(Physical Chemistry) ASSIGNMENT (Class -11th)

Chemical Equilibrium
1. In the figure shown below reactant A (represented by square) is in equilibrium with product B
represented by circle). The equilibrium constant is :

(A) 4 (B) 8 (C) 1 (D) 2

[Jee Main, 2020]
2. At 298 K, the equilibrium constant is 2 × 1015 for the reaction:
Cu(s) + 2Ag + (aq) Cu 2+ (aq) + 2Ag(s)

The equilibrium constant for the reaction

1 2+ 1
Cu (aq) + Ag(s) Cu(s) + Ag + (aq) is x × 10–8. The value of x is ________.
2 2
(Nearest Integer)
[JEE Main, July 2022]
3. For the reaction

A+B 2C

the value of equilibrium constant is 100 at 298 K. If the initial concentration of all the three
species is 1 M each, then the equilibrium concentration of C is x × 10–1 M. The value of x
is__________. (Nearest integer)
[JEE Main, July 2021]

4. At 1990 K and 1 atm pressure, there are equal number of Cl2 molecules and Cl atoms in the
reaction mixture. The value KP for the reaction Cl2 2Cl(g) under the above conditions is x
× 10–1. The value of x is (Rounded of to the nearest integer)
[JEE Main, Feb 2021]

5. PCl5 dissociates as
PCl5 (g)  PCl3 (g) + Cl2 (g)

5 moles of PCl5 are placed in a 200 litre vessel which contains 2 moles of N2 and is maintained
at 600 K. The equilibrium pressure is 2.46 atm. The equilibrium constant Kp for the
dissociation of PCl5 is_____ × 10–3. (nearest integer)

APNI KAKSHA 1
(Physical Chemistry) ASSIGNMENT (Class -11th)

(Given: R = 0.082 L atm K–1 mol–1 : Assume ideal gas behaviour) [JEE Main, June 2022]
6. When 5.1 g of solid NH4HS is introduced into a two litre evacuated flask at 27°C, 20% of the
solid decomposes into gaseous ammonia and hydrogen sulphide. The Kp for the reaction at
27°C is x × 10–2. The value of x is _______. (Integer answer)
[Given R = 0.082 L atm K–1 mol–1] [JEE Main, August 2021]

7. For the reaction, 2SO2(g) + O2(g) 2SO3(g), H = –57.2 kJ mol–1 and KC = 1.7×1016.Which of
the following statement is INCORRECT ?
(A) The equilibrium constant is large suggestive of reaction going to completion and so no
catalyst is required.
(B) The addition of inert gas at constant volume will not affect the equilibrium constant.
(C) The equilibrium constant decreases as the temperature increases.
(D) The equilibrium will shift in forward direction as the pressure increases.
[Jee Main, April 2019]
8. For the reaction

Fe2N(s) + H2(g) 2Fe(s) + NH3(g)
2
(A) Kc = Kp(RT) (B) Kc = Kp(RT)3/2 (C) Kc = Kp(RT)1/2 (D) Kc = Kp(RT)–1/2
[Jee Main, 2020]
9. The value of Kp/KC for the following reactions at 300 K are, respectively :
(At 300 K, RT = 24.62 dm3 atm mol–1) [Chemical Equilibrium]
N2(g) + O2(g) 2NO(g)
N2O4(g) 2NO2(g)
N2(g) + 3H2(g) 2NH3(g)
(A) 24.62 dm3 atm mol–1
606.0 dm6 atm2 mol–2
1.65 × 10–3 dm–6 atm–2 mol–2
(B) 1, 4.1 × 10–2 dm–3 atm–1 mol,
606.0 dm6 atm2 mol–2
(C) 1, 24.62 dm3 atm mol–1,
606.0 dm6 atm2 mol–2,
(D) 1, 24.62 dm3 atm mol–1,
1.65 × 10–3 dm–6 atm–2 mol2. [Jee Main, Jan 2019]

APNI KAKSHA 2
(Physical Chemistry) ASSIGNMENT (Class -11th)

10. Consider the following reaction:

N2O4(g) 2NO2(g) ; H° = +58K

For each of the following cases (a, b), the direction in which the equilibrium shifts is:
(a) Temperature is decreased
(b) Pressure is increased by adding N2 at constant T.
(A) (a) towards product, (b) no change
(B) (a) towards reactant, (b) no change
(C) (a) towards product, (b) towards reactant
(D) (a) towards reactant, (b) towards product
[Jee Main, 2020]
11. Two solids dissociate as follows

The total pressure when both the solids dissociate simultaneously is :-

(A) x2 + y2 (B) 2 ( )
x + y atm (C) (x + y) atm (D) x + y atm

[Jee Main, Jan 2019]

Ionic Equilibrium
1. Ka for butyric acid (C3H7COOH) is 2 × 10–5. The pH of 0.2 M solution of butyric acid is _______ ×
10-1. (Nearest integer) [Given log 2 = 0.30]
[JEE Main, July 2022]

2. 200 mL of 0.01 M HCl is mixed with 400 mL of 0.01M H2SO4. The pH of the mixture is __________.
(A) 1.14 (B) 1.78 (C) 2.34 (D) 3.02
[JEE Main, July 2022]
3. Arrange the following solutions in the decreasing order of pOH:
(a) 0.01 M HCl (b) 0.01 M NaOH
(c) 0.01 M CH3COONa (d) 0.01 M NaCl
(A) (b) > (c) > (d) > (s) (B) (a) > (c) > (d) > (b)
(C) (b) > (d) > (c) > (a) (D) (a) > (d) > (c) > (b)
[Jee Main, 2020]

APNI KAKSHA 3
(Physical Chemistry) ASSIGNMENT (Class -11th)

4. 20 mL of 0.1 M H2SO4 solution is added to 30 mL of 0.2 M NH4OH solution. The pH of the

resultant mixture is : [pkb of NH4OH = 4.7]. [Ionic Equilibrium]
(A) 9.4 (B) 5.0 (C) 9.0 (D) 5.2
[Jee Main, Jan 2019]
5. Class XII students were asked to prepare one litre of buffer solution of pH 8.26 by their
chemistry teacher. The amount of ammonium chloride to be dissolved by the student 1n 0.2 M
ammonia solution to make one litre of the buffer is
(Given pKb (NH3)=4.74; Molar mass of NH3=17g mol–1; Molar mass of NH4Cl= 53.5g mol–1)
(A) 53.5 g (B) 72.3 g (C) 107.0 g (D) 126.0 g
[JEE Main, July 2022]
6. Consider the following statements
(a) The pH of a mixture containing 400 mL of 0.1 M H2S04 and 400 mL of 0.1 M NaOH will be
approximately 1.3.
(b) Ionic product of water is temperature dependent.
(c) A monobasic acid with Ka = 10–5 has a pH = 5. The degree of dissociation of this acid is 50%.
(d) The Le Chatelier's principle is not applicable to common-ion effect.
The correct statements are :
(A) (a), (b)and(c) (B) (a) and (b) (C) (b) and (c) (D) (a), (b) and (d)
[Jee Main, April 2019]
7. An acidic buffer is obtained on mixing :
(A) 100 mL of 0.1 M HCl and 200 mL of 0.1 M NaCl
(B) 100 mL of 0.1 M HCl and 200 mL of 0.1 M CH3COONa
(C) 100 mL of 0.1 M CH3COOH and 100 mL of 0.1 M NaOH
(D) 100 mL of 0.1 M CH3COOH and 200 mL of 0.1 M NaOH
[Jee Main, 2020]
8. Given below are two statements.
Statement I: In the titration between strong acid and weak base methyl orange is suitable as
an indicator.
Statement II: For titration of acetic acid with NaOH phenolphthalein is not a suitable indicator.
In the light of the above statements, choose the most appropriate answer from the options
given below:
(A) Statement I is false but Statement II is true
(B) Statement I is true but Statement II is false
(C) Both Statement I and Statement II are true

