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30T CHEM
2020
CHEMISTRY
(Theory)
* Full Marks : 70
Pass Mark
Time : Three hours
The figures in the margin indicate full, marks
for the questions.
General Instructions :
() All questions are compulsory
(ii) Marks for each question are indicated against it.
(ii) Answers should be specific and to the point.
(iv) Question numbers 1 to 8 consist of eight very short
answer type questions and carry 1 mark each. 1x8 = 8
(v) Question numbers 9 to 18 consist of ten short answer
type questions and carry 2 marks each. 2x10 = 20
(vi) Question numbers.19 to 27 consist of nine short answer
type questions and carry 3 marks each. 3x9 =27
(vii) Question numbers 28 to 30 consist of three long answer
type questions and carry 5 marks each. 5x3 = 15
Total = 70
Contd. Choose the correct answer :
When temperature of a solution increases then —
“6 Molarity decreases and molality increases
(&) Molality decreases and molarity increases
() No change occur for both molarity and molality
(@ Molarity increases and no change in molality.
oq Bead! TR Bical ¢
cafat bi wee Bevel yf Zn™ (aq)+2Ag(s)
ae is observed when a beam of, light is passed through a colloidal
1
solution ?
ab Sart Bee Tre corres aR aAfSeICA FF aifterPFS eA?
5 Which form of the iron is the purest form of commercial iron ? 1
So Rem aerifiie aia Borel eaBaera HAC ITASCA BA?
‘Arrange the following inthe order of increasing bond dissociation
enthalpy 1
wae fara aah Rene sretaita Bal wae AEA 2
Fy, Clo, Bra, In
30T CHEM cy: 2
“gga. The Br, SO ; a. .
fou Cy HCH and CH;— CH cl which is
Zz
8
CH; CH
more reactive towards SN; reaction and why ? 1
Cant —CH,—Cl 8 CH,;— CH,— ca Cl CMGI GRACIA
CH; CH;
SN, Rita ofS Afsror AR Oe fea?
Tite the Reimer-Tiemann reaction. 1
atanebera Sferarcht fret
‘Arrange the following compounds in increasing order of their acid strength =
1
was Frarcary BE AS EPA Bel x cara 8
CH3CH,CH (Br) COOH, CH3CH(Br) CH,COOH, (CH3),CHCOOH,
CH;CH,CH,COOH
(a) Give the ‘significance of a ‘lattice point’. Which point defect increases
the density of a crystal? 141-2
cathe Rey 4 TARE Frat) HRC fy Sliea “ate aba wre yi WA?
Or / Bat
0 lo: semiconductor. Classify each of the following as being either
a p-type or an n-type semiconductor : 1+(¥2t¥2)=2
(a) Ge doped with In
(b) B doped with Si.
oie een Frat | wae Gear Fal ARCHT p- cD a n-AAN fhate FAI
@) Get In & OR FRA
(2) BS SiG UPAR
30T CHEM (3) Contd. malleable and ductile ?
””, Explain.
Yat 1-2
10. t type of solids are electrical conductors,
7 / “Tonic solids conduct electricity in molten state but not in solid state’
crea ree a rae Revs Rege aA’, aaa irs aTOARTTT A?
pasta afi ate (lonic solids) Rene aire erawre Rigor yore’ Fe cary
BES FA”! Blot FAH
11. Aefine the following terms : (any four) Yaxd=2
(i) Krafft temperature
(ii) Mole fraction
(iii) Isotonic solutions
(iv) van‘t Hoff factor
(0) Ideal solution.
aS CE FAUCTROS AAT ral ¢ (Aaceercat BrP)
@ BRS Gast
(i) TH SI
(iii) WTSS (Isotonic) Ha
(iv) OB BE BRS
(2) Sef wa
12. (a) A solution is obtained by mixin;
40% solution by mass. Calculate
in solution.
8 300g of 25% solution and 400g of
the mass) Percentage (w/z) of water
2
25% Bet 300 Sty eI 40% BEE 400 Fie §
ae 2.
FROGS eta otahe we xTeHeR] (e/w) Ref eat ee corm ta
30T CHEM [4] Or / eat
() A100 molal aqueous solution of trichloroacetic acid (CCl;COOR) is
heated to its boiling point. The solution has the boiling point of
100.18°C. Determine the van’t Hoff factor for trichloroacetic acid.
