4.2. ES 4 Conditions of use affecting exposure

4.2.1 ES 4 - CS 1: Control of environmental exposure: Use at industrial sites (Use of
non-reactive processing aid at industrial site (no inclusion into or onto article)) (ERC4)

Product characteristics
Physical Form (at time of use) : Liquid, vapour pressure < 0.5 kPa at Standard Temperature
and Pressure
Remarks : Non-hydrophobic

Amount used
Daily amount per site : 137 kg/day
Annual amount per site : 50 tonnes/year
Daily amount per site (Msafe) : 316.000 kg

Other given operational conditions affecting environmental exposure

Number of emission days per year : 365
Remarks : Continuous process, Continuous release

Technical conditions and measures / Organizational measures

Remarks : Prevent environmental discharge consistent with regulatory
requirements.

Waste management measures

Waste treatment : External treatment and disposal of waste should comply with
applicable local and/or national regulations., Dispose of waste
product or used containers according to local regulations.,
This material and its container must be disposed of as
hazardous.

4.2.2 ES 4 - CS 2: Control of worker exposure: Use at industrial sites (General

measures applicable to all activities) (CS135)
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 62(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

Product characteristics
Concentration of the Substance in : <= 100 %
Mixture/Article

Physical Form (at time of use) : Liquid, vapour pressure < 0.5 kPa at Standard Temperature
and Pressure
Remarks : Assumes use at not more than 20°C above ambient
temperature.

Frequency and duration of use

Exposure duration : 12 h
Remarks : Continuous process

Other operational conditions affecting workers exposure

Remarks : Assumes a good basic standard of occupational hygiene is
implemented

Risk Management Measures

Organisational measures to : Ensure there is no direct skin contact with product.
prevent /limit releases, dispersion Identify potential areas for indirect skin contact.
and exposure Clear spills immediately.
Wash off any skin contamination immediately.
Ensure operatives are trained to minimise exposures.
Avoid direct eye contact with product, also via contamination
on hands.
Avoid splashing.

Personal protective measures : Use suitable eye protection.

For further specification, refer to section 8 of the SDS.

Personal protective measures : In case of potential exposure:

Wear suitable gloves tested to EN374.
For further specification, refer to section 8 of the SDS.

4.2.3 ES 4 - CS 3: Control of worker exposure: Use at industrial sites (Transfer of

substance or mixture (charging/discharging) at dedicated facilities) (PROC8b)

Remarks : Bulk transfers from tote tanks and supply vessels

Filling of equipment from drums or containers

Risk Management Measures

Note : No other specific measures identified.

4.2.4 ES 4 - CS 4: Control of worker exposure: Use at industrial sites (Manufacture or

formulation in the chemical industry in closed batch processes with occasional
controlled exposure or processes with equivalent containment condition) (PROC3)

Remarks : Drilling mud (re-)formulation

Treatment and disposal of filtered solids
Process sampling
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 63(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

Risk Management Measures

Note : No other specific measures identified.

4.2.5 ES 4 - CS 5: Control of worker exposure: Use at industrial sites (Chemical

production where opportunity for exposure arises) (PROC4)

Remarks : Drill floor operations

Scale squeeze operations

Risk Management Measures

Note : No other specific measures identified.

4.2.6 ES 4 - CS 6: Control of worker exposure: Use at industrial sites (Chemical

production where opportunity for exposure arises) (PROC4)

Remarks : Operation of solids filtering equipment

With potential for aerosol generation
Elevated temperature

Risk Management Measures

Technical conditions and : Provide extract ventilation to points where emissions occur.
measures

4.2.7 ES 4 - CS 7: Control of worker exposure: Use at industrial sites (Transfer of

substance or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Remarks : Cleaning of solids filtering equipment

Risk Management Measures

Technical conditions and : Drain down system prior to equipment break-in or
measures maintenance.
Provide a good standard of general ventilation (not less than 3
to 5 air changes per hour).

4.2.8 ES 4 - CS 8: Control of worker exposure: Use at industrial sites (Transfer of

substance or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Remarks : Cleaning of solids filtering equipment

Risk Management Measures

Organisational measures to : Ensure operation is undertaken outdoors.
prevent /limit releases, dispersion
and exposure

Technical conditions and : Drain down system prior to equipment break-in or

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 64(76)

Substance key: 000000473131 Revision Date: 14.03.2023
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measures maintenance.

