No.

of Printed Pages : 8 BCHCT-131

om
BACHELOR OF SCIENCE (GENERAL)
(BSCG)
Term-End Examination

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February, 2021

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BCHCT-131 : ATOMIC STRUCTURE, BONDING,

u
GENERAL ORGANIC CHEMISTRY AND
ALIPHATIC HYDROCARBONS

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Time : 2 hours en Maximum Marks : 50
Note :
(i) Attempt any five questions from Part A and any five
questions from Part B on separate answer-sheets.
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(ii) All questions carry equal marks.
ign

PART A (Maximum marks : 25)

1. (a) With the help of a suitable diagram, briefly

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explain Sommerfeld modification to Bohr

Atom Model. 4
UA

(b) Write the electronic configuration of

chromium. (Atomic No. of Cr = 24) 1
NO

2. (a) What are the observed results of black body

radiation experiment ? 3
(b) State Hund’s rule. What is the reason
IG

behind this rule ? 2

BCHCT-131 1 P.T.O.
 3. (a) What is a well behaved wave function ?
Illustrate using suitable diagram/s. 3

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(b) Write the resonance structures of hydrogen
chloride. Which of these structures is the
most important one ? 2

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4. (a) Draw the shapes of three p-orbitals with

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appropriate labelling. 3
(b) Which one has higher lattice energy — KF or

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NaF ? Give reason why. 2

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5. (a) (i) Name the spectral lines of the atomic
spectrum of hydrogen which appear in
en
the visible region. 1
(ii) What are matter waves ? 1
(iii) Give the significance of  2. 1
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(b) What is the hybridisation of each of
the carbon atoms present in the compound
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HC  C – CH = CH2 ? 2

6. (a) Compare any four properties of ionic and

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covalent compounds. 4
(b) Why is the dipole moment of BF3 zero ? 1
UA

7. (a) Write the molecular orbital configurations

2–
of O2 and O 2 . Also calculate their bond
NO

orders. 4
(b) How many chloride ions are present around
a sodium ion in the sodium chloride crystal ? 1
IG

BCHCT-131 2
 PART B (Maximum marks : 25)

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8. (a) Draw the enantiomers of 2-butanol. 2

(b) Which one will have lower pKa value —

chloroethanoic acid or iodoethanoic acid ?

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Give reason for your answer. 3

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9. (a) Write the geometrical isomers of

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HOOC – CH = CH – COOH. How can you
differentiate between the isomers using a

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chemical reaction ? 3

(b)
en
Why is aniline less basic than ammonia ?
Explain. 2
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10. (a) Write the mechanism of the reaction
between ethyne and HBr. Also name the
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product formed. 3

(b) Which one of the following is more stable

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and why ? 2
H 2 CCH3 or (CH3 )2 CH
UA

11. (a) Give the products formed by the

Wurtz reaction involving bromoethane and
NO

1-bromopropane. 3

(b) What is pericyclic addition ? Illustrate with

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the help of a suitable example. 2

BCHCT-131 3 P.T.O.
 12. (a) Write the mechanism of the reaction of

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propene with HBr in the presence of a
peroxide. 3

(b) Write the structure of naphthalene and

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number of carbon atoms present in it. 2

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13. (a) Draw various conformations of cyclohexane. 4

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(b) State Hückel’s rule. 1

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14. (a) Write the mechanism of Wittig reaction.
en 4

(b) Write the IUPAC name of the following

compound : 1
m
ign
ss
UA
NO
IG

BCHCT-131 4
 ~r.gr.EM.gr.Q>r.-131

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{dkmZ ñZmVH$ (gm_mÝ`)
(~r.Eg.gr.Or.)
gÌm§V narjm

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\$adar, 2021

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~r.gr.EM.gr.Q>r.-131 : na_mUw g§aMZm, Am~§YZ,

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gm_mÝ` H$m~©{ZH$ agm`Z Am¡a Eo{b\¡${Q>H$ hmBS´>moH$m~©Z

g_` : 2 KÊQ>o
tG A{YH$V_ A§H$ : 50
en
ZmoQ> :
(i) AbJ-AbJ CÎma-nwpñVH$mAm| na ^mJ H$ go {H$Ýht nm±M àíZm|
m
Am¡a ^mJ I go {H$Ýht nm±M àíZm| Ho$ CÎma Xr{OE &
(ii) g^r àíZm| Ho$ A§H$ g_mZ h¢ &
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^mJ H$ (A{YH$V_ A§H$ : 25)

