Srivastava 2021
Srivastava 2021
A
https://doi.org/10.1007/s40030-021-00521-4
ORIGINAL CONTRIBUTION
Abstract The utilization of coal bottom ash (CBA) as between compressive strength and UPV were exponential
natural sand replacement in mortar is a feasible solution to in nature with high correlation coefficient varying from
reduce the environmental issues created due to its disposal. 0.91 to 0.99. The feasibility of developed empirical equa-
However, strength behavior of CBA mortar varies from tions in predicting the compressive strength was validated
conventional natural sand mortar. For design and quality by comparing the predicted results with measured test
control in the field, there is a need to assess the feasibility results.
of nondestructive test methods in estimating the in situ
mechanical properties of CBA mortar. To address this, the Keywords Coal bottom ash Compressive strength
present research study elaborates the correlation between Correlations Empirical relations Mortar
compressive strength and ultrasonic pulse velocity to pre- Ultrasonic pulse velocity
dict the compressive strength of CBA mortar using UPV
test. The influence of CBA replacement level and curing
age was examined. The experimental program involves two Introduction
mortar mix proportioned cement-fine aggregate ratios of
1:3 and 1:5 having standard flow of 110–115%. The natural The construction industry is accountable for over dredging
sand replacement with CBA varies from 20 to 100% in of natural sand from river beds to meet the increase
increment of 20%. Control mortar mix contains 100% demand of shelter. Mortar is one of the key components of
natural sand. Mortar samples were casted, cured at ambient building structure, which mainly consist of cement, fine
temperature and then tested at curing age of 7 days, aggregate, water and admixtures. Utilization of CBA which
28 days, 56 days, 90 days and 120 days. Workability and is a by-product from thermal power plant as fine aggregate
density test of mortar specimens have also conducted for in mortar is a sustainable and eco-friendly step toward
reference. Results indicate that the UPV and compressive sustainable construction [1–3]. Many researchers [4–7]
strength of CBA mortar were lower than those of the have investigated the behavior and feasibility of incorpo-
control mortar for all replacement levels at all curing age rating the CBA as replacement to natural sand (NS) in
and for all mixes. The empirical relationships obtained mortar, and encouraging results of 20–50% replacement
were reported.
Compressive strength is one of the decisive properties of
& Abhishek Srivastava cementitious materials. Many physical and durability
[email protected]
properties like elastic modulus, impermeability, and resis-
S. K. Singh tance to weathering environment are believed to be
[email protected]
dependent on strength and thus are deduced from strength
Chandra Shekhar Sharma test data. There are several techniques for estimating the
[email protected]
mechanical properties of cementitious materials, which are
1
CSIR-Central Building Research Institute, Roorkee 247667, broadly classified as destructive and nondestructive tech-
India niques. Destructive methods are costly, time consuming,
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and requires sophisticated instruments. Nondestructive Tan [17] proposed empirical relationship between UPV and
techniques are economical and simple alternative of ultrasonic pulse attenuation with compressive strength of
destructive techniques to assess the material property. In cement mortar. Voigt et al. [18] investigated the effect of
nondestructive methods, material property is correlated curing temperature on the correlation of ultrasonic pulse
with certain measurable experimental parameter. reflection loss with compressive strength of cement mortar
The UPV technique is a popular nondestructive tech- by conducting studies at different water-cement ratio of
nique used for evaluating the mechanical properties of 0.35, 0.50, 0.60 and curing temperature of 15–35 °C. It was
concrete [8], mortar [9, 10], rock [11], masonry [12], bricks observed that the relationship is independent to curing
[13], cement paste backfill [14, 15], etc. The versatility, temperature. Table 1 summarizes the relationships between
repeatability and simplicity make UPV test effective for the compressive strength and UPV provided by different
condition assessment of materials. It involves measurement researchers.
of the speed of ultrasonic pulses moving through the given Studies in the past literature have revealed that UPV test
material test specimens [16]. There are many studies is extensively used for characterizing the mortar properties.
