Ltun2 Case Chebot A QP
Ltun2 Case Chebot A QP
.UNIT TEST - 2 A
Std : Long term (Batch - A) Max. Marks: 720
Test Date : 03.03.2023 CHEMISTRY & BOTANY Time : 3 Hrs.
Note :
For every correct answer four marks will be awarded. For every wrong answer one mark
will be reduced. For unanswered questions zero mark.
Choose the correct answer : 180 x 4 = 720
1. How many hydrogen bonded water 6. What is the position of the element in the
molecule(s) are associated with CuSO4.5H2O? periodic table satisfying the electronic
1) 1 2) 2 configuration (n–1)d1ns2 for n = 4?
3) 3 4) 4 1) 3rd period and 3rd group
2. In which pair, the first atom or ion is not larger 2) 4th period and 3rd group
in size than the second? 3) 3rd period and 2nd group
1) Br–, Br 2) Pb2+, Pb4+ 4) 4th period and 2nd group
3) N, P 4) N, F 7. An element ‘A’ has atomic number 56. What
3. Select the correct statement will be the formula of its halide?
1) Cl2O7 is the most acidic oxide
1) AX 2) AX2
2) Non-metallic character decreases in a
3) AX3 4) A2X3
period
8. The electron affinity for
3) BeO is a basic oxide
4) All are correct 1) Carbon is greater than oxygen
4. First and second ionization energies of 2) Fluorine is less than iodine
magnesium are 7.646 and 15.035 eV 3) Fluorine is less than chlorine
respectively. The amount of energy in kJ 4) Sulpher is less than oxygen
needed to convert all the atoms of magnesium
9. Which of the following is more stable
into Mg2+ ions present in 12 mg of magnesium
carbanion
vapour is [Given : 1 eV = 96.5 kJ mol–1]
1) 1.1 2) 2.5
1)
3) 2.0 4) 0.5
5. The lanthanide contraction is responsible for
the fact that
1) Zr and Hf have about the same radius
2)
2) Zr and Y have about the same radius
3) Zr and Nb have similar oxidation state
4) Zr and Zn have the same oxidation state
2 Test ID : 813[A]
16. IUPAC name of the compound
3)
1) 1-bromobut-2-ene
4) 2) 2-bromo-2-butene
3) 4-bromobut-2-ene
10. The volume strength of 10 N H2O2 is 4) 1-bromobut-3-ene
1) 112 2) 11.2 17. Among the following, the pair in which the
3) 0.112 4) 56 two species are not isostructural is
11. Which of the following has sp3 carbon 1) SiF4 and SF4 2) IO3− and XeO3
1) cyclo pentadiene 3) BH −4 and NH 4+ 4) PF6− and SF6
2) cyclo pentadiene anion
18. Match the column I with column II and mark
3) cyclo octatetraene the appropriate choice.
4) benzene
Column I Column II
12. Which of the following hydrides is electron-
A) C 2 H2 i) sp3d2 hybridisation
precise hydride?
1) B2H6 2) NH3 B) SF6 ii) sp3d3 hybridisation
3) H2O 4) CH4 C) SO2 iii) sp hybridisation
13. Which of the following reactions increases D) IF7 iv) sp2 hybridisation
production of dihydrogen? 1) A-i, B-iii, C-ii, D-iv
1270K
1) CH4(g) + H2O(g) Ni → CO(g) + 3H2(g)
2) A-iii, B-i, C-iv, D-ii
1270K
3) A-ii, B-iii, C-i, D-iv
2) C(s) + H2O(g) → CO(g) + H2(g) 4) A-iv, B-i, C-iii, D-ii
673K
3) CO(g) + H2O(g)
Cat. → CO2(g) + H2(g) 19. The ONO bond angle is maximum in
1270K
4) C2H6 + 2H2O 1) NO3− 2) NO +2
Ni → 2CO + 5H2
14. A fisher projection of (2R, 3S)-2,3-butanediol 3) NO −2 4) NO2
CH3 CH3
20. Which of the following compounds shows
HO H HO H
1) HO H
2) Metamerism
H OH
a) Alcohols b) Carboxylic acid
CH3 CH3
CH3 OH c) Esters d) Ethers
H OH CH3 H
3) HO 4) 1) a and d 2) b and c
H HO H
3) c and d 4) a and c
CH3 CH3
21. In which of the following molecule/ion all the
15. The ratio of σ to π-bonds in mesitylene is
bonds are not equal?