ss

1. (H$) C{MV {MÌ H$s ghm`Vm go, ~moa Ho$ na_mUw _m°S>b _|
UA

gmo_a\o$ëS> g§emoYZ H$s g§{jßV ì`m»`m H$s{OE & 4

(I) H«$mo{_`_ H$m BboŠQ´>m°{ZH$ {dÝ`mg {b{IE & (Cr H$m

NO

na_mUw H«$_m§H$ = 24) 1

2. (H$) H¥$pîUH$m {d{H$aU à`moJ Ho$ Š`m ào{jV n[aUm_ h¢ ? 3

IG

(I) hþ§S> {Z`_ {b{IE & Bg {Z`_ Ho$ nrN>o Š`m H$maU h¡ ? 2

BCHCT-131 5 P.T.O.
 3. (H$) EH$ g§VmofOZH$ ì`dhm[aH$ Va§J \$bZ Š`m hmoVm
h¡ ? C{MV {MÌ/{MÌm| Ûmam Xem©BE & 3

om
(I) hmBS´>moOZ ŠbmoamBS> H$s AZwZmX g§aMZmE± {b{IE &
BZ_| go H$m¡Z-gr g§aMZmE± g~go A{YH$ _hÎdnyU© h¡ ? 2

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4. (H$) C{MV Zm_m§H$Z Ho$ gmW VrZ p-H$jH$m| H$s AmH¥${V`m±
Amao{IV H$s{OE & 3

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(I) KF `m NaF, _| go {H$gH$s OmbH$ D$Om© A{YH$ h¡ ?

u
H$maU ~VmBE {H$ Š`m| & 2

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5. (H$) (i) hmBS´>moOZ Ho$ na_mUw ñnoŠQ´>_ _| CZ ñnoŠQ´>_r
aoImAm| Ho$ Zm_ ~VmBE Omo Ñí` joÌ _|
{XImB© XoVr h¢ &
en 1
(ii) Ðì` Va§J| Š`m hmoVr h¢ ? 1
(iii)  2 H$s gmW©H$Vm ~VmBE & 1
m
(I) `m¡{JH$ HC  C – CH = CH2 _| CnpñWV àË`oH$
H$m~©Z na_mUw H$m g§H$aU Š`m h¡ ? 2
ign

6. (H$) Am`Zr Am¡a ghg§`moOH$ `m¡{JH$m| Ho$ {H$Ýht Mma

JwUY_mªo H$s VwbZm H$s{OE & 4
ss

(I) BF3 H$m {ÛY«wd AmKyU© eyÝ` Š`m| hmoVm h¡ ? 1

Am¡a O 22 – Ho$ {bE AUw H$jH$ {dÝ`mg

UA

7. (H$) O2
{b{IE & CZHo$ Am~§Y H«$_m| H$mo ^r n[aH${bV
H$s{OE & 4
NO

(I) gmo{S>`_ ŠbmoamBS> OmbH$ ({H«$ñQ>b) _| EH$ gmo{S>`_

Am`Z Ho$ Mmam| Amoa {H$VZo ŠbmoamBS> Am`Z CnpñWV
IG

hmoVo h¢ ? 1

BCHCT-131 6
 ^mJ I (A{YH$V_ A§H$ : 25)

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8. (H$) 2-ã`yQ>oZm°b Ho$ EZ¡pÝQ>Amo_am| H$mo Amao{IV H$s{OE & 2

(I) ŠbmoamoEWoZmoBH$ Aåb `m Am`moS>moEWoZmoBH$ Aåb _| go

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{H$gH$m pKa _mZ H$_ hmoJm ? AnZo CÎma Ho$ {bE
H$maU ~VmBE & 3

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9. (H$) `m¡{JH$ HOOC – CH = CH – COOH Ho$ {bE

u
Á`m{_Vr` g_md`d {b{IE & Amn BZ g_md`dm| _|

tG
{H$gr amgm`{ZH$ A{^{H«$`m Ûmam {H$g àH$ma A§Va
en
H$a|Jo ? 3

(I) Eo{ZbrZ A_mo{Z`m go H$_ jmar` Š`m| hmoVr h¡ ?

m
ì`m»`m H$s{OE & 2
ign

10. (H$) EWmBZ Am¡a HBr Ho$ ~rM A{^{H«$`m H$s {H«$`m{d{Y
{b{IE & àmßV CËnmX H$m Zm_ ^r {b{IE & 3
ss