related to the use of UPV test of mortar. Tharmaratnam and CBA mortar is an eco-friendly material, which has the
Table 1 Summary of relationship between compressive strength and UPV provided by different authors
Authors Type of Studies Correlations R2 Remarks
cementitious
material
Tharmaratnam Mortar Attenuation of ultrasonic pulse fc ¼ 0:015e1:83UPV 0.908 Attenuation is well correlated with
and Tan [17] in cement mortar fc ¼ 0:023e1:72UPV 0.906 compressive strength
Del Rio et al. Concrete Characterization and hardening fc ¼ eð5:40:8Þþð0:001850:00018ÞUPV 0.92 Exponential relationship exists
[20] of concrete with ultrasonic between strength of concrete and
testing UPV
Nash et al. [19] Concrete Finding an unified relationship fc ¼ 1:19e0:715UPV 0.59 Strong correlation exist between
between crushing strength of concrete strength and UPV
concrete and nondestructive
tests
Gul et al. [21] Mortar Compressive strength and fc ¼ 0:1414e0:0015UPV 0.94 Correlation between compressive
ultrasound pulse velocity of strength and UPV is well
mineral admixtured mortars accounted by the exponential
relationship
Qiu et al. [9] Mortar Determination of mechanical fc ¼ 0:134e0:0:000149UPV 0.869 Correlation between strength and
properties of cement asphalt UPV was exponential in nature
mortar via UPV method
Omer et al. Mortar Relationship between fc ¼ 0:00114e0:0019UPV 0.88 The compressive strength possesses
[10] compressive strength and fc ¼ 3:03e0:0011UPV 0.95 exponential relationship with
UPV of GGBFS based UPV before and after the
fc ¼ 6:29e0:0011UPV 0.98
geopolymer mortars exposed exposure to elevated temperature
to elevated temperatures fc ¼ 3:267e0:0028UPV 0.98 with R2 ranging from 95 to 98%
Mohammed Concrete Effects of maximum aggregate fc ¼ 0:088e1:581UPV 0.722 Correlating UPV with compressive
and size on UPV of brick fc ¼ 0:388e1:186UPV 0.660 strength and Young’s modulus
Mahmood aggregate concrete well established
fc ¼ 0:226e1:32UPV 0.696
[22]
fc ¼ 0:409e1:136UPV 0.542
Shariq et al. Concrete Studies in ultrasonic pulse fc ¼ 0:23e1:16UPV – Correlations between UPV and
[23] velocity of concrete fc ¼ 0:114e1:13UPV compressive strength can be used
containing GGBFS for predicting the strength of
fc ¼ 0:195e1:19UPV
GGBFS concrete at all
fc ¼ 0:199e1:14UPV replacement percentage
fc ¼ 0:1e1:29UPV
fc ¼ 0:175e1:16UPV
Rao et al. [24] Concrete Experimental studies in fc ¼ 1:526e0:761UPV 0.895 Concrete mix with fly ash cement
ultrasonic pulse velocity of replacement shows increase in
roller compacted concrete UPV values with age
pavement containing fly ash
and M-sand
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NS 0.57 0.45 1.38 1.05 0.05 1.83 9.85 82.80 0.62 1.40
CBA 1.01 1.38 2.19 2.56 0.06 4.78 18.10 65.30 2.52 2.10
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Mix Proportions accordance with the ASTM C1437 [28]. In all the mortar
mixes, super-plasticizer (polycarboxylic ether based) con-
In this study, two volumetric mixes of 1:3 and 1:5 cement/ firming to IS: 9103[29] was added for improving the
fine aggregate ratio were used. Natural sand was substi- consistency. The procedure of mixing the materials was in
tuted with CBA by 20%, 40%, 60%, 80%, and 100%. accordance with ASTM C305 [30]. It firstly involves
Control mortar contains 100% natural sand as fine aggre- placing the cement and water in mixing bowl of mixer and
gate. The mix proportions of the mortars are given in mixed for 30 and then sand is gradually added while
Table 4. Determination of mortar flow was done in mixing over 30 s. After that mixer was stopped and then
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mix was allowed to stand for 90 s (mortar attached to bowl estimated through flow table test to obtain the flow of
wall were scrapped), finally mixing was again done for 110–115% as per IS 2250-1981[31]. For each mix, three
60 s. specimens were casted. Determination of specimen’s den-
sity was in accordance with ASTM C642 [32]. To deter-
Specimen Preparation and Testing Procedure mine the compressive strength, the
50 mm 9 50 mm 9 50 mm cube samples were casted as
Workability or flowability is one of the important proper- per ASTM C109 [33]. The mortar samples were tested at 7,
ties of mortar for its easy application as rendering mortar 28, 56, 90 and 120 days of curing age using 1000 kN
and also aids in the proper filling of masonry joints. Mortar Universal Testing machine.