(Ky for water = 0.512K kg mol"). 2
Jae cabs aBUs 1.00 TA GAT HA IF ON Gomes AT FA
VA HAD Bors (AE 100.18° Toy BR Tab hE abut COT VF
araecel friefat Sat (AA K; = 0.512K kg mol!)
13 ie molar conductivity of a solution Explain how molar conductivity
changes with change in concentration of solution for a weak and a strong
electrolyte. 1+1=2
waist aR aet frat Ge ais ay AgeRarT abi wats ARR ST
AIS HAT: AREA ST?
19 Towing reactions occur at cathode during the electrolysis of aqueous
silver chloride. .
Ag*(aq)+e > Ag(s) E* =+0.80V
H*(aqg)+e” > 1/2 H,(g) E° =0.00V
On the basis of their standard reduction electrode potential (E*)
values, which reaction is feasible at the cathode and why ? 1
wat fae Fakes ge Rate Fears Racer acai BA)
Ag’ (aq)+e > Ag(s) E° =+0.80V
H*(aq)+e” > /2H,(g) B= 0.00V
arma Rare Reet (2°) HA FSS CHR Rit HATS AMA I ATE
fae
30T CHEM [5] Contd. State Kohlrausch law of independent migration of ions. Write an
expression for the molar conductivity of acetic acid at infinite dilution
according to Kohlrausch law. Vet Yor1
cpa are tetera PSR eva ABET Fare | PaTATA MS HCG ON A
SANS cfbfee efoua was Raker sort aC Frat |
15. (a) A reaction is first order in A and second order in B.
(a) Write the differential rate equation.
(b) How is the rate affected on increasing the concentration of B
three times ? 14+1=2
bt afr A aceICe eiet SAT STs B FICOR RET wae BA!
@) ffeabr aca aseaer 2a 3S Fr!
() Ba sie Pome 3% aH Rita aw Bera tere aa?
Or / wear
f a certain chemical reaction variation in the concentration in [R]
vs time (s) plot is given below. Yaxd=2
®
In[R]
t(s)
For this reaction
(i) What is the order of the reaction?
(ii) What is the unit of rate constant k?
(ii), Write the relationship between k and ty.
. (iv) What does the slope of the above line indicate ?
CM co oott
30TCHEM SN Nowy [6] RTCA BI APHIS FAFRPRTS HITONA Ra Cote [R] AAT A (HHS)
Ge fa wae fae we AL
In[R]
t(s)
<& Rae
(@) Rita aa fea?
(2) Randi ae as ks oer Ae
(8) kB tyyo9 Bere HAE FAT
(4) 69a GIA DI (slope) Bits fF AHI?
16. (a) t are “minerals” and “ores” ? Differentiate between them.
14+1=2
ae aie are ares fee yaoi were aes fret
Or/ war
» ©) What is roasting and calcinations ? Explain with a chemical equation
of each. 1+1=2
STR CS Wiel HH ACT? AIC Pata frat HATS Gee re |
17. Explain the bleaching action of chlorine. 2
wits Ree of aro AI
18. is
72+ reducing and Mn3* oxidizing when both have d*
: 2
configuration ?
Crt eats Mn3* Ceoue dt RemBAM Flee ACS Cr2* CH FRET HH Mn
GATS eof crgale fae
30T CHEM {7] Contd. i jon is
19, Fora first order reaction, show that time required for 99% completion 2
twice the time required for the completion of 90% of reaction.
caQeat GF, ot ere wae fees 99% red afaetar RSET 90% FIT
aieater Ail RT FOI OTF |
20. (a) What are emulsions ? What are their different types ? Give example
of each type. 141415
‘aE (emulsions) TF areal? Pea fsa sae EDI FH fe ecOITCA
cratblees Garza fa |
Or / wat
() tt is shape selective catalysis ? Describe some features of catalysis
by zéolites. iw 1+2=3
Bigs Ferber Seba Riga Fe revs at Ace Gqeba Rigas
fee TARR aft wat :
21. (a). Answer the following :
wR waa fats
@ t is lanthanide contraction? Why actinide contraction is
greater from element to element that lanthanide contraction ?