4.2.9 ES 4 - CS 9: Control of worker exposure: Use at industrial sites (Chemical

production or refinery in closed process without likelihood of exposure or processes
with equivalent containment conditions) (PROC1)

Remarks : Application by injection

Risk Management Measures

Note : No other specific measures identified.

4.2.10 ES 4 - CS 10: Control of worker exposure: Use at industrial sites (Transfer of

substance or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Remarks : Transfer from/pouring from containers

Risk Management Measures

Technical conditions and : Provide a good standard of general ventilation (not less than 3
measures to 5 air changes per hour).

4.2.11 ES 4 - CS 11: Control of worker exposure: Use at industrial sites (Transfer of

substance or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Remarks : Transfer from/pouring from containers

Risk Management Measures

Organisational measures to : Ensure operation is undertaken outdoors.
prevent /limit releases, dispersion
and exposure

4.2.12 ES 4 - CS 12: Control of worker exposure: Use at industrial sites (Manual

maintenance (cleaning and repair) of machinery) (PROC28)

Remarks : Equipment cleaning and maintenance

Risk Management Measures

Technical conditions and : Provide a good standard of general ventilation (not less than 3
measures to 5 air changes per hour).

4.2.13 ES 4 - CS 13: Control of worker exposure: Use at industrial sites (Manual

maintenance (cleaning and repair) of machinery) (PROC28)

Remarks : Equipment cleaning and maintenance

Risk Management Measures

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 65(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

Organisational measures to : Ensure operation is undertaken outdoors.

prevent /limit releases, dispersion
and exposure

4.2.14 ES 4 - CS 14: Control of worker exposure: Use at industrial sites (Chemical

production or refinery in closed continuous process with occasional controlled
exposure or processes with equivalent containment conditions) (PROC2)

Remarks : General exposures

Closed systems
Storage
With sample collection

Risk Management Measures

Note : No other specific measures identified.

4.3. ES 4 Exposure estimation and reference to its source

4.3.1 ES 4 - CS 1: Environmental release and exposure: Use at industrial sites (Use
of non-reactive processing aid at industrial site (no inclusion into or onto article))
(ERC4)

Release route Release rate Release estimation method

Air 0% (Initial release prior to RMM)
Water 100 % (Initial release prior to RMM)
Soil 0% (Initial release prior to RMM)

protection target Exposure estimation and reference to its source RCR

(CHARM model)
Marine water 0,000381 mg/L (Risk from environmental exposure is < 0,01
driven by marine water.)
Marine sediment 0,000924 μg/kg dry weight < 0,01

4.3.3 ES 4 - CS 3: Worker exposure: Use at industrial sites (Transfer of substance or

mixture (charging/discharging) at dedicated facilities) (PROC8b)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 6,7 ppm (ECETOC TRA worker v3, long-term) 0,33
inhalative 20 ppm (ECETOC TRA worker v3, short-term) 0,4
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

4.3.4 ES 4 - CS 4: Worker exposure: Use at industrial sites (Manufacture or

formulation in the chemical industry in closed batch processes with occasional
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 66(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

controlled exposure or processes with equivalent containment condition) (PROC3)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4 ppm (ECETOC TRA worker v3, long-term) 0,2
inhalative 12 ppm (ECETOC TRA worker v3, short-term) 0,24
dermal 0,69 mg/kg bw/day (ECETOC TRA worker v3)

4.3.5 ES 4 - CS 5: Worker exposure: Use at industrial sites (Chemical production

where opportunity for exposure arises) (PROC4)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 6,7 ppm (ECETOC TRA worker v3, long-term) 0,33
inhalative 20 ppm (ECETOC TRA worker v3, short-term) 0,4
dermal 6,9 mg/kg bw/day (ECETOC TRA worker v3)

4.3.6 ES 4 - CS 6: Worker exposure: Use at industrial sites (Chemical production

where opportunity for exposure arises) (PROC4)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 2,7 ppm (ECETOC TRA worker v3, long-term) 0,13
inhalative 7,98 ppm (ECETOC TRA worker v3, short-term) 0,16
dermal 6,9 mg/kg bw/day (ECETOC TRA worker v3)

4.3.7 ES 4 - CS 7: Worker exposure: Use at industrial sites (Transfer of substance or

mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 1,9 ppm (ECETOC TRA worker v3, long-term) 0,09
inhalative 5,59 ppm (ECETOC TRA worker v3, short-term) 0,11
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