(I) {ZåZ{b{IV _| go H$m¡Z-gm EH$ A{YH$ ñWm`r h¡ Am¡a

Š`m| ? 2
UA

H 2 CCH3 `m (CH3 )2 CH

11. (H$) ~«mo_moEWoZ Am¡a 1-~«mo_moàmonoZ H$s dwQ²>©µO A{^{H«$`m

NO

Ûmam ~Zo CËnmX {b{IE & 3

(I) n[aa§^Z g§H$bZ Š`m hmoVm h¡ ? C{MV CXmhaU H$s

IG

ghm`Vm go Xem©BE & 2

BCHCT-131 7 P.T.O.
 12. (H$) nam°ŠgmBS> H$s CnpñW{V _| àmonrZ H$s HBr Ho$ gmW

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A{^{H«$`m H$s {H«$`m{d{Y {b{IE & 3

(I) Z¡µâWbrZ H$s g§aMZm {b{IE Am¡a Cg_| CnpñWV

H$m~©Z na_mUwAm§o H$mo g§»`m§{H$V H$s{OE & 2

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13. (H$) gmBŠbmoh¡ŠgoZ Ho$ {d{^Þ H$m°Ý\$m°_}eZm| H$mo Amao{IV
H$s{OE & 4

u
(I) hH$b {Z`_ {b{IE & 1

14.

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(H$) {d{Q>J A{^{H«$`m H$s {H«$`m{d{Y {b{IE & 4
en
(I) {ZåZ{b{IV `m¡{JH$ H$m AmB©.`y.nr.E.gr. Zm_
{b{IE : 1
m
ign
ss
UA
NO
IG

BCHCT-131 8
 No. of Printed Pages : 12 BCHCT-131

om
BACHELOR OF SCIENCE (GENERAL)
(BSCG)
Term-End Examination

.c
June, 2022

ru
BCHCT-131 : ATOMIC STRUCTURE, BONDING,

u
GENERAL ORGANIC CHEMISTRY AND
ALIPHATIC HYDROCARBONS

tG
Time : 2 hours en Maximum Marks : 50

Note : (i) Attempt any five questions from Part A and

any five questions from Part B on separate
m
answer sheets.
(ii) All questions carry equal marks.
ign

PART A (Maximum Marks : 25)

ss

1. (a) Discuss the contribution of Rutherford in

explaining the structure of an atom. 3
UA

(b) Which of the following molecules has a

dipole moment, CH4 or NH3 ? Give reason. 1
NO

(c) Name the force by which the molecules are

held together in the crystal structure of a
compound. 1
IG

BCHCT-131 1 P.T.O.
 2. (a) Why is oxygen paramagnetic ? Explain
using molecular orbital theory. 3

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(b) State the type of hybridisation present in
benzene and SF4 molecules. 2

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3. (a) Write the steps used in valence bond
method to arrive at the structure of a

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molecule. 3

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(b) Classify the following statements as true or
false. Also give reason in support of your
en
answer. 2
(i) Ionisation energy of sodium is less
than that of magnesium.
m
(ii) First ionisation energy of magnesium
is more than its second ionisation
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energy.
ss

4. (a) Write all steps to obtain the Lewis

structure of CO2. 3
UA

(b) Briefly explain the photoelectric effect. How

did Einstein explain it ? 2
NO

5. Name the four quantum numbers of an electron

and give their significance. What is Pauli’s
IG

Exclusion Principle ? 5

BCHCT-131 2
 6. (a) Explain the difference between a covalent

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and a coordinate covalent bond with a
suitable example. 3
(b) Write the electronic configurations of

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Cr (At. No. = 24) and Ag (At. No. = 47). 2

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7. (a) Explain the significance of  and 2. 2

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(b) Give the characteristics of a well-behaved

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wave function. Draw a suitable diagram for
the well-behaved wave function.
en 3
m
ign
ss
UA
NO
IG

BCHCT-131 3 P.T.O.
 PART B (Maximum Marks : 25)

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8. (a) What is the product of Kolbe’s electrolysis
of sodium acetate ? Write the reaction and
its mechanism. 3

.c
(b) How will you convert 2-pentyne to cis and
trans-2-pentene ? 2

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9. (a) Write the products of oxidative ozonolysis of

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2-methyl-2-butene. 2

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(b) Arrange the following compounds in the
increasing order of their acidity and give
reason for answer : 3
en
CH3CHCH2COOH, CH3CH2CHCOOH,
| |
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Cl Cl

ClCH2CH2CH2COOH
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10. (a) Which one of the following compounds will

exibit optical activity and why ?
ss

OH
|
UA

(i) CH3CHCOOH
(ii) HOOC(CH2)2COOH
NO

Draw two Fischer projections of

compound (i). 3

(b) How will you prepare 1-hexyne from

IG

ethyne ? 2

BCHCT-131 4
 11. What are electrophiles and nucleophiles ? Give

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one example each of (i) a neutral electrophile,
(ii) a neutral nucleophile, and (iii) a charged
electrophile. 5

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12. (a) Explain Saytzeff ’s rule with the help of a
suitable example. 3

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(b) Write the products formed by the reaction of

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HBr and propene when (i) no peroxide is
present, and (ii) in the presence of peroxide.
en 2

13. (a) Draw the conformations of cyclohexane.