1+1=2
ACRES ARCHING FS SE? ICE ACTA BANS
RI oO Cnn ce aTIRAS FCM wa ce Bee
_ 0) 2 cats are colourless while Cu salts are coloured. Why >
. Why ? «
1
2a SRR RE CITAIGS Cu aE AEH) Riaye
30T CHEM [8] Or / Beat
(») Answer the following :
Wak SICHRGI Ges frat ¢
(Use Hund’s rule to derive the electronic configuration of Ce*
ion and calculate its magnetic moment. 141=2
ees Fae Fe ti Co nme Bega err rt ore Bae
Pan ane Fela sat
(ii) CuO) has d" configuration, while Cu (Il) had d? configuration.
Still Cu (11) is more stable in aqueous solution than Cu (1). Why ?
1
Cu (1) 4 0 Reg GIF Cu (1) 4 a? ROT BIER! wre Gale wIS
Cu (I) St Cu (I) & wee fea! Rar?
22. Answer either (a) and () or (c) and (d) :
(a) SIS (b) RAT (c) BIE (d) @ Bea aI ¢
(@) A solution of [Ni(H0),]** is green but a solution of [Ni(CN),]* is
colourless. Explain. 2
[vi(H,0),]* 320 at cba saa Re [Ni(CN),]? Fee aI eeHBR
UT FT|
@) Aefine the term ‘coordination sphere’ with one example. 1
aor Barats OS AVE) gor” a Ae Pr
(©) What are the ambidentate ligands ? Give one suitable example of
ambidentate ligand. 1+1=2
aaRcects Frteras Re catrwcte fnes abl Serge Bare frat!
30T-CHEM [9] a Contd. i i lowing
(@) How many geometrical isomers are possible in the follo fl
coordination entity ?
wae Baile aaah zee ores Facet MRO Aes?
[cr(C204).]”
23. (a) Give reasons : 14+14+1=3
aed Wofat 8
(@ C—C1 bond length in chlorobenzene is shorter than C — Cl
bond length in chloromethane.
FT oRer C— Clare Org wafer C — Cl et Oreste
pi a
ii) Haloalkanes easily dissolve in organic solvents.
. AAA TERS HIG AVIS BAYS I
(iii) The presence of nitro group (-NO3) at o/p positions increases
the reactivity of haloarenes towards nucleophilic substitution
reactions,
O/ p ERPS ARG? skis (-NO.) GaREfBer Ceerraraera BERET eae
afalie Rtas afm wa
Or / Beat
© Aknswer the following : * Wetis3
wae frateaebis Ber fey 2
() Write the mechanism of the following reaction ;
ae fsa RMR ret ¢
CH3CHLOH HS CH CH Br + HyO
30T CHEM [10] (Wy Give the structures of 4, B and C in the following reactions :
ard RAPA A, BORE C Feta sat 2 Nth
jc gsc
CHBr KC» (quills yp tN,
2. oe the main product(s) in each of the following reactions :
1414153
ware feat fracas crari ay Refseatate amie (care) Frat =
CH;
cH NOs
@ 3 —C—O—CH, +HI —>
[os
st CH;
“wo G,— crc, UO,
li]3#202/0H-
a faq. Naor
; “C,H; — OH ———_—>
>
fi]co,, H*
2 . onset
(6) How do you convert the following ? 141413
was Faia rae “RAGA ERA?
(a) Phenol to anisole
‘Aeerers iat eet,
\. (bp) Propan-2-ol to 2-methylpropan-2-ol
Soite-2-t % at 2-Reieereiote- 2-7
(©) Aniline to phenol.
efiera at Perr |
30T CHEM [11] Contd. 25.- (a)
)
26. (a)
cv
d ©)
oy.
on treatment with aqueous ammonia and
heating with Bro and KOH
formula CéH7N. Write the
3
‘An aromatic compound ‘A’
heating forms compound ‘B’ which on
forms a compound ‘C’ of molecular
structures and IUPAC names of compounds A, B and C.
eo eatate Gin ‘A’ 3 ear awa Bios Pfs +8 see FARA “B’
cb “15H BAI “B’ Bry TS KOH TCS Ta AACA “C’ AT TON BA
a TAR A LAR CoHyN 1A, BE C Cet FSIBE 1051 GI TUPAC At
‘fret
Or / @aAt
How do you convert the following ? 1+141=3
ware fata, RAHA AAS Rate
pCa to phenol Cons! i ae?
afoot oat Fre {Set
(i) Nitromethane to dimethylamine th WN
FT Rea vat weasels
Gi)_Aailine to phenylisocyanide. Len
_, Sr oat ReieraRE ARTES
Arr ing it
‘ange the following in decreasing order of the pK, values: 1
OAS
Be Bere
C,HSNH,
2HSNH2, CoHSNHCH,, (Coys). and C.AsNH>
How are vitamins classifi ?
