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finot__Scannmah Enann “anewaedt Reach wr
(fechion A) [ Exgineening
Papier eh se
Hatta Nuvrben>
Role of Hotta rumber in the occurance of
Reaction in the Film
To mow sshe wethen oreaotimn 1's fant an ptow on the unit
Aurfuce of gar Sigpad interface we acrwme thet gor phase
Nepintince and we defire aftr carvenrin porate ay canpidobs
e the goo-phare Aeeirtace ao neg higi bte « OF the value of My te
fasge enough then ali the neachine ccourp inthe filer and
punface arta ie the controiicg facton.
On the othen bond if the value af Mu te ver Secor
‘am ng seachion Scere in the file amd buble Velume
becrmen the camtreliling gate Fasten
mz Max. poset ite coreverpiion in the film
a= ——_
arian. de Heoredih tramppat through the Film
4
Mechamiom of Surface Kimetrer >
»
A mnolecute 12 obagibe om te the puoface amd ta akicheol
to am achive alte.
2) gt then neacts exthen with anbthen anglecule an am
adjacent pide, a Ct aimpty lecampencn ante aite amd
fovnat'on of product take place
3> The product ane chrpolve frum the protface and maven
into the lowtk of the Plu, whith Deane the active Oven alt orate egiatitr >
My
Daa aL ath
vou
fi) y= MHevernde = Me I= INge - —
Fonatted-s Aoverale = M+ Nt Is4 - —
Prawer Ae > iiel
EffechVencop factors
Effectivencae factan 1'a the meapute
of how omer “the visachim, ote i Lowencl olue 49 the
lePiatamce ef pane chifuaion.
> Seis defined ap the sate ofachal ang: Meackion rake itty
the pore to the neaction sate in the aboence af pare
de ffupton atepintamce .
) The mate of steactio inthe abpence ef pare diflunien,
NEALE tance tA the onaa. mate of reach.
> The sate of
the Neacktent
Calomar puofuce |
dteackiin etl be max. when ~fhe Canc. af
the pone 1) wane ap that of the
Effechvencee factan (€) = Octuak ercam meachion nate wipers |
ake Prete foscel by pare feffaatin
l—-s>2,s2-—__
@ = Aim with athe
Ola, erthout dettueien oeaintonce)
= ®
y Amowen no = 4@
» Low neanive Corvenrim Modet >
The meactant ap emtonp andl
Neacta though out “the pankide atoll tine mont aikely
OF different ousep ond cet” decoction esith bn the portiete
Thue the Adlid reactant te converted pragrereively + contimuounls
Preyshout the porbcle
Racking position —>
(
& a
2) Shoinking re Moelal 4
1
Gane
of xcactant
polled The oteactiio ocreura finot at the outer pkin of the
poutrcle them the eachion zene orove inte the aolid
Heawing behind ~the cormphetety canyortedl aaatoual amd
rot pated we mefer ty them ap ‘ach’, thu at any
dime there exiot gral umseeactel cane of onatoual
which ehruink tn atze cLesring the teachin amd tend
to 2g When Complete CONVoelim otcUp , Pmowen vor
Effcctvencon fackan fan ganden reaction at Far oy Serabrweak
pare >
.
. _ « J ade
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et fm Sopher C8? gx
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fot olen Ez fare 2
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Geof Gan
phase
cacti
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© Ky EG Me Ky
oute f unncoctel Gre = = diNa
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noe LE
cvte ot the eurface = KG —o
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mal dN el
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via Fit He ("Cag
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4nse Ky
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— Ja = 77
b
Ng = Sg V
dp = fav ob i aM,
eects
“Ma
te = BAY | oy Anata
oe bak
ot = 21 x th pete
Sane bb KM ag
t= ~Fm dae
bE Gy
t Te
Jot= ~%2 fade
Beg oe
t= =Pa_ (-e)
Fy
te (- ae
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ot,
then Ampusea Vo? 6
me Jr
Shsunbirg Care moclet fan pphoweaS partmlie of un chargeo
an fixed at2e>
Ace” to thin onodel the fallowing atepe cum dhautry the
pobrel — Purl stcaction+
5 Dethworem of gaoeoun eackont FP through the fulm
Burroumching the porhtte to the Auodace af poli
Qemenally Known an extovnat oleflroren-
2 Panentration ¢ Dr'ffier'r of reactor PR treyh the Layeno of
ach tthe surface of umnenet eal care Kmowr oF Pane ON g
intowat dit ffreres.