mix was prepared, and the amount of water to be added is
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Fig. 5 Compressive strength (28 days) of mortar mixes at different CBA content
The lower strength of CBA mortar specimens is attrib- CBA mortar leads to increased porosity and thus adversely
uted due to high water–cement ratio of CBA mortar com- affects the performance under compression loading. The
pare to control mortar samples [6]. High water content in observed trends are in agreement with the results reported
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Fig. 7 Evolution of
compressive strength with age
for 1:3 CBA mortar mix
Fig. 8 Evolution of
compressive strength with age
for 1:5 CBA mortar mix
in the literature [4, 6]. However, higher reduction in values decreases with increasing CBA content. In 1:3 mortar mix
was observed in the present study which is probably due to proportion, the reduction in UPV value varies from 2.88 to
greater CBA content and higher w/c ratio of the mixes as 23.41% for 3CBA20 to 3CBA100 mortar specimens.
compared to the mixes in literature. Similar to this, 28-day cured samples of 1:5 CBA mortar
In Fig. 6, the UPV values of different mortar specimens specimens have UPV values ranging between 2912 and
are presented. In general, UPV values of CBA mortar are 2286 m/s, which was lower than UPV value of 5NS
lower than those of the control mortar and it continuously (3114 m/s) samples as can be seen in Fig. 6.This reduction
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evolution and extent of enhancement is not similar in the products (i.e., C–S–H) leading to more compact and dense
specimens. This behavior is attributed due to variation in mortar specimens. Thus, velocity of ultrasonic pulses
composition of different mortar mixes. increases as less time is required by the pulses to pass
A substantial increase in strength was observed to occur through the solid mortar matrix. These results are in
between 7 and 28 days; afterward, strength increases agreement with those in previous studies [5].
gradually. Also, strength of CBA mortar specimens was
observed to be lower than the control mortar specimens for Correlation Between UPV and Compressive
all replacement level. The two factors ascribed to this trend Strength
were high water content in CBA mortar samples which
increases the porosity and replacement of dense natural The test results show that the UPV and compressive
sand with porous CBA [7]. strength of mortar are significantly affected by CBA con-
Figures 9 and 10 show UPV results on different curing tent and curing age. The experimental investigation was
age for cement: fine aggregate ratio of 1:3 and 1:5, carries out at mortar age of 7, 28, 56, 90 and 120 days. To
respectively. Similar to compressive strength, UPV values establish the relationship, all the data points are merged
of all the specimen’s increase with increase in age irre- together and plotted as shown in Fig. 11. Plotting of test
spective of type of aggregate. For instance, the average results shows that compressive strength of CBA mortar is
gain in UPV values at 120 days curing corresponding to its exponentially correlated with UPV as:
value at 28 days varies from 4.07 to 5.92% for control
fc ¼ aebVc ð2Þ
mortar mixes. In CBA mortar mix, the long-term UPV
improvement varies from 5.58 to 7.38% for 1:3 mortar mix, where fc (MPa) is the compressive strength of mortar, a, b
whereas it is 6.01–9.51% for 1:5 mortar mix at 120 days are the empirical constant, and Vc (m/s) is the UPV. The
compared to 28-day UPV values. general empirical equations obtained to predict
As the hydration proceeds with longer curing period, compressive strength from UPV values were:
pores in the mortar matrix were filled with the hydration fc ¼ 0:2458e0:0016V ð1 : 3 Mortar mixÞ ð3Þ
fc ¼ 0:2765e0:0016V ð1 : 5 Mortar mixÞ ð4Þ
2
The coefficient of determination R of general relationships
was 0.93 for both 1:3 and 1:5 mortar mix proportions. This
represents that the variation in compressive strength with
UPV is accounted well by exponential relationship. The
earlier research work of Qui et al. [9], Omer et al. [10] and
Tharmaratnam et al. [17], has also shown that the UPV and
compressive strength of mortar were correlated
exponentially.