1) 3 2) 7
1) XeF4 2) BF4−
3) 5 4) 6
3) C2H4 4) SiF4
3 Test ID : 813[A]
22. Match the following correctly 27. The correct order of decreasing bond length
Detection/ Respective species of CO, CO2 and CO32− is
Estimation formed 1) CO > CO2 > CO32−
A) Lassaigne’s test of N K) [Fe(CN)5NOS]-4 2) CO32− > CO2 > CO
B) Lassaigne’s test of S L) NH3
3) CO2 > CO > CO32−
C) Duma’s method M) Fe4[Fe(CN)6]3
4) CO2 > CO32− > CO
D) Kjeldahl’s method N) N2
28. In which of the following species the bond is
1) A-K, B-M, C-L, D-N
non-directional?
2) A-M, B-K, C-L, D-N
1) NF3 2) RbCl
3) A-K, B-M, C-N, D-L
3) BeCl2 4) BCl3
4) A-M, B-K, C-N, D-L
29. Which one of the following is not an isomer of
23. What is the order of stability of N2 and its ions? 3-methyl but-1-yne
1) N 2 > N 2+ > N 2− > N 22 − 1) pent-1-yne 2) Buta-1, 3-diene
2) N +2 > N −2 > N 2 > N 22 − 3) pent-2-yne 4) penta-1, 3-diene
3) N −2 > N +2 > N 2 > N 22 − 30. The element that exhibits both electro valency
& covalency is
4) N 22 − > N −2 > N +2 > N 2
1) Ne 2) Na
24. Which type of hybridization is shown by
3) Ba 4) Cl
carbon atoms from left to right in the given
31. Which of the following is hypervalent
compound?
molecule?
CH2 = CH – C ≡ N
1) PCl5 2) PCl3
1) sp2, sp2, sp 2) sp2, sp, sp
3) H2O 4) PH3
3) sp, sp2, sp3 4) sp3, sp2, sp
32. In Kjeldahl’s method for estimation of
25. Which of the following is an addition reaction
nitrogen present in a soil sample, ammonia
1) CH3 – Cl + Aq NaOH → CH3 – OH + NaCl evolved from 0.75g of sample neutralized
dryether
2) CH3 – Cl + Na → CH3 – CH3 + NaCl 10mL of 1 M H2SO4. The percentage of
nitrogen in the soil is
3) CH2 = CH2 + HBr → CH3 – CH2 – Br
1) 37.33 2) 45.33
∆
4) CH3 – CH2 – Br + Alc. NaOH → 3) 54.33 4) 64.33
3-
CH2 = CH2 + NaBr 33. In PO4 ion, the average charge on oxygen
26. The most stable shape of ClF3 is shown by atom and P-O bond order respectively are
1) -0.75, 1.25 2) -0.75, 1
3) -0.75, 0.6 4) -3, 1.25
34. Which of the following is optically inactive?
1) Meso tartaric acid
2) Active tartaric acid
1) (i) only 2) (i) and (iii) 3) Erythro ribose
3) (ii) only 4) (iii) only
4) Threo ribose
4 Test ID : 813[A]
35. The correct order of acidic strength is 41. The number of significant figures in 2.6531 ×
1) CH3COOH < HCN < H2O < C2H5OH 104 is
2) CH3COOH > HCN > H2O > C2H5OH 1) 8 2) 7
3) HCN > CH3COOH > H2O > C2H5OH 3) 5 4) 4
4) CH3COOH > HCN > C2H5OH > H2O 42. The law of multiple proportions is illustrated
36. In Carius method of estimation of halogen by one of the following pairs
0.15 g of an organic compound gave 0.12g 1) H2S and SO2 2) NH3 and NO2
AgBr. The percentage of bromine in the
3) Na2S and Na2O 4) N2O and NO
compound is
43. In the formation of SO2 and SO3 the ratio of
1) 34.04% 2) 68.08%
the weight of oxygen which combines with
3) 12.6% 4) 48.2%
10kg sulphur is
37. Select a pair of species in which both have
different number of dative bond(s)? 1) 1 : 1 2) 3 : 2
3) 2 : 3 4) 3 : 4
1) H3O+ and NH +4
44. Which of the following has more number of
2) N2O3 and N2O5
atoms?
