Sip - Bioplastics
Sip - Bioplastics
By:
CHAPTER 1
INTRODUCTION
"I realized that plastic had become part of my life and that it had become invisible to
me." Craig Leeson is an award-winning journalist and director of The Plastic Ocean. This
quotation provides us with insights into how we normalize using plastics in the modern world.
staggering global production of over 300 million tons of plastic every year. In daily life, the
benefits of plastic are undeniable. Its durability and lightweight nature make it essential for
packaging, preserving food, and securing the safety of medical supplies. Humans currently
produce more than 350 million metric tons of plastic waste per year. Without changes to
current policies, global plastic waste generation is projected to triple by 2060, to a staggering
one billion metric tons. In contrast, if new measures and policies are introduced, such as
increased taxes on plastic use and a vastly improved global recycling system, this figure
could drop to less than 700 million metric tons. (Alves, 2024)
The phrase "Reduce, Reuse, Recycle" dates back to the USA in 1976 and became a
staple of the sustainability movement. But in 2019 459,746,020 tons of plastics were
produced which is 751% of relative change compared in 1976 which had 54,000,000 tons
only (Geyer et al. 2017 ;(OECD 2022). This statistical significance entails that the reduce,
reuse, recycle movement is not effective and there is overproduction of plastics that leads to
Solid Waste Problems. Recycling plastic has been marketed as a solution to the waste
more plastic but also maintain a steady supply for incineration. (Guevara, 2022)
worldwide, contributing to an estimated 0.75 million metric tons of ocean plastic every year.
Dubbed as the “sachet economy,” the Philippines is notorious for irresponsible trash haulers
and open dump sites that cause the plastic to spill into the seas. (Guevarra, 2022)
Remulla said solid waste management is the number one problem of Cavite when it
comes to the environment, as he noted that an estimated 50 percent of solid waste in the
province goes to its rivers accounting for approximately 2,000 tons a day, of which 90
Single-Use Plastics and Packaging Applications. More specifically it aims to answer the
following questions.
A. Solubility
B. Flexibility
C. Degradability
A. Cornstarch
C. Gulaman
3. Is there a significant difference between the bases of bioplastic in terms of the following?
A. Solubility
B. Flexibility
C. Degradability
single-use plastic and packaging applications at our university and assess the feasibility and
sources, impacts, and current management practices of plastic waste, the study aims to
propose effective strategies for reducing environmental pollution and improving sustainability
on campus.
HYPOTHESIS
A. Bioplastic will have higher solubility in water compared to conventional single-use plastics,
which makes it unsuitable for eating that requires some degree of water resistance.
B. Bioplastic will be less flexible than conventional single-use plastics due to the natural
polymers used in its production, but it will still possess enough flexibility to be a viable
option.
Gelatin-based bioplastic will be the most effective among the bases tested (cornstarch,
wheat flour, gelatin) due to its favorable properties in solubility, flexibility, and degradability.
3. Is there a significant difference between the bases of bioplastic in terms of the following?
A. There is a significant difference in solubility between cornstarch, wheat flour, and gelatin-
based bioplastics, with gelatin-based bioplastics being the least soluble in water.
B. There is a significant difference in flexibility between cornstarch, wheat flour, and gelatin-
environments.
provides empirical data and insights into the environmental and operational impacts of
plastic waste, contributing to the broader field of sustainable materials and waste
management practices.
FOR STUDENTS AND FACULTY. The findings will benefit students and faculty by creating
with sustainability issues will foster a culture of environmental responsibility among the
university community.
with insights to develop and implement more effective waste management and sustainability
policies, thereby reducing plastic waste on campus and promoting a greener environment.
FOR POLICYMAKERS. This study will offer valuable data to policymakers, enabling them to
craft broader environmental policies and regulations that address plastic use and waste
adopting bioplastics. This can lead to more efficient waste reduction strategies and better
FOR FUTURE RESEARCHERS. The study will supply future researchers with new data and
insights, which can serve as a reference for further studies on plastic waste management
This study aims to explore the issue of single-use plastic waste and the potential for
bioplastics as an alternative at our university. The analysis will focus on understanding the
sources, impacts, and management practices of plastic waste on campus, while also
assessing the feasibility and benefits of integrating bioplastics into the university's waste
management system. By collecting and analyzing data through trial, analysis, and
observations, the study intends to provide comprehensive recommendations for enhancing
However, it is critical to note the study's inherent limitations. For starters, the findings
may be limited to the specific context of the university campus and may not be generalizable
to other settings. The reliance on self-reported data from surveys and interviews may
introduce biases or inaccuracies. The study may also face constraints in accessing certain
data or information, particularly regarding current waste management practices and costs.
and require resources beyond the scope of this study. The awareness and willingness of
stakeholders to adopt bioplastics may vary, impacting the feasibility of proposed solutions.