The plot of compressive strength and UPV for CBA
mortar samples at different curing age plotted separately is
illustrated in Figs. 12 and 13 and empirical equations are
shown in Table 5. The coefficient of determination (R2)
varies from 0.91 to 0.99 and from 0.95 to 0.99 for 1:3 and
1:5 CBA mortar mixes, respectively.
Feasibility Analysis
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Conclusions
Table 5 UPV and compressive strength correlation for different mixes with variation of curing age
Mix proportion Curing age (days) Correlation between compressive strength and UPV R2 Equation number
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The present study implicated that UPV technique is 6. P. Ramadoss, T. Sundararajan, Utilization of lignite-based bottom
feasible for rapid estimation of CBA mortar characteristics ash as partial replacement of fine aggregate in masonry mortar.
Arab. J. Sci. Eng. 39(2), 737–745 (2014)
both in the laboratory and at the site. For future studies in 7. P. Torkittikul, T. Nochaiya, W. Wongkeo, A. Chaipanich,
the line of this research to advances the utilization of CBA Utilization of coal bottom ash to improve thermal insulation of
mortar, investigation on the effect of other controlling construction material. J. Mater. Cycles Waste Manage. 19(1),
factors like particle size distribution, curing regime, CBA 305–317 (2017)
8. A. Masood, M. Shariq, M.M. Alam, T. Ahmad, A. Beg, Effect of
mineralogy, admixture, etc., on UPV and strength rela- elevated temperature on the residual properties of quartzite,
tionships for CBA mortar is recommended. granite and basalt aggregate concrete. J. Inst. Eng. Ser. A 99(3),
485–494 (2018)
Acknowledgements The authors acknowledge the financial support 9. K. Qiu, H. Chen, W. Sun, L. Sun, J. Hong, G. Zhao, Determi-
from M/s National Buildings Construction Corporation Limited nation of mechanical properties of cement asphalt mortar via
(NBCC) India, New Delhi, under projects: GAP 0018. UPV method. J. Mater. Civ. Eng. 26(6), 04014009 (2014)
10. S.A. Omer, R. Demirboga, W.H. Khushefati, Relationship
Declarations between compressive strength and UPV of GGBFS based
geopolymer mortars exposed to elevated temperatures. Constr.
Conflict of interest The authors declare that they have no conflict of Build. Mater. 94, 189–195 (2015)
interest. 11. E. Vasanelli, D. Colangiuli, A. Calia, M. Sileo, M.A. Aiello,
Ultrasonic pulse velocity for the evaluation of physical and
mechanical properties of a highly porous building limestone.
Ultrasonics 60, 33–40 (2015)
References 12. E. Vasanelli, A. Calia, V. Luprano, F. Micelli, Ultrasonic pulse
velocity test for non-destructive investigations of historical
1. C. Argiz, A. Moragues, E. Menéndez, Use of ground coal bottom masonries: an experimental study of the effect of frequency and
ash as cement constituent in concretes exposed to chloride applied load on the response of a limestone. Mater. Struct. 50(1),
environments. J. Clean. Prod. 170, 25–33 (2018) 38 (2017)
2. J.Y. Yoon, J.Y. Lee, J.H. Kim, Use of raw-state bottom ash for 13. D. Dizhur, R. Lumantarna, D.T. Biggs, J.M. Ingham, In-situ
aggregates in construction materials. J. Mater. Cycles Waste assessment of the physical and mechanical properties of vintage
Manage. 21(4), 838–849 (2019) solid clay bricks. Mater. Struct. 50(1), 63 (2017)
3. A. Srivastava, S.K. Singh, Utilization of alternative sand for 14. B. Ercikdi, T. Yılmaz, G. Külekci, Strength and ultrasonic
preparation of sustainable mortar: a review. J. Clean. Prod. 253, properties of cemented paste backfill. Ultrasonics 54(1), 195–204
119706 (2020) (2014)
4. H.K. Kim, J.H. Jeon, H.K. Lee, Flow, water absorption, and 15. T. Yılmaz, B. Ercikdi, K. Karaman, G. Külekçi, Assessment of
mechanical characteristics of normal-and high-strength mortar strength properties of cemented paste backfill by ultrasonic pulse