3) NH +4 and NO3−
1) 11.2L of SO2 at STP
4) [Cu(H2O)4]2+ and [Ni(CN)4]2- 2) 1g atom of Al
38. The correct order of lattice energy is 3) 34g of NH3
1) NaCl > MgF2 > MgO 4) 8g of O2
2) NaCl < MgF2 < MgO 45. How many moles of potassium chlorate
3) MgF2 < NaCl < MgO needed to produce 11.2 litre oxygen at STP?
4) MgO < NaCl < MgF2 1) 0.5 mol 2) 0.33 mol
39. Statement – I : Benzyl amine is less basic 3) 0.25 mol 4) 0.66 mol
than ethyl amine.
46. Hyper conjugation involves delocalization of
Statement – II : In benzyl amine phenyl
1) σ-electrons of C – H with the unshared
shows +I effect.
p-orbital
1) Both Statement-I and II are true
2) Both Statement-I and II are false 2) p-electrons with the π-electrons of C-C
bond
3) Statement-I is true and Statement-II is false
4) Statement-I is false and Statement-II is true 3) π-electrons of C = C with the unshared
40. The stability order of the following species p-orbital
4) Interaction of two π bonds (or) between a π
bond and lone pair of electrons
47. If X gms of an element ‘A’ reacts with 16 gms
of oxygen then the equivalent weight of
element ‘A’ is
X X
1) 2)
1) iv < iii < ii < i 2) i < ii < iii < iv 4 2
3) iv < iii < i < ii 4) iii < iv < ii < i 3) X 4) 2X
5 Test ID : 813[A]
14 17
48. Nitrogen has two isotopes N and N whose The velocity corresponds to x is
relative abundance are 90% and 10%
2RT 3RT
respectively, average atomic weight 1) 2)
M M
1) 14 u 2) 15 u
3) 14.5 u 4) 14.3 u 8RT 3RT
3) 4)
49. 4g of H2 and 16g of O2 is allowed to react to πM πM
form water then which of the following 55. The volume of oxygen required for complete
statement is correct? combustion of 0.25 cm3 of CH4 at STP is
1) O2 is limiting reagent 1) 0.25 cm3 2) 0.5 cm3
2) H2 is limiting reagent 3) 0.75 cm3 4) 1 cm3
3) O2 is reagent in excess
56. Among the following mixtures dipole-dipole
4) 20g water is formed
as the major interaction is present in
50. Which of the following methods of expressing
concentration varies with temperature? 1) C6H6 and CCl4
1) Molality 2) Molarity 2) C6H6 and C2H5OH
3) Mole fraction 4) All 3) CH3COCH3 and CH3CN
51. The volume of oxygen at STP used when x 4) KCl and H2O
gms of Zn is converted to ZnO is (At. mass of 57. The number possible stereo isomers in
Zn = 65g) OH OH
2x x | |
1) × 5.6L 2) × 5.6L CH 2 = CH − CH − CH − CH − CH = CH − CH 3
65 65 |
4x 2x Br
3) × 5.6L 4) ×11.2L
65 65 1) 18 2) 20
52. The equivalent mass of divalent metal is W. 3) 14 4) 16
The molecular mass of its chloride is
58. Consider a gas in a vessel. If the
1) W + 35.5 2) W + 71 intermolecular interactions suddenly begin to
3) 2W + 71 4) 2W + 35.5
act then which of the following will
53. 6.02 × 1020 molecules of acetic acid are happened?
present in 500 ml of its solution. The
concentration of solution is 1) The pressure decreases
2) The pressure increases
1) 0.002 M 2) 10.2 M
3) 0.012 M 4) 0.01 M 3) The pressure remains unchanged
54. Graph between fraction of molecules and 4) The gas collapsed
velocity is given below. 59. Which of the following is correct for an ideal
gas (m = mass, M = molar mass)?