APNI KAKSHA 4
(Physical Chemistry) ASSIGNMENT (Class -11th)

(D) Both Statement I and Statement II are false [JEE Main, August 2021]
9. In base vs. Acid titration, at the end point methyl orange is present as
(A) quinonoid form (B) heterocyclic form (C) phenolic from (D) benzenoid form
[JEE Main, July 2022]
10. If Ksp of Ag2CO3 is 8 × 10–12, the molar solubility of Ag2CO3 in 0.1M AgNO3 is :
[Ionic Equilibrium]
(A) 8×10–10 M (B) 8 ×10–13 M (C) 8×10–12 M (D) 8×10–11 M
[Jee Main, Jan 2019]
11. The solubility of Ca(OH)2 in water is:
[Given : The solubility product of Ca(OH)2 in water = 5.5 × 10–6]
(A) 1.77 × 10–6
(B) 1.11 × 10–6
(C) 1.11 × 10–2
(D) 1.77 × 10–2 [JEE Main, Feb 2021]
12. The solubility of AgCl will be maximum in which of the following?
(A) 0.01 M KCl (B) 0.01 M HC1
(C) 0.01 M AgNO3 (D) De-ionised water
[JEE Main, June 2022]

13. When 35 mL of 0.15 M lead nitrate solution is mixed with 20 mL of 0.12 M chromic sulphate
solution, ________ × 10–5 moles of lead sulphate precipitate out. (Round off to the Nearest
Integer) [JEE Main, March 2021]

14. The solubility of AgCN in a buffer solution of pH=3 is x. The value of x is: (Assume : No cyano
complex is formed; Ksp (AgCN) =2.2×10–16 and Ka(HCN) = 6.2×10–10]
(A) 0.625 × 10–6
(B) 1.9 × 10–5
(C) 2.2 × 10–16
(D) 1.6 × 10–6 [JEE Main, Feb 2021]
15. The number of moles of NH3, that must be added to 2 L of 0.80 M AgNO3 in order to reduce the
concentration of Ag+ ions to 5.0×10–8 M (Kformation for [Ag(NH3)2]+ =1.0× 108) is ________ .
(Nearest integer)
[Assume no volume change on adding NH3]
[JEE Main, August 2021]

APNI KAKSHA 5
(Physical Chemistry) ASSIGNMENT (Class -11th)

Redox Reaction
1. Which of the following oxoacids of sulphur contains “S” in two different oxidation states?
(A) H2S2O3 (B) H2S2O6 (C) H2S2O7 (D) H2S2O8
[JEE Main, June 2022]
2. Which one of the following is an example of disproportionation reaction?
(A) 3MnO24− + 4H+ ⎯→ 2MnO−4 + MnO2 + 2H2O

(B) MnO24− + 4H+ + 4e– ⎯→ MnO2 + 2H2O

(C) 10I– + 2MnO−4 + 16H+ ⎯→ 2Mn +2 + 8H2O + 5I2

(D) 8MnO−4 + 3S2O32− + H2O ⎯→ 8MnO2 + 6SO24− + 2OH–

[JEE Main, June 2022]

3. 2MnO4— + bC2O42— + cH+⎯→ xMn2+ + yCO2 + zH2O
If the above equation is balanced with integer coefficients, the value of c is _______.
(Round off to the Nearest Integer).
[JEE Main, March 2021]
4. The neutralization occurs when 10 mL of 0.1 M acid ‘A’ is allowed to react with 30 mL of 0.05 M
base M(OH)2. The basicity of the acid 'A' is______. [M is a metal]
[JEE Main, June 2022]
5. In the reaction of oxalate with permanganate in acidic medium, the number of electrons
involved in producing one molecule of CO2 is : [Equivalent Concept]
(A) 10 (B) 6 (C) 1 (D) 2
[Jee Main, Jan 2019]
6. A 20.0 mL solution containing 0.2 g impure H2O2 reacts completely with 0.316 g of KMnO4 in
acid solution. the purity of H2O2 (in%) is _______
(mol. wt. of H2O2 = 34; mol. wt. of KMnO4 = 158)
[Jee Main, 2020]
7. 15 mL of aqueous solution of Fe2+ in acidic medium completely reacted with 20 mL of 0.03 M
aqueous Cr2O72–. The molarity of the Fe2+ solution is _______ × 10–2 M.
(Round off to the Nearest Integer) [JEE Main, March 2021]
8. In order to oxidise a mixture of one mole of each of FeC2O4, Fe2(C2O4)3 and Fe2(SO4)3 in acidic
medium, the number of moles of KMnO4 required is : (Equivalent Concept)
(A) 1 (B) 3 (C) 2 (D) 1.5
[Jee Main, April 2019]

APNI KAKSHA 6
(Physical Chemistry) ASSIGNMENT (Class -11th)

9. A 2.0 g sample containing MnO2 is treated with HCl liberating Cl2. The Cl2 gas is passed into a
solution of KI and 60.0 mL of 0.1 M Na2S2O3 is required to titrate the liberated iodine. The
percentage of MnO2 in the sample is __________. (Nearest integer)
[Atomic masses (in u) Mn = 55; Cl = 35.5; O = 16, I = 127, Na = 23, K = 39, S = 32]
[JEE Main, June 2022]
10. 20 mL of 0.02 M hypo solution is used for the titration of 10 mL of copper sulphate solution, in
the presence of excess of KI using starch as an indicator. The molarity of Cu2+ is found to be
________ × 10–2 M [nearest integer]
Given: 2Cu2+ + 41– → Cu2I2 + I2
2− 2−
I2 + 2S2O3 → 2I– + S4O6

[JEE Main, July 2022]

Atomic Structure
1. If the Thompson model of the atom was correct, then the result of Rutherford's gold foil
experiment would have been :
(A) All of the -particles pass through the gold foil without decrease in speed.
(B) -Particles are deflected over a wide range of angles.
(C) All -particles get bounced back by 180°
(D) -Particles pass through the gold foil deflected by small angles and with reduced speed.
[JEE Main, July 2021]
2. The figure that is not a direct manifestation of the quantum nature of atoms is :

Intensity of T2 > T1 Internal

black body T1 energy of
300400 500 600
radiation Ar
Wavelength Temperature (K)
(A) (B)

Rb K
Kinetic Na

Increasing wavelength energy of

photoelectrons
Frequency of incident
Absorption spectrum radiation
(C) (D)
[Jee Main, 2020]

APNI KAKSHA 7
(Physical Chemistry) ASSIGNMENT (Class -11th)

3. A 50 watt bulb emits monochromatic red light of wavelength of 795 nm. The number of
photons emitted per second by the bulb is x × 1020. The value of x is _________.
[Given : h = 6.63 × 10–34 Js and c = 3.0 × 108 ms–1]
[JEE Main, August 2021]
4. According to Bohr's atomic theory :-
Z2
(a) Kinetic energy of electron is 
n2
(b) The product of velocity (v) of electron and principal quantum number (n), 'vn'  Z2
Z3
(c) Frequency of revolution of electron in an orbit is 
n3
Z3
(d) Coulombic force of attraction on the electron is 
n4
Choose the most appropriate answer from the options given below :
(A) (c) Only
(B) (a) Only
(C) (a), (c) and (d) only
(D) (a) and (d) only
[JEE Main, Feb 2021]