Finally, due to time and resource constraints, the study may not address all potential factors
DEFINITION OF TERMS
plastics.
in ways that protect and improve the natural environment, often through practices like
Global Plastic Production. The massive annual production of plastic materials is estimated
1976 aimed at reducing waste by encouraging the reduction, reuse, and recycling of
materials.
Sachet Economy. A term describing the economic model prevalent in the Philippines,
where small, single-use plastic sachets are widely used, leading to significant plastic waste
Solid Waste Management. The processes involved in collecting, treating, and disposing of
Sustainability. The practice of meeting present needs without compromising the ability of
This chapter is composed of the review of all the related literature and studies that
STARCH-BASED BIOPLASTICS
According to Ozdamar & Ates (2018), biodegradable plastics are derived from renewable
basic resources (Stevens, 2002). Stevens divided biodegradable plastics into three groups in
the same study: (a) bioplastics made of conventional polymers like starch; (b) bioplastics
made from polymers produced by microbial fermentation; and (c) bioplastics made from
Starch is a natural polymer occurring in plants. Starch is mainly comprised of two types of
starch significantly impacts the structure and thermal stability of its bioplastics (Ghasemlou
et al. 2022). The mechanical strength of the starch generally depends on its amylose
content. In general, high-amylose starch has better mechanical properties. However, the
and viscosity. Starch has long been considered the best candidate for making bioplastics
due to its abundant natural availability, low cost, renewability, and biodegradability. However,
Murdoch, & Adhikari, 2020). Moreover, pure starch-based bioplastics are too brittle and
fragile and almost impossible to extrude. Plasticization of starch is a common way to reduce
its brittleness, increase flexibility, and allow processability. Plasticizers such as glycerol,
glycol, and sorbitol are usually added to the starch to plasticize it and form thermoplastic
starch (TPS) (Rao, Naidu, & Tiwari, 2022). TPS is the marketable form of starch-based
bioplastics, contributing to half of global bioplastics. TPS often yields bioplastics with great
sensitivity to moisture and poor mechanical and thermal properties. Therefore, bioplastics
industries often blend TPS with other biodegradable polyester such as PBAT, polyvinyl
alcohol (PVOH), PLA, and PCL to improve its unsatisfactory water uptake and weak
mechanical characteristics. Bioplastics made from cellulose, chitin and chitosan, with similar
the market; however, the high cost or poor availability of biomass resources and/or complex
biosynthesis from agricultural biomass are major barriers to their large-scale deployment in
The raw elements needed to make bioplastics are readily available, renewable, naturally
occurring, and biodegradable (Scotts, 2002, as referenced in Gadhave, et al., 2018). Three
suitable raw ingredients can be used to create a bioplastic: cellulose, which is typically found
in all plants; lignin, which is naturally found in woods; and starch, which is prevalent in most
root crops.
Based on its affordability and accessibility, starch is a renewable resource that shows
promise for application in bioplastics (Kaith et al., 2009, quoted in Arikan & Bilgen, 2019).
Starch is the second-largest biomass produced on Earth ever. According to Jane (1995, as
referenced in Shrirakshaya et al., 2020), it is an organic compound that is white and granular
and produced by all green plants. From starch and its derivatives, a wide range of biomass
and raw materials are generated economically, such as banana peels, corn, wheat, peas,
Global production of starch has been estimated between 88.1 and 97.7 million tons in
2020. Of this total, 75% comes from corn, followed by cassava (14%), wheat (7%), and
potatoes (4%). China and the United States are the main producers, mainly from corn.
Thailand is the main producer of cassava starch and Europe of wheat and potato starches.
Hydrolyzed starches are the most consumed, followed by native and modified starches, and
these are important as a food source. Paper industry has the highest consumption of starch,
GRACILARIA (GULAMAN)
most extensively used in agar manufacture in the Manila area. Gracilaria is our main source
of agar-agar or gulaman. The value of agar lies in its strongly hydrophilic colloid and high gel
thickening, or gelling agent is desired. It is used in some bakery and dairy products and in
candy, jelly, canned foods, and other items. Its most important service to mankind, however,
is as a bacteriological culture medium, although the amount used for this purpose is
relatively small. In the fresh state, this is used for food in the form of salad and also as
supplemental food for the bañgos chanos. Quite recently, Gracilaria became a big export
item in our economy. Japan especially was our biggest importer of the product, so a need for
the development of the industry, especially keeping up a constant supply through its culture,
is in order.