4.3.8 ES 4 - CS 8: Worker exposure: Use at industrial sites (Transfer of substance or

mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 1,9 ppm (ECETOC TRA worker v3, long-term) 0,09
inhalative 5,59 ppm (ECETOC TRA worker v3, short-term) 0,11
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 67(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

4.3.9 ES 4 - CS 9: Worker exposure: Use at industrial sites (Chemical production or

refinery in closed process without likelihood of exposure or processes with
equivalent containment conditions) (PROC1)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 0,013 ppm (ECETOC TRA worker v3, long-term) < 0,01
inhalative 0,0399 ppm (ECETOC TRA worker v3, short-term) < 0,01
dermal 0,03 mg/kg bw/day (ECETOC TRA worker v3)

4.3.10 ES 4 - CS 10: Worker exposure: Use at industrial sites (Transfer of substance

or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 9,3 ppm (ECETOC TRA worker v3, long-term) 0,47
inhalative 27,9 ppm (ECETOC TRA worker v3, short-term) 0,56
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

4.3.11 ES 4 - CS 11: Worker exposure: Use at industrial sites (Transfer of substance

or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 9,3 ppm (ECETOC TRA worker v3, long-term) 0,47
inhalative 27,9 ppm (ECETOC TRA worker v3, short-term) 0,56
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

4.3.12 ES 4 - CS 12: Worker exposure: Use at industrial sites (Manual maintenance

(cleaning and repair) of machinery) (PROC28)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 9,3 ppm (ECETOC TRA worker v3, long-term) 0,47
inhalative 27,9 ppm (ECETOC TRA worker v3, short-term) 0,56
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

4.3.13 ES 4 - CS 13: Worker exposure: Use at industrial sites (Manual maintenance

(cleaning and repair) of machinery) (PROC28)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 9,3 ppm (ECETOC TRA worker v3, long-term) 0,47
inhalative 27,9 ppm (ECETOC TRA worker v3, short-term) 0,56
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 68(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

4.3.14 ES 4 - CS 14: Worker exposure: Use at industrial sites (Chemical production

or refinery in closed continuous process with occasional controlled exposure or
processes with equivalent containment conditions) (PROC2)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 1,3 ppm (ECETOC TRA worker v3, long-term) 0,07
inhalative 3,99 ppm (ECETOC TRA worker v3, short-term) 0,08
dermal 1,4 mg/kg bw/day (ECETOC TRA worker v3)

4.4. ES 4 Guidance to Downstream User to evaluate whether he

works inside the boundaries set by the Exposure Scenario
Health
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Risk management measures are based on qualitative risk characterisation.
Available hazard data do not enable the derivation of a DNEL for eye irritant effects.
Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites;
thus, scaling may be necessary to define appropriate site-specific risk management measures.

5. ES 5: Use at industrial sites; Use in oil and gas field

drilling and production operations, on-shore
5.1. Title section

Environment
CS1: Use at industrial sites (Use of non-reactive processing aid at industrial ERC4
site (no inclusion into or onto article))
Workers
CS2: Use at industrial sites (General measures applicable to all activities) CS135
CS3: Use at industrial sites (Transfer of substance or mixture PROC8b
(charging/discharging) at dedicated facilities)
CS4: Use at industrial sites (Manufacture or formulation in the chemical PROC3
industry in closed batch processes with occasional controlled exposure
or processes with equivalent containment condition)
CS5: Use at industrial sites (Chemical production where opportunity for PROC4
exposure arises)
CS6: Use at industrial sites (Chemical production where opportunity for PROC4
exposure arises)
CS7: Use at industrial sites (Transfer of substance or mixture PROC8a
(charging/discharging) at non dedicated-facilities)
CS8: Use at industrial sites (Transfer of substance or mixture PROC8a
(charging/discharging) at non dedicated-facilities)
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according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 69(76)

Substance key: 000000473131 Revision Date: 14.03.2023
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CS9: Use at industrial sites (Chemical production or refinery in closed process PROC1
without likelihood of exposure or processes with equivalent containment
conditions)
CS10: Use at industrial sites (Transfer of substance or mixture PROC8a
(charging/discharging) at non dedicated-facilities)
CS11: Use at industrial sites (Transfer of substance or mixture PROC8a
(charging/discharging) at non dedicated-facilities)
CS12: Use at industrial sites (Manual maintenance (cleaning and repair) of PROC28
machinery)
CS13: Use at industrial sites (Manual maintenance (cleaning and repair) of PROC28
machinery)
CS14: Use at industrial sites (Chemical production or refinery in closed PROC2
continuous process with occasional controlled exposure or processes
with equivalent containment conditions)

