No.
of Printed Pages : 14 BCHCT-131
BACHELOR OF SCIENCE (GENERAL)
(BSCG)
Term-End Examination
December, 2022
BCHCT-131 : ATOMIC STRUCTURE, BONDING,
GENERAL ORG ANIC CHEMISTRY AND
ALIPHATIC HYDRO CARBONS
Time : 2 Hours Maximum Marks : 50
Note : (i) This question paper contains two Parts.
(ii) Students are required to answer both the
two Parts in two separate answer books.
Write your Enrolment number, course
code and part title clearly on each of the
two answer books.
(iii) Marks are indicated against each
question.
P. T. O.
[2] BCHCT-131
Part—I (Marks : 25)
Note : Attempt any five questions from question
nos. 1 to 7.
1. (a) Calculate the wave number, and
frequency of a light of wavelength,
300 nm . 2
(b) What is a well-behaved wave function ?
Explain using suitable diagram. 3
2. (a) Find the values of principal, azimuthal and
magnetic quantum numbers of an electron
in a 4d orbital. 3
(b) Write the electronic configuration of the
elements La (atomic no. 57) and Sr (atomic
no. 38). 2
3. (a) Justify the fact that formation of Li+ ion is
easier than that of Ne+ ion. 2
(b) Give any three limitations of Bohr’s theory.
3
4. (a) The ionic radii of Li+ and Be2+ are 60 p.m.
and 31 p.m. respectively though they are
isoelectronic. Give reason. 1
[3] BCHCT-131
(b) What is photoelectric effect ? How did
Einstein explain it ? 4
5. (a) State Hund’s rule for filling of electrons in
orbitals. Give its reason. 2
(b) Write the molecular orbital configuration
of O 2 molecule and calculate its bond order.
3
6. (a) The charge on H atom in HCl is
2.8 × 10–20 C and the bond length is
127.5 p.m. Calculate the dipole moment of
HCl in Cm and also in Debye units. 2
(b) Using VSEPR theory, predict the shape of
IF 5 molecule. 3
7. (a) Write resonance structures of nitrate ion. 3
(b) Draw suitable diagrams for the bonding
and anti-bonding molecular orbitals formed
from overlap of two p y orbitals. 2
P. T. O.
[4] BCHCT-131
Part—II (Marks : 25)
Note : Attempt any five questions from question
nos. 8 to 14.
8. (a) What are Bronsted acids and bases ? Give
one example of each. 3
(b) Which of the following compounds can
exhibit geometrical isomerism ? 1
(i) CHCl = CHCl
(ii) CH 2 = CHCl
(c) Assign Z/E configuration to the following
compound : 1
CH3 OH
C C
H 5C 2 OCH3
9. (a) Give the name of type of the each reaction
shown below : 3
(i)
CH 2 X CH 2 X CH3
(ii)
CH 2 CHCH3 CH C CH3
(iii) CH 2 CH CH 2 X
(b) Give one example each of position isomers
and chain isomers. 2
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10. (a) Which of the following compounds can
have diastereoisomers ? Write the Fischer
projections of the diastereoisomers : 3
(i) CH 3 CHOHCOOH
(ii) COOH – CHOH – CHOH – COOH
(b) Why is the boat conformation of
cyclohexane less stable than the chair
conformation ? 2
11. (a) Define the following terms : 3
(i) Racemic mixture
(ii) Racemisation
(iii) Resolution
(b) Which is aromatic— cyclopentadienyl
carbanion or cyclopentadienyl carbocation ?
Give reason. 2
12. (a) Define the terms (i) nucleophile and (ii)
electrophile giving one example of each. 3
(b) Write the structures of the tautomers for
the following : 2
(i) CH 2 C CH3
|
OH
O
||
(ii) CH3 CH 2 C C(CH3 )3
P. T. O.
[6] BCHCT-131
13. (a) Write the product of addition reaction of
HBr to propene. What product will be
formed when this reaction is done in the
presence of peroxide ? 2
(b) Write the product of ozonolysis of
CH3 C C CH3 . 1
(c) How is cyclohexene prepared using Diels-
Alder reaction ? 2
14. (a) Arrange the following carbocations in an
decreasing order of their stability : 3
RCH 2, RCH CH CH 2 , R 2CH
Explain your answer.
(b) Write one reaction each for the
following : 2
(i) Addition polymerisation
(ii) Condensation polymerisation