Comment on their relative stabilities. 3
m

(b) How are straight chain alkanes converted to

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branched chain alkanes ? What is the

importance of this reaction ? 2
ss

14. (a) Assign Z or E configuration to the following

UA

compounds and explain your answer : 3

NO
IG

BCHCT-131 5 P.T.O.
 (b) Which of the following are aromatic in

om
nature ?

.c
u ru
tG
en
Give reason in support of your answer. 2
m
ign
ss
UA
NO
IG

BCHCT-131 6
 ~r.gr.EM.gr.Q>r.-131

om
{dkmZ ñZmVH$ (gm_mÝ`)
(~r.Eg.gr.Or.)
gÌm§V narjm

.c
OyZ, 2022

ru
~r.gr.EM.gr.Q>r.-131 : na_mUw g§aMZm, Am~§YZ,
gm_mÝ` H$m~©{ZH$ agm`Z Am¡a Eo{b\¡${Q>H$ hmBS´>moH$m~©Z

u
tG
g_` : 2 KÊQ>o A{YH$V_ A§H$ : 50

ZmoQ> : (i) AbJ-AbJ CÎma-nwpñVH$mAm| _| ^mJ H$ go {H$Ýht nm±M

en
àíZm| Am¡a ^mJ I go {H$Ýht nm±M àíZm| Ho$ CÎma Xr{OE &
(ii) g^r àíZm| Ho$ A§H$ g_mZ h¢ &
m

^mJ H$ (A{YH$V_ A§H$ : 25)

ign

1. (H$) na_mUw H$s g§aMZm H$s ì`m»`m H$aZo _| aXa\$moS>© Ho$

`moJXmZ H$s MMm© H$s{OE & 3
ss

(I) {ZåZ{b{IV _| go {H$g AUw H$m {Û-Y«wd AmKyU© h¡ ?

UA

CH4 `m NH3

H$maU ^r Xr{OE & 1

NO

(J) Cg ~b H$m Zm_ ~VmBE {OgHo$ Ûmam {H$gr `m¡{JH$

IG

H$s {H«$ñQ>b g§aMZm _| AUw Amng _| Ow‹S>o hmoVo h¢ & 1

BCHCT-131 7 P.T.O.
 2. (H$) Am°ŠgrOZ AZwMw§~H$s` Š`m| hmoVr h¡ ? AUw H$jH$

om
{gÕm§V Ho$ Cn`moJ Ûmam ì`m»`m H$s{OE & 3

(I) ~oݵOrZ Am¡a SF4 AUwAm| _| CnpñWV g§H$aU Ho$

àH$ma H$mo {b{IE & 2

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3. (H$) g§`moOH$Vm Am~§Y {d{Y Ho$ AZwgma {H$gr AUw H$s

ru
g§aMZm {ZYm©[aV H$aZo Ho$ MaUm| H$mo {b{IE & 3

u
(I) {ZåZ{b{IV H$WZm| H$mo ghr Am¡a JbV Ho$ ê$n _|

tG
dJuH¥$V H$s{OE & AnZo CÎma H$s nw{îQ> Ho$ {bE H$maU
^r Xr{OE & 2
en
(i) gmo{S>`_ H$s Am`ZZ D$Om© _¡½Zr{e`_ H$s
Am`ZZ D$Om© go H$_ hmoVr h¡ &
m

(ii) _¡½Zr{e`_ H$s àW_ Am`ZZ D$Om© CgH$s

ign

{ÛVr` Am`ZZ D$Om© go A{YH$ hmoVr h¡ &

4. (H$) CO2 H$s byBg g§aMZm àmßV H$aZo Ho$ g^r MaUm|
ss

H$mo {b{IE & 3

UA

(I) àH$me-{dÚwV² à^md H$s g§{jßV ì`m»`m H$s{OE &

AmBÝñQ>mBZ Zo BgH$s ì`m»`m {H$g àH$ma H$s ? 2
NO

5. {H$gr BboŠQ´>m°Z Ho$ {bE Mma Šdm§Q>_ g§»`mAm| Ho$ Zm_

~VmBE Am¡a CZH$s gmW©H$Vm {b{IE & nmCbr AndO©Z
IG

{gÕm§V Š`m hmoVm h¡ ? 5

BCHCT-131 8
 6. (H$) C{MV CXmhaU Ûmam ghg§`moOH$ Am~§Y Am¡a
Cnghg§`moOH$ Am~§Y _| A§Va H$s ì`m»`m H$s{OE & 3

om
(I) Cr (na_mUw H«$_m§H$ = 24) Am¡a Ag (na_mUw H«$_m§H$
= 47) Ho$ {bE BboŠQ´>m°{ZH$ {dÝ`mg {b{IE & 2