8) Reaction ef gopeoue steackrt “F urthaolith ak tin
Oeachirn urfice. .
4) Diflucron of gaocour product “throug. the bfankeb Fon
do the eatorral pustfice of eoticl kmowmay REVERES
frtermad cl Hiern .
©) Difworm af gaocous product Yrsorgh the Biomed gop
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neveroe extemal offer. ce
MEERUT INSTITUTE OF ENGINEERING AND TECHNOLOGY
Pre University Test Even Sem. April 2018
‘Subject Name: Chemical Reaction Engineering-II
Subject code: NCH-601
Time- 3:00 Hrs
Note: Ask for graph paper if required in any question
Course: B.tech Branch: Chemical M.M=100
Section _A
Q.1. Attempt All the parts (No Choice) (1X2 =22)
a) Define Cold Shot Cooling & cold inert injection? CO1
) Determine the heat effects during reaction within the particle and within the film? CO 3
©) Write the performance equation for reactors with porous catalyst particles? CO 5
4d) What are hetrogeneous reactions? Explain different types of hetrogeneous reactions
with examples? CO
©) What are effectiveness factor and thiele modulus? CO 1
f) Determine stokes law regime? CO1
2) Differentiate between competitive and non-competitive inhibition? CO 2
h) What do you understand by monolithic catalyst? CO4
i) Define supported catalyst & unsupported catalyst. CO 4
j) What is active site theory and under which conditions it is applicable? CO 2
k) Explain biochemical reaction system? Differentiate between enzyme & microbial
fermentation? CO2
Section _B
Q.2. Attempt any Six Questions from this section (six questions out of ten)
(6X8 =48)
(a) What is the importance of Michaelis-Menton (M-M) equation? Explain with the
proper derivation the coefficient of M-M Kinetics? Co 2
(b) Derive the relationship between observed activation energy, Eyy, & actual activation
energy, Exrue? COS (©) Derive equation for effectiveness factor for a first order reaction at for cylindrical
pore? COS
(A) Derive overall rate expression for non-linear process. CO 4
(© Explain briefly SCM and write down its limitations, CO 3
( List out all assumptions and derive langmuir adsorption isotherm equation for
catalytic reaction. Also discuss the significance for the failure of Langmuir model
and necessary conditions CO 5
(® Write a short note on: Catalyst promoters, inhibitors and poisions. CO §
(h) An ore of uniform size particles is to be roasted in fluidized bed reator. The time
required for complete conversion of particle is 20 min and mean residense time is
40 min. The solids remain unchanged in size during reaction, Calculate the
fraction of original ore remaining unccnverted assuming (Chemical reaction step
is rate controlling). Co 6
(i) Briefly explain physical properties of catalyst. CO 4
() Find a rate equation to represent the breakdown of cellulose by cellulose in the
absence of inhibitor. CO2
Section C
Q. 3. Attempt any three Questions from this section (three questions out of five)
(3X10=30)
(a) Determine controlling resistances and there rate equations in solid catalytic
reactions? CO 4
(b) A feed consisting of 20% of 1-mm particles, 30% of 2-mm particles and 50% of 4-
mm particles passes through a rotating tubular reactor where it reacts with gas to
yield hard non-friable solid product according to the shrinking-core model (SCM)
with chemical reaction controlling. The time required for complete conversion of
4-mm particles is 4hr.