5.2. ES 5 Conditions of use affecting exposure

5.2.1 ES 5 - CS 1: Control of environmental exposure: Use at industrial sites (Use of
non-reactive processing aid at industrial site (no inclusion into or onto article)) (ERC4)

Product characteristics
Physical Form (at time of use) : Liquid, vapour pressure < 0.5 kPa at Standard Temperature
and Pressure
Remarks : Non-hydrophobic

Amount used
Annual amount per site : 50 tonnes/year
Daily amount per site : 137 kg/day
Daily amount per site (Msafe) : 7.930 kg

Environment factors not influenced by risk management

Dilution Factor (River) : 10
Dilution Factor (Coastal Areas) : 100

Other given operational conditions affecting environmental exposure

Number of emission days per year : 365
Remarks : Continuous process, Continuous release

Technical conditions and measures / Organizational measures

Water : Do not let product enter drains.
Remarks : Bund storage facilities to prevent soil and water pollution in
the event of spillage.
Prevent environmental discharge consistent with regulatory
requirements.

Conditions and measures related to sewage treatment plant

Type of Sewage Treatment Plant : Onsite Sewage Treatment Plant
Flow rate of sewage treatment : 2.000 m3/d
plant effluent
Effectiveness (of a measure) : 87 %
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CORRTREAT 3747 Page 70(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

Waste management measures

Waste treatment : External treatment and disposal of waste should comply with
applicable local and/or national regulations., Dispose of waste
product or used containers according to local regulations.,
This material and its container must be disposed of as
hazardous.

5.2.2 ES 5 - CS 2: Control of worker exposure: Use at industrial sites (General

measures applicable to all activities) (CS135)

Product characteristics
Concentration of the Substance in : <= 100 %
Mixture/Article

Physical Form (at time of use) : Liquid, vapour pressure < 0.5 kPa at Standard Temperature
and Pressure
Remarks : Assumes use at not more than 20°C above ambient
temperature.

Frequency and duration of use

Exposure duration : 12 h
Remarks : Continuous process

Other operational conditions affecting workers exposure

Remarks : Assumes a good basic standard of occupational hygiene is
implemented

Risk Management Measures

Organisational measures to : Ensure there is no direct skin contact with product.
prevent /limit releases, dispersion Identify potential areas for indirect skin contact.
and exposure Clear spills immediately.
Wash off any skin contamination immediately.
Ensure operatives are trained to minimise exposures.
Avoid direct eye contact with product, also via contamination
on hands.
Avoid splashing.

Personal protective measures : Use suitable eye protection.

For further specification, refer to section 8 of the SDS.

Personal protective measures : In case of potential exposure:

Wear suitable gloves tested to EN374.
For further specification, refer to section 8 of the SDS.

5.2.3 ES 5 - CS 3: Control of worker exposure: Use at industrial sites (Transfer of

substance or mixture (charging/discharging) at dedicated facilities) (PROC8b)

Remarks : Bulk transfers from tote tanks and supply vessels

Filling of equipment from drums or containers

Risk Management Measures

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 71(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

Note : No other specific measures identified.

5.2.4 ES 5 - CS 4: Control of worker exposure: Use at industrial sites (Manufacture or

formulation in the chemical industry in closed batch processes with occasional
controlled exposure or processes with equivalent containment condition) (PROC3)

Remarks : Drilling mud (re-)formulation

Treatment and disposal of filtered solids
Process sampling

Risk Management Measures

Note : No other specific measures identified.

5.2.5 ES 5 - CS 5: Control of worker exposure: Use at industrial sites (Chemical

production where opportunity for exposure arises) (PROC4)

Remarks : Drill floor operations

Scale squeeze operations

Risk Management Measures

Note : No other specific measures identified.

