Govt Of Karnalakaa

Departrnent of Pre Univeraity Education, Yadag1ri

Yadagiri District P.U. College Principals' Associalion (Regd.)
Second Year Mid Term Examination- 2016
Marks 70 Subject CHEMISTRY (34) Tirne 3 15 Hrs
INSTRUCTIONS
) The question paperhas luuI rts A hi ad
1 Al he parts are compuiur
) Write balanced chemical equations and draw fabeied diagyama w herevet usksd
) Use log lathies and siiple calculatom if necv Laty
s e ofscientific calculators is not allowed

PART-A
Answer all the questions
10X1-10
Define moiality?
State Raoulrs law for liqud-aqud salutaons
GIve an cxan1yle for a sold solutun in which wolate is gas"
What is the principle of zone tefinin
Amongcarbon and carbon monoxide which one is the hetler reducing agent for c 0 ,a

lowertemiperature ranges in blast furmace"

Name a mectal which ts refined by Van-Arkcl process
Write the general valerice shell electume configuration of 1tth group clemett
Name the solvent used in Fittig reactun
9 Which of the following Is confirmed by Tolien'u test" aldchyue or kclore
10 Arrange thc following acids in the incTCasing order of their acidic strengtha
HCOOH. CH,COOH and C,1,CO0OH

PART-B
I. Answer any five of the following questious 5N2 10
CGive any two differences between Schuttky und Frenkel defects?
12 Classify the following into n-type and p-type scrmi conductors
i silicon doped with boron )germaniun doped with arscne
13 C o m p l e t e t h e reaction: HC H0 -RMp

14 How is phenoi prepared from aniline" Write the cquation"

15 How is ethoxyethane prepred Irom cthanol? Write equation?
16 Give the gerneral cquation for the prepuratiorn of aldehydes from mitrnles' Name the rcacton
17 How are ketones prepared by using dhalk yl cautmiurn? CGive an cxample"
18 Explain Clemmensons reduction with an example?

PARTC
Answer any ive of the follow ing questions 5 X3 =15
19 Write the cquations involved in the leaching of aBumina from Bauxite ore
20 Explain the smelting of roasted coppet ore with chermical cyuations
21. Give the chemical reactions taking place durng the extraction of iron in blast furnace ut
a) combustion zone b) reduction zone and c) slag zone

Complete the following cquations? a) 2F, 1 o

2
b)HS C1
c8NH,3C1, -

23 a) Describe the preparation of oxygen with an cquation' b) Name the oxidized product forned
when ozone reacts with lead sulphide"
24 For the manufacture of ammonia a) draw flow chart b) write the chermical equation"
25 a) Explain the charring action of conc H,SO, on carbohydrate and give the cquuation
b) Complete the cquation
2PhO
Describe the manufacture of nite acd by Ostwalds methd witi cyuation
26

PTO
 FARI DV and V)
IV. X5 15
Answer any three of the follow ing
questio
27A) Caleulate the pacà ing cticicncy in f
b ive any twn diflerences between cryatalline und arptunus 01

lace centerrd cutic unit cell The cdge lehgth l

Eieicni having atomic mass o) tas
the unit cell 023x 10
the urnit cell is 4i0 pu
What
Fnd tha densty of N, 6
2
are anti ferTomagnetic nutmtatces"Give cLatipl
A ) vapour prexuure of watcr at 298K s 175i5 muniy Calrulatc the vugnonr presaire nt wale

al 93k when 25 g of ghwose in dinoved n 450 g water' (given mular iiuss ot gluceoe
and water ure INO and I8 p'meol respectively)
) What the (ant
ta i
Hofl fartor) valur lur i) Nat I1)R,S, assurring Lan irtiuti
ditution

a The biling pointofa solutsnn ofo 10500 g ofa sutntance in 15 B4 g ether was lound to t
nigher than that of ether What is molevulat weight of the substance ( h, 02 K
Rg'mol)
What hagpens lo the red blood cells it they are placed in saline water with a concentratio
ot i) grealer than OP 2
Iless than 0 9%

3 a ) Give three di fferences between non ideal solution with positive and negstive oeviathu
b) State Roult's iaw of relative lowering of vapour pressure And give its rathemalical
Cxptessio 32

. Answer any four of the following question 4X5 20

32 a) Expain the mechunisn involved in hydrolysis of methyl chlonde to methyi alcohol
b) Grve an example for i) allylic haiide i) benzylie halde i vinylic halide *

33. a) Explair1 the nature of C-X bond in haloalkanes

b) Give an cxarnple for i) Swart's reaction 11) Fittug reaction
ni preparation of LitiynArd
reagent 2+3

34.a) Write the mechanism for delydration of ethanol to ethane?

b) How do you convert phiernol into picric acid' Explain with equation

35. a) Explain Reimer Tiemann reactaon with oquation

b) Explain Williamson's cthet syntheis with an example 3+2

36.a) What is aldol condensation? Give an Cxample?

