NALFLEET 2000

Wilhelmsen Ships Service AS

Part Number: 777710 - 777711 - 778640 Issue Date: 29/03/2022
Version No: 15.41 Print Date: 10/07/2023
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) L.REACH.NOR.EN

SECTION 1 Identification of the substance / mixture and of the company / undertaking

1.1. Product Identifier

Product name NALFLEET 2000

Chemical Name Not Applicable

Product Part Number: 777710 (25Ltr) - 777711 (210Ltr) - 778640 (5Ltr) -Cooling water treatment Pr No: 308303 (Norway)
Synonyms
Product no: L777032
Chemical formula Not Applicable
Other means of
777710 - 777711 - 778640, 777710, 777711, 778640
identification

1.2. Relevant identified uses of the substance or mixture and uses advised against
Chemical Product
PC37 Water treatment chemicals
Category

Sectors of Use SU22 Professional uses: Public domain (administration, education, entertainment, services, craftsmen)

Relevant identified uses Water Treatment Chemical

Uses advised against No specific uses advised against are identified.

1.3. Details of the manufacturer or supplier of the safety data sheet

Outback (M)SDS portal:
Wilhelmsen Ships Service AS*
Registered company name Wilhelmsen Ships Service AS http://jr.chemwatch.net/outb/account
Central Warehouse
/autologin?login=wilhelmsen
--------Use our Outback portal to obtain our
(M)SDSs in other languages and/or
Strandveien 20 Lysaker 1366 format.--------- For questions relating to our Willem Barentszstraat 50 Rotterdam
Address
Norway SDSs please use Email: Netherlands
[email protected]
--------- Norway
Telephone +47 67 58 40 00 Not Available +31 10 4877 777
Fax Not Available Not Available Not Available
Website http://www.wilhelmsen.com/ http://www.wilhelmsen.com http://www.wilhelmsen.com
Email [email protected] [email protected] [email protected]

Registered company name Wilhelmsen Ships Service AS* Central Warehouse

Address Willem Barentszstraat 50 Rotterdam Netherlands
Telephone +31 10 4877 777
Fax Not Available

Website http://www.wilhelmsen.com

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NALFLEET 2000

Email [email protected]

1.4. Emergency telephone number

Association / Organisation Giftinformasjonssentralen - 24 timer 24hrs - Chemwatch Dutch nat. poison centre

Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers

Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Association / Organisation Dutch nat. poison centre CHEMWATCH EMERGENCY RESPONSE (24/7)
Emergency telephone
+ 31 30 274 88 88 +47 23 25 25 84
numbers
Other emergency
+ 31-10-4877700 +61 3 9573 3188
telephone numbers

Once connected and if the message is not in your preferred language then please dial 01

SECTION 2 Hazards identification

2.1. Classification of the substance or mixture

Considered a hazardous mixture according to Reg. (EC) No 1272/2008 and their amendments. Not classified as Dangerous Goods for
transport purposes.

Classification according to
regulation (EC) No
H319 - Serious Eye Damage/Eye Irritation Category 2
1272/2008 [CLP] and
amendments [1]

Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

2.2. Label elements

Hazard pictogram(s)

Signal word Warning

Hazard statement(s)
H319 Causes serious eye irritation.

Supplementary statement(s)
EUH208 Contains sodium 2-mercaptobenzothiazole. May produce an allergic reaction.

CLP classification (additional)

Not Applicable

Precautionary statement(s) Prevention

P280 Wear protective gloves, protective clothing, eye protection and face protection.
P264 Wash all exposed external body areas thoroughly after handling.

Precautionary statement(s) Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.