5.2.6 ES 5 - CS 6: Control of worker exposure: Use at industrial sites (Chemical

production where opportunity for exposure arises) (PROC4)

Remarks : Operation of solids filtering equipment

With potential for aerosol generation
Elevated temperature

Risk Management Measures

Technical conditions and : Provide extract ventilation to points where emissions occur.
measures

5.2.7 ES 5 - CS 7: Control of worker exposure: Use at industrial sites (Transfer of

substance or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Remarks : Cleaning of solids filtering equipment

Risk Management Measures

Technical conditions and : Drain down system prior to equipment break-in or
measures maintenance.
Provide a good standard of general ventilation (not less than 3
to 5 air changes per hour).

5.2.8 ES 5 - CS 8: Control of worker exposure: Use at industrial sites (Transfer of

substance or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 72(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

Remarks : Cleaning of solids filtering equipment

Risk Management Measures

Organisational measures to : Ensure operation is undertaken outdoors.
prevent /limit releases, dispersion
and exposure

Technical conditions and : Drain down system prior to equipment break-in or

measures maintenance.

5.2.9 ES 5 - CS 9: Control of worker exposure: Use at industrial sites (Chemical

production or refinery in closed process without likelihood of exposure or processes
with equivalent containment conditions) (PROC1)

Remarks : Application by injection

Risk Management Measures

Note : No other specific measures identified.

5.2.10 ES 5 - CS 10: Control of worker exposure: Use at industrial sites (Transfer of

substance or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Remarks : Transfer from/pouring from containers

Risk Management Measures

Technical conditions and : Provide a good standard of general ventilation (not less than 3
measures to 5 air changes per hour).

5.2.11 ES 5 - CS 11: Control of worker exposure: Use at industrial sites (Transfer of

substance or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Remarks : Transfer from/pouring from containers

Risk Management Measures

Organisational measures to : Ensure operation is undertaken outdoors.
prevent /limit releases, dispersion
and exposure

5.2.12 ES 5 - CS 12: Control of worker exposure: Use at industrial sites (Manual

maintenance (cleaning and repair) of machinery) (PROC28)

Remarks : Equipment cleaning and maintenance

Risk Management Measures

Technical conditions and : Provide a good standard of general ventilation (not less than 3
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according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 73(76)

Substance key: 000000473131 Revision Date: 14.03.2023
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measures to 5 air changes per hour).

5.2.13 ES 5 - CS 13: Control of worker exposure: Use at industrial sites (Manual

maintenance (cleaning and repair) of machinery) (PROC28)

Remarks : Equipment cleaning and maintenance

Risk Management Measures

Organisational measures to : Ensure operation is undertaken outdoors.
prevent /limit releases, dispersion
and exposure

5.2.14 ES 5 - CS 14: Control of worker exposure: Use at industrial sites (Chemical

production or refinery in closed continuous process with occasional controlled
exposure or processes with equivalent containment conditions) (PROC2)

Remarks : General exposures

Closed systems
Storage
With sample collection

Risk Management Measures

Note : No other specific measures identified.

5.3. ES 5 Exposure estimation and reference to its source

5.3.1 ES 5 - CS 1: Environmental release and exposure: Use at industrial sites (Use
of non-reactive processing aid at industrial site (no inclusion into or onto article))
(ERC4)

Release route Release rate Release estimation method

Air 0,5 % (Initial release prior to RMM)
Water 7% (Initial release prior to RMM)
Soil 0% (Initial release prior to RMM)

protection target Exposure estimation and reference to its source () RCR

Sewage treatment plant 0,623 mg/L < 0,01
Freshwater 0,152 mg/L (Risk from environmental exposure is driven 0,02
by freshwater.)
Freshwater sediment 0,596 mg/kg dry weight 0,02
Soil 0,0000359 mg/kg dry weight < 0,01

5.3.3 ES 5 - CS 3: Worker exposure: Use at industrial sites (Transfer of substance or

mixture (charging/discharging) at dedicated facilities) (PROC8b)
SAFETY DATA SHEET
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CORRTREAT 3747 Page 74(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

Route of exposure and type Exposure estimate RCR

of effects
inhalative 6,7 ppm (ECETOC TRA worker v3, long-term) 0,33
inhalative 20 ppm (ECETOC TRA worker v3, short-term) 0,4
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

5.3.4 ES 5 - CS 4: Worker exposure: Use at industrial sites (Manufacture or

formulation in the chemical industry in closed batch processes with occasional
controlled exposure or processes with equivalent containment condition) (PROC3)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 4 ppm (ECETOC TRA worker v3, long-term) 0,2
inhalative 12 ppm (ECETOC TRA worker v3, short-term) 0,24
dermal 0,69 mg/kg bw/day (ECETOC TRA worker v3)