5. The radius of the second Bohr orbit, in terms of the Bohr radius, a0, in Li2+ is :
2a 0 4a 0 2a 0 4a 0
(A) (B) (C) (D)
3 3 9 9
[Jee Main, 2020]
1 1
6. For the Balmer series in the spectrum of H atom,  = R H  2 − 2  , the correct statements
 n1 n 2 
among (I) to (IV) are :
(I) As wavelength decreases, the lines in the series converge
(II) The integer n1 is equal to 2
(III) The lines of longest wavelength corresponds to n2 = 3
(IV) The ionization energy of hydrogen can be calculated from wave number of these lines
(A) (I), (III), (IV) (B) (I), (II), (III) (C) (II), (III), (IV) (D) (I), (II), (IV)
[Jee Main, 2020]

APNI KAKSHA 8
(Physical Chemistry) ASSIGNMENT (Class -11th)

7. The ratio of the shortest wavelength of two special series of hydrogen spectrum is found to be
about 9. The spectral series are : (Atomic Structure)
(A) Paschen and Pfund (B) Balmer and Brackett
(C) Lyman and Paschen (D) Brackett and Pfund
[Jee Main, April 2019]
8. The work function of sodium metal is 4.41 × 10–19 J. If photons of wavelength 300 nm are
incident on the metal, the kinetic energy of the ejected electrons will be (h = 6.63 × 10–34 J s; c =
3 × 108 m/s) _________ × 10–21 J. [Jee Main, 2020]
9. The wavelength of an electron and a neutron will become equal when the velocity of the
electron is x times the velocity of neutron. The value of x is ____. (Nearest Integer)
(Mass of electron is 9.1 × 10–31 kg and mass of neutron is 1. 6 × 10–27 kg)
[JEE Main, July 2022]
10. The minimum uncertainty in the speed of an electron in an one dimensional region of length
2a0 (Where a0 = Bohr radius 52.9 pm) is____________ km s–1.
(Given: Mass of electron = 9.1 × 10–31 kg, Planck's constant h = 6.63 × 10–34 Js)
[JEE Main, July 2022]
11. Identify the incorrect statement from the following.
(A) A circular path around the nucleus in which an electron moves is proposed as Bohr's orbit.
(B) An orbital is the one electron wave function () in an atom.
(C) The existence of Bohr's orbits is supported by hydrogen spectrum.
(D) Atomic orbital is characterized by the quantum numbers n and l only
[JEE Main, July 2022]
12. The correct statement about probability density (except at infinite distance from nucleus) is :
(A) It can negative for 2p orbital (B) It can be zero for 1s orbital
(C) It can never be zero for 2s orbital (D) It can be zero for 3p orbital
[Jee Main, 2020]
13. Which of the following is the correct plot for the probability density (r) as a function of
distance 'r' of the electron form the nucleus for 2s orbital?

(A) (B)

APNI KAKSHA 9
(Physical Chemistry) ASSIGNMENT (Class -11th)

(C) (D)

[JEE Main, June 2022]

14. Consider the following statements:
(a) The principal quantum number ‘n’ is a positive integer with values of ‘n’ = 1, 2, 3,….
(b) The azimuthal quantum number ‘l’ for a given ‘n’ (principal quantum number) can have
values as ‘l’ = 0, 1, 2, …. n
(c) Magnetic orbital quantum number ‘ml’ for a particular ‘l’ (azimuthal quantum number) has
(2l + 1) values.
(d) ±1/2 are the two possible orientations of electron spin.
(e) For l = 5, there will be a total of 9 orbital.
Which of the above statements are correct?
(A) (a), (b) and (c)
(B) (a), (c), (d) and (e)
(C) (a), (c) and (d)
(D) (a), (b), (c) and (d) [JEE Main, June 2022]
15. The Azimuthal quantum number for the valence electrons of Ga+ ion is_________. (Atomic
number of Ga = 31) [JEE Main, July 2021]
16. Consider the following pairs of electrons
1
(A) (a) n = 3, 1 = 1, m1 = 1, ms = +
2
1
(b) n = 3, 1 = 2, m1 = 1, ms = +
2
1
(B) (a) n = 3, 1 = 2, m1 = – 2, ms = –
2
1
(b) n = 3, 1 = 2, m1 = –1, ms = –
2
1
(C) (a) n = 4, 1 = 2, m1 = 2, ms = +
2
1
(b) n = 3, 1 = 2, m1 = 2, ms = +
2
The pairs of electron present in degenerate orbitals is/are:
(A) Only A (B) Only B (C) Only C (D) (B) and (C)
[JEE Main, June 2022]
APNI KAKSHA 10
(Physical Chemistry) ASSIGNMENT (Class -11th)

17. What is the spin-only magnetic moment value (BM) of a divalent metal ion with atomic number 25,
in it's aqueous solution?
(A) 5.92 (B) 5.0 (C) zero (D) 5.26
[JEE Main, March 2021]
Gaseous
1. 0.5 moles of gas A and x moles of gas B exert a pressure of 200 Pa in a container of volume 10
m3 at 1000 K. given R is the gas constant in JK–1 mol–1, x is :
2R 2R 4−R 4+R
(A) (B) (C) (D)
4 + 12 4 − 12 2R 2R
[JEE Main, Jan 2019]
2. A spherical balloon of radius 3 cm containing helium gas has a pressure of 48 × 10–3 bar. At the
same temperature, the pressure, of a spherical balloon of radius 12 cm containing the same
amount of gas will be ………….. ×10–6 bar. [JEE Main, 2020]

3. Geraniol, a volatile organic compound, is a component of rose oil. The density of the vapour is
0.46 gL–1 at 257°C and 100 mm Hg. The molar mass of geraniol is ___________ (Nearest Integer)
[Given R = 0.082 L atm K–1 mol–1]
[JEE Main, June 2022]
4. Which one of the following graphs is not correct for ideal gas ?

d d d d

T T 1/T P
I II III IV

d = Density, P = Pressure, T = Temperature

(A) IV (B) II (C) III (D) I
[JEE Main, 2020]
5. Which amongst the given plots is the correct plot for pressure (p) vs density (d) for an ideal
gas?

(A) (B)

APNI KAKSHA 11
(Physical Chemistry) ASSIGNMENT (Class -11th)

(C) (D)

[JEE Main, June 2022]

6. 'x' g of molecular oxygen (O2) is mixed with 200 g of neon (Ne). The total pressure of the
nonreactive mixture of O2 and Ne in the cylinder is 25 bar. The partial pressure of Ne is 20 bar
at the same temperature and volume. The value of 'x' is
[Given: Molar mass of O2 = 32 g mol–1. Molar mass of Ne = 20 g mol–1]
[JEE Main, July 2022]
7. Points I,II and III in the following plot respectively correspond to (Vmp :most probable velocity)
(Ideal Gas)

(A) Vmp of O2 (400 K) ; Vmp of N2 (300 K); Vmp of H2 (300 K)

(B) Vmp of N2 (300 K) ; Vmp of H2 (300 K); Vmp of O2 (400 K)
(C) Vmp of H2 (300 K) ; Vmp of N2 (400 K); Vmp of O2 (300 K)
(D) Vmp of N2 (300 K) ; Vmp of O2 (400 K); Vmp of H2 (300 K) [JEE Main, April 2019]
8. For a real gas at 25°C temperature and high pressure (99 bar) the value of compressibility
factor is 2, so the value of Vander Waal' s constant 'b' should be × 10–2 L mol–1 (Nearest integer)
(Given R = 0.083 L bar K–1 mol–1)
[JEE Main, July 2022]
9. At a given temperature T, gases Ne, Ar, Xe and Kr are found to deviate from ideal gas behaviour.
Their equation of state is given as

APNI KAKSHA 12
(Physical Chemistry) ASSIGNMENT (Class -11th)