Precautionary statement(s) Storage

Not Applicable

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Precautionary statement(s) Disposal

Not Applicable

2.3. Other hazards

May produce discomfort of the eyes*.

sodium borate anhydrous

Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply)
(na2b4o7)

SECTION 3 Composition / information on ingredients

3.1.Substances
See 'Composition on ingredients' in Section 3.2

3.2.Mixtures
1. CAS No
Nanoform
2.EC No Classification according to regulation (EC) SCL /
%[weight] Name Particle
3.Index No No 1272/2008 [CLP] and amendments M-Factor
Characteristics
4.REACH No

1. 7632-00-0 Oxidizing Solids Category 3, Acute Toxicity

2.231-555-9 (Oral) Category 3, Hazardous to the Aquatic
4.9 sodium nitrite * Not Available
3.007-010-00-4 Environment Acute Hazard Category 1; H272,
4.Not Available H301, H400 [2]
Corrosive to Metals Category 1, Skin
1. 6834-92-0*
Corrosion/Irritation Category 1B, Specific
2.229-912-9
2 disodium metasilicate Target Organ Toxicity - Single Exposure 0 Not Available
3.014-010-00-8
(Respiratory Tract Irritation) Category 3; H290,
4.01-2119449811-37-XXXX
H314, H335 [1]
1. 1330-43-4*
Reproductive Toxicity Category 1B, Serious
2.215-540-4 sodium borate anhydrous Not
2.8 Eye Damage/Eye Irritation Category 2; Not Available
3.005-011-00-4 (na2b4o7) Available
H360D, H319 [1]
4.Not Available
Serious Eye Damage/Eye Irritation Category
1. 2492-26-4* 1, Hazardous to the Aquatic Environment
2.219-660-8 sodium Long-Term Hazard Category 1, Corrosive to Not
<1 Not Available
3.Not Available 2-mercaptobenzothiazole Metals Category 1, Sensitisation (Skin) Available
4.Not Available Category 1, Skin Corrosion/Irritation Category
1B; H318, H410, H290, H317, H314 [1]
1. 7732-18-5
2.231-791-2 Not
60-100 water Not Classified [3] Not Available
3.Not Available Available
4.Not Available

Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from
C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties

SECTION 4 First aid measures

4.1. Description of first aid measures

If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally
Eye Contact
lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid
Inhalation procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket
mask as trained. Perform CPR if necessary.

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Transport to hospital, or doctor, without delay.

If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
prevent aspiration.
Ingestion Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5 Firefighting measures

5.1. Extinguishing media

There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.

5.2. Special hazards arising from the substrate or mixture

Fire Incompatibility None known.

5.3. Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard.
Fire Fighting Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Non combustible.
Not considered a significant fire risk, however containers may burn.
Fire/Explosion Hazard
May emit poisonous fumes.
May emit corrosive fumes.

SECTION 6 Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

See section 8

6.2. Environmental precautions

See section 12

6.3. Methods and material for containment and cleaning up

Clean up all spills immediately.
Minor Spills Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.

Moderate hazard.
Major Spills Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.

6.4. Reference to other sections

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

7.1. Precautions for safe handling

Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Safe handling
Use in a well-ventilated area.
DO NOT allow clothing wet with material to stay in contact with skin

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Fire and explosion

See section 5
protection
Other information

7.2. Conditions for safe storage, including any incompatibilities

Polyethylene or polypropylene container.
Suitable container Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.

Storage incompatibility None known

Hazard categories in
accordance with
Not Available
Regulation (EC) No
1272/2008

Qualifying quantity
(tonnes) of dangerous
substances as referred to Not Available
in Article 3(10) for the
application of

+ x + o + + +

X — Must not be stored together

0 — May be stored together with specific preventions
+ — May be stored together

Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes
of dangerous goods are stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly.