V P MV P
1) = 2) =
n RT m RT
d P
3) = 4) All of these
M RT
6 Test ID : 813[A]
60. At constant pressure for a fixed moles of a 65. At STP the order of the RMS speeds of
gas, volume and temperature are related as molecules of H2, N2, O2 and HBr gases is
t 1) H2 > N2 > O2 > HBr
1) Vt = V0 1 + 2) HBr > H2 > O2 > N2
273
3) HBr > O2 > N2 > H2
273
2) Vt = V0 1 + 4) N2 > O2 > H2 > HBr
t
66. Which of the following is correct order for
t
3) V0 = Vt 1 + strength of overlapping of orbitals
273
1) S-S > P-P > S-P 2) S-P > P-P > S-S
273
4) V0 = Vt 1 + 3) P-P > S-S > S-P 4) P-P > S-P > S-S
t
67. Compressibility factor for one mole of CO2 at
61. In a series ethane; ethylene and acetylene the 400K and 71.0 bar is 0.86. Molar volume of
C−H bond energy is CO2 under these conditions is
1) the same in all the three compound 1) 22.4 L 2) 2.24 L
2) greatest in acetylene 3) 0.403L 4) 19.5 L
3) greatest in ethylene 68. Temperature at which gas behaves ideally
4) greatest in ethane over a wide range of pressure is called as
62. Partial pressure of 3 gases A, B and C in their 1) Boyle’s temperature
mixture are pA, pB and pC respectively. Find 2) Critical temperature
the correct relation if the number of moles of 3) Absolute zero temperature
A, B, C are equal 4) Kraft temperature
1) pA > pB > pC 69. At very high pressure, Vander Waal’s
2) pA = pB = pC equation for one mole gas is
3) pA < pB < pC RT a RT a
1) P = − 2 2) P = +
4) pA + pB = pC V V V V2
63. Calculate relative rate effusion of O2 to CH4 RT RT
3) P = 4) P =
from a container. In which O2 and CH4 are in V−b V+b
3 : 2 mass ratio 70. Capillary action of the liquid can be explained
3 2 3 on the basis of
1) 2) 1) resistance to flow
4 4 2
3 2) surface tension
3) 4) 4 3) heat of vapourisation
2
4) refractive index
64. The kinetic energy per unit volume is
71. For the reaction Fe0.95O → Fe2O3 what is the
3 3 equivalent mass of Fe0.95O. (Molar mass is M)
1) T 2) P
2 2
M M
3 RN 3 RT 1) 2)
3) 4) 0.85 0.95
2 N0 2 n
M M
3) 4)
0.875 200
7 Test ID : 813[A]
−
72. What is the normality of resulting solution 79. Statement – I : I2 → IO + I– is an example
3
obtained by dilution of 200 ml of 0.2M HCl of a disproportionation reaction
solution to 1 litre?
Statement – II : Oxidation number of ‘I’ can
1) 0.02 2) 0.03 vary from –1 to +7
3) 0.04 4) 0.06
1) Both Statement-I and II are true
73. A redox reaction always involves
2) Both Statement-I and II are false
1) change in oxidation number
3) Statement-I is true and Statement-II is false
2) change in phase
3) the transfer of protons 4) Statement-I is false and Statement-II is true
4) the formation of ions 80. Total number of peroxy bonds in ‘X’
ether
74. 10gm of XeF4 gas was introduced into vessel K2Cr2O7 + H2SO4 + H2O2 → K2SO4+ X+ H2O
of 11 litre capacity at 75oC. What is the 1) 5 2) 3
pressure of the gas in atmosphere (XeF4 M.wt 3) 4 4) 2
is 207.3) 81. The specialized cells present in Nostoc that are
1) 0.125 atm 2) 0.135 atm involved in nitrogen fixation are called as
3) 0.145 atm 4) 0.155 atm 1) Auxospores 2) Pyrenoids
75. In Fe(II) and MnO −4 titration HNO3 is not 3) Heterocysts 4) Akinetes
used because 82. Identify the incorrect statements
1) It oxidises Mn+2 2) It reduces MnO −4 i) Diatoms are the chief producers in the
terrestrial habitat
3) It oxidises Fe+2 4) It reduces Fe+2
ii) The spores of slime moulds possess true
76. What are the values of X, Y and Z in the
walls
following equation?