RT
P= at T.
V–b
Here, b is the Vander Waals constant. Which gas will exhibit steepest increase in the plot of Z
(compression factor) vs p? (Real Gas)
(A) Kr (B) Ar (C) Xe (D) Ne
[JEE Main, April 2019]
10. Consider the following table : (Real Gas)
Gas a/(k Pa dm6 mol–1) b/(dm3 mol–1)
A 642.32 0.05196
B 155.21 0.04136
C 431.91 0.05196
D 155.21 0.4382
a and b are van der Waals constants. The correct statement about the gases is :
(A) Gas C will occupy lesser volume than gas A; gas B will be more compressible than gas D
(B) Gas C will occupy more volume than gas A; gas B will be more compressible than gas D
(C) Gas C will occupy lesser volume than gas A; gas B will be lesser compressible than gas D
(D) Gas C will occupy more volume than gas A; gas B will be lesser compressible than gas D
[JEE Main, April 2019]
Mole Concept
1. A protein ‘A’ contains 0.30% of glycine (molecular weight 75). The minimum molar mass of the
protein ‘A’ is________ × 103 g mol–1 [nearest integer]
[JEE Main, June 2022]
2. 5 moles of AB2 weigh 125 × 10–3 kg and 10 moles of A2B2 weigh 300 × 10–3 kg. The molar mass
of A (MA) and molar mass of B (MB) in kg mol–1 are:
(A) MA = 5 × 10–3 and MB = 10 × 10–3 (B) MA = 50 × 10–3 and MB = 25 × 10–3
(C) MA = 25 × 10–3 and MB = 50 × 10–3 (D) MA = 10 × 10–3 and MB = 5 × 10–3
[Jee Main, April 2019]
3. 1 mol of an octahedral metal complex with formula MCl3 · 2L on reaction with excess of AgNO3
gives 1 mol of AgCl. The denticity of Ligand L is ________ . (Integer answer)
[JEE Main, August 2021]

4. NaClO3 is used, even in space crafts, to produce O2. The daily consumption of pure O2 by a
person is 492 L at 1 atm, 300 K. How much amount of NaClO3, in grams is required to produce
O2 for the daily consumption of a person at 1 atm, 300 K ? _________.

APNI KAKSHA 13
(Physical Chemistry) ASSIGNMENT (Class -11th)

NaClO3(s) + Fe(s) → O2(g) + NaCl(s) + FeO(s)

R = 0.082 L atm mol–1 K–1
[Jee Main, 2020]
5. For a reaction,
N2(g) + 3H2(g) ⎯→ 2NH3(g); identify dihydrogen (H2) as a limiting reagent in the following
reaction mixtures. (Mole Concept)
(A) 28 g of N2 + 6 g of H2 (B) 56 g of N2 + 10 g of H2
(C) 14 g of N2 + 4 g of H2 (D) 35 g of N2 + 8 g of H2
[Jee Main, April 2019]
6. CNG is an important transportation fuel. When 100 g CNG is mixed with 208 oxygen in vehicles,
it leads to the formation of CO2 and H2O and produces large quantity of heat during this
combustion, then the amount of carbon dioxide, produced in grams is________. [nearest integer]
[Assume CNG to be methane] [JEE Main, June 2022]

7.

Consider the above reaction where 6.1 g of benzoic acid is used to get 7.8 g of m-bromo
benzoic acid. The percentage yield of the product is_____.
(Round off to the Nearest integer)
[Given : Atomic masses : C = 12.0u, H : 1.0u, O : 16.0u, Br = 80.0 u]
[JEE Main, March 2021]

8. 116 g of a substance upon dissociation reaction, yields 7.5 g of hydrogen, 60g of oxygen and
48.5 g of carbon. Given that the atomic masses of H, O and C are 1, 16 and 12 respectively. The
data agrees with how many formulae of the following?
(A) CH3COOH (B) HCHO (C) CH3OOCH3 (D) CH3CHO
[JEE Main, June 2022]

APNI KAKSHA 14
(Physical Chemistry) ASSIGNMENT (Class -11th)

9. On complete combustion 0.30 g of an organic compound gave 0.20 g of carbon dioxide and 0.10
g of water. The percentage of carbon in the given organic compound is ________ (Nearest
integer).
[JEE Main, June 2022]
10. At 300 K and 1 atmospheric pressure, 10 mL of a hydrocarbon required 55 mL of O2 for
complete combustion, and 40 mL of CO2 is formed. The formula of the hydrocarbon is:
(A) C4H7Cl (B) C4H10 (C) C4H8 (D) C4H6
[Jee Main, April 2019]
11. 100 mL of Na3PO4 solution contains 3.45 g of sodium. The molarity of the solution is _____×10–2
mol L–1. (Nearest integer)
[Atomic Masses - Na : 23.0 u, O : 16.0 u, P : 31.0 u]
[JEE Main, August 2021]
12. 8g of NaOH is dissolved in 18g of H2O. Mole fraction of NaOH in solution and molality (in mol
kg–1) of the solutions respectively are : [Concentration Terms]
(A) 0.2, 22.20 (B) 0.167,22.20 (C) 0.167, 11.11 (D) 0.2, 11.11
[Jee Main, Jan 2019]
13. Chlorophyll extracted from the crushed green leaves was dissolved in water to make 2 L
solution of Mg of concentration 48 ppm. The number of atoms of Mg in this solution is x × 1020
atoms. The value of x is ___ . (Nearest Integer)
(Given: Atomic mass of Mg is 24 g mol–1, NA= 6.02 × 1023 mol–1)
[JEE Main, July 2022]
14. The mole fraction of a solute in a 100 molal aqueous solution _______ × 10–2.
(Round off to the Nearest Integer).
[Given : Atomic masses : H : 1.0 u, O : 16.0 u]
[JEE Main, March 2021]
15. A solution of two components containing n1 moles of the 1st component and n2 moles of the 2nd
component is prepared. M1 and M2 are the molecular weights of component 1 and 2
respectively. If d is the density of the solution in g mL–1, C2 is the molarity and x2 is the mole
fraction of the 2nd component, then C2 can be expressed as :
dx1 000x 2
(A) C2 = (B) C2 =
M2 + x 2 (M2 − M1 ) M1 + x 2 (M2 − M1 )
1000dx 2 dx 2
(C) C2 = (D) C2 =
M1 + x 2 (M2 − M1 ) M2 + x 2 (M2 − M1 )
[Jee Main, 2020]

APNI KAKSHA 15
(Physical Chemistry) ASSIGNMENT (Class -11th)

16. The molarity of HNO3 in a sample which has density 1.4g/mL and mass percentage of 63% is
______. (Molecular weight of HNO3 = 63)
[Jee Main, 2020]
17. The volume strength of 1M H2O2 is: [Concentration Terms]
(Molar mass of H2O2 = 34 g mol–1)
(A) 16.8 (B) 11.35 (C) 22.4 (D) 5.6
[Jee Main, Jan 2019]
18. The number of moles of CuO, that will be utilized in Dumas method for estimation nitrogen in a
sample of 57.5g of N, N-dimethylaminopentane is ________ × 10–2. (Nearest integer)
[JEE Main, August 2021]
19. In Duma's method of estimation of nitrogen, 0.1840 g of an organic compound gave 30 mL of
nitrogen collected at 287 K and 758 mm of Hg pressure. The percentage composition of
nitrogen in the compound is ______. (Round off to the Nearest Integer).
[Given : Aqueous tension at 287 K = 14 mm of Hg]
[JEE Main, March 2021]
20. In an estimation of bromine by Carius method, 1.6 g of an organic compound gave 1.88 g of
AgBr. The mass percentage of bromine in the compound is …………
(Atomic mass, Ag= 108, Br = 80 g mol–1) [Jee Main, 2020]