7.3. Specific end use(s)

See section 1.2

SECTION 8 Exposure controls / personal protection

8.1. Control parameters

DNELs PNECs
Ingredient
Exposure Pattern Worker Compartment

0.005 mg/L (Water (Fresh))

0.006 mg/L (Water - Intermittent release)
0.005 mg/L (Water (Marine))
Inhalation 2 mg/m³ (Systemic, Chronic)
sodium nitrite 0.019 mg/kg sediment dw (Sediment (Fresh Water))
Inhalation 2 mg/m³ (Systemic, Acute)
0.022 mg/kg sediment dw (Sediment (Marine))
0.001 mg/kg soil dw (Soil)
21 mg/L (STP)

Dermal 1.49 mg/kg bw/day (Systemic, Chronic)

7.5 mg/L (Water (Fresh))
Inhalation 6.22 mg/m³ (Systemic, Chronic)
1 mg/L (Water - Intermittent release)
disodium metasilicate Dermal 0.74 mg/kg bw/day (Systemic, Chronic) *
7.5 mg/L (Water (Marine))
Inhalation 1.55 mg/m³ (Systemic, Chronic) *
1000 mg/L (STP)
Oral 0.74 mg/kg bw/day (Systemic, Chronic) *
Dermal 316.4 mg/kg bw/day (Systemic, Chronic)
2.9 mg/L (Water (Fresh))
Inhalation 6.7 mg/m³ (Systemic, Chronic)
2.9 mg/L (Water - Intermittent release)
sodium borate anhydrous Dermal 159.5 mg/kg bw/day (Systemic, Chronic) *
13.7 mg/L (Water (Marine))
(na2b4o7) Inhalation 3.4 mg/m³ (Systemic, Chronic) *
5.7 mg/kg soil dw (Soil)
Oral 0.79 mg/kg bw/day (Systemic, Chronic) *
10 mg/L (STP)
Oral 0.79 mg/kg bw/day (Systemic, Acute) *

Dermal 2.8 mg/kg bw/day (Systemic, Chronic)

Inhalation 10 mg/m³ (Systemic, Chronic) 0.004 mg/L (Water (Fresh))
Inhalation 1 mg/m³ (Local, Chronic) 0 mg/L (Water - Intermittent release)
Dermal 2.8 mg/kg bw/day (Systemic, Acute) 0.005 mg/L (Water (Marine))
sodium
Inhalation 10 mg/m³ (Systemic, Acute) 0.147 mg/kg sediment dw (Sediment (Fresh Water))
2-mercaptobenzothiazole
Inhalation 1 mg/m³ (Local, Acute) 0.015 mg/kg sediment dw (Sediment (Marine))
Dermal 1.5 mg/kg bw/day (Systemic, Chronic) * 0.027 mg/kg soil dw (Soil)
Inhalation 2.5 mg/m³ (Systemic, Chronic) * 0.3 mg/L (STP)
Oral 1.5 mg/kg bw/day (Systemic, Chronic) *

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DNELs PNECs
Ingredient
Exposure Pattern Worker Compartment
Inhalation 1 mg/m³ (Local, Chronic) *
Dermal 1.5 mg/kg bw/day (Systemic, Acute) *
Inhalation 2.5 mg/m³ (Systemic, Acute) *
Oral 1.5 mg/kg bw/day (Systemic, Acute) *
Inhalation 1 mg/m³ (Local, Acute) *
Dermal 0.4 mg/kg bw/day (Systemic, Chronic)
Inhalation 0.544 mg/m³ (Systemic, Chronic)
Dermal 5 mg/kg bw/day (Systemic, Acute)
Inhalation 8.8 mg/m³ (Systemic, Acute)
Dermal 0.2 mg/kg bw/day (Systemic, Chronic) *
water Not Available
Inhalation 0.083 mg/m³ (Systemic, Chronic) *
Oral 0.056 mg/kg bw/day (Systemic, Chronic) *
Dermal 2.5 mg/kg bw/day (Systemic, Acute) *
Inhalation 2.2 mg/m³ (Systemic, Acute) *
Oral 2.5 mg/kg bw/day (Systemic, Acute) *

* Values for General Population

Occupational Exposure Limits (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