Determine the mean conversion of the solids for the residence time of 15 min. COS
(©) The result of a kinetic runs on the reaction A-»R made in an experimental
packed bed reactor using a fixed feed rate, Fao= 10 kmol/h are as follows: CO4
W, Kg cat. 1 2 3 4 5 6 7
Xa 0.12 | 0.20 | 0.27 | 0.33 | 0.37 | 0.41 | 0.44
Find the reaction rate at 40% conversion and also find the amount of catalyst
needed for 40% conversion if feed rate is 400 kmol/h. (a) Substrate A and enzyme E flow through a MFR (V= 6 Itr.). From the entering & exit
concentrations and flow rate find a rate equation to represent the action of
enzyme on substrate. CO 6
Cro, moVitr. Cyo, mol/itr Cy, mol/ltr v, Itr./hr
0.02 0.2 0.04 3.0
0.01 0.3 0.15 40
0.001 0.69 0.60 1.2
(©) Calculate the amount of catalyst needed in a packed bed reactor to achieve 80%
conversion of 1000 m?/h of pure gaseous A (C49=100 mol/m*) for: COS
Eee s0cgtee ancl
Se Rr, ~ 1+0.02¢,’ hKg cat
a = ec2, mal
fi, AFR 14 = 86 oe “> Pre University “Teal -\.
_Areaiby
| Heot — affect: cuning Readion uithin the — fasticle 4
In ote élete the heat Pl likin on elements
Aniclneas ef te pavticle iG Wllemced ey the heat genera
by chemical Yeach'sn:
ATporticle = De Clns~Carcenter) CoAHy)
L Kee
a [Mest elect dining Feackon within the films
jane note. het — generehion rreaction within the
pellet ig get equal to the vote ey heal removal
Hyrouyh the film
Fas Hem) m9
eT,
Ang 15 Pesfesxmance. equation fers Reacr with Pou Cotalrygt =
|For Ply flew rovers
moleg A teacled
Fain moe, Frau * Fy CI-Xpect)
Noh of Colalygt= Vg Ang 14)
|
wo
&
Pow geactent B
Madteniad, bolonce
E digaprectronce 4 8
Sopa yne anteat el B
fy, Crtnin) = Pan LI-taws) + CRI AM
vant = (ora) Wg
AR
Coe
e
Knox —Xnin
ae
e
Hekre aug Reachon-,
Hekrogeneaus Neat
A Hetergenenus “Peat ae
these Im whith more thon one phage ig frvelved to
proceed:
Helregereoss reachon meg two
Cotalyetic helewegenous Reaching
aan I cadalytic — hete’ rogene Oh
Rear Hien ugualy catalygt 18 og Bola -
4ybea~
Exarmp le
Gog _golid — veachons
= as /o gos Ligue - Solid veactrong -
/ | Neon Nen_ catalytic _hetev heferogemeoug Reaction -,
—_—_
Reactant from the bulk et one — phage must be
Hranaprted do the «= mtoyface «Ol the | phage, | OT Into
the bulk % the then Phage -
Bx
© |Cr0g @olid Teaching: Toasting 4 gulprise Tes, Gmbust-
tom % cool
@e1e)| CfPectiveness fact} I ig determine the — heww
much the “feathon wate (@ lewend due fo the
weeaigtnce of pave diffusion -
Jt ie the ‘ratio actual overage Yeachiyn Fate.
within the pore +o the weathon ryete jim the abgene
“pore diffualon — Feaibtence- ”
[»Sa |
« Miz ig the thidle modulug.