21. In Carius method, halogen containing organic compound is heated with fuming nitric acid in
the presence of: [JEE Main, July 2021]
(A) HNO3 (B) AgNO3 (C) CuSO4 (D) BaSO4
22. In the sulphur estimation, 0.471 g of an organic compound gave 1.44 g of barium sulphate. The
percentage of sulphur in the compound is _____%. (Nearest integer)
(Atomic Mass of Ba = 137 u) [JEE Main, August 2021]
23. 0.8 g of an organic compound was analysed by Kjeldahl's method for the estimation of nitrogen.
If the percentage of nitrogen in the compound was found to be 42%, then_________ mL of 1 M
H2SO4 would have been neutralized by the ammonia evolved during the analysis.
[JEE Main, July 2021]
24. A 0.166 g sample of an organic compound was digested with cone. H2SO4 and then distilled
with NaOH. The ammonia gas evolved was passed through 50.0 mL of 0.5 N H2SO4. The used
acid required 30.0 mL of 0.25 N NaOH for complete neutralization. The mass percentage of
nitrogen in the organic compound is____.
[JEE Main, June 2022]

APNI KAKSHA 16
(Physical Chemistry) ASSIGNMENT (Class -11th)

ANSWER KEY
Chemical Equilibrium
1. (D) 2. (2) 3. (25) 4. (5) 5. (1107)6. (6) 7. (A)
8. (C) 9. (D) 10. (B) 11. (B)
Ionic Equilibrium
1. (27) 2. (B) 3. (D) 4. (C) 5. (C) 6. (A) 7 (B)
8. (B) 9. (A) 10. (A) 11. (C) 12. (D) 13. (525) 14. (B)
15. (4)
Redox Reaction
1. (A) 2. (A) 3. (16) 4. (3) 5. (C) 6. (85) 7. (24)
8. (C) 9. (13) 10. (4)
Atomic Structure
1 (D) 2. (B) 3. (2) 4. (C) 5. (B) 6. (B) 7. (C)
8. (222) 9. (1758)10. (548) 11. (D) 12. (D) 13. (B) 14. (C)
15. (0) 16. (B) 17. (A)
Gaseous State
1. (C) 2. (750) 3. (152) 4. (B) 5. (B) 6. (80) 7. (D)
8. (25) 9. (C) 10. (B)
Mole Concept
1. (25) 2. (A) 3. (2) 4. (2120 to 2140) 5. (B) 6. (143)
7. (78) 8. (B) 9. (18) 10. (D) 11. (50) 12. (C) 13. (24)
14. (64) 15. (C) 16. (14) 17. (B) 18. (1125)19. (19) 20. (50)
21. (B) 22. (42) 23. (12) 24. (63)

APNI KAKSHA 17
(Physical Chemistry)

CHEMICAL KINETICS

1. NO2 required for a reaction is produced by the decomposition of N2O5 in CCl4 as per the
equation, 2 N2O5(g) → 4 NO2(g) + O2(g)

The initial concentration of N2O5 is 3.00 mol L–1 and it is 2.75 mol L–1 after 30 minutes. The rate
of formation of NO2 is:

(A) 1.667 × 10–2 mol L–1 min–1 (B) 2.083 × 10–3 mol L–1 min–1

(C) 4.167 × 10–3 mol L–1 min–1 (D) 8.333 × 10–3 mol L–1 min–1

[Jee Main, April 2019]

2. For a given chemical reaction

1A + 2B → 3C + 4D

Concentration of C changes from 10 mmol dm–3 to 20 mmol dm–3 in 10 seconds. Rate of

appearance of D is 1.5 times the rate of disappearance of B which is twice the rate of
disappearance A. The rate of appearance of D has been experimentally determined to be 9
mmol dm–3 s–1. Therefore, the rate of reaction is ______________mmol dm–3 s–1. (Nearest Integer)

[JEE Main, June 2022]

3. For a first order reaction, the time required for completion of 90% reaction is 'x' times the half
life of the reaction. The value of 'x' is

(Given: ln 10 = 2.303 and log 2 = 0.3010)

(A) 1.12 (B) 2.43 (C) 3.32 (D) 33.31

[JEE Main, June 2022]

4. At 30°C, the half life for the decomposition of AB2 is 200 s and is independent of the initial
concentration of AB2. The time required for 80% of the AB2 to decompose is

(Given: log 2 = 0.30; log 3 = 0.48)

(A) 200 s (B) 323 s (C) 467 s (D) 532 s

[JEE Main, July 2022]

5. Sucrose hydrolyses in acid solution into glucose and fructose following first order rate law with
a half-life of 3.33 h at 25°C. After 9 h, the fraction of sucrose remaining is f. The value of log10=
1
  is ______ × 10–2. (Rounded off to the nearest integer)
f 

APNI KAKSHA 1
(Physical Chemistry)

[Assume : ln 10 = 2.303, ln 2 = 0.693]

[JEE Main, Feb 2021]
6. For the first order reaction A → 2B, 1 mole of reactant A gives 0.2 moles of B after 100 minutes.
The half life of the reaction is ...... min. (Round off to the nearest integer).

[Use : ln 2 = 0.69, ln 10 = 2.3

x
Properties of logarithms : ln xy = y ln x; ln   = ln x − ln y ]
y

(Round off to the nearest integer)

[JEE Main, July 2021]

7. For the reaction 2A + B → C, the values of initial rate at different reactant concentrations are
given in the table below. The rate law for the reaction is : (Chemical
Kinetics)

[A] (mol L–1) [B] (mol–1) Initial Rate (mol L–1s–1)

0.05 0.05 0.045
0.10 0.05 0.090
0.20 0.10 0.72

(A) Rate = k[A][B] (B) Rate = k[A]2[B]2 (C) Rate = k[A]2[B] (D) Rate = k[A][B]2

[Jee Main, April 2019]

8. For the following graph:

Concentration

t1/2
(a) Rate (b) (c)

Initial
Time Time
concentration

APNI KAKSHA 2
(Physical Chemistry)

Concentration
Rate
(d) (e)

Concentration
Time

Choose from the options given below, the correct one regarding order of reaction is :
(A) (b) zero order (c) and (e) First order
(B) (a) and (b) Zero order (e) First order
(C) (b) and (d) zero order (e) first order
(D) (a) and (b) Zero order (c) and (e) First order
[JEE Main, July 2021]

9. For a reaction A → 2B + C the half lives are 100 s and 50 s when the concentration of reactant A
is 0.5 and 1.0 mol L–1 respectively. The order of the reaction is__________. (Nearest Integer)

[JEE Main, July 2022]

10. Consider the given plots for a reaction obeying Arrhenius equation (0ºC < T < 300ºC) : (k and
Ea are rate constant and activation energy, respectively) [Chemical Kinetics]

Choose the correct option :

(A) I is right but II is wrong (B) Both I and II are wrong
(C) I is wrong but II is right (D) Both I and II are correct
[Jee Main, Jan 2019]

11. The rate constant (k) of a reaction is measured at different temperature (T), and the data are
plotted in the given figure. The activation energy of the reaction in kJ mol–1 is : (R is constant)

APNI KAKSHA 3
(Physical Chemistry)

10

ln k
5

0 1 2 3 4 5
103
T
(A) 2R (B) 1/R (C) 2/R (D) R
[Jee Main, 2020]

1
12. Consider the following plots of rate constant versus for four different reactions. Which of the
T
following orders is corrects for the activation energies of these reactions?

log k a
d c

b
1/T

(A) Ea > Ec > Ed > Eb (B) Eb > Ea > Ed > Ec

(C) Ec > Ea > Ed > Eb (D) Eb > Ed > Ec > Ea

[Jee Main, 2020]

13. Catalyst A reduces the activation energy for a reaction by 10 kJ mol–1 at 300 K. The ratio of rate
k
T, Catalysed
constants, k
is ex. The value of x is _______. [nearest integer]
T, Uncatalysed

[Assume theat the pre-exponential factor is same in both the cases.