Norway regulations on action

rvalues o​ a nd limitf values ​
physical and chemical
sodium borate anhydrous Natriumtetraborater: 1 Not Not Not
factors in the work
(na2b4o7) Vannfritt mg/m3 Available Available Available
environment and infection
risk groups for biological
factors (Norwegian)

Emergency Limits

Ingredient TEEL-1 TEEL-2 TEEL-3

sodium nitrite 6.4 mg/m3 71 mg/m3 240 mg/m3

disodium metasilicate 3.8 mg/m3 42 mg/m3 250 mg/m3
sodium borate anhydrous
6 mg/m3 88 mg/m3 530 mg/m3
(na2b4o7)

Ingredient Original IDLH Revised IDLH

sodium nitrite Not Available Not Available

disodium metasilicate Not Available Not Available

sodium borate anhydrous
Not Available Not Available
(na2b4o7)
sodium
Not Available Not Available
2-mercaptobenzothiazole
water Not Available Not Available

Occupational Exposure Banding

Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit

sodium nitrite E ≤ 0.01 mg/m³

disodium metasilicate E ≤ 0.01 mg/m³

sodium
D > 0.01 to ≤ 0.1 mg/m³
2-mercaptobenzothiazole
Notes: Occupational exposure banding is a process of assigning chemicals into specific categories or bands based on a chemical's
potency and the adverse health outcomes associated with exposure. The output of this process is an occupational exposure
band (OEB), which corresponds to a range of exposure concentrations that are expected to protect worker health.

MATERIAL DATA
Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposure standards for
these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations require that nearly every
individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or
more.

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8.2. Exposure controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
8.2.1. Appropriate
provide this high level of protection.
engineering controls
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.

8.2.2. Individual protection

measures, such as
personal protective
equipment

Safety glasses with side shields.

Eye and face protection Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants.
Skin protection See Hand protection below
Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from
Hands/feet protection manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material
can not be calculated in advance and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be
observed when making a final choice.
Body protection See Other protection below

Overalls.
Other protection P.V.C apron.
Barrier cream.

Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the computer-generated selection:
NALFLEET 2000

Material CPI
BUTYL A

NEOPRENE A
VITON A
NATURAL RUBBER C

PVA C

* CPI - Chemwatch Performance Index

A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of
gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

8.2.3. Environmental exposure controls

See section 12

SECTION 9 Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Liquid, red

Relative density (Water =

Physical state Liquid 1.095 - 1.125
1)
Partition coefficient
Odour Not Available Not Available
n-octanol / water

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Auto-ignition temperature
Odour threshold Not Available Not Available
(°C)
Decomposition
pH (as supplied) 11 Not Available
temperature (°C)
Melting point / freezing
Not Available Viscosity (cSt) Not Available
point (°C)
Initial boiling point and
Not Available Molecular weight (g/mol) Not Available
boiling range (°C)
Flash point (°C) Not Available Taste Not Available

Evaporation rate Not Available BuAC = 1 Explosive properties Not Available

Flammability Not Available Oxidising properties Not Available

Surface Tension (dyn/cm
Upper Explosive Limit (%) Not Available Not Available
or mN/m)
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water Miscible pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L Not Available
Nanoform Particle
Nanoform Solubility Not Available Not Available
Characteristics
Particle Size Not Available

9.2. Other information

Not Available

SECTION 10 Stability and reactivity

10.1.Reactivity See section 7.2

Unstable in the presence of incompatible materials.

10.2. Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.
10.3. Possibility of
See section 7.2
hazardous reactions
10.4. Conditions to avoid See section 7.2
10.5. Incompatible
See section 7.2
materials

10.6. Hazardous
See section 5.3
decomposition products

SECTION 11 Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in a substantial
number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first
removing or neutralising the irritant and then repairing the damage. The repair process, which initially evolved to protect
Inhaled
mammalian lungs from foreign matter and antigens, may however, produce further lung damage resulting in the impairment of
gas exchange, the primary function of the lungs.
Not normally a hazard due to non-volatile nature of product

Ingestion Accidental ingestion of the material may be damaging to the health of the individual.

Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a substantial
number of individuals following direct contact, and/or produces significant inflammation when applied to the healthy intact skin of
animals, for up to four hours, such inflammation being present twenty-four hours or more after the end of the exposure period.
Skin irritation may also be present after prolonged or repeated exposure; this may result in a form of contact dermatitis
(nonallergic). The dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which may progress to
Skin Contact blistering (vesiculation), scaling and thickening of the epidermis.
The material may accentuate any pre-existing dermatitis condition
Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce
health damage following entry through wounds, lesions or abrasions.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with

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harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial number of individuals
and/or may produce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of
Eye experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to windburn) of the
conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic
problems.
Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving
Chronic organs or biochemical systems.
On the basis, primarily, of animal experiments, concern has been expressed by at least one classification body that the material
may produce carcinogenic or mutagenic effects; in respect of the available information, however, there presently exists
inadequate data for making a satisfactory assessment.

TOXICITY IRRITATION
NALFLEET 2000
Not Available Not Available

TOXICITY IRRITATION

sodium nitrite Inhalation(Rat) LC50: 0.006 mg/L4h[2] Eye (rabbit): 500 mg/24hr - mild

Oral (Rat) LD50: 180 mg/kg[2]

TOXICITY IRRITATION
dermal (rat) LD50: >5000 mg/kg[1] Not Available
disodium metasilicate
Inhalation(Rat) LC50: >2.06 mg/l4h[1]

Oral (Rat) LD50: 1153 mg/kg[2]

TOXICITY IRRITATION
sodium borate anhydrous
Oral (man) LDLo: 709 mg/kg[2] Eye: adverse effect observed (irritating)[1]
(na2b4o7)
Oral (Rat) LD50: 2660 mg/kg[2] Skin: no adverse effect observed (not irritating)[1]

TOXICITY IRRITATION
Dermal (rabbit) LD50: 5010 mg/kg*[2] Eye : SEVERE*
sodium
Oral (Rat) LD50: 5200 mg/kg*[2] Eye: adverse effect observed (irritating)[1]
2-mercaptobenzothiazole
Skin: adverse effect observed (corrosive)[1]
Skin: SEVERE / Sensitiser*

TOXICITY IRRITATION
water
Oral (Rat) LD50: >90000 mg/kg[2] Not Available

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

Tumorigenic - Carcinogenic by RTECS criteria.

Exposure to the material may result in a possible risk of irreversible effects. The material may produce mutagenic effects in man.
SODIUM NITRITE
This concern is raised, generally, on the basis of
appropriate studies using mammalian somatic cells in vivo.

sodium borate anhydrous

Reproductive effector in rats Mutagenic towards bacteria
(na2b4o7)
The following information refers to contact allergens as a group and may not be specific to this product.
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The
pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type.
The material may produce respiratory tract irritation. Symptoms of pulmonary irritation may include coughing, wheezing,
laryngitis, shortness of breath, headache, nausea, and a burning sensation.
Unlike most organs, the lung can respond to a chemical insult or a chemical agent, by first removing or neutralising the irritant
sodium and then repairing the damage (inflammation of the lungs may be a consequence).
2-mercaptobenzothiazole
The repair process (which initially developed to protect mammalian lungs from foreign matter and antigens) may, however, cause
further damage to the lungs (fibrosis for example) when activated by hazardous chemicals. Often, this results in an impairment of
gas exchange, the primary function of the lungs.
for 2-mercaptobenzothiazole (MBT)
The sulfenamide group (-NH-C(=S)-S-) is the prime determinant of toxicity for all members of the Benzothiazole-based Thiazoles
category. The acute and subchronic toxicity of MBT is relatively low. Skin and eye irritation effects are not present or are mild, but

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allergic skin reaction is possible in susceptible persons.