iii) The cell wall of euglenoids has stiff
H2C2O4 + XH2O2 → YCO2 + ZH2O
cellulosic plates
1) 2, 1, 2 2) 1, 2, 2
iv) Protists reproduce sexually by a process
3) 2, 2, 1 4) 1, 2, 1
involving cell fusion and zygote formation
77. 5 mol of Fe2(C2O4)3 is oxidized by X mol of
v) The plasmodium of slime moulds causes
K2Cr2O7 in acidic medium for complete
malaria
reaction the value of X is
1) i, ii and iii 2) i, iii and v
1) 2 2) 3
3) iv and v 4) i and iv
3) 5 4) 6
83. Identify the incorrect match
78. The redox reaction among the following is
1) Entamoeba – Amoeboid protozoan
1) 2NaOH + Cl2 → NaCl + NaOCl + H2O
2) Gonyaulax – Flagellated protozoan
2) 2KMnO4 + 10FeSO4 + 8H2SO4 → 2MnSO4 +
3) Paramoecium – Ciliated protozoan
5Fe2(SO4)3 + K2SO4 + 8H2O
4) Trypanosoma – Parasitic protozoan
3) CuCl2 + Cu → Cu2Cl2
4) All the above 84. Dikaryotic phase is observed in
1) Ascomycetes 2) Phycomycetes
3) Basidiomycetes 4) Both (1) and (3)
8 Test ID : 813[A]
85. The fungi used extensively in biochemical and 89. A) Sex organs are absent
genetic research work is B) Produce exogenous sexual spores
1) Aspergillus 2) Claviceps C) Asexual spores are absent
3) Neurospora 4) Rhizopus The above features belongs to
86. Match the following 1) Ascomycetes 2) Basidiomycetes
List – I List – II 3) Phycomycetes 4) Deuteromycetes
90. Identify the labelled part ‘A’ from the diagram
A) Smut fungi I) Puccinia
given below.
B) Sac fungi II) Penicillium
C) Edible fungi III) Agaricus
D) Rust fungi IV) Ustilago
1) A – I, B – IV, C – III, D – II
2) A – IV, B – II, C – III D – I
3) A – III, B – I, C – II, D – IV 1) ssDNA 2) dsDNA
4) A – I, B – III, C – IV, D – II 3) ssRNA 4) dsRNA
87. Identify the correct statements. 91. Identify the incorrect match
A) The maximum type of nutritional diversity 1) Beijerinck – Contagium vivum fluidum
is found in Monera.
2) T.O. Diener – Discovered prions
B) As per whittakers classification four
3) Stanley – Crystallized TMV
kingdoms consists of multicellular
4) Ivanowsky – Recognised causal organism
eukaryotes.
of tobacco mosaic disease
C) Aristole classified plants into trees, shrubs
92. Statement – I : Cyanobacteria appear only in
and herbs based on evolutionary
filamentous form.
relationships
Statement – II : Chemosynthetic autotrophs
D) The first oxygenic photosynthetic
play a major role in recycling nutrients.
monerans are cyanobacteria
1) Both the statements are correct
1) A and B
2) Both the statements are incorrect
2) B and C
3) Statement – I is correct, statement – II is
3) C and D incorrect
4) A and D 4) Statement – I is incorrect, statement – II is
88. How many organisms in the given list belongs correct
to kingdom protista as per whittakers
93. Identify incorrect statement w.r.t Viroids
classification?
