Eng.

Admission Program-2024
Revision test-01 (Written) Physical
Set-C

D”PZi MwYZ HMath

01 10
hw` (h, 0), (a, b) Ges (0, k) we›`yÎq GKB †iLvi Dci Ae¯’vb If the three points (h, 0), (a, b) and (0, k) lie on the same
K‡i, Z‡e †`LvI †h, + = 1| h = 1, k = 1 Ges b = 2 line, then show that + = 1. If h = 1, k = 1 and b = 2
Ges we›`yÎq Øviv MwVZ wÎfz‡Ri †ÿÎdj 2 eM©GKK n‡j, a Gi gvb and the area of the triangle formed with the points is 2
wbY©q Ki| square units then determine the value of ‘a’.
(h, 0), (a, b), (0, k) GKB †iLvi Dci¯’ weavq G‡`i Øviv MwVZ As (h, 0), (a, b) and (0, k) lie on the same straight line so
wÎfz‡Ri †ÿÎdj k~b¨| the area of the triangle formed by them is zero.
h 0 1 h 0 1
∴ a b 1 = 0 ⇒ h(b − k) + 0 + 1(ak − 0) = 0 ∴ a b 1 = 0 ⇒ h(b − k) + 0 + 1(ak − 0) = 0
0 k 1 0 k 1
⇒ hb − hk + ak = 0 ⇒ hb − hk + ak = 0
⇒ hb + ak = hk ⇒ hb + ak = hk
⇒ + = 1 (showed) ⇒ + = 1 (showed)
Avevi, Again,
1 0 1 1 0 1
a 2 1 =2 a 2 1 =2
0 1 1 0 1 1
⇒ 1 + a = ±4 ; a = 3, −5 ⇒ 1 + a = ±4 ; a = 3, −5

b¤^i eÈbt Marks Distribution:

h 0 1 h 0 1
a b 1 = 0; wbY©q Kivi Rb¨ 01 b¤^i| 01 mark for determining,a b 1 =0
0 k 1 0 k 1
+ = 1; †`Lv‡bvi Rb¨ 04 b¤^i| 04 marks for showing, + = 1
1 0 1 1 0 1
a 2 1 = 2; wbY©q Kivi Rb¨ 01 b¤^i| 01 mark for determining, a 2 1 = 2
0 1 1 0 1 1
a = 3, −5; wbY©q Kivi Rb¨ 04 b¤^i| 04 marks for determining, a = 3, −5

D”PZi MwYZ HMath

02 10
2x − 3y + 4 = 0 mij‡iLvi Dci GKwU Pjgvb we›`y P| hw` P is a moving point on the straight line 2x − 3y + 4 = 0. If
Q(1,4) I R(3, −2) `ywU w¯’i we›`y nq, Z‡e ΔPQR Gi fi‡K‡›`ªi Q(1,4) and R(3, −2) are two fixed points, then determine
mÂvic_wUi mgxKiY I cÖK…wZ wbY©q Ki| the nature and equation of the locus of the centroid of
ΔPQR.

awi, fi‡K›`ª (x, y) Let, centroid (x, y)

P n‡jv (x , y ) hvnv Pjgvb we›`y I 2x − 3y + 4 = 0 Gi Dci P (x , y ), which is a moving point and lies on 2x − 3y +
Aew¯’Z| 4=0
∴ 2x − 3y + 4 = 0 ∴ 2x − 3y + 4 = 0
∴y = ∴y =
Avevi, fi‡K›`ª x = = ⇒ 3x = 4 + x … (i) Again, centroid x = = ⇒ 3x = 4 + x … (i)