5.3.5 ES 5 - CS 5: Worker exposure: Use at industrial sites (Chemical production

where opportunity for exposure arises) (PROC4)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 6,7 ppm (ECETOC TRA worker v3, long-term) 0,33
inhalative 20 ppm (ECETOC TRA worker v3, short-term) 0,4
dermal 6,9 mg/kg bw/day (ECETOC TRA worker v3)

5.3.6 ES 5 - CS 6: Worker exposure: Use at industrial sites (Chemical production

where opportunity for exposure arises) (PROC4)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 2,7 ppm (ECETOC TRA worker v3, long-term) 0,13
inhalative 7,98 ppm (ECETOC TRA worker v3, short-term) 0,16
dermal 6,9 mg/kg bw/day (ECETOC TRA worker v3)

5.3.7 ES 5 - CS 7: Worker exposure: Use at industrial sites (Transfer of substance or

mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 1,9 ppm (ECETOC TRA worker v3, long-term) 0,09
inhalative 5,59 ppm (ECETOC TRA worker v3, short-term) 0,11
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

5.3.8 ES 5 - CS 8: Worker exposure: Use at industrial sites (Transfer of substance or

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CORRTREAT 3747 Page 75(76)

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mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 1,9 ppm (ECETOC TRA worker v3, long-term) 0,09
inhalative 5,59 ppm (ECETOC TRA worker v3, short-term) 0,11
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

5.3.9 ES 5 - CS 9: Worker exposure: Use at industrial sites (Chemical production or

refinery in closed process without likelihood of exposure or processes with
equivalent containment conditions) (PROC1)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 0,013 ppm (ECETOC TRA worker v3, long-term) < 0,01
inhalative 0,0399 ppm (ECETOC TRA worker v3, short-term) < 0,01
dermal 0,03 mg/kg bw/day (ECETOC TRA worker v3)

5.3.10 ES 5 - CS 10: Worker exposure: Use at industrial sites (Transfer of substance

or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 9,3 ppm (ECETOC TRA worker v3, long-term) 0,47
inhalative 27,9 ppm (ECETOC TRA worker v3, short-term) 0,56
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

5.3.11 ES 5 - CS 11: Worker exposure: Use at industrial sites (Transfer of substance

or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 9,3 ppm (ECETOC TRA worker v3, long-term) 0,47
inhalative 27,9 ppm (ECETOC TRA worker v3, short-term) 0,56
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

5.3.12 ES 5 - CS 12: Worker exposure: Use at industrial sites (Manual maintenance

(cleaning and repair) of machinery) (PROC28)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 9,3 ppm (ECETOC TRA worker v3, long-term) 0,47
inhalative 27,9 ppm (ECETOC TRA worker v3, short-term) 0,56
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

CORRTREAT 3747 Page 76(76)

Substance key: 000000473131 Revision Date: 14.03.2023
Version : 7 - 0 / EU Date of printing : 16.03.2023

5.3.13 ES 5 - CS 13: Worker exposure: Use at industrial sites (Manual maintenance

(cleaning and repair) of machinery) (PROC28)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 9,3 ppm (ECETOC TRA worker v3, long-term) 0,47
inhalative 27,9 ppm (ECETOC TRA worker v3, short-term) 0,56
dermal 14 mg/kg bw/day (ECETOC TRA worker v3)

5.3.14 ES 5 - CS 14: Worker exposure: Use at industrial sites (Chemical production

or refinery in closed continuous process with occasional controlled exposure or
processes with equivalent containment conditions) (PROC2)

Route of exposure and type Exposure estimate RCR

of effects
inhalative 1,3 ppm (ECETOC TRA worker v3, long-term) 0,07
inhalative 3,99 ppm (ECETOC TRA worker v3, short-term) 0,08
dermal 1,4 mg/kg bw/day (ECETOC TRA worker v3)

5.4. ES 5 Guidance to Downstream User to evaluate whether he

works inside the boundaries set by the Exposure Scenario
Health
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Risk management measures are based on qualitative risk characterisation.
Available hazard data do not enable the derivation of a DNEL for eye irritant effects.
Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites;
thus, scaling may be necessary to define appropriate site-specific risk management measures.