Given R = 8.31 J K–1 mol–1]

[JEE Main, June 2022]

14. If the activation energy of a reaction is 80.9 kJ mol–1, the fraction of molecules at 700 K, having
enough energy to react to form products is e–x. The value of x is _______.
(Rounded off to the nearest integer) [Use R = 8.31 J K–1 mol–1]

APNI KAKSHA 4
(Physical Chemistry)

[JEE Main, Feb 2021]

15. The reaction rate for the reaction
[PtCl4]2– + H2O [Pt(H2O)Cl3]– + Cl–

was measured as a function of concentrations of different species. It was observed that

−d [PtCl4 ]2− 
= 4.8 10−5 [PtCl4 ]2−  − 2.4 10−3 [Pt(H 2O)Cl3 ]−  [Cl – ]
dt
where square brackets are used to denote molar concentrations. The equilibrium constant
Kc =_____. (Nearest integer)
[JEE Main, August 2021]

ANSWER KEY

CHEMICAL KINETICS

1. (A) 2. (1) 3. (C) 4. (C) 5. (81) 6. (300) 7. (D)

8. (D) 9. 02.00 10. (D) 11. (A) 12. (C) 13. (4) 14. (14)

15. (50)

APNI KAKSHA 5
(Physical Chemistry)

Thermodynamics

1. Among the following the number of state variable is _________. [JEE Main, July 2022]

Internal energy (U)

Volume (V)

Heat (q)

Enthalpy (H)

2. 5 moles of an ideal gas at 100 K are allowed to undergo reversible compression till its
temperature becomes 200 K. If Cv,m = 28 J K–1 mol–1, calculate U and PV for this process.
(R = 8.0 J K–1 mol–1) [Jee Main, April 2019]

(A) U = 14 J; (PV) = 0.8 J (B) U = 2.8 kJ; (PV) = 0.8 kJ

(C) U = 14 kJ; (PV) = 18 kJ (D) U = 14 kJ; (PV) = 4 kJ

3. For one mole of an ideal gas, which of these statements must be true?

(a) U and H each depends only on temperature

(b) Compressibility factor z is not equal to 1

(c) CP, m – CV, m = R

(d) dU = CVdT for any process

(A) (a) and (c) (B) (b), (c) and (d) (C) (a), (c) and (d) (D) (c) and (d)

[Jee Main, 2020]

4. For water vap H = 41 kJ mol–1 at 373 K and 1 bar pressure. Assuming that water vapour is an
ideal gas that occupies a much larger volume than liquid water, the internal energy change
during evaporation of water is_____kJ mol–1 [Use : R = 8.3 J mol–1 K–1]
[JEE Main, August 2021]

5. For combustion of one mole of magnesium in an open container at 300 K and 1 bar pressure,
CHΘ = –601.70 kJ mol–1, the magnitude of change in internal energy for the reaction is _____ kJ.
(Nearest integer)

(Given : R = 8.3 J K–1 mol–1) [JEE Main, June 2022]

APNI KAKSHA 6
(Physical Chemistry)

6. 2.2 g of nitrous oxide (N2O) gas is cooled at a constant pressure of 1 atm from 310 K to 270 K
causing the compression of the gas from 217.1 mL to 167.75 mL. The change in internal energy
of the process, U is '–x' J. The value of 'x' is ______. [Nearest integer]

(Given: atomic mass of N = 14 g mol–1 and of O = 16 g mol–1.

Molar heat capacity of N2O is 100 JK–1 mol–1)

[JEE Main, June 2022]

7. The combination of plots which does not represent isothermal expansion of an ideal gas is:
[Thermodynamics]

(A) (B)

(C) (D)

(A) (B) and (D) (B) (A) and (D) (C) (A) and (C) (D) (B) and (C)
[Jee Main, Jan 2019]
8. An ideal gas undergoes isothermal compression from 5 m3 to 1 m3 against a constant external
pressure of 4 Nm–2. Heat released in this process is used to increase the temperature of 1 mole
of Al. If molar heat capacity of Al is 24 J mol–1 K–1, the temperature of Al increases by :
[Thermodynamics]
3 2
(A) K (B) 2 K (C) 1 K (D) K
2 3
[Jee Main, Jan 2019]

9. Match List-I with List-II

List-I List-II
(A) Spontaneous process (I) H < 0

APNI KAKSHA 7
(Physical Chemistry)

(B) Process with P = 0, T = 0 (II) GT.P. < 0

(C) Hreaction (III) Isothermal and isobaric process
(D) Exothermic process (IV) [Bond energies of molecules in
reactants] - [Bond energies of product
molecules
Choose the correct answer from the options given below:

(A) (A) – (III), (B) – (II), (C) – (IV), (D) – (I)

(B) (A) – (II), (B) – (III), (C) – (IV), (D) – (I)

(C) (A) – (II), (B) – (III), (C) – (I), (D) – (IV)

(D) (A) – (II), (B) – (I), (C) – (III), (D) – (IV) [JEE Main, June 2022]

10. Which of the following relation is not correct?

(A) H = U – PV (B) U = q + W

(C) Ssys + Ssurr  0 (D) G = H – TS

[JEE Main, July 2022]

11. For the reaction;

A(l) → 2B(g)

U = 2.1 kcal, S = 20 cal K–1 at 300 K.

Hence G in kcal is___________ :

[Jee Main, 2020]

12. A process has H = 200 Jmol–1 and S = 40 JK–1mol–1. Out of the values given below, choose the
minimum temperature above which the process will be spontaneous : [Thermodynamics]
(A) 12K (B) 20K (C) 4K (D) 5K
[Jee Main, Jan 2019]
13. Data given for the following reaction is as follows:
FeO(s) + C(graphite) ⎯→ Fe(s) + CO(g)

APNI KAKSHA 8
(Physical Chemistry)

The minimum temperature in K at which the reaction becomes spontaneous is ________ .(Integer
answer) [JEE Main, July 2021]

14. For the chemical reaction X Y , the standard reaction Gibbs energy depends on
temperature T (in K) as : [Thermodynamics]
3
rG° (in kJ mol–1) = 120 – T
8
The major component of the reaction mixture at T is :
(A) Y if T = 280 K (B) X if T = 315 K (C) Y if T = 300 K (D) X if T = 350 K
[Jee Main, Jan 2019]

15. 2O3 (g)  3O2(g)

At 300 K, ozone is fifty percent dissociated. The standard free energy change at this

temperature and 1 atm pressure is (–) _______J mol –1 (Nearest integer)

[Given: ln 1.35 = 0.3 and R = 8.3 J K–1 mol–1]

[JEE Main, June 2022]

Answer key

1. (3) 2. (D) 3. (C) 4. (38) 5. (600) 6. (195) 7. (A)

8. (D) 9. (B) 10. (A) 11. (–2.70) 12. (D) 13. (964)
14. (B) 15. (747)

APNI KAKSHA 9
(Physical Chemistry)

IONIC EQUILIBRIUM

1. Ka for butyric acid (C3H7COOH) is 2 × 10–5. The pH of 0.2 M solution of butyric acid is _______ ×
10-1. (Nearest integer) [Given log 2 = 0.30] [JEE Main, July 2022]

2. 200 mL of 0.01 M HCl is mixed with 400 mL of 0.01M H2SO4. The pH of the mixture is __________.