Avevi, y = = = Again y = = =
⇒ 3y = ⇒ 9y = 2x + 4 + 6 = 2x + ⇒ 3y = ⇒ 9y = 2x + 4 + 6 = 2x + 10 … (ii)
10 … (ii) (i) × 2 ⇒ 6x = 8 + 2x
(i) × 2 ⇒ 6x = 8 + 2x (ii) ⇒ 9y = 10 + 2x
(ii) ⇒ 9y = 10 + 2x ; 2 × (i) − (ii) K‡i cvB, 2 × (i) − (ii) gives us 6x − 9y = −2
6x − 9y = −2 ∴ Required locus is 6x − 9y = −2 which is equation of a
∴ wb‡Y©q mÂvic_wU n‡jv, 6x − 9y = −2 hvnv mij‡iLvi straight line.
mgxKiY|
Marks Distribution:
b¤^i eÈbt 02 marks for determining, y =
y = ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, 3x = 4 + x
3x = 4 + x ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, 3y = 2x + 10
3y = 2x + 10; wbY©q Kivi Rb¨ 02 b¤^i| 04 marks for determining, locus, 6x − 9y = −2
mÂvic_, 6x − 9y = −2; wbY©q Kivi Rb¨ 04 b¤^i|

D”PZi MwYZ HMath

03 10
x + y − 14x + 26y − 71 = 0 e„‡Ëi †K‡›`ª 2 tan Determine the equation of the chord of the circle x + y −
†KvY DrcbœKvix Ges 5x − 12y + 40 = 0 Gi mgvšÍivj R¨v Gi 14x + 26y − 71 = 0 which produces angle 2 tan with
mgxKiY wbY©q Ki| the center and parallel to 5x − 12y + 40 = 0.

x + y − 14x + 26y − 71 = 0 e„‡Ë, In circle x + y − 14x + 26y − 71 = 0

†K›`ª c ≡ , ≡ (7, −13) ≡ (x , y ) Center c ≡ , ≡ (7, −13) ≡ (x , y )

e¨vmva© r = 7 + (−13) − (−71) = 17 GKK Radius r = 7 + (−13) − (−71) = 17 unit

cÖkœg‡Z, 2θ = 2 tan ⇒ θ = tan According to question, 2θ = 2 tan ⇒ θ = tan
GLb, †K›`ª n‡Z R¨v-i j¤^ `~iZ¡ h = r cos θ = Now, perpendicular distance of the chord from the center
17 cos tan = 15 GKK h = r cos θ = 17 cos tan = 15 unit
GLb, 5x − 12y + 40 = 0 Gi mgvšÍivj R¨v awi, 5x − Now, let the chord parallel to 5x − 12y + 40 = 0 is 5x −
12y + k = 0 12y + k = 0
| |
GLb, h =
| | Now, h =
( )
( )
⇒ 13 × 15 = |5 × 7 − 12 × (−13) + k| ⇒ 13 × 15 = |5 × 7 − 12 × (−13) + k|
⇒ |191 + k| = 195 ⇒ |191 + k| = 195
⇒ k = −386,4 ⇒ k = −386,4
R¨v Gi mgxKiY, Equation of chord,
5x − 12y − 386 = 0 Ges 5x − 12y + 4 = 0 5x − 12y − 386 = 0 and 5x − 12y + 4 = 0
 Marks Distribution:
b¤^i eÈbt 02 marks for determining, θ = tan
θ = tan ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, h = 15
h = 15 ; wbY©q Kivi Rb¨ 02 b¤^i| 03 marks for determining, k = −386,4
k = −386,4 ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, 5x − 12y − 386 = 0 and 5x −
5x − 12y − 386 = 0 Ges 5x − 12y + 4 = 0 ; wbY©q Kivi 12y + 4 = 0
Rb¨ 03 b¤^i|

D”PZi MwYZ HMath

04 10
(4,1) we›`y w`‡q AwZµgKvix e„Ë 3x + 4y − 1 = 0 I x = 3 The circle passing through the point (4,1) touches the
†iLv `yBwU‡K ¯úk© K‡i| e„ËwUi e¨vmva© r n‡j †`LvI †h, r − lines 3x + 4y − 1 = 0 and x = 3. If ‘r’ is the radius of the
20r + 40 = 0 circle then show that r − 20r + 40 = 0.

