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COMPETENCY ASSIGNMENT -1
SUBJECT : __CHEMISTRY GRADE : XI
CHAPTER : SOLUTION MONTH: _APRIL
S.NO. QUESTIONS MARKS
1. Van’t Hoff factor for Na2SO4.10H2O solution, assuming complete
ionization is
(i) 1 (ii) 3 (iii) 13 (iv) 2
2. Isotonic solution have the same:
(i)Density (ii) refractive index (iii) osmotic pressure (iv) volume
3. Van’t Hoff factor for KCl solution assuming the complete dissociation
is :
(i)1 (ii) 2 (iii) 0.5 (iv) 1.5
4. Van’t Hoff factor for K2SO4 solution , assuming complete ionization
is :
(i)1 (ii) 3 (iii) 13 (iv) 2
5. The boiling point of an azeotropic mixture of water and ethanol
is less than that of water and ethanol. The mixture shows
(i) no deviation from Raoult’s Law.
(ii) positive deviation from Raoult’s Law.
(iii) negative deviation from Raoult’s Law.
(iv) that the solution is unsaturated.
6. Which has the lowest boiling point at 1 atm pressure?
(i) 0.1 M KCl (ii) 0.1 M Urea (iii) 0.1 M CaCl2 (iv) 0.1 M A1Cl3
7. Osmotic pressure of a solution is 0.0821 atm at a temperature
of 300 K. The concentration in moles/litre will be
(i) 0.33 (ii) 0.666 (iii) 0.3 × 10-2 (iv) 3
8. People add sodium chloride to water while boiling eggs. This is
to:
(i) decrease the boiling point
(ii) increase the boiling point
(iii) prevent the breaking of eggs
(iv) make eggs tasty
9. The molal elevation constant depends upon
(i) nature of solute.
(ii) nature of the solvent.
(iii) vapour pressure of the solution.
(iv) enthalpy change
10. If a molecule AB undergoes dimerization in Benzene, its Van’t Hoff
factor is found to be 0.60. The degree of dissociation of AB is
(i) 20% (ii) 60% (iii) 80% (iv) 50%
Each question consists of two statements, namely, Assertion (A) and
Reason (R).For selecting the correct answer, use the following code:
(a) Both Assertion (A) and Reason (R) are the true and Reason (R) is a
correct explanation of Assertion (A).
(b) Both Assertion (A) and Reason (R) are the true but Reason (R) is not a
correct explanation of Assertion (A).
(c) Assertion (A) is true and Reason (R) is false.
(d) Assertion (A) is false and Reason (R) is true.
11 Assertion : If a liquid solute more volatile than the solvent is added to
the solvent, the vapour pressure of the solution may increase i.e.
ps > po.
Reason : In the presence of a more volatile liquid solute, only the
solute will form the vapours and solvent will not.
12 Assertion : Azeotropic mixtures are formed only by non-ideal
solutions and they may have boiling points either greater than both the
components or less than both the components.
Reason : The composition of the vapour phase is same as that of the
liquid phase of an azeotropic mixture.
13 Assertion :When a solution is separated from the pure solvent by a
semi- permeable membrane, the solvent molecules pass through it
from pure solvent side to the solution side
Reason : Diffusion of solvent occurs from a region of high
concentration solution to a region of low concentration solution.
14 Assertion : When NaCl is added to water a depression in freezing
point is observed.
Reason : The lowering of vapour pressure of a solution causes
depression in the freezing point.
15 (i) Ishan’s automobile radiator is filled with 1.0kg of water. How
many grams of ethylene glycol must Ishan add to get the freezing
point of solution lowered to 2.8 oC. Kf for water is 1.86 K kg mol-1.
(ii) What type of deviation from Raoult’s Law is shown by ethanol
and acetone mixture? Give reason