ADVANTAGES OF BIOPLASTIC
The main benefits of bioplastics are outlined in this section based on research by
Sarkingobir, Y., & Lawal, A. A. Bioplastics: Their advantages and concerns published in
2021.
a. Ecofriendly
Traditional plastics are made from resources derived from oil. The environmental
contrast, bioplastics are typically derived from renewable resources, which lower
environmental pollution.
b. Biodegradable
In a matter of months, bacteria can readily break down bioplastics into end
chemicals, sparing the environment from the pollution that conventional plastics
cause. Certain bioplastics are strong and take a few years to break down entirely.
Because the byproducts naturally occur in the ecosystem, this feature does not
c. Compostable
d. Recyclability
cleaning, shredding, and re-extruding into new forms like pellets or fibers for
infrastructure.
reducing reliance on fossil fuels and lowering the carbon footprint associated with
plastic production.
DISADVANTAGES OF BIOPLASTIC
As stated in Bioplastics: Pros and Cons, and the Future of Bioplastics by B. Hardman
a. Costly to Create
The technology related to the bioplastics sector isn't cheap because the industry
is relatively new. Industrial composters are needed to break down bioplastics into
soil at the end of their life, and specialized manufacturing processors and
plastic.
Many nations lack the facilities necessary to handle bioplastics at this time due to
the high cost of the necessary equipment. If material, including bioplastic, can’t
be recycled and processed properly, it usually means that it’ll end up in a landfill.
If this is the case, then it’s not too much better than a non-biodegradable type of
plastic.
The cultivation of feedstock crops for bioplastics could potentially compete with
food production, raising concerns about food security and land use conflicts. This
is partially the reason why in recent years efforts have been focused on finding
METHODOLOGY
This chapter presents the research methodology employed to evaluate the potential of
bioplastics as sustainable alternatives to single-use plastics, particularly within the context of
packaging at the university. The materials used, procedures followed, and data analysis
methods are discussed to assess their viability.
RESEARCH DESIGN
The research design employed in this study is experimental to allow precise control
over variables and enable the researchers to establish cause-and-effect relationships. This
design is used to systematically investigate the effects of different bioplastic formulations
while minimizing bias within each variable.
Methodology:
Procedures Followed:
1. Preparation of Ingredients:
● To begin the preparation of bioplastics, precise measurements of the ingredients are
essential to ensure consistent results. Start by measuring 8 tablespoons of water and
pouring it into a mixing bowl. Next, add 2 teaspoons of vinegar to the water, which
acts as a catalyst in the bioplastic formation process. Add glycerin, which is typically
used to add flexibility to bioplastics. For the first batch of our experiment, measure 2
tablespoons of flour and combine it with the other ingredients in the bowl. Thoroughly
mix all components until a uniform consistency is achieved, ensuring that the flour is
fully dissolved and the glycerin is evenly distributed. For the second batch, repeat the
process using 2 tablespoons of cornstarch instead of flour. For the third batch, use 2
tablespoons of gelatin as the base. This mixture forms the base for the bioplastic,
which will be subjected to further processing steps to create the final product.
For the second method, we placed molds in the refrigerator. This approach
significantly speeds up the cooling process and is useful when time is a constraint.
However, the cold temperature can sometimes cause the bioplastic to become brittle,
potentially leading to cracks or fractures.
Lastly, we used an oven set to a low temperature for the third method. This technique
offers precise control over the drying process and can produce consistent results
quickly. Nonetheless, it consumes more energy and requires careful monitoring to
prevent overheating, which can degrade the bioplastic.
By comparing these methods, we observed that while sun drying is the most eco-
friendly option, it is the slowest. The refrigerator method is faster but may
compromise the structural integrity of the bioplastic. Using the oven provides a
balance of speed and control but at the cost of higher energy consumption.
Independent Variables:
● Type of starch used (flour, cornstarch): The type of starch used serves as an
independent variable, as it can affect the properties of the resulting bioplastic. Wheat
flour and cornstarch offer different molecular structures and properties, which can
influence factors such as texture, flexibility, strength, and biodegradability. By varying
the type of starch, the researchers can observe how these properties change and
determine the most suitable starch for specific applications.
● Addition of gulaman: The addition of gulaman as an alternative base material
introduces another independent variable. Gulaman possesses unique properties
compared to starch-based bioplastics, such as greater flexibility and elasticity. By
incorporating gulaman into the bioplastic formulation, the researchers can explore its
impact on the physical properties of the bioplastic, including texture, flexibility,
strength, and biodegradability.
● Use of glycerin: Glycerin is commonly used in bioplastic formulations to enhance
flexibility. The researchers can assess their effectiveness in achieving similar
properties to glycerin and explore any differences in bioplastic performance.