incorporating fine bottom ash aggregates. Constr. Build. Mater. velocity test. Ultrasonics 54(5), 1386–1394 (2014)
26(1), 249–256 (2012) 16. R. Demirboğa, İ Türkmen, M.B. Karakoc, Relationship between
5. E. Baite, A. Messan, K. Hannawi, F. Tsobnang, W. Prince, ultrasonic velocity and compressive strength for high-volume
Physical and transfer properties of mortar containing coal bottom mineral-admixtured concrete. Cem. Concr. Res. 34(12),
ash aggregates from Tefereyre (Niger). Constr. Build. Mater. 125, 2329–2336 (2004)
919–926 (2016)
123
J. Inst. Eng. India Ser. A
17. K. Tharmaratnam, B.S. Tan, Attenuation of ultrasonic pulse in 27. IS 2386(Part-III)-1963, Indian standard code of practice, Methods
cement mortar. Cem. Concr. Res. 20(3), 335–345 (1990) of test for aggregates for concrete, part-III specific gravity, den-
18. T. Voigt, Z. Sun, S.P. Shah, Comparison of ultrasonic wave sity, voids, absorption and bulking, Bureau of Indian standards,
reflection method and maturity method in evaluating early-age New Delhi (2002)
compressive strength of mortar. Cement Concr. Compos. 28(4), 28. Standard, ASTM C1437. Standard Test Method for Flow of
307–316 (2006) Hydraulic Cement Mortar (2007)
19. I.H. Nash’t, S.H. Arsquobour, A.A. Sadoon, Finding an unified 29. IS: 9103, Concrete Admixtures-Specifications, Bureau of Indian
relationship between crushing strength of concrete and non-de- Standards, New Delhi, India (1999)
structive tests, in Proceedings of 3rd MENDT—Middle East 30. Standard, ASTM C305. Standard Practice for Mechanical Mixing
Nondestructive Testing Conference and Exhibition, Bahrain, of Hydraulic Cement Pastes and Mortars of Plastic Consistency.
Manama, Springer, Bahrain Society of Engineering, pp. 1–7 Annual book of ASTM standards (2006)
(2005) 31. IS: 2250, Code of Practice for Preparation and Use of Masonry
20. L.M. Del Rıo, A. Jimenez, F. Lopez, F.J. Rosa, M.M. Rufo, J.M. Mortars, Bureau of Indian Standards, New Delhi, India (1981)
Paniagua, Characterization and hardening of concrete with 32. Standard, ASTM C642. Standard Test Method for Density,
ultrasonic testing. Ultrasonics 42(1–9), 527–530 (2004) Absorption, and Voids in Hardened Concrete
21. R. Gül, R. Demirboğa, T. Güvercin, Compressive strength and 33. Standard, ASTM C109-standard test method for compressive
ultrasound pulse velocity of mineral admixtured mortars. Indian strength of hydraulic cement mortars. ASTM International, West
J. Eng. Mater. Sci. 13(1), 18–24 (2006) Conshohocken, PA (2008)
22. T.U. Mohammed, A.H. Mahmood, Effects of maximum aggre- 34. L.K. Gupta, A.K. Vyas, Impact on mechanical properties of
gate size on UPV of brick aggregate concrete. Ultrasonics 69, cement sand mortar containing waste granite powder. Constr.
129–136 (2016) Build. Mater. 191, 155–164 (2018)
23. M. Shariq, J. Prasad, A. Masood, Studies in ultrasonic pulse 35. M. Singh, R. Siddique, Strength properties and micro-structural
velocity of concrete containing GGBFS. Constr. Build. Mater. 40, properties of concrete containing coal bottom ash as partial
944–950 (2013) replacement of fine aggregate. Constr. Build. Mater. 50, 246–256
24. S.K. Rao, P. Sravana, T.C. Rao, Experimental studies in ultra- (2014)
sonic pulse velocity of roller compacted concrete pavement 36. IS 13311, Method of non-destructive testing of concrete–part 1:
containing fly ash and M-sand. Int. J. Pavem. Res. Technol. 9(4), ultrasonic pulse velocity (1992)
289–301 (2016)
25. IS: 8112, Specification for Ordinary Portland Cement, Bureau of
Indian Standards, New Delhi, India (2013) Publisher’s Note Springer Nature remains neutral with regard to
26. IS: 383, Coarse and fine aggregate for concrete-Specification, jurisdictional claims in published maps and institutional affiliations.
Bureau of Indian Standards, New Delhi, India (2016)
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