GLv‡b, |h − 3| = r ⇒ h = 3 ± r Here, |h − 3| = r ⇒ h = 3 ± r
MÖnY‡hvM¨ h = 3 + r (wPÎ Abymv‡i) Acceptable h = 3 + r [according to figure]
| | | |
Avevi, = r ⇒ 3(3 + r) + 4k − 1 = ±5r Again, = r ⇒ 3(3 + r) + 4k − 1 = ±5r
⇒ k = −2 + (+wb‡q) ⇒ k = −2 + (considering +)

cÖkœg‡Z, (3 + r − 4) + −2 + − 1 =r According to question, (3 + r − 4) + −2 + − 1 =r

⇒ r − 2r + 1 + − 3r + 9 = r ⇒ r − 2r + 1 + − 3r + 9 = r
⇒ r − 20r + 40 = 0 (‡`Lv‡bv n‡jv) ⇒ r − 20r + 40 = 0 (Showed)

b¤^i eÈbt Marks Distribution:

h = 3 + r; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, h = 3 + r

k = −2 + ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, k = −2 +

02 marks for determining, (3 + r − 4) + −2 + − 1 =

(3 + r − 4) + −2 + − 1 = r ; wbY©q Kivi Rb¨ 02
b¤^i| r
02 marks for determining, r − 20r + 40 = 0
r − 20r + 40 = 0; wbY©q Kivi Rb¨ 02 b¤^i|

D”PZi MwYZ HMath

05 10
x = ay + by + c cive„‡Ëi kxl© (−4,3) we›`y‡Z Aew¯’Z Ges The vertex of the parabola x = ay + by + c is situated at
GwU (0,5) we›`yMvgx| a, b I c Gi gvb wbY©q Ki| point (−4,3) and it passes through the point (0,5).
Determine the value of a, b and c.
cive„‡Ëi Aÿ‡iLv x-A‡ÿi mgvšÍivj, (y − 3) = Axis of the parabola is parallel to x-axis, (y − 3) =
4a(x + 4) … (i) 4a(x + 4) … (i)
(i) bs †iLv (0,5) we›`yMvgx| d‡j, (5 − 3) = 4a(0 + 4) Line (i) passes through the point. So, (0,5) (5 − 3) =
4a(0 + 4)
∴a= = ∴a= =
× ×
∴ cive„‡Ëi mgxKiYwU n‡e, (y − 3) = 4 × (x + 4) ∴ The equation of parabola will be, (y − 3) =
⇒ y − 6y + 9 = x + 4 4 × (x + 4)
∴ x = y − 6y + 5 … (ii) ⇒ y − 6y + 9 = x + 4
(ii) bs mgxKiYwU x = ay + by + c Gi mv‡_ Zzjbv K‡i cvB, ∴ x = y − 6y + 5 … (ii)
a=1 Comparing the equation (ii) with x = ay + by + c, we get,
b = −6 a=1
c=5 b = −6
c=5
b¤^i eÈbt
(y − 3) = 4a(x + 4); wbY©q Kivi Rb¨ 02 b¤^i| Marks Distribution:
(y − 3) = 4 × (x + 4); wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, (y − 3) = 4a(x + 4)
02 marks for determining, (y − 3) = 4 × (x + 4)
a = 1, b = −6 I c = 5; wbY©q Kivi Rb¨ (02×03) = 06
b¤^i| (02×03) = 06 marks for determining, a = 1, b = −6 & c =
[we.`«: m~Î bv wj‡L mivmwi gvb emv‡jI m~‡Îi Rb¨ eivÏK…Z b¤^i 5
cv‡e|] [Note: Direct input of values without writing formula is also
acceptable.]

D”PZi MwYZ HMath

06 10
GKwU Dce„‡Ëi †dvKvm (1, −1) Ges wbqvgK 2x + y + 1 = 0| Focus of the ellipse is (1, −1) and directrix is 2x + y + 1 =
Dce„ËwU (1,0) we›`yMvgx n‡j, Gi mgxKiY Ges Gi Dc‡Kw›`ªK j‡¤^i 0. If the ellipse passes through the point (1,0) then
ˆ`N©¨ wbY©q Ki| determine its equation and length of latus rectum.