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ru
7. (H$)  Am¡a 2 H$s gmW©H$Vm H$s ì`m»`m H$s{OE & 2
(I) {H$gr g§VmofOZH$ ì`mdhm[aH$ Va§J \$bZ Ho$ JwUY_©

u
~VmBE & g§VmofOZH$ ì`mdhm[aH$ Va§J \$bZ Ho$ {bE

tG
C{MV {MÌ Amao{IV H$s{OE & 3
en
m
ign
ss
UA
NO
IG

BCHCT-131 9 P.T.O.
 ^mJ I (A{YH$V_ A§H$ : 25)

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8. (H$) gmo{S>`_ EogrQ>oQ> Ho$ H$moë~o {dÚwV²-AnKQ>Z go Š`m
CËnmX àmßV hmoVm h¡ ? BgH$s A{^{H«$`m Am¡a
{H«$`m{d{Y {b{IE & 3

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(I) Amn 2-noÝQ>mBZ H$mo {gg Am¡a Q´>mÝg-2-noÝQ>rZ _| {H$g

ru
àH$ma ê$nm§V[aV H$a|Jo ? 2

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9. (H$) 2-_o{Wb-2-ã`yQ>rZ Ho$ Am°ŠgrH$mar AmoµOmoZmo{b{gg Ho$
CËnmX {b{IE & 2

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(I) {ZåZ{b{IV `m¡{JH$m| H$mo CZH$s AåbVm Ho$ ~‹T>Vo hþE
en
H«$_ _| ì`dpñWV H$s{OE Am¡a AnZo CÎma Ho$ {bE
H$maU ~VmBE : 3
m
CH3CHCH2COOH, CH3CH2CHCOOH,
| |
Cl Cl
ign

ClCH2CH2CH2COOH
ss

10. (H$) {ZåZ{b{IV _| go H$m¡Z-gm `m¡{JH$ Y«wdU KyU©H$Vm

àX{e©V H$aVm h¡ Am¡a Š`m| ?
OH
UA

|
(i) CH3CHCOOH
NO

(ii) HOOC(CH2)2COOH
`m¡{JH$ (i) Ho$ {bE Xmo {\$ea àjon Amao{IV
H$s{OE & 3
IG

(I) Amn EWmBZ go 1-h¡ŠgmBZ {H$g àH$ma ~ZmE±Jo ? 2

BCHCT-131 10
 11. BboŠQ´>m°ZñZohr Am¡a Zm{^H$ñZohr Š`m hmoVo h¢ ? {ZåZ{b{IV
Ho$ {bE EH$-EH$ CXmhaU Xr{OE : 5

om
(i) EH$ CXmgrZ BboŠQ´>m°ZñZohr
(ii) EH$ CXmgrZ Zm{^H$ñZohr

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(iii) EH$ Amdo{eV BboŠQ´>m°ZñZohr

12. (H$) C{MV CXmhaU H$s ghm`Vm go g¡ËOoµ\$ {Z`_ H$s

ru
ì`m»`m H$s{OE & 3

u
(I) àmonrZ H$s HBr Ho$ gmW A{^{H«$`m go ~Zo CËnmXm| H$mo
{b{IE O~ 2

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(i) H$moB© nam°ŠgmBS> CnpñWV Z hmo, Am¡a
en
(ii) H$moB© nam°ŠgmBS> CnpñWV hmo &
13. (H$) gmBŠbmoh¡ŠgoZ Ho$ H$m°Ýµ\$m°_}eZm| H$mo Amao{IV
m
H$s{OE & CZHo$ Amno{jH$ ñWm{`Ëd na {Q>ßnUr
H$s{OE & 3
ign

(I) G$Ow ûm¥§Ibm EoëHo$Zm| H$mo em{IV ûm¥§Ibm EoëHo$Zm| _|

{H$g àH$ma n[ad{V©V {H$`m Om gH$Vm h¡ ? Bg
A{^{H«$`m H$m Š`m _hÎd h¡ ? 2
ss

14. (H$) {ZåZ{b{IV `m¡{JH$m| H$m Z `m E {dÝ`mg {ZYm©[aV

UA

H$s{OE Am¡a AnZo CÎma H$s ì`m»`m H$s{OE : 3

NO
IG

BCHCT-131 11 P.T.O.
 (I) {ZåZ{b{IV _| go H$m¡Z-go àH¥${V _| Eoamo_¡{Q>H$ h¢ ?