Data from in vitro and in vivo studies indicate a low concern for mutagenicity caused by MBT.
Mercaptobenzothiazole (MBT) is a potent skin sensitiser in man and cross reactions with other rubber chemicals can occur.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis. Histologically there may be
intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis.
Data for 50% aqueous solution Evidence of carcinogenic activity in rats; increased incidence of mononuclear cell leukemias,
pancreatic cell and pituitary adenomas and adrenal gland pheochromocytomas following vegetable oil gavage.*
WATER No significant acute toxicological data identified in literature search.

NALFLEET 2000 & Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a
disodium metasilicate & non-allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of
sodium borate anhydrous highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic
(na2b4o7) & sodium individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the
2-mercaptobenzothiazole irritant.
SODIUM NITRITE &
The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to
sodium
irritants may produce conjunctivitis.
2-mercaptobenzothiazole

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

11.2 Information on other hazards

11.2.1. Endocrine disrupting properties

No evidence of endocrine disrupting properties were found in the current literature.

11.2.2. Other information

See Section 11.1

SECTION 12 Ecological information

12.1. Toxicity

Endpoint Test Duration (hr) Species Value Source

NALFLEET 2000 Not Not Not
Not Available Not Available
Available Available Available

Endpoint Test Duration (hr) Species Value Source

EC50 72h Algae or other aquatic plants >100mg/l 2

EC50 48h Crustacea ca.12.51mg/l 1

sodium nitrite
EC50 96h Algae or other aquatic plants 1600mg/l 4
LC50 96h Fish 0.00016mg/l 4

NOEC(ECx) 672h Fish 0.01mg/l 4

Endpoint Test Duration (hr) Species Value Source

EC50 72h Algae or other aquatic plants 207mg/l 2

disodium metasilicate EC50 48h Crustacea 22.94-49.01mg/l 4

LC50 96h Fish 180mg/l 1

EC50(ECx) 48h Crustacea 22.94-49.01mg/l 4

Endpoint Test Duration (hr) Species Value Source

sodium borate anhydrous EC50 96h Algae or other aquatic plants 2.6-21.8mg/l 4
(na2b4o7)
LC50 96h Fish 1900mg/l 4

Continued...
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NALFLEET 2000

EC50(ECx) 96h Algae or other aquatic plants 2.6-21.8mg/l 4

Endpoint Test Duration (hr) Species Value Source

EC50 72h Algae or other aquatic plants 0.1-2mg/l 4

sodium EC50 48h Crustacea 0.71mg/l 2

2-mercaptobenzothiazole EC50 96h Algae or other aquatic plants 0.04-3mg/l 4

EC50(ECx) 96h Algae or other aquatic plants 0.04-3mg/l 4

LC50 96h Fish 0.31-9.03mg/L 4

Endpoint Test Duration (hr) Species Value Source

water Not Not Not
Not Available Not Available
Available Available Available

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Toxic to aquatic organisms.

Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning
equipment or disposing of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
DO NOT discharge into sewer or waterways.

12.2. Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
sodium nitrite LOW LOW
sodium
HIGH HIGH
2-mercaptobenzothiazole
water LOW LOW

12.3. Bioaccumulative potential

Ingredient Bioaccumulation

sodium nitrite LOW (LogKOW = 0.0564)

sodium
LOW (LogKOW = 1.8295)
2-mercaptobenzothiazole

12.4. Mobility in soil

Ingredient Mobility

sodium nitrite LOW (KOC = 23.74)

sodium
LOW (KOC = 21.41)
2-mercaptobenzothiazole

12.5. Results of PBT and vPvB assessment

P B T

Relevant available data Not Available Not Available Not Available

PBT
vPvB

PBT Criteria fulfilled? No

vPvB No

12.6. Endocrine disrupting properties

No evidence of endocrine disrupting properties were found in the current literature.

12.7. Other adverse effects

No evidence of ozone depleting properties were found in the current literature.