Dependent Variables:
Controls:
Set-up B (cornstarch)
- 8 tablespoons of water
- 2 tablespoons of cornstarch
- 2 tsp of vinegar
- 2 tsp of glycerin
Set-up C (gulaman)
- 8 tablespoons of water
- 2 tsp of vinegar
- 2 tablespoons of gulaman
- 2 tsp glycerin
Observations:
Gulaman (C) Translucent Soft and Very flexible Flexible, may Slight odor,
and gel-like, flexible, similar and elastic, lack structural usually mild,
shiny surface to gelatin capable of strength and dissipates
desserts or stretching and compared to with time
gummy bending easily other
candies bioplastics
Comparative Analysis:
Bioplastics made from different ingredients and using varied procedures exhibit
distinct properties. Bioplastics derived from wheat flour typically appear opaque and off-
white, with a relatively smooth texture. In contrast, those made from cornstarch tend to be
translucent or semi-translucent, displaying a pale yellowish hue and a smoother, slightly slick
texture. Gulaman-based bioplastics appear translucent, gel-like, and shiny, with a soft and
Regarding flexibility, wheat flour bioplastics can range from stiff to somewhat flexible,
while cornstarch bioplastics vary from flexible to rigid based on formulation. Gulaman
bioplastics excel in flexibility, being very elastic and stretchable. In terms of strength, wheat
flour, and cornstarch bioplastics exhibit moderate strength suitable for various applications,
wheat flour moderately so, and gulaman bioplastics degrading more slowly. Water
resistance also differs, with wheat flour and cornstarch bioplastics showing moderate
resistance, while gulaman bioplastics have poor water resistance and tend to dissolve in
water.
Considering cost and availability, wheat flour bioplastics may be more accessible and
cost-effective due to the widespread availability of wheat flour. Gulaman may be more
biodegradability, cost, and availability being crucial factors to assess. Overall, the data
analysis reveals that gulaman is highly effective in producing bioplastics with desirable
properties such as transparency, smooth texture, and high biodegradability. However, the
the intended application, taking into account factors such as flexibility, strength, water
Trend Identification:
● In reviewing the data collected from our experiments, several trends emerge,
the influence of the base material on the appearance and texture of the
Another discernible trend is the impact of the base material on flexibility and strength.
Wheat flour bioplastics can exhibit varying degrees of flexibility, spanning from stiff to
somewhat flexible, contingent upon the specific recipe and processing method employed.
being highly flexible while others may lean towards rigidity. However, gulaman bioplastics
consistently showcase high flexibility and elasticity, rendering them suitable for applications
requiring stretchability.
biodegradability and water resistance, whereas gelatin bioplastics degrade more slowly and
their transparent or translucent appearance and smooth, slightly tacky texture, offer an
intriguing alternative. They boast excellent flexibility, and moderate strength, and emit a faint
sweet odor reminiscent of glycerin. This trend underscores the importance of considering
glycerine as a viable base material in bioplastic formulation, particularly for applications
Interpretation:
The trends in bioplastic characteristics that have been noticed provide important
information on the viability and efficiency of using various materials or techniques to produce
sustainable substitutes for single-use plastics. The results of our research indicate that the
biodegradability, and water resistance, are greatly influenced by the choice of base material.
smooth texture, mild elasticity, and strength, wheat flour and cornstarch show promise as
basis materials. But cornstarch is unique because of its remarkable water resistance and
biodegradability is essential. Flexible packaging and biomedical devices can benefit from the
unique benefits that gulaman-based bioplastics offer in terms of elasticity and flexibility.
Because of their slower rate of deterioration, they might be less appropriate for applications
potential for specific uses where biocompatibility and flexibility are critical.
These revelations highlight how crucial it is to take into account a variety of starting
materials and processing techniques when creating bioplastics. We can enhance bioplastic
and lowering dependency on traditional plastics by understanding the distinct qualities and
Conclusion Drawing:
3. Wheat flour also shows potential as a base material for bioplastics, offering similar
properties to cornstarch but with variances in appearance and texture. Further
exploration of wheat flour-based formulations could yield additional sustainable
packaging options.
4. Gulaman-based bioplastics exhibit exceptional flexibility and elasticity, yet may have
limitations in water resistance and biodegradability. While suitable for specific
applications, such as flexible packaging and biomedical devices, their use may be
restricted in certain contexts.
Overall, our findings contribute to the growing understanding of bioplastics and their
role in mitigating the environmental impact of single-use plastics. By identifying effective
materials and procedures for producing bioplastics with desirable properties, we lay the
groundwork for the development of sustainable packaging solutions aligned with principles of
environmental stewardship and circular economy principles. Further research and
development efforts are warranted to optimize bioplastic formulations and processing
methods, considering factors such as flexibility, strength, water resistance, biodegradability,
cost, and availability.
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