Prgigr) Differentiate behoeen CompetiHve omd Non Gmpehitive
imhib tose
Tom petitive Yahibi tore =
—— —— ——* fIhen the Bubstrote (8) oma (B)
jnhibitor attack the @ome Bite on the enzyme
then Inhibitesg Called = Gmpetitive inkit/ texe-
| Enzyme Gmblex 18 tmachve blhen = the Inhibor to 8
tile On the eM2yME
doing go it Store
inhibiting’ §— 1B called
Amgi-bh Memolithic_Cotalyet
Broce 18 flat «The “Weathien — cHeNHty take lace
on A monolith Catayok in the Perm of o plde
whee 46 pereent
Prettin] Suppeoted Catalyst =
al — boged — Cokatygt
The guppost may
[Unecppasted code et
oft temed to ib:
Non Gmbetitive Imhi bias,
adtack the different tybes
garghate and in
the achon % A then the
meng@mpeH Hye:
a ig a type cotabyat whe
Grveugion 'S athieved-
Supported Catalyst 18 4 meatouiat
ugu a Bld with a high @urface area do ehich
q codelyst J — offixed
the activit peferogenenus — Gatalyst and -romomets
occurs ott «the ataface ecto:
be imet ov Padticitoate pin
the Catalyst — VeaChiong -
Ft te ag fybes | cetedyat that
Ip not — Bupported by q marks omd 18 mot neat)
Biochemicad, Reackon — |
> IL ote a “Ceachion m vis
the taone formation + one ameleaeg to @ different
molecule tmaide a cell:
These are mediated &g emzymeg whith Fe
biological catalyet that con altey the tate and
Specify Chemical —yeachion frside Cellg- e
Eneyme, Pomentodion ] Miaobial FeswmenteHon
Ctolye+ agent — does rot Cotabyet agent seproduces
sepmduce Iteulf thaelf - :
Bt ig nok auetocodalytic GH 18 aukcatadyhc-
Active eile themy.
H ig a region on enzyme = Whee gubelrate
motecutes bind md ymdergo Chemica seachon - =
se atte atte cémaisde 4 veaidye thats form — tempornry
hows wlth the Bubelrete omy Veldues thet cadaly ne
@ reaction of tat grbelyate- nga (a);}
>Cm mest af the ernyme 1g jn bound Peam [a
XCAE) -
The rate 4 fermation WB the product R-
Re ky .
she net vode. ¥ Pessmotion ch the Comblex 18-
Tq kiEeCn hn — 13 & —@
hese Ce = we 1%
A~Ka G20
ye Kia Gy KG
ky Se lee al + ka
Gr (lata) 2 eile Co hee
Cx (ia +3) = Ky Ce Cg > Ce Che ths) 4 ky Ca = [ey ee
Uef( Kets) + iCe ] = kate Ge
c= tle
Cate) +h, Co
> keg ky KV Ce, Co
@
ABBE} le knows tect °
hing onde, = —Ca_
Cag
let For Pingt der ay. eadhiong - er
+o
Kens Cag
— cl
OB = t Ga dx
Ta = ot ff eax.
(eartier ~
| Gs + Caan
iE fe fees |
ne wr th Mux)
ons GahMe
Ca Cas Gah m Cx)
Ghet .
Ms ol [ Ths Gath UK) dk
1 ts 6 Gah
> Cas
l
7 Gbh M (Ex) «
LCas Gah mie. \ dx
aes MUX) dx
come | Ge hm (l-x)
ls
= + __T =I ginh mlex
L Gg hML [ aie 0)
a ~ BinhMe
manent ]
> SinhmMe
ML GBhML
[vt aa
ee Mt BF
n39 @5 Shai nking Love,
Si nee
Ar SLE EEE EL
"aid PolBhion,
«lama md@ — aaaume that the teachin frmt — beaing, ot
the audoy Birrfote 4 tne @olid Particle and tne deepesr
layer dowet dake pot im the “reaction unlill all the mute
jee hae chonghormed ils glia ow Goacous — preduch-
Moted (SCM) -)
= i
Relid
+ [Bn Unrectled — Corre. + aolid Continniualy decreage, in
|eize during eatin uti) Te ig entirely Gnaumed
The core ig the unreacted ue Bo thig meade?
[ia acfesred to og shvinicing unveacted Cone, medel a
Chem) \
mick Reachin glep ag rate Gort voll —
Xe = LE rE) Ae ys mS
l20
T= 20 min, t=48min
a
y
ECHEY) -F, OATH Caray
0-096
Reh diffusion Btep ag yee alc
HB (Ey nae (EP
= OF OZ
él S1 led
@=L (046%) - en (6 41cH yy 4 4 = (0 4164
Q-0
O76
"
I-
emai 4
Te frrachiy of the origina? ove
umenverted 18 [Kes OeFd = Bey Ping HY
(ay
i.)