(A) 1.14 (B) 1.78 (C) 2.34 (D) 3.02

[JEE Main, July 2022]

3. Arrange the following solutions in the decreasing order of pOH:

(a) 0.01 M HCl (b) 0.01 M NaOH
(c) 0.01 M CH3COONa (d) 0.01 M NaCl
(A) (b) > (c) > (d) > (a) (B) (a) > (c) > (d) > (b)
(C) (b) > (d) > (c) > (a) (D) (a) > (d) > (c) > (b)
[Jee Main, 2020]

4. 20 mL of 0.1 M H2SO4 solution is added to 30 mL of 0.2 M NH4OH solution. The pH of the

resultant mixture is : [pkb of NH4OH = 4.7]. [Ionic Equilibrium]
(A) 9.4 (B) 5.0 (C) 9.0 (D) 5.2
[Jee Main, Jan 2019]
5. Class XII students were asked to prepare one litre of buffer solution of pH 8.26 by their
chemistry teacher. The amount of ammonium chloride to be dissolved by the student 1n 0.2 M
ammonia solution to make one litre of the buffer is

(Given pKb (NH3)=4.74; Molar mass of NH3=17g mol–1; Molar mass of NH4Cl= 53.5g mol–1)

(A) 53.5 g (B) 72.3 g (C) 107.0 g (D) 126.0 g

[JEE Main, July 2022]

6. Consider the following statements

(a) The pH of a mixture containing 400 mL of 0.1 M H2S04 and 400 mL of 0.1 M NaOH will be
approximately 1.3.

(b) Ionic product of water is temperature dependent.

(c) A monobasic acid with Ka = 10–5 has a pH = 5. The degree of dissociation of this acid is 50%.

APNI KAKSHA 10
(Physical Chemistry)

(d) The Le Chatelier's principle is not applicable to common-ion effect.

The correct statements are :

(A) (a), (b)and(c) (B) (a) and (b) (C) (b) and (c) (D) (a), (b) and (d)

[Jee Main, April 2019]

7. An acidic buffer is obtained on mixing :

(a) 100 mL of 0.1 M HCl and 200 mL of 0.1 M NaCl

(B) 100 mL of 0.1 M HCl and 200 mL of 0.1 M CH3COONa

(C) 100 mL of 0.1 M CH3COOH and 100 mL of 0.1 M NaOH

(D) 100 mL of 0.1 M CH3COOH and 200 mL of 0.1 M NaOH

[Jee Main, 2020]

8. Given below are two statements.

Statement I: In the titration between strong acid and weak base methyl orange is suitable as
an indicator.
Statement II: For titration of acetic acid with NaOH phenolphthalein is not a suitable indicator.
In the light of the above statements, choose the most appropriate answer from the options
given below:
(A) Statement I is false but Statement II is true
(B) Statement I is true but Statement II is false
(C) Both Statement I and Statement II are true
(D) Both Statement I and Statement II are false
[JEE Main, August 2021]

9. In base vs. Acid titration, at the end point methyl orange is present as

(A) quinonoid form (B) heterocyclic form (C) phenolic from (D) benzenoid form

[JEE Main, July 2022]

10. If Ksp of Ag2CO3 is 8 × 10–12, the molar solubility of Ag2CO3 in 0.1M AgNO3 is :
[Ionic Equilibrium]
(A) 8×10–10 M (B) 8 ×10–13 M (C) 8×10–12 M (D) 8×10–11 M
[Jee Main, Jan 2019]

APNI KAKSHA 11
(Physical Chemistry)

11. The solubility of Ca(OH)2 in water is:

[Given : The solubility product of Ca(OH)2 in water = 5.5 × 10–6]
(A) 1.77 × 10–6
(B) 1.11 × 10–6
(C) 1.11 × 10–2
(D) 1.77 × 10–2
[JEE Main, Feb 2021]

12. The solubility of AgCl will be maximum in which of the following?

(A) 0.01 M KCl (B) 0.01 M HC1

(C) 0.01 M AgNO3 (D) De-ionised water

[JEE Main, June 2022]

13. When 35 mL of 0.15 M lead nitrate solution is mixed with 20 mL of 0.12 M chromic sulphate
solution, ________ × 10–5 moles of lead sulphate precipitate out. (Round off to the Nearest
Integer)
[JEE Main, March 2021]
14. The solubility of AgCN in a buffer solution of pH=3 is x. The value of x is: (Assume : No cyano
complex is formed; Ksp (AgCN) =2.2×10–16 and Ka(HCN) = 6.2×10–10]
(A) 0.625 × 10–6
(B) 1.9 × 10–5
(C) 2.2 × 10–16
(D) 1.6 × 10–6
[JEE Main, Feb 2021]
15. The number of moles of NH3, that must be added to 2 L of 0.80 M AgNO3 in order to reduce the
concentration of Ag+ ions to 5.0×10–8 M (Kformation for [Ag(NH3)2]+ =1.0× 108) is ________ .
(Nearest integer)
[Assume no volume change on adding NH3]
[JEE Main, August 2021]
ANSWER KEY
1. (27) 2. (B) 3. (D) 4. (C) 5. (C) 6. (A) 7. (B)

8. (B) 9. (A) 10. (A) 11. (C) 12. (D) 13. (525) 14. (B)
15. (D)
APNI KAKSHA 12
(Physical Chemistry)

Electrochemistry
1. For the reaction
2Fe3+(aq) + 2I–(aq) → 2Fe2+(aq) + I2(s)
the magnitude of the standard molar free energy change, rGm° = – ______ kJ.
(Round off to the Nearest Integer)

 E 0Fe2+ /Fe(s) = −0.440V; E 0Fe3+ /Fe(s) = −0.036V 

 
 E I /2I− = 0.539V;
0
F = 96500C 
 2 

[JEE Main, March 2021]

2. Given that the standard potentials (E°) of Cu2+ /Cu and Cu+ /Cu are 0.34 V and 0.522 V
respectively, the E° of Cu2+/Cu+ is :

(A) –0.182 V (B) –0.158 V (C) 0.182 V (D) +0.158 V

[Jee Main, 2020]

3. Given:

Co3+ + e– → CO2+ ; Eº = + 1.81 V

Pb4+ + 2e– → Pb2+ ; Eº = + 1.67 V

Ce+4 + 3e → Ce3+ ; Eº = + 1.61 V

Bi3+ + 3e– → Bi ; Eº = + 0.20 V

Oxidizing power of the species will increase in the order:

(A) Ce4+ < Pb4+ < Bi3+ < Co3+ (B) Co3+ < Pb4+ < Ce4+ < Bi3+

(C) Bi3+ < Ce4+ < Pb4+ < Co3+ (D) Co3+ < Ce4+ < Bi3+ < Pb4+

[Jee Main, April 2019]

4. If the standard electrode potential for a cell is 2 V at 300 K, the equilibrium constant (K) for the
reaction [Electrochemistry]
Zn(s) + Cu (aq)
2+ Zn (aq) + Cu(s)at 300 K is approximately.
2+

(R = 8 JK–1 mol–1, F = 96000 C mol–1)

(A) e–80 (B) e–160 (C) e160 (D) e320
[Jee Main, Jan 2019]

5. For the given cell ;

APNI KAKSHA 13
(Physical Chemistry)

Cu(s)|Cu2+ (C1M)||Cu2+ (C2M)|Cu(s) change in Gibbs energy (G) is negative, if :

(A) C1 = 2C2 (B) C2 = Cl (C) C1 = C2 (D) C2 = 2C1

2
[Jee Main, 2020]
6. Consider the cell at 25°C
Zn | Zn2+ (aq), (1M) || Fe3+ (aq), Fe2+ (aq)| Pt (s)
The fraction of total iron present as Fe3+ ion at the cell potential of 1.500 V is x×10–2. The value
of x is_________. (Nearest integer)

(Given: E0Fe3+
/Fe2+
= 0.77V, E0Zn 2+
/Zn
= −0.76V )

[JEE Main, July 2021]

7. In the cell Pt(s)|H2(g, 1bar)|HCl(aq)|AgCl(s)|Ag(s)|Pt(s) the cell potential is 0.92 V when a 10–6
molal HCl solution is used. The standard electrode potential of (AgCl/Ag,Cl–) electrode is :
 2.303RT 
Given, = 0.06 V at 298 K  [Electrochemistry]
 F 
(A) 0.94 V (B) 0.40 V (C) 0.20 V (D) 0.76 V
[Jee Main, Jan 2019]

8. 108g of silver (molar mass 108g mol–1) is deposited at cathode from AgNO3(aq) solution by a
certain quantity of electricity. The volume (in L) of oxygen gas produced at 273 K and 1 bar
pressure from water by the same quantity of electricity is ______ .