S ≡ (1, −1) S ≡ (1, −1)

w`Kvÿ: 2x + y + 1 = 0 directrix: 2x + y + 1 = 0
awi, Dr‡Kw›`ªKZv e Ges Dce„‡Ëi Dci¯’ we›`y P(x, y) Let, eccentricity is ‘e’ and P(x, y) is point on the ellipse.
∴ SP = e. PM ∴ SP = e. PM
⇒ SP = e PM ⇒ SP = e PM
( ) ( )
⇒ (x − 1) + (y + 1) = e × … (i) ⇒ (x − 1) + (y + 1) = e × … (i)
(i) bs mgxKiYwU (1,0) we›`yMvgx, Equation (i) passes through the point (1,0)
( × ) ( × )
∴ (1 − 1) + (0 + 1) = e × ∴ (1 − 1) + (0 + 1) = e ×

⇒5=e ×9 ⇒5=e ×9
√ √
∴e= = ∴e= =

( ) ( )
(i) ⇒ (x − 1) + (y + 1) = × (i) ⇒ (x − 1) + (y + 1) = ×

⇒ 9{(x − 1) + (y + 1) } = (2x + y + 1) (Ans.) ⇒ 9{(x − 1) + (y + 1) } = (2x + y + 1)

Dc‡Kw›`ªK j‡¤^i ˆ`N©¨ = 2 × Dr‡Kw›`ªKZv × †dvKvm Ges Gi Length of latus rectum = 2 × eccentricity ×perpendicular
Abyiƒc w`Kv‡ÿi j¤^ `~iZ¡ distance of focus and its directrix
 √ | | √ √ | | √
=2× × =2× × = GKK =2× × =2× × = unit
( ) ( ) √ ( ) ( ) √

b¤^i eÈbt Marks Distribution:

SP = e. PM; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, SP = e. PM
√ √
e= ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, e =

Length of latus rectum = unit; wbY©q Kivi Rb¨ 05 b¤^i| 05 marks for determining, Length of latus rectum = unit
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| [Note: 01 mark will be deducted if unit is not written or
m~Î bv wj‡L mivmwi gvb emv‡jI m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|] wrong unit is written. Direct input of values without writing
formula is also acceptable.]

D”PZi MwYZ HMath

07 10
1 1 1 + 3x 1 1 1 + 3x
1 + 3y 1 1 = A(Bxyz + xy + yz + If 1 + 3y 1 1 = A(Bxyz + xy + yz + Czx),
1 1 + 3z 1 1 1 + 3z 1
Czx) n‡j A, B I C Gi gvb wbY©q Ki| then what is the value of A, B and C?
1 1 1 + 3x 1 1 1 + 3x
Δ = 1 + 3y 1 1 Δ = 1 + 3y 1 1
1 1 + 3z 1 1 1 + 3z 1
+3 +3
= xyz +3 = xyz +3

+3 +3
+ + +3 + + +3 + + +3 + + +3 + + +3 + + +3

= xyz +3 = xyz +3

+3 +3
[r = r + r + r ] [r = r + r + r ]
1 1 1 1 1 1
+3 +3
= xyz + + +3 = xyz + + +3
+3 +3
0 0 1 0 0 1
3 0 [c = c − 3 0 [c = c − c ; c =
= xyz × = xyz ×
−3 3 −3 3
c ;c = c − c ] c −c ]
= (xy + yz + zx + 3xyz) × 9 = 9(3xyz + xy + yz + = (xy + yz + zx + 3xyz) × 9 = 9(3xyz + xy + yz + zx)
zx) Values of A,B and C are respectively 9,3,1
∴ A, B I C Gi gvb h_vµ‡g 9,3,1
Marks Distribution:
b¤^i eÈbt +3
+3 03 marks for determining, xyz +3
xyz +3 ; wbY©q Kivi Rb¨ 03 b¤^i| +3
+3 02 marks for determining, [r = r + r + r ]
[r = r + r + r ] ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, [c = c − c ; c = c − c ]
[c = c − c ; c = c − c ] ; wbY©q Kivi Rb¨ 02 b¤^i| 03 marks for determining, Values A,B and C are
A, B I C Gi gvb h_vµ‡g 9,3,1 wbY©q Kivi Rb¨ 03 b¤^i| respectively 9,3,1