5
9)
5)
Physicad probertieg J covlodys t 4
_ ~ , a >
A catshyst wemams —unchemyed in 118 Ome
lad chemical Qympositin at the end 4 the
seach,
A mall — omaumt a 4 catalyst 18 after
eubficient — to catabyne 0 Teachlor.
A catolygt does not: Change fhe tote or
Chemiarnd equlllorium’
A Catalyst 18 usually @pecific in nature. ©
A catalyat — Yeachion genevally hae a lawey
ach yvoch'en Rmergy than men cotalyged Teectinn
Cackatyeed veochbn — Proceed& at fat ey
rate -
\
Ove wede for nom liners Roceag—:
_ 2 All) + (8) — ed)
[mn 8
Ka (Cn Cas) = KGa
HeR, +kacng ~ Kalan > ©
Ge = Ka NE AT Ratan
Qk"
othe Wy fog (- EIT ag )] m Ang a3)
“eo
«
"
2 > ——
f Yd! Kala 4 Me _ Ia + 4h Racae
7 ak
“ty ~ Ko — 2
> 3 wl at Cog + hy — ky Hicks |
Catalyst Pro motera +
% ie a @estonees —ushich_—them@elves ave ot;
catabyet but when 18 mixed @mall quonbiteg sith
the catolyst — increase their etficency ore called 0g
Catalyst — praneterg.
[Ext Sn Hobevig — PUDLEBE Pow the aynthesia Nty
traces of cently beens imereage the activity os
finely divided ‘ron whith «atte 08 Codey
Fospmg-| St is ubstemcer thith —deatrny.
piss ’
tne activity of Pe Codalyst by their PVR ENce
are mow ag Codalytic —poigone-
Lx} The platinum Cadalyst uged tn the Oxidation
a a ta te polgomed by co.
Fnhibites@, St |e a @rbglonqe that Blow _ or
—_—_
with a chemical ash'en
interferes
ae at reduce oT BUPPIRSBes the acuity
| @ubptonce th
og omether Bubs ce £ echion-C
celine
Aing3b= eth
THR
Tx Ry TKR ond Ty sc Ry
Rrl mm
Rota mm
R= 4m
ow
ct OR
«
= THER 4 h
Tt ee Et
2G he _ 4en
Tas a Apt kh
E> tes lSmin = 0264
far ie a pantie different out Urchenging gine
he = bn Ci xp ei] FED —@
For’ Chemical reation Gnin| Gaweigion
Hime reledfendhip
E 1-Unweys
Mitre 9h patie in play Plow of eah Rize
ate oe Li-xglhi)3
THR)
[rev] . (r 45) ne
= 3 3 s
\- ke = (ee \ Fay (2) Fo) 4 [te |. Be
Ti e ty e tw) FF fer 1- mm isle
pimcle Fur 890F go eth
e e
Rra- ™ did
POtde Fay _ BaF Lago aaah
f ‘ :
sr} ~ mm patce Fu. OSF = 080 THe cae
+ Fr
te= oish
3
reali asefaonee r fiost (ASF
\e ~ ORS
« ya zt Obst F a
——
= ;
(% = 303%
& Ans
ecu Galetionaes
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Ce, Ge oo) Ools
Caen tw
~ Gn t ky Se Ht
7 3 the =
Slope > kg = M4
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0-29
7 a Cp, Ca
O20 +Cy
Plot grobh Cy vis Sea AT
Coo~ Ca
6°08)
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| +0.02¢p
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7 ¥p> 8 - aa
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* We O02 Cy te O02 CH oC )
= Soxlce Ctrxs)
j0ren.x (o0( JKR)
“vg ~~ So0e Une)
1+ 2Cl-xA)
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wee (dy ra Loe) oi
fe Ua l Soso ErtA]
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Wo= Fre an |
Bq, LO
Chee 00 mel) we
l= je
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(w= 9]
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