© TYPE IMCQs with Only ONE Correct Alternate 1 If Avogadro's number N, is changed from 6.02210 mot to 6.022 10" mol”, this would change (@) the definition of ama (6) the mass of one mole of carbon (©) the ratio of chemical species to each other in a balanced equation (@ the ratio of elements to each other in a compound 2 20.0 g magnesium carbonate sample decomposes on heating to give CO, (that escapes) and 8.0 g of magnesium oxide. Per cent purity of magnesium carbonate sample is (a) 75 (0) 96 (60 (84 3 What mass of white precipitate of AgC! is formed when 50 mL of 17% solution of AgNO, is mixed with 50 mL. 0f 5.85% solution of NaCl ? (@) 0.05 mol (6) 0.10 mol (©) 0.15 mol (60.20 mot 4 The mass of CaCO, required to react completely with 20 mL of 1.0 M HC! in the following reaction is CaCO, +2HCI—> CaCl, + CO, +H,0 @le 2g ©l0g @20g 5 Number of neutrons present in 1.4 mg of {Cis (@)4.214x10" (b) 3.612% 10 (©) 8.428% 10" (@)4.816x 10 6 Number of electrons present in 6.0 g of CO}. is (@) 1.806 10% (6) 1.9264 10 (©) 3.7324 10% (@) None of these 7 Mass of calcium that has same number of atoms as in 16g, of CH, is (@) 200g () 100g (© 408 208 8 The volume strength of 1 MHz is (Molar mass of HO, = 34 g mol) [JEE Main 2019 () NTA] @56 (168 @)224 (11.25 9 4.10 mg effervescent tablet containing sodium bicarbonate and oxalic acid releases 0.25 mL CO, at 298.15 K and p=lbar. If molar volume of CO, is 25.0 L under such conditions, what is the percentage of sodium bicarbonate in each tablet? (Molar mass of NaHCO, = 84 g mol!) WEE Main 2019 (1) NTAJ (a) 084 (0) 8.4 (c) 16.80 (@) 336 10 Largest mass of hydrogen atoms is contained in (@) 5.0 moles of GH,O, (b) 1-1 moles of CjHyO3 (©) 1.5 moles of CyH4O, _(@)4.0 moles of CH,O2 11 How many moles of CI” ions are present in 50.0 mL of 0.20 M BaCl, solution? (0.02 mol (b) 10 mol (©) 0.01 mol 12 How many moles of Na ,CO, are needed to prepare 500 mL of a solution contaning 10.0 mg CO} per mL? (@) 0.0833 mot (b) 0.0417 mol (© 0.167 mot (@ 1.67 mot 13 A solution contains 75 mg NaCI per mL. To what extent rust it be diluted to give a solution of 15 mg NaCl per mL? (@) Five times (©) One-fifth times (© Fifty times (@ Two times 14 How many mL of 0.2 M NaOH will completely neutralise 10 mL of 0.25 MH,S0,? (@)125 mL (b)25.0mL (€)50.0mL (A) 10.0 mL 15 4.g ofa mixture of calcium carbonate and sand is treated with an excess of dilute HSO, and 0.880 g of CO is produced. Thus, per cent of CaCO; in the original mixture is 20% —()30% (©) 40% (4) 50% 16 A dot mark of a lead pencil has mass of 6 ug of carbon. Thus, number of carbon atoms in one dot mark (@)3.01x 107 (b) 6.02 107 (©)3.01x 10° (@ 6.02x10° 17 Mass of one drop of water molecule is 0.0018 g, Thus, number of water molecules in one drop is (@) 6.02108 (0) 3.01x 10 (©) 6.02x 10 (@)6.02x 10 18 For CuSO, - SHO, which is the correct mole relationship ? (2) 9 x mole of Cu=mole of 0 (b) 5 x mole of Cu=mole of O (©)9 x mole of Cu =mole of 0, (@ Mole of Cu =9 x mole of 0 19 The equivalent mass of a metal is twice that of oxygen. How many times is the equivalent mass of its oxide than the equivalent mass of the metal ? @4 (3 ©2 @1s 20 0.1596 g of M0; is reduced to metal M by 0.006 g of hydrogen. The atomic mass of metal M is @I1SS8 —(O)558 (1558 (6 20 mol 55821 Volume of concentrated H,SO4(d = 1.84 g mL) containing 98.0% H,SO, by weight that would contain 4.0 2H,S0, is ()222mL (b) LID mL (6) 4.44mL (4) 6.96 mL 22 A mixture of 100 milli. mol of Ca(OH), and 2 g of sodium sulphate was dissolved in water and the volume was made upto 100 mL. The mass of CaSO, formed and the concentration of OH in the resulting solution, EE Main 2019 (1) NTAI (&) 1.9, 0.14 mol Lt (@) 13.69, 0.14 mol L™ respectively are: (@) 1.91 g,0.28 mol L* (©) 13.6 g, 0.28 mol L™ 123 In the reaction of oxalate with permanganate in acidic ‘medium, the number of electrons involved is producing ‘one mole of CO, is “ [JEE Main 2019 (1) NTA) (10 (b)2 5 @1 24 A50.0 mL of sample of HCI solution requires 1.0 g of pure CaCO, for complete neutralisation. Thus, HCl is ()02N b)01N (004N (4) 04N 125 The number of lead atoms present in a small piece of lead with a volume of 0.105 em’ is (density of lead =11.34 g/m’, lead weight = 200). (a) 3.48x 107 (b) 1.56x 107 (0) 5.57x10" () 6.50x 10% 26 How many moles are there in one atom? (a) 6.02« 10° (b) 1.66% 107% (©) 1.00 (None of these 27 Number of moles in I kg electron is (a) 1.83x 10° (0) 9.1x 107" (©) 9.1x107* (@)L.1x 10 28 What volume of 0.25 N solution contain 10 milli equivalent ofa solute? (2) 40.0 mL (040 mL 29 How many equivalents of a solute are present in 60 mL of 4.0N solution? (240 ()240(0)2.4 (0240 30 Normality of 0.3 M HPO, solution based on the following reaction is HPO, +20H"—+ HPO} +2H,0 (b) 4.0 mL (@) 0.04 mL. (2)03N —0)06N @)OIM —(@) 0.15 N 31 What the ratio of volume of 12.0 N and 3.0 N HCI in a mixture to give 1.00 L of 6.00 N HCI. (ist )2z1 NZ @13 32 90 mL of HsPO, is neutralised by 120 mL of 0.531 N NaOH, Thus, HPO, is (@)0531M (©) Both (a) and (b) (b) 1.593.N (@) None of these SS 33 The vapour density of a gas is 11.2. The volume og, by I g of the gas at STP is (a) LOL ()224L 34 What is the atomic weight of an element X fora 4 sample containing 1.58% 10° atoms weigh 1.05 g @28e 0g =) 4G 35 8g of a gas at STP ocoupies 5.6 L, hence number of moles present in 64 g of the gas will be @1 (o)2 ©3 @s 36 A divalent metal cation has equivalent weight 12, Ty, molecular weight of its oxide is 7 (a) 16 (b)32 @40 @2 37 Permanent hardness in hard water is 20 mg Ca* ang 12 mg Mg”* pet litre. Thus, volume of 2 NNa,Co, solution to remove hardness is 7 (@)imL = (b)10mL_ +) 100mL_ (2m. 38 A particular lead-cadmium alloy is 8% cadmium by mg What mass ofthis alloy, in grams, must you weight oxy obtain a sample containing 6.50x 10 Cd -atoms? (Cd=112) (a)O0.121 kg (b)1.512kg (Cc) 0.135 kg (@)0.0097 ig 39 Volume of 5.00 N H,SO, required to neutralise 25 got ‘NaOH is (a) 25.0 mL (b) 12.5 mL (0) 0.25 mL (@) 50.0 mL 40 0.25 g of a sample of an acid was dissolved in water ad exactly neutralised by 40.0 mL of 0.125 N base. Thus, equivalent weight of acid is (@) 25.0 gequiv™ (c) 50.0 gequiv! 