.c om
u ru
tG
AnZo CÎma H$s nw{îQ> Ho$ {bE H$maU Xr{OE &
en 2
m
ign
ss
UA
NO
IG

BCHCT-131 12
 No. of Printed Pages : 14 BCHCT-131

om
BACHELOR OF SCIENCE (GENERAL)
(BSCG)

u.c
Term-End Examination

ur
December, 2022

tG
BCHCT-131 : ATOMIC STRUCTURE, BONDING,
GENERAL ORGANIC CHEMISTRY AND
en
ALIPHATIC HYDROCARBONS

Time : 2 Hours Maximum Marks : 50

m
ign

Note : (i) This question paper contains two Parts.

(ii) Students are required to answer both the

two Parts in two separate answer books.
ss

Write your Enrolment number, course

UA

code and part title clearly on each of the

two answer books.
NO

(iii) Marks are indicated against each

question.
IG

P. T. O.
 [2] BCHCT-131

Part—I (Marks : 25)

Note : Attempt any five questions from question

om
nos. 1 to 7.

1. (a) Calculate the wave number, ν and

u.c
frequency of a light of wavelength,
λ =300 nm . 2

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(b) What is a well-behaved wave function ?

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Explain using suitable diagram. 3

2. (a) Find the values of principal, azimuthal and

en
magnetic quantum numbers of an electron
in a 4d orbital. 3
m

(b) Write the electronic configuration of the

ign

elements La (atomic no. 57) and Sr (atomic

no. 38). 2
ss

3. (a) Justify the fact that formation of Li+ ion is

easier than that of Ne+ ion. 2
UA

(b) Give any three limitations of Bohr’s theory.

3
NO

4. (a) The ionic radii of Li+ and Be2+ are 60 p.m.

and 31 p.m. respectively though they are
IG

isoelectronic. Give reason. 1

 [3] BCHCT-131

(b) What is photoelectric effect ? How did

om
Einstein explain it ? 4

5. (a) State Hund’s rule for filling of electrons in

orbitals. Give its reason. 2

u.c
(b) Write the molecular orbital configuration
of O 2 molecule and calculate its bond order.

ur
3

tG
6. (a) The charge on H atom in HCl is
2.8 × 10–20 C and the bond length is
en
127.5 p.m. Calculate the dipole moment of
HCl in Cm and also in Debye units. 2
m

(b) Using VSEPR theory, predict the shape of

ign

IF 5 molecule. 3

7. (a) Write resonance structures of nitrate ion. 3

ss

(b) Draw suitable diagrams for the bonding

and anti-bonding molecular orbitals formed
UA

from overlap of two p y orbitals. 2

NO
IG

P. T. O.
 [4] BCHCT-131

Part—II (Marks : 25)

om
Note : Attempt any five questions from question
nos. 8 to 14.

u.c
8. (a) What are Brö nsted acids and bases ? Give
one example of each. 3

ur
(b) Which of the following compounds can
exhibit geometrical isomerism ? 1

(i) CHCl = CHCl

tG
en
(ii) CH 2 = CHCl
(c) Assign Z/E configuration to the following
m

compound : 1
ign

CH3 OH
C=C
H 5C 2 OCH3
ss

9. (a) Give the name of type of the each reaction

shown below : 3
UA

(i)
→ CH X − CH X − CH
2 2 3
(ii)
=
CH 2 CHCH3 → CH ≡ C − CH3
NO

(iii)
 =
→ CH 2 CH − CH 2 X

(b) Give one example each of position isomers

IG

and chain isomers. 2

 [5] BCHCT-131

10. (a) Which of the following compounds can

have diastereoisomers ? Write the Fischer

om
projections of the diastereoisomers : 3
(i) CH 3 CHOHCOOH

u.c
(ii) COOH – CHOH – CHOH – COOH
(b) Why is the boat conformation of
cyclohexane less stable than the chair

ur
conformation ? 2

tG
11. (a) Define the following terms : 3
(i) Racemic mixture
en
(ii) Racemisation
(iii) Resolution
m

(b) Which is aromatic— cyclopentadienyl

carbanion or cyclopentadienyl carbocation ?
ign

Give reason. 2

12. (a) Define the terms (i) nucleophile and (ii)

ss

electrophile giving one example of each. 3

(b) Write the structures of the tautomers for
UA

the following : 2
(i) CH= C − CH3
NO

2
|
OH
O
IG

||
(ii) CH3 − CH 2 − C − C(CH3 )3

P. T. O.
 [6] BCHCT-131

13. (a) Write the product of addition reaction of

HBr to propene. What product will be

om
formed when this reaction is done in the
presence of peroxide ? 2

u.c
(b) Write the product of ozonolysis of
CH3 − C ≡ C − CH3 . 1

ur
(c) How is cyclohexene prepared using Diels-
Alder reaction ? 2

tG
14. (a) Arrange the following carbocations in an
en
decreasing order of their stability : 3
+ + +
RCH 2, RCH − CH =
CH 2 , R 2CH
m