D”PZi MwYZ HMath

08 10
x + y = 9 e„Ë Ges − = 1 Awae„‡Ëi mvaviY ¯úk©‡Ki Determine the equation of the common tangent of the circle

mgxKiY wbY©q Ki| x + y = 9 and hyperbola − =1

a = 4; b = 3 a = 4; b = 3
awi, ¯úk©‡Ki mgxKiY, ⇒ y = mx + c Let, the equation of the tangent ⇒ y = mx + c
c = a m − b ; c = 16m − 9 c = a m − b ; c = 16m − 9
e„‡Ëi †ÿ‡Î, c = 9(m + 1) In case of the circle, c = 9(m + 1)
√ √
∴ 16m − 9 = 9m + 9 ∴ 7m = 18 ∴ m = ± ∴ 16m − 9 = 9m + 9 ∴ 7m = 18 ∴ m = ±
√ √

∴ c = 16 × −9 ∴ c = 16 × −9

c=± c=±
√ √
√ √
∴ ¯úk©‡Ki mgxKiY, y = ± x± ∴ Equation of the tangent, y = ± x±
√ √ √ √

b¤^i eÈbt Marks Distribution:

c = 16m − 9; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, c = 16m − 9
√
m=±
√
; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, m = ±
√
√

c=± ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, c = ±

√
√
√
√ 02 marks for determining, y = ± x±
y=± x± ; wbY©q Kivi Rb¨ 02 b¤^i| √ √
√ √
[we.`«: m~Î bv wj‡L mivmwi gvb emv‡jI m~‡Îi Rb¨ eivÏK…Z b¤^i [Note: Direct input of values without writing formula is also
acceptable.]
cv‡e|]

D”PZi MwYZ HMath

09 10
1 3 2 1 3 2
A = 2 0 3 Ges B = A − 2A + A − 2I n‡j, If A = 2 0 3 and B = A − 2A + A − 2I, What is
1 −1 1 1 −1 1
|5B | Gi gvb KZ? the value of |5B |?
1 3 2 9 1 13 1 3 2 9 1 13
A= 2 0 3 ⇒A = 5 3 7 ⇒A A= 2 0 3 ⇒A = 5 3 7 ⇒A =
1 −1 1 0 2 0 1 −1 1 0 2 0
24 14 34 24 14 34
= 18 8 26 18 8 26
4 0 6 4 0 6
24 14 34 24 14 34
∴ B = A − 2A + A − 2I = 18 8 26 − ∴ B = A − 2A + A − 2I = 18 8 26 −
4 0 6 4 0 6
18 2 26 1 3 2 2 0 0 18 2 26 1 3 2 2 0 0
10 6 14 + 2 0 3 − 0 2 0 10 6 14 + 2 0 3 − 0 2 0
0 4 0 1 −1 1 0 0 2 0 4 0 1 −1 1 0 0 2
 5 15 10 5 15 10
= 10 0 15 = 10 0 15
5 −5 5 5 −5 5
∴ |B| = 250 ∴ |5B |= = = ∴ |B| = 250 ∴ |5B |= = =
| | | |

b¤^i eÈbt Marks distribution:

9 1 13 24 14 34 (2 × 2) = 04 marks for determining, A =
A = 5 3 7 , A = 18 8 26 ; wbY©‡qi Rb¨ 9 1 13 24 14 34
0 2 0 4 0 6 5 3 7 , A = 18 8 26
(2×2) = 04 b¤^i| 0 2 0 4 0 6
5 15 10 5 15 10
B = 10 0 15 ; wbY©‡qi Rb¨ 04 b¤^i| 04 marks for determing, B = 10 0 15
5 −5 5 5 −5 5
|5B | = ; wbY©‡qi Rb¨ 02 b¤^i| 02 marks for determing, |5B | =

D”PZvi MwYZ HMath

10 10
†Kv‡bv e‡M©i GKwU KY© 2x + 3y − 2 = 0 Ges GKwU kxl©we›`y The diagonal of a square is 2x + 3y − 2 = 0 and one vertex
(1,2) n‡j, Aci kxl©we›`y¸‡jv wbY©q Ki| is (1,2). Determine the coordinates of the other vertices.