[Jee Main, 2020]

9. An acidic solution of dichromate is electrolyzed for 8 minutes using 2A current. As per the following
equation
Cr2 O72− + 14H + + 6e − → 2Cr 3+ + 7H 2O
The amount of Cr3+ obtained was 0.104 g. The efficiency of the process (in %) is
(Take : F = 96000 C, At. mass of chromium = 52) ________.
Given 60.31
[Jee Main, 2020]

10. A dilute solution of Sulphuric acid is electrolysed using a current of 0.10 A for 2 hours to
produce hydrogen and oxygen gas. The total volume of gases produced at STP is ________ cm3.
(Nearest integer) [Given : Faraday constant F = 96500 C mo1–1 at STP, molar volume of an ideal
gas is 22.7 L mo1–1]

[JEE Main, June 2022]

11. Consider the statements S1 and S2 :

S1: Conductivity always increases with decrease in the concentration of electrolyte.

APNI KAKSHA 14
(Physical Chemistry)

S2: Molar conductivity always increases with decrease in the concentration of

electrolyte.

The correct option among the following is:

(A) Both S1 and S2 are wrong (B) Both S1 and S2 are correct

(C) S1 is wrong and S2 is correct (D) S1 is correct and S2 is wrong

[Jee Main, April 2019]

12. Given below are two statements:
Statement I: The limiting molar conductivity of KCl (strong electrolyte) is higher compared to
that of CH3COOH (weak electrolyte).
Statement II: Molar conductivity decreases with decrease in concentration of electrolyte.
In the light of the above statements, choose the most appropriate answer from the options
given below:
(A) Statement I is true but Statement II is false.
(B) Statement I is false but Statement II is true.
(C) Both Statement I and Statement II are true.
(D) Both Statement I and Statement II are false.
[JEE Main, August 2021]

13. The molar conductivity of a conductivity cell filled with 10 mole of 20 mL NaCl solution is  m1

and that of 20 moles another identical cell having 80 mL NaCl solution is  m2 , The

conductivities exhibited by these two cells are same.

The relationship between  m2 and  m1 is

(A)  m2 = 2 m1 (B) m2 = m1 / 2 (C)  m2 = 2 m1 (D)  m2 = 4 m1

[JEE Main, July 2022]

14. The limiting molar conductivities of NaI, NaNO3 and AgNO3 are 12.7, 12.0 and 13.3 mS m2 mol–
1, respectively (all at 25°C). The limiting molar conductivity of AgI at this temperature is _____

mS m2 mol–1

[JEE Main, June 2022]

15. The conductivity of a weak acid HA of concentration 0.001 mol L–1 is 2.0×10–5S cm–1. If
 0m (HA) = 190 S cm2 mol–1, the ionization constant (Ka) of HA is equal to ____ × 10–6.

(Round off to the nearest integer)

[JEE Main, July 2021]

APNI KAKSHA 15
(Physical Chemistry)

ANSWER KEY
1. (46) 2. (D) 3. (C) 4. (C) 5. (D) 6. (24) 7. (C)
8. (5.67 or 5.68) NTA Ans. (5.66 to 5.67) 9. (60) 10. (127) 11. (C)
12. (D) 13. (A) 14. (14) 15. (12)

APNI KAKSHA 16
(Physical Chemistry)

Thermochemistry
1.

Based on the above thermochemical equations, find out which one of the following algebraic
relationships is correct ?
(A) x = y–z (B) y = 2z–x (C) z = x + z (D) x = y + y
[Jee Main, Jan 2019]

2. ( )
The standard heat of formation  ƒ H 0298 of ethane (in kJ/mol), if the heat of combustion of

ethane, hydrogen and graphite are –1560, –393.5 and –286kJ/mol, respectively is _________.

[Jee Main, 2020]

3. At 25C and 1 atm pressure, the enthalpy of combustion of benzene (1) and acetylene (g) are –
3268 kJ mol–1 and –1300 kJ mol–1, respectively. The change in enthalpy for the reaction 3
C2H2(g) → C6H6(l), is

(A) + 324 kJ mol–1 (B) +632 kJ mol–1

(C) – 632 kJ mol–1 (D) – 732 kJ mol–1

[JEE Main, June 2022]

4. 2.4 g coal is burnt in a bomb calorimeter in excess of oxygen at 298 K and 1 atm pressure.
The temperature of the calorimeter rises from 298 K to 300 K. The enthalpy change during the
combustion of coal is – x kJ mol–1. The value of x is ___________. (Nearest integer)

(Given : Heat capacity of bomb calorimeter 20.0 kJ K–1. Assume coal to be pure carbon)

[JEE Main, July 2022]

5. For the reaction
C2H6 → C2H4 + H2
the reaction enthalpy rH = ______ kJ mol–1.
(Round off to the Nearest Integer).
[Given : Bond enthalpies in kJ mol–1 : C–C : 347, C=C : 611; C–H : 414, H–H : 436]
[JEE Main, March 2021]

APNI KAKSHA 25
(Physical Chemistry)

6. If enthalpy of atomisation for Br2(l) is x kJ/mol and bond enthalpy for Br2 is y kJ/mol, the
relation between them :

(A) is x = y (B) is x > y (C) does not exist (D) is x < y

[Jee Main, 2020]

7. The Born-Haber cycle for KCl is evaluated with the following data:
 f H– for KCl = – 436.7 kJ mol–1 ;
 sub H–for K = 89.2 kJ mol–1;
 ionization H– for K = 419.0 kJ mol–1;
 electron gain H– for Cl(g) = – 348.6 kJ mol–1;

 bond H– for Cl2 = 243.0 kJ mol–1;

The magnitude of lattice enthalpy of KCl in kJ mol–1 is _______ (Nearest integer)
[JEE Main, August 2021]

8. Lattice enthalpy and enthalpy of solution of NaCl are 788 kJ mol–1 and 4 kJ mol–1, respectively.
The hydration enthalpy of NaCl is :
(A) 784 kJ mol–1 (B) –780 kJ mol–1 (C) –784 kJ mol–1 (D) 780 kJ mol–1
[Jee Main, 2020]

9. While performing a thermodynamics experiment, a student made the following observations,

HCl + NaOH → NaCl+ H2O H = –57.3 kJ mol–1

CH3COOH + NaOH → CH3COONa + H2O H = –55.3 kJ mol–1.

The enthalpy of ionization of CH3COOH as calculated by the student is________ kJ mol–1.

(Nearest integer)

[JEE Main, July 2022]

10. When 600 mL of 0.2 M HNO3 is mixed with 400 mL of 0.1M NaOH solution in a flask, the rise in
temperature of the flask is _________ × 10–2 0C.

(Enthalpy of neuralization = 57 kJ mol–1 and specific heat of water = 4.2 JK–1 g–1)

(Neglect heat capacity of flask)

[JEE Main, July 2022]

APNI KAKSHA 26
(Physical Chemistry)

ANSWER KEY

1. (D) 2. (–192.50) NTA Ans. (–192.00 to –193.00) 3. (C) 4. (200)

5. (128) 6. (B) 7. (718) 8. (C) 9. (2) 10. (54)

APNI KAKSHA 27