b) Explain Hell-Vohlard-Zelinsky rcaction with an cxample? +!
37. a) iHow do prepare carboxylic acids from nitirles" Explain with an example
b Write the cquations for i) Gatterman-Koxh teaction i) Rosenmund redctiom 3+2
 MID TERM EXAMINATION DECEMBER 2021
MARKS:70
CLASS: 1I PUC sUBJECT: CHEMISTRY (34)
TIME3 Hours 15 Mins.
Instructions:
1. This question paper contains four parts. All parts are compulsory.
2. Part-A carries 10 marks, Each Question carries I mark
Part-B carries 10 marks, Each Question carries 2 marks.
Part-C carries 15 marks, Each Question carries 3
Part-D carries 35 marks, Each Question carries 5 marks.
marks.
3. Write balanced chemical equations and draw diagrams wherever necessary
Use log tables and simple calculators if necessary. (Use of scientific cakulator is no

allowed)
PART A
10x 10
Answer all the questions. Each question carries one mnark
What is meant by the term "Co-ordimation nurnber" ?
Give an exanpe ofa solid solution in which the solute is a Gas

Namce an clectrolyte used in Lcad-Storage hattery

Wrte the unit for Molar conductivityof the solution.
What are isotonic solutions?
Name the transition element which does not exhibit variable oxidation states.
Write the IUPAC name for [NiCO),]

What happens when Methyl chloride reacts with potassium cyanide"

Complete the folowing reaction.
OH

(Dust)

Benzenamine
10. Write the structural forrmula of N, N-Dinmethyl
PART B
10
Five of the following questions. Each question carries 2 marks : 512-
Answer
any
Classify cach of the following
as p-type or n-type semkconductor
11. with In
IM
a) Ge dopcd M
b) Sidoped with B
State "Henry's Law" with mathematikal expression
12. Cakulate the
A solution ofCusO, is ekctrolysed lor 10 minutes witha current of 1.5 amperes.
13. 63 10u)
(Atomic wenght ofcopper
mass
of copper deposited at the cathode.
14. Mention any two dependent factors of lonic Conductance.
The limiting molar conductivity at infinite dilution () of Ca and C ons is

15.
Cakulte the linting molar condcutivity of
119.0Scm' mo and 76.3 Scm' mot' respectively
CaC
(PTO)
 16. Calcukate the 'Spin only muagnetic moment of Fe" on.
17. Explain Wurtz reaction with an
exampk.
18. Give reason "Nitrophenols are more acidic than pheno
PART C
Answer any FIVE ofthe following questions. (Each question earries 3 marks) 5x3-15

19.What are interstitial compounds ? Write any two

20.
characteristics of them
Write three balanced reactions involved in the
Chromite ore.
preparation of potassium dichromate from its
What is Lanthanoid Contraction? Write its
a) Give two reasons "Transistion metals are good
consequences
b) What is "Mischmetall"? catalysts" 2M
IM
23. Write any three
postulates of "Werner's Theory of co-ordination compounds".
24 a) Define Homoeptic complexes with one example 2M
b) Write the structure ofEDTA.
IM
With the help of Valence bond theory, explain the hybridisation, Geometry and magnetic
property of [Co(NH,),)"" ion
a) Draw a neat energy level diagram of Crystal ficld splitting in Octahedral Co-ordination
Complexes 2M
b) Give one example for Metal Carbonyls. IM

PART D
IVAnswer any THREE of the following questions. (Each question carries 5 marks):
3x51 15
) Cakulate the packimg efficicncy in sirmple cubic unit cell 3M
b) Silver forms CCP latice and edge length of its unit cell is 408.6 pm. Cakulate the density of
Silver [Atomic mass-
107.9u 2M
28Write any two diferences between Schottky defect and Frenkel defect 2M
b Cakukate the Number of partices contributed per unit cell in BCC. 2M
)What are Ferromagnetic substances IM
29. a) The boiling point of Bezene is 353.23K. When 1.80g ofnon volatile solute was disokved in
90g of Benzene, the boiling pointis raised to 354.11K. Caleulate the molar mass ofthe solute.
(Given K, for benzene 2.53 Kkg mo") 3M
b) What are the efect ofTermperature and pressure on solubility of a gas in solution 2M

3 .a) Mention any three diferences between ideal and non-ideal solutiwons 3M
b) Define "Van't Hoff factor" (). Write the value of"T for association ofmokcules 2M

T h estandardclectrode potential for Danielcellis 1.IV. Cakculatethestandard Gbs Energy

for the reaction.

Zn+Cu Zn+C 3M
b)What are 'Fuel Cells ? Write it's overal cell reaction. 2M
(P.T.O)
 Answer any FOUR ofthe following questions. (Each question carries 5 marks):
4x5 20
32a) Explain the Mechanism of S, I reaction with an example. 3M
b) Give reason "Aryl halides does not undergo Nuclkcophilic substitution reactions readily" 2M

33. a) Explain p- elimination reaction with an example 3M

b) Write Fricdal crafts alkylation of chlorobenzene. 2M
34. a) How do you prepare different types of alcobos from Grignard reagents? 3M
b) Explain "Williamson's ether synthesis" 2M
a) Explain the preparation
b) Name the following
of phenol from Cunene process with equations 3M
reactions.
OH OH
CHO
nCHCLq Na0 1M

0-CH, OCH, OCH,

CH, IM
+CH,CIAnyrenAKCL,

36. Explain the following reactions. CH,

a)R-NH, 2M

NH, , LAM 2M

c)Give one example for primary Amine IM

37. a) What is Hinsberg's reagent ? How it reacts with different types of amines. 4M
b) Give reason "Methyl amine is more basic thanammonia" IM