1) Smaller than viruses
Paramoecium, Chlorella, Chlamydomonas,
2) Free RNA of low molecular weight
Nostoc, Anabaena, Spirogyra, Amoeba,
Trichoderma 3) Causes mad cow disease in cattle
1) Five 2) Two 4) Causes potato spindle tuber disease
3) Three 4) Four
9 Test ID : 813[A]
94. Identify incorrect statement w.r.t 99. In which of the following plant, both
Methanogens gametophyte and sporophyte have
1) Present in the gut of ruminant animals independent free living existence?
2) Responsible for the production of biogas 1) Funaria 2) Sphagnum
3) Belongs to Archaebacteria 3) Fern 4) Polytrichum
4) Primitive eukaryotic organisms 100. Tracheophytic archegoniate plant among the
95. Artificial system of classification is based on following is
1) Chromosomal number and behaviour 1) Salvia
2) Chemical constituents of the plant 2) Selaginella
3) Gross superficial morphological characters 3) Porphyra
4) All the above 4) Both (1) and (2)
96. The hydrocolloid substances like algin and 101. Assertion (A) : Bryophytes are called as
carrageen are obtained respectively from amphibians of the plant kingdom.
Reason (R) : Bryophtyes live in soil but are
1) Green and brown algae
dependent on water for sexual reproduction.
2) Red and brown algae
1) Both (A) and (R) are correct but (R) is not
3) Brown and red algae
the correct explanation of (A).
4) Red and green algae
2) Both (A) and (R) are correct and (R) is the
97. A : Produce gametes that bear two laterally correct explanation of (A)
attached flagella.
3) (A) is not correct but (R) is correct
B : Stored form of food is floridean starch.
Based on the above characters identify the 4) Both (A) and (R) are incorrect
102. Prothallus in pteridophytes represents
suitable option that matches correctly for A
and B. 1) haploid sporophyte
1) A – Polysiphonia, B – Dictyota 2) diploid sporophyte
2) A – Fucus, B – Porphyra 3) haploid gametophyte
3) A – Ectocarpus, B – Ulothrix 4) diploid gametophyte
4) A – Chlamydomonas, B – Laminaria 103. Identify the incorrect match
98. Identify the incorrect statement w.r.t 1) Tallest tree – Sequoia
Marchantia 2) Branched stem – Pinus
i) Reproduce asexually through gemma cups 3) Unbranched stem – Cedrus
ii) Spores germinate to give protonema 4) Corolloid roots – Cycas
iii) Both male and female reproductive parts 104. Highly evolved last archegoniates are also
present on same thallus known as
iv) The thallus is dorsiventral and closely 1) first embryophytes
appressed to the substratum 2) first tracheophytes
1) ii and iii 2) i and iv 3) first spermatophytes
3) iii and iv 4) ii and iv 4) first land plants
10 Test ID : 813[A]
105. Which of the following are unique features of 112. Which of the following is the most common
angiosperms? non membranous cell organelle found in plant
I) Presence of endosperm cell?
II) Presence of seed 1) Lysosomes 2) Centriole
III) Double fertilization 3) Ribosomes 4) Both (2) and (3)
113. In animal cell, 70s ribosomes are found in
IV) Fruit formation
I) Chloroplast II) Mitochondria
V) Presence of tap roots III) Cytoplasm IV) RER
1) II, III and V 2) III and IV 1) I and II 2) II and III
3) Only IV 4) I, II, III, IV and V 3) II, III and IV 4) Only II
106. Atracheophytic, homosporous and archegoniate 114. The special membranous extensions which
plant exhibiting haplodiplontic life cycle is contain pigments in cyanobacteria are called
1) Ectocarpus 2) Polysiphonia 1) Mesosomes 2) Chromatophores
3) Sphagnum 4) Selaginella 3) Chloroplasts 4) Chromoplasts
107. Zygoticmeiosis is the characteristic feature of 115. Identify the incorrect statement w.r.t plasmid