2x + 3y − 2 = 0 ⋅⋅⋅⋅⋅⋅ (i) 2x + 3y − 2 = 0 ⋅⋅⋅⋅⋅⋅ (i)

m =− m =−
(i) Gi mv‡_ 45 †KvY ˆZwi K‡i Ggb †iLvi Xvj m n‡j, If the slope of the line that makes 45 angle with (i) is m,

tan 45 = ± ⇒ ±1 = ⇒ ±1 = ⇒ tan 45 = ± ⇒ ±1 = ⇒ ±1 = ⇒m=

m = , −5 , −5
∴ AB I AD †iLvi mgxKiY, ∴Equations of AB and AD are,
AB: x − 5y + 9 = 0 ⋅⋅⋅⋅⋅⋅ (ii) AB: x − 5y + 9 = 0 ⋅⋅⋅⋅⋅⋅ (ii)
AD: 5x + y − 7 = 0 ⋅⋅⋅⋅⋅⋅⋅ (iii) AD: 5x + y − 7 = 0 ⋅⋅⋅⋅⋅⋅⋅ (iii)
(i), (ii) Ges (i), (iii) mgvavb K‡i, Solving (i), (ii) and (i), (iii),

B≡ − , B≡ − ,

D≡ ,− D≡ ,−
Avevi, Again,
A n‡Z, (i) Gi Dci Aw¼Z j¤^, 3x − 2y + 1 = 0 ⋅⋅⋅⋅⋅ (iv) From A, perpendicular drawn on (i) is, 3x − 2y + 1 = 0 ⋅⋅⋅⋅
(i) I (iv) mgvavb K‡i- ⋅ (iv)
Solving (i) & (iv) ,
E≡ , hv AC Gi ga¨we›`y|
E≡ , which is the midpoint of AC.
∴C≡ − ,
∴C≡ − ,

b¤^i eÈb:
Mark distribution:
m = , −5; wbY©‡qi Rb¨ 01 b¤^i| 01 mark for determining m = , −5.
B, C I D kxl© we›`y¸‡jvi ¯’vbv¼ (3×3) = 09 marks for determining, the coordinates of the
− , , − , & ,− wbY©‡qi Rb¨ (3×3) = vertices B, C and D are − , , − , & ,−
09 b¤^i|

D”PZvi MwYZ HMath

11 10
wZbwU e„Ë ci¯úi‡K ewnt¯úk© K‡i Av‡Q| hw` ¯úk©we›`y‡Z Aw¼Z Three circles touch each other externally. If the tangents
¯úk©K¸‡jv Ggb we›`y‡Z wgwjZ nq, hv †_‡K †h‡Kv‡bv ¯úk©we›`yi `~iZ¡ drawn at point of contact meet at a point from which the
4 GKK nq, Z‡e e„Ë·qi e¨vmva©¸‡jvi ¸Ydj I †hvMd‡ji AbycvZ distance from any point of contact is 4 unit, then determine
wbY©q Ki| the ratio of the product and the sum of the radii of the
circles.