41 Volume of concentrated H,SO, (d=1.835g mL", 93.2% H,$0O, by weight) required to make up 500 mf 3.00 NH, 80, is (a) 86.0 mL (b) 21.5 mL (©) 50.0 mL, (43.0 mL 42 Mass of wet NaOH containing 12% water is required to prepare 60 L of 0.50 N solution is (a) 1.364 kg (b) 0.082 kg (0) 2.728kg (@ None of these 43 Equivalents of N, O and Cl in the following reactions formed are in the ratio of N, + 3H, —>2NH, 0, + 2H) —> 2,0 Cl, + Hy — 2HCI (b)3:2:1 (d)6:3:2 (b) 2L (d) None of these ich (b) 37.5 gequi (8 605 gequivee {44 The same amount of metal combines with 0.200 g oxygen and 3.17 g of halogen, Hence, equivalent mass of halogen is (127 gequiv (0355 gequiv"' () 80 gequiv™' (4) 9 gequiv! 45 Daily intake of glucose (C,H,,O,) of a patient is 400 mL ‘of 9% concentration per day. The number of glucose rolecules taken by him per hour is (@) 50x10" (0) 1.2010 (0) 2.17% 10 (50x10 46 Equivalent mass of sulphur in SCI, is 16 equiv". ~ ‘Thus, equivalent mass of S in $,Cl, is : (0) 32 gequi ©) 16 gequiv © 8 gequiv (@) 64 gequiv™ 47 Number of moles of dibasic acid in 0.10 dm? of the aqueous solution to give decinormal solution is (0.10 mol (&)0.01 mol (@) 0.005 mol. (4) 0.50 mol 48 An aqueous solution of glucose is 10% mass by volume. The volume in which 0.1 mole will be dissolved is @90mL—(&)900mL (©) 180ml (A) 1800mL 49 Solute and solvent have mold es in solution is 10% by mass of s solute in the solution is. = 0.75 @)050 — ©)1.0x10* (@)9.9x107 50 50 mL of 0.5 M oxalic acd is needed to neutralise 50 mL. of sodium hydroxide solution. The amount of NaOHin 500 mL of the given sodium hydroxide solution is LUEE Main 2019 (1) NTA] @10g ©) 408 (80g @ 20g ‘51 What is the simplest formula of a compound of elements Xand Y based on following data X 50% Atomic weight 10 Y 50% Atomic weight 202 @Y OXY OX, OKs ‘52 The hardness of water sample (in terms of equivalents of ‘CaCO, ) containing 10 M CaSO, is (molar mass of CaSO, = 136g mol™') WEE Main 2019 (1) NTAJ (@)50ppm —(b) 90 ppm _—(c) 100 ppm (4) 10 ppm 53 8 g of NaOHis dissolved in 18 g H,O.Mole fraction of ‘NaOH in solution and molality (in mol kg~' )of the solution respectively are LUEE Main 2019 () NTA} @02,11.11 (©) 0.167, 22.20 (©)0.167, 22.20 (0.107, 11.11 54 If molarity of a solution of solute (50 g mol) is 9 mol L? and molality is 10 mol kg~", then its density (@) 1.0. gmL* (b) 0.91 gmL" (©) 1.05 g mi @ 1.35 g mi 55 In shombie sulphur, S- atoms are joined into Sx molecules with density 2.07 g /em’. ‘Number of S, molecules in a erystal of 0.568 mm? is (0)1.336%10 221.10 (2.765 10" (0) 2.765%10 ‘56 The molarity of a solution obtained by mixing 750 mL of 0.5 MHC! with 250 mL of 2M HCI will be MEE Main 2013) (0875 M (6) 1.00 M (@LI5M (0.0975 M 57 The