ASTER PUBLIC SCHOOL (GNW)
CLASS- XI, SUBJECT- CHEMISTRY
1. A system absorb 400 J of heat and does work equivalent to 150 J on the surrounding. Calculate the
change in internal energy of the system.
2. A gas expand against a constant pressure of one atm from a volume of 5L to 10L. During the process
system absorb 400 J of heat from the surroundings. Calculate the change in internal energy of the system.
3. If 5.0 L cylinder contained 10 mole of hydrogen gas at 27°C. Due to leakage, entire gas escape into the
atmosphere. The atmospheric pressure is 1 atm. Calculate the work done by the gas assuming hydrogen to
be an ideal gas.
4. The enthalpy change (∆H) for the reaction N2(g) + 3H2(g) →2NH3(g)
Is -92.38 KJ at 298 K. What is ∆U at 298K?
5. Calculate the different between the heat of reaction at constant pressure and volume for the reaction
2C6H6(l) + 15O2(g) →12CO2(g) + 6H2O(l) at 25°C in KJ.
6. The heat of combustion of methane CH4(g) is measured in a bomb calorimeter at 298.2 K and is found
to be -885.50 KJ/mil. Find the value of enthalpy change ∆H.
7. 2 mole of an ideal gas at 2.0 atm and 25° C are compressed isothermally to 1/3 of its volume by an
external pressure of 6 atm. Calculate heat, work done and change in internal energy.
8. A system has internal energy 500 J. If 500 aj of heat is supplied to it and at the same time it does 300 J
of work. Calculate the internal energy of the system in the new state.
9. Heat of combustion of methane at constant volume and 298 K has been found to be 885 Kjmol-¹.
Calculate the enthalpy of combustion under constant pressure. .
10. 0.16 g of methane was subjected to combustion at 27°C in a bomb calorimeter. The temperature of
calorimeter system was found to be raised by 0.5° C. Calculate the heat of combustion of methane at
constant volume and at constant pressure. The thermal capacity of calorimeter system is 17.7 KJ K-¹.
11. Heat of combustion of methane at constant volume and at 298 K has been found to be -885 KJ mol-¹.
Calculate the enthalpy of its combustion under constant pressure condition.
12. When 2 gram of benzene are burnt in a bomb calorimeter, the heat produced is 83.6 Kj at 298 K.
Calculate the enthalpy of combustion of benzene.
13. 400 cm³of a gas are compressed to half of it’s volume by applying a pressure of 0.5 atm. During the
process 6.5 j of heat flows out to the surroundings. Calculate ∆U of the system.
14. Calculate the work done in calories when 5 moled of an ideal gas are compressed isothermally andd
reversibly from a pressure of 1.5 atm to 15 atm at 27°C.
15. 10 moles of a gas are heated at constant volume from 20°C to 30°C. Calculate the change in the
internal energy of the gas. The molar heat capacity of the gas at constant pressure, Cp=6.82 cal K-¹mol-¹
and R= 1.987 calK-¹mol-¹.
16. For the reaction, NH4Cl(s) →NH3(g) + HCl(g) at 25°C, enthalpy change ∆H=+177 KJ/mil and
entropy change ∆S=+285 J/k mol. Calculate the free energy change at 25°C and predict wheather the
reaction is spontaneous or not.
17. Calculate the standard enthalpy change for the reaction: CH4(g) + 2O2(g) →CO2(g) + 2H2O(l) ,
given that the standard heats of formation of CH4(g), CO2(g) and H2O(l) are -74.91 KJ mol-¹, -394.12 KJ
mol-¹ and -286.31 KJ mol-¹ respectively.