Explain your answer.

ign

(b) Write one reaction each for the

following : 2
ss

(i) Addition polymerisation

(ii) Condensation polymerisation

UA
NO
IG
 [7] BCHCT-131

BCHCT-131

om
foKku Lukrd (lkekU;) (ch- ,l&lh- th-)

u.c
l=kkar ijh{kk

fnlEcj] 2022

ur
ch-lh-,p-lh-Vh--131 % ijek.kq lajpuk] vkca/u]

tG
lkekU; dkcZfud jlk;u vkSj ,sfyiQSfVd gkbMªksdkcZu
en
le; % 2 ?k.Vs vf/dre vad % 50
m

uksV % (i) bl iz'u&i=k ds nks Hkkx gSaA

ign

(ii) Nk=kksa dks nksuksa Hkkxksa ds mÙkj nks vyx&vyx

ss

mÙkj&iqfLrdkvksa esa nsus gSaA nksuksa mÙkj&

UA

iqfLrdkvksa ij viuk vuqØekad] ikB~;Øe

dksM vkSj Hkkx dk uke lkiQ&lkiQ fyf[k,A

NO

(iii) izR;sd iz'u ds vad mlds lkeus fn, x, gSaA

IG

P. T. O.
 [8] BCHCT-131

HkkxµI (vad % 25)

om
uksV % iz'u la- 1&7 esa ls fdUgha ik¡p iz'uksa ds mÙkj
nhft,A

u.c
1- (d) rjaxnS?;Z] λ =300 nm okys izdk'k ds fy,
rjax la[;k] ν vkSj vko`fÙk ifjdfyr dhft,A

ur
2

tG
([k) larks"ktud O;kogkfjd iQyu D;k gksrk gS \
mfpr fp=k }kjk O;k[;k dhft,A 3
en
2- (d) 4 d d{kd esa mifLFkr fdlh bysDVªkWu ds fy,
m

eq[;] fnxa'kh vkSj pqacdh; DokaVe la[;kvksa ds

eku Kkr dhft,A 3
ign

([k) rRoksa La (ijek.kq la[;k 57) vkSj Sr (ijek.kq

la[;k 38) ds bysDVªkWfud foU;kl fyf[k,A 2
ss
UA

3- (d) bl rF; ds fy, mfpr dkj.k crkb, fd Ne+

vk;u dh rqyuk esa Li+ vk;u dk cuuk vklku

NO

gksrk gSA 2
IG

([k) cksg~j ds fl¼kUr dh dksbZ rhu lhek,¡ crkb,A 3

 [9] BCHCT-131

4- (d) Li+ vkSj Be2+ dh vk;fud f=kT;k,¡ Øe'k%

om
60 p.m. vkSj 31 p.m. gSa tcfd os lebysDVªkWuh

gSaA dkj.k crkb,A 1

u.c
([k) izdk'k&fo|qr izHkko D;k gksrk gS \ vkbULVhu us

ur
bldh O;k[;k fdl izdkj dh \ 4

tG
en
5- (d) d{kdksa esa bysDVªkWuksa ds Hkjus ds gqaM ds fu;e
dks fyf[k,A bldk dkj.k Hkh nhft,A 2
m
ign

([k) O2 v.kq dk v.kq d{kd foU;kl fyf[k, vkSj

bldk vkca/ Øe ifjdfyr dhft,A 3

ss
UA

6- (d) HCl esa gkbMªkstu ijek.kq ij 2.8 × 10–20 C

vkos'k gS vkSj HCl dh vkca/ yackbZ

NO

127.5 p.m. gSA HCl dk f}/zqo vk?kw.kZ Cm vkSj

fMckbZ ek=kdksa esa ifjdfyr dhft,A 2

IG

P. T. O.
 [ 10 ] BCHCT-131

([k) VSEPR fl¼kUr ds mi;ksx }kjk IF 5 v.kq dh

om
vkd`fr Kkr dhft,A 3

7- (d) ukbVªsV vk;u dh vuqukn lajpuk,¡ fyf[k,A 3

u.c
([k) nks py d{kdksa ds vfrO;kiu ls cus vkca/h vkSj

ur
vukca/h v.kq d{kdksa ds mfpr fp=k cukb,A 2

tG
en
m
ign
ss
UA
NO
IG
 [ 11 ] BCHCT-131

HkkxµII (vad % 25)