Continued...
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NALFLEET 2000

SECTION 13 Disposal considerations

13.1. Waste treatment methods

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws
operating in their area. In some areas, certain wastes must be tracked.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
Product / Packaging In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
disposal Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable
treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or incineration in a
licensed apparatus (after admixture with suitable combustible material).

Waste treatment options Not Available

Sewage disposal options Not Available

SECTION 14 Transport information

Labels Required
Marine Pollutant NO

Land transport (ADR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

14.1. UN number or ID
Not Applicable
number

14.2. UN proper shipping

Not Applicable
name

14.3. Transport hazard Class Not Applicable

class(es) Subsidiary risk Not Applicable

14.4. Packing group Not Applicable

14.5. Environmental
Not Applicable
hazard

Hazard identification (Kemler) Not Applicable

Classification code Not Applicable

14.6. Special precautions Hazard Label Not Applicable

for user Special provisions Not Applicable

Limited quantity Not Applicable

Tunnel Restriction Code Not Applicable

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable

14.2. UN proper shipping

Not Applicable
name

ICAO/IATA Class Not Applicable

14.3. Transport hazard
ICAO / IATA Subrisk Not Applicable
class(es)
ERG Code Not Applicable

14.4. Packing group Not Applicable

14.5. Environmental
Not Applicable
hazard

Special provisions Not Applicable

Cargo Only Packing Instructions Not Applicable

14.6. Special precautions Cargo Only Maximum Qty / Pack Not Applicable
for user
Passenger and Cargo Packing Instructions Not Applicable

Passenger and Cargo Maximum Qty / Pack Not Applicable

Continued...
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NALFLEET 2000

Passenger and Cargo Limited Quantity Packing Instructions Not Applicable

Passenger and Cargo Limited Maximum Qty / Pack Not Applicable

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable

14.2. UN proper shipping

Not Applicable
name

14.3. Transport hazard IMDG Class Not Applicable

class(es) IMDG Subrisk Not Applicable

14.4. Packing group Not Applicable

14.5. Environmental
Not Applicable
hazard

EMS Number Not Applicable

14.6. Special precautions
Special provisions Not Applicable
for user
Limited Quantities Not Applicable

Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. UN proper shipping
Not Applicable
name
14.3. Transport hazard
Not Applicable Not Applicable
class(es)
14.4. Packing group Not Applicable
14.5. Environmental
Not Applicable
hazard

Classification code Not Applicable

Special provisions Not Applicable
14.6. Special precautions
Limited quantity Not Applicable
for user
Equipment required Not Applicable
Fire cones number Not Applicable

14.7. Maritime transport in bulk according to IMO instruments

14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable

14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
sodium nitrite Not Available

disodium metasilicate Not Available

sodium borate anhydrous

Not Available
(na2b4o7)

sodium
Not Available
2-mercaptobenzothiazole

water Not Available

14.7.3. Transport in bulk in accordance with the IGC Code

Product name Ship Type
sodium nitrite Not Available

disodium metasilicate Not Available

sodium borate anhydrous

Not Available
(na2b4o7)

Continued...
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NALFLEET 2000

Product name Ship Type

sodium
Not Available
2-mercaptobenzothiazole
water Not Available

SECTION 15 Regulatory information

15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture

sodium nitrite is found on the following regulatory lists

Europe EC Inventory European Union (EU) Regulation (EC) No 1272/2008 on Classification,