density of a solution prepared by dissolving 120 g of ‘urea (molar mass =60 u) in 1000 g of water is 1.15 g/mL. ‘The molarity of this solution is IAIEEE 2012] (050M (b) 178M © 102M (2.05 M 58 The molality of a urea solution in which 0.0100 g of urea, [0NH, )2 CO] is added to 0.3000 dm? of water at STP is AIEEE 2011] (@) 555x104 M (333M (©333x107M (0555 M 59 Number of atoms in 560 g of Fe (atomic mass =56 g IAIEEE 2002] (@) twice that 70 2N (b) half that of 20 gH (© Both (a) and (b) (@None of these 60 1 mole each of CaHl and H,Oare allowed to react to form (@) 1 mole H, (b)2 moles H (05 mole H, (@)0.25 mole Hy 61 25 mL of the given HCI solution requires 30 mL of 0.1 M Na,CO, solution. What is the volume of this HCl solution required to titrate 30 mL of 0.2 M aqueous ‘NaOH solution? LUE Main 2019 (1) NTA] (®) 75 mL (©) 25 mL . (125 mL (@) 50 mL (62 Water is evaporated from 135 mL of 0.188 MK SO, solution until the solution becomes 105 mL. Thus, molarity of the resultant solution is (@0.179M (b) 0.242 M (©)0.146M (@None of these 63 A mixture of CuSO, and CuSO, -SH,O weight of 1.245g is strongly heated to drive off water, when 0.882 g of residue is formed. Thus, mass percent of anhydrous salt in the mixture is (a) 19.7% (0) 70.8% (384% (A) 71.6%64 What is formula of 4 based on following reaction? Fe,0, “25 Fe+H,0 Wosit, cant, @Fe0, (FO, (FeO) FeO 665 Excess of CO, is passed through 50 mL of 0.5 M Ca(OH) solution, Resultant solution was evaporated to dryness and required V mL of 0.1N HCl for complete neutralisation, Thus, Vis (@)200mL (6) 500 mL (©)400mL = (d) 300 mL 66 How many gram of sodium must react with 150 mL HO to produce a solution that is 0.175 M NaOH? @O0312g ()0543g (©) 1085g (4) 0.604g 67 A solution of solute Xs 40% X by weight of solution. On cooling 800 g ofthis solution 100 gof solute Xis Precipitated. Thus, resultant solution is (a) 31.4% (b) 20.0% (©) 23.0% 68 In the following reaction, (@) 24.0% Mg 24, Product of Mg and N (4) . 023 oon empirical formula of A is (@)MgN —(b)Mg;N, (©) MeN, (@) Mg,N 69 Based on the following reaction (unbalanced) CO, +C—+C0+C0, eZ led ISL Thus, moles of CO formed at STP is @vu2 (b) 1/22.4 (© 1422.4 (@) 28/22.4 70 CaCO; sample is 25% pure. 100 g ofthis sample is. heated strongly and CO, formed is passed into NaOH solution. Na,CO; formed is (@) 2652 (6) 1060¢ (©) 13.25¢ 530g 71 Per cent yield of NH; in the following reaction is 80%, NH, CONH, +2Na0H—*»Na,CO, +2NH,, 4 2 If6 g of (4) reacts with 8 g of (B), then NH; formed is, (@)3.40¢ Q)ll2g ©4258 @272¢ 72 Aqueous solutions of 1 mole of SO,Cl, is neutralised by (a) two moles of NaOH (b) three moles of NaOH (©) two moles of Ca(OH), —_(d) three moles. of Ca(OH), 73 1 mole of BaF, is mixed with 2 moles of H,SO,. Filtrate required ......... moles of NaOH to neutralise acid. (a)2 moles of KOH (6) 4 moles of KOH (©)3 moles of KOH @ Vole of KOH 4 74 What mass of (NH )2 03 consis 6.02510” yap, atoms? (@) 19.28 (b) 5.76 g (© 120g (600g 75 How many moles of SO, contain the same number of atoms as in 1 mole of CH,O? @Lo = 2030 @os 76 The ratio of masses of oxygen and nitrogen of a partcy ‘gaseous mixture is 1 : 4. The ratio of number of their molecules is EE Main 24g @i:4 (7:32 © (03:16 77 Mixture of x mL of 2 N HCI, 50 mL of 4 N HNO, and 62.5 mL of 2M H,S0, is diluted to IL, $0 mL of this solution required 25 mL of 0.5°M Na,CO; solution for complete reaction. Thus, xis @25mL — @)40mL = ©) 6OmL — (4) 100 mL 78 2g ofa mixtiré containing equal number of moles of LizCOs (74 g mol”) and M3 CO, required 21.6 mL of 0.5 MH,S0, for complete neutralisation: Thus, stomic mass of M is (25 23 51 @us 79 1 L of hard water required 0.050 g of lime for removing ‘temporary hardness. Thus, temporary hardness in ppm of CaCO, is (@) 100 (b) 200 © 50 (@)20 80 Hardness in a sample of hard water containing L.1]'mg CaCl, and 0.95 mg MgCl; per litre in terms of ppm of CaCO; is (@)2 ppm (0) 3 ppm (©) 6ppm @4 ppm 81 Ina sample of hard water with hardness 200 ppm. Select incorrect statement, (@) Mass ratio of CaCO, to H,Ois 2x 10+ (0) Mole ratio of CaCO, to H,Ois 3.0% 10> (©) CaCO, is02gL! (@) 1 kg of hard water has 1 milliequivalent 82 A sample of NaClO, is converted to NaCl and 0, by heating. There is a loss of 0.16 g O,. The residue is dissolved in water and precipitated as AgCl. Thus, mast, of AgCl obtained is (molar mass of AgCl =143.5g mol Na =23,Cl=35.5) EE Main 2018) @oalg (0) 0358 (© 048g 054g 83 H,SO, is 80% pure (w/V), with density 1.8 g mL". Thus, its molality is (@) 8.16 mol kg! (©) 4.53 mol kg”! (b) 1.02 mol kg" (@) None of these84 100 mL of 10% NaOH (w/V) is added of 10Y HC! (v/”), thus resoltant mores, meget (2) 0.12 Min terms of HY (6) 0.12 M in terms of OF (©) 0.048 Min terms of H* (4) 0.192 M in terms of Ht 85 The ammonia (NH; )released on (0.6 g urea (NH,CONH, can be neutralised by (@)200 mL of 0.2N HI (© 100 mL of 0.1N HCI 86 How many millilitres of 0,1 200 mL of 0.1 MH, SO, tantitative reaction of 2 with sodium hydroxide (NaOH) WEE Main 2020 1) NTA] (b) 200 mL of 0.4 N HCI (@) 100 mL of 0.2N HCL MIN@OH must be added to 6 t0 give a solution that is 0.07 M in ,$0,? (2) 100 mL. ©) 150 mL (©) 200 mL. (som. 87 Public water supply has CHCI; as impurity tothe extent of 0.10 ppb. How many molecules of CHCl. present in I mL of this water? dapehe (@) 5.0410" (©) 5.04x 10" (©) 1.02% 10 (6.02 10% 8 Thee ‘types of solutions are supplied to students A, B and 4:5 g0f15 MNaOH (d=1gmL") B: Smal of 50% (wi) NaOH C:5 g of 40% (wi) NaOH (d=1.25 g mb) Increasing order of mass of NaOH in the above solution is @A 2NH, (g), identify dihydrogen (H, )as a limiting reagent in the following reaction. mixtures. WEE Main 2019 (11) NTA] (@) 56 gofN, +10gofH, (b) 35 g of N, + 8g of H, (14 g0fN, +4gofH; (€)28gofN, + 6g0f Hy 102 A certain mixture of MnO and MnO, contains 66.67 mol % of MnO. What is the approximate weight per cent of Mn in it? (Mn = 55) (@)66.67 on (0) 33.33 (28