om
uksV % iz'u la- 8&14 esa ls fdUgha ik¡p iz'uksa ds mÙkj

u.c
nhft,A

ur
8- (d) czksUlVsM vEy vkSj {kkjd D;k gksrs gSa \ izR;sd

tG
dk ,d mnkgj.k nhft,A
en 3

([k) fuEufyf[kr ;kSfxdksa esa ls dkSu&lk T;kferh;

m

leko;ork iznf'kZr dj ldrk gS \ 1

ign

(i) CHCl = CHCl

(ii) CH 2 = CHCl
ss

(x) fuEufyf[kr ;kSfxd dk foU;kl fu/kZfjr

UA

Z/E

dhft, % 1
NO

CH3 OH
C=C
IG

H 5C 2 OCH3

P. T. O.
 [ 12 ] BCHCT-131

9- (d) uhps nh xbZ vfHkfØ;kvksa ds fy, izR;sd ds

om
fy, vfHkfØ;k dk izdkj crkb, % 3

u.c
(i)
→ CH X − CH X − CH
2 2 3
(ii)
=
CH 2 CHCH3 → CH ≡ C − CH3
= CH − CH 2 X

ur
(iii)
 → CH 2

tG
([k) LFkku vkSj Ük`a[kyk leko;oksa ds fy, ,d&,d

mnkgj.k nhft,A 2
en
m
10- (d) fuEufyf[kr ;kSfxdksa esa ls fdlds MkbLVhfj;ksej
ign

laHko gSa \ mu MkbLVhfj;ksejksa ds fiQ'kj iz{ksi

fyf[k, % 3
ss

(i) CH 3 CHOHCOOH
UA

(ii) COOH – CHOH – CHOH – COOH

NO

([k) lkbDyksgsDlsu dh dqlhZ dkWUiQkWesZ'ku ls ukSdk

dkWUiQkWesZ'ku de LFkk;h D;ksa gksrh gS \ 2

IG
 [ 13 ] BCHCT-131

11- (d) fuEufyf[kr inksa dks ifjHkkf"kr dhft, % 3

om
(i) jslhfed feJ.k

jslhehdj.k

u.c
(ii)

(iii) foHksnu

ur
([k) dkSu&lk ,sVkseSfVd gS& lkbDyksisUVkMkbbZukby

dkcZ&½.kk;u
tG ;k lkbDyksisUVkMkbbZukby
en
dkcZ&/uk;u \ dkj.k crkb,A 2
m

12- (d) (i) ukfHkdLusgh vkSj (ii) bysDVªkWuLusgh inksa dh

ign

ifjHkk"kk nhft, vkSj mudk ,d&,d mnkgj.k

nhft,A 3
ss

([k) fuEufyf[kr ds pyko;oksa dh lajpuk,¡ fyf[k, %

UA

2
(i) CH= C − CH3
NO

2
|
OH
O
IG

||
(ii) CH3 − CH 2 − C − C(CH3 )3

P. T. O.
 [ 14 ] BCHCT-131

13- (d) izksihu ij HBr dh ladyu vfHkfØ;k dk

om
mRikn fyf[k,A ijkWDlkbM dh mifLFkfr esa bl
vfHkfØ;k dk D;k mRikn cusxk \ 2

u.c
([k) CH3 − C ≡ C − CH3 ds vkstksuksfyfll ls
izkIr mRikn fyf[k,A 1

ur
(x) MhYl&,sYMj vfHkfØ;k ds mi;ksx }kjk

tG
lkbDyksgsDlhu dks fdl izdkj cuk;k tkrk gS \
2
en
14- (d) fuEufyf[kr dkcZ&/uk;uksa dks muds LFkkf;Ro
m
ds ?kVrs Øe esa O;ofLFkr dhft, % 3
ign

+ + +
RCH 2, RCH − CH =
CH 2 , R 2CH

vius mÙkj dh O;k[;k dhft,A

ss

([k) fuEufyf[kr izR;sd ds fy, ,d vfHkfØ;k

fyf[k, % 2
UA

(i) ladyu cgqydu

NO

(ii) la?kuu cgqydu

IG

BCHCT–131
IG
NO
UA
ss
ign
m
en
tG
ur
u.c
om
IG
NO
UA
ss
ign
m
en
tG
ur
u.c
om
IG
NO
UA
ss
ign
m
en
tG
ur
u.c
om
IG
NO
UA
ss
ign
m
en
tG
ur
u.c
om
IG
NO
UA
ss
ign
m
en
tG
ur
u.c
om
IG
NO
UA
ss
ign
m
en
tG
ur
u.c
om