2 ssified ? naam
coagulation of blood, fied ? Name the vitamin respon for the
14+1=2
PRD CHER wnt aah ap
x Pan SERRE CER cept FERRE
30T CHEM.
[12] Or / Beat
Write the important structural and functional differences between
DNA and RNA. 2
DNA SIs RNA 4 sida Gis ortertors ya axes ED FAT
27. (a) tis the difference between a nucleoside and a nucleotide? 1
REE oS ors AEG TaEe aterw aides ee
()) _What-type of bonding helps in stabilising the -helix structure of
Proteins ? 1
OR eacis SracH afte -ceferar aid bre fea BR Cora?
(Classify the following as addition polymer or condensation polymer.
1
wae fren aT casi wea wise fore GHARTIER |
,
(@) Teflon
Coa
(ii) Bakelite.
ARE |
28. Answer either (a) and (b) or (c) and (d) :
(a) SH® (b) AAT (c) AK (d) 4 SER FA
(a) _Gk¥e reasons :
art Heals
_ (i) Afdugh nitrogen exhibits +5 oxidation states but it does not
form pentahalide. 1
* affte AARD CTH +5 ate Cre CHART REE ofS aR AI
(ii falogens are coloured. 1
A TPRR ASH |
30T CHEM [13] 2 Contd. (iti) AH form hydrogen bond but PH3 does not.
NHy Gl G8y' Ce Tal 915A PRA vis (FE PH3 GI ATRIA!
i =2
(») Complete the following reactions : 141
ont frat Rizariag Af FIs
(I/CH 0, > ?
‘4NaCl+ MnO, + 4H,SO, > ?
(9. When HC! reacts with finely powdered iron, it forms ferrous chloride
and not ferric chloride. Why ?
cafeat BR oF eats ame HCI cH Rea aa Coe AIR FAT AS
Bi, Cate False ae xe
(2) (i) Whats the oxidation state of phosphorus in H3PO3 ? 1
HPO; © Weraty Gal GTR fea BAe
(i) How can you prepare Clp from HCI and HCl from Cly? Write
reactions only. 11-2
BAR Crees HC] 4 FA Cl OIF Cl,a At HCl eee ate act
fafa fret
29. (a) How will you convert the following ? Give equations only.
1+1=2
wre Pinta cote oiRae sate ceaa Ae a |
(Benzene to acetophenone
Fiat AAD? Fee
GW) Benzoic acid to Benzaldehyde
rere aes oa eaCTABAES |
[14] (0)
Or / wa
Although phenoxide ion has more number of resonating structures
than carboxylate ion, carboxylic acid is a stronger acid than phenol.
Why ? 2
afte Rermitu oRAE Ge cai ae ae EATER IR, Sale TABI
aoe Frets a fet os fre
An organic compound contains 69.77% carbon, 11.63% hydrogen and
Test oxygen. The molecular mass of the compound is 86. It does not
reduce Tollens’ reagent but forms an addition compound with sodium
hydrogensulphite and give positive iodoform test. On vigorous
oxidation it gives ethanoic and propanoic acid. Identify the compound
and write equations for chemical reactions involved. 3
SB THR A 69.77% TH, 11.63% BAW’ SH BIS AERA OPERA
ethee | AiSia Tiss Ta 861 S Bea Rowse Rerlte qos SE
ptan Baw comereresbe GR gar Tet a ea re Owe Ae
ryan SETA Tile Bara Z Barf os erate Sw fre CTA
fate Fa ors Ria GB ES Ase Hr
30. (oan the term copolymerisation and give one example. 1+1=2
= wa-aRATANS (copolymerisation). fF bt Sareer7y FER Fret |
OF" Why should not medicines be taken without consulting doctors ?
[e
1
aides vane faa Ted fA Catal Vw AA?
+h forces are involved in holding the drugs to the active site of
enzymes? 2
arG aa Af BAS Sa CT (drug) F a aaa ARATE AS BIS
mae ‘
Or / Beat
What is meant by the term ‘broad spectrum antibiotics’ ? Explain
with an example. 2
“fege afters ePoI’ RS aA Fee Careers Grew gaIR KraI|
x.
30T CHEM [15]