European Union - European Inventory of Existing Commercial Chemical Labelling and Packaging of Substances and Mixtures - Annex VI
Substances (EINECS) International Agency for Research on Cancer (IARC) - Agents Classified by
the IARC Monographs

disodium metasilicate is found on the following regulatory lists

EU European Chemicals Agency (ECHA) Community Rolling Action Plan European Union - European Inventory of Existing Commercial Chemical
(CoRAP) List of Substances Substances (EINECS)
Europe EC Inventory European Union (EU) Regulation (EC) No 1272/2008 on Classification,
Labelling and Packaging of Substances and Mixtures - Annex VI

sodium borate anhydrous (na2b4o7) is found on the following regulatory lists

Chemical Footprint Project - Chemicals of High Concern List Europe EC Inventory

EU REACH Regulation (EC) No 1907/2006 - Annex XVII - Restrictions on the European Union - European Inventory of Existing Commercial Chemical
manufacture, placing on the market and use of certain dangerous substances, Substances (EINECS)
mixtures and articles European Union (EU) Regulation (EC) No 1272/2008 on Classification,
EU REACH Regulation (EC) No 1907/2006 - Annex XVII (Appendix 6) Labelling and Packaging of Substances and Mixtures - Annex VI
Reproductive toxicants: Category 1 B dNorway regulations on
n action values ​ and limit
a values ​ for physical
EU REACH Regulation (EC) No 1907/2006 - Proposals to identify Substances chemical factors in the work environment and infection risk groups for
of Very High Concern: Annex XV reports for commenting by Interested biological factors (Norwegian)
Parties previous consultation

sodium 2-mercaptobenzothiazole is found on the following regulatory lists

Europe EC Inventory European Union - European Inventory of Existing Commercial Chemical
Substances (EINECS)

water is found on the following regulatory lists

Europe EC Inventory European Union - European Inventory of Existing Commercial Chemical
Substances (EINECS)

This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, - 94/33/EC,
- 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2020/878; Regulation (EC) No 1272/2008 as updated through ATPs.

Information according to 2012/18/EU (Seveso III):

Seveso Category Not Available

15.2. Chemical safety assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

National Inventory Status

National Inventory Status

Australia - AIIC / Australia

Yes
Non-Industrial Use

Canada - DSL Yes

Canada - NDSL No (sodium nitrite; disodium metasilicate; sodium borate anhydrous (na2b4o7); sodium 2-mercaptobenzothiazole; water)

China - IECSC Yes

Europe - EINEC / ELINCS /

Yes
NLP

Japan - ENCS Yes

Korea - KECI Yes

New Zealand - NZIoC Yes

Continued...
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NALFLEET 2000

National Inventory Status

Philippines - PICCS Yes

USA - TSCA Yes

Taiwan - TCSI Yes

Mexico - INSQ Yes

Vietnam - NCI Yes

Russia - FBEPH No (sodium 2-mercaptobenzothiazole)

Yes = All CAS declared ingredients are on the inventory

Legend: No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require
registration.

SECTION 16 Other information

Revision Date 29/03/2022

Initial Date 13/09/2017

CONTACT POINT
- For quotations contact your local Customer Services - http://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheet Wilhelmsen
Ships Service AS - Prepared by: Compliance Manager, - Email: Email: [email protected] - Telephone: Tel.: +47 67584000

Full text Risk and Hazard codes

H272 May intensify fire; oxidiser.
H290 May be corrosive to metals.
H301 Toxic if swallowed.

H314 Causes severe skin burns and eye damage.

H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.

H335 May cause respiratory irritation.

H360D May damage the unborn child.
H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

SDS Version Summary

Date of
Version Sections Updated
Update

Toxicological information - Acute Health (inhaled), Toxicological information - Chronic Health, Hazards
identification - Classification, Disposal considerations - Disposal, Exposure controls / personal protection -
Engineering Control, Ecological Information - Environmental, First Aid measures - First Aid (eye), Composition /
14.41 29/03/2022
information on ingredients - Ingredients, Accidental release measures - Spills (major), Accidental release
measures - Spills (minor), Identification of the substance / mixture and of the company / undertaking - Synonyms,
Name

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios.

For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:
EN 166 Personal eye-protection
EN 340 Protective clothing
EN 374 Protective gloves against chemicals and micro-organisms
EN 13832 Footwear protecting against chemicals
EN 133 Respiratory protective devices

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end of SDS