awi, r , r Ges r n‡jv e„Ë wZbwUi e¨vmva© hv‡`i †K›`ª h_vµ‡g Let, r , r and r be the radii of three circles whose centers
A, B Ges C| GB e„˸‡jv G‡K Aci‡K ewnt¯’fv‡e ¯úk© K‡i, are A,B and C respectively. These circles touch each other
†hgbwU wP‡Î †`Lv‡bv n‡q‡Q| externally, as shown in the figure.
OL = ON = OM OL = ON = OM
awi, O n‡j Zv‡`i Radical center ( †h we›`y‡Z ¯úkK©¸‡jv wgwjZ Let ‘O’ be their radical center the point where the tangents
n‡q‡Q) Avevi, O n‡jv ΔABC Gi AšÍt†K›`ª| meet. Also, O is the incenter of ABC.
∴ O †K›`ªwewkó e„Ë ΔABC Gi evû¸‡jv‡K ¯úk© K‡i hv‡e| The circle with center O will touch the sides of ΔABC.
Since OL = 4,
†h‡nZz, OL = 4,
∴ The radius of the incircle is 4.
∴ AšÍte„ËwUi e¨vmva© 4 GKK|
Now AB = r + r = c, BC = r + r = a and CA = r +
GLb, AB = r + r = c, BC = r + r = a Ges CA =
r =b
r +r =b
∴s= =r +r +r
∴s= = r + r + r | d‡j, s − a = r , s − b =
As a result, s − a = r , s − b = r and s − c = r
r Ges s − c = r
Thus, area of ABC = s(s − a)(s − b)(s − c) =
ZvB ΔABC Gi †ÿÎdj = s(s − a)(s − b)(s − c) =
(r + r + r )r r r
(r + r + r )r r r
We know that, = radius of incircle
Avgiv Rvwb †h, = AšÍte„‡Ëi e¨vmva©
( )
( ) ∴ =4⇒ = 16
∴ =4⇒ = 16
Therefore, the required ratio = 16 : 1
myZivs, wb‡Y©q AbycvZ = 16: 1
Mark distribution:
b¤^i eÈb: 02 marks for determining, the radius of the circle is 4.
e„ËwUi e¨vmva© 4 GKK; wbY©‡qi Rb¨ 02 b¤^i| 04 marks for determining, area of ABC =
ΔABC Gi †ÿÎdj = (r + r + r )r r r ; wbY©‡qi Rb¨ (r + r + r )r r r
04 b¤^i| 04 marks for determining, the required ratio = 16 : 1
wb‡Y©q AbycvZ = 16: 1; wbY©‡qi Rb¨ 04 b¤^i|
D”PZi MwYZ HMath
12 10
0 0 7 5 0 0 0 7 5 0
0 0 −3 7 2 0 0 −3 7 2
|A| = 2 15 5 12 −2 If |A| = 2 15 5 12 −2
0 0 0 1 0 0 0 0 1 0
−1 3 0 5 4 −1 3 0 5 4
−6 1 −6 1
Ges A = n‡j, x Gi gvb wbY©q Ki| and A = , then find the value of x.
3 x 3 x
|A| Gi PZz_© mvwi eivei we¯Ívi K‡i cvB, Expanding along fourth row of |A|
0 0 7 0
0 0 7 0 |A| = 0 0 −3 2
0 −3 2 2 15 5 −2
|A| = 0 −1 3 0 4
2 15 5 −2
−1 3 0 4 0 0 2
|A| = 7 2 15 −2 = 294 [Expanding along first row]
−1 3 4
0 0 2
|A| = 7 2 15 −2 = 294 [cÖ_g mvwi eivei we¯Ívi
−1 3 4 |A| = −6x − 3 = 294
K‡i] ∴ x = −49.5(Ans. )

|A| = −6x − 3 = 294 Mark distribution:

∴ x = −49.5(Ans. ) 0 0 7 0
For determining |A| = 0 0 −3 2
2 15 5 −2
b¤^i eÈbt −1 3 0 4
0 0 7 0 ; 03 marks.
|A| = 0 0 −3 2 ; wbY©‡qi Rb¨ 03 b¤^i| For determining |A| = 294 ; 04 marks.
2 15 5 −2
−1 3 0 4 For determining x = −49.5; 03 marks.
|A| = 294; wbY©‡qi Rb¨ 04 b¤^i|
x = −49.5; wbY©‡qi Rb¨ 03 b¤^i|

D”PZi MwYZ HMath

13 10
GKwU cwieZ©bkxj mij‡iLvi Dci (3,1), (−1,2) Ges (1,3) On a changing straight line three perpendiculars are drawn
we›`y n‡Z Aw¼Z j¤^`~i‡Z¡i cÖ_g `yBwUi †hvMdj n‡Z Z…ZxqwUi `~i‡Z¡i from the points (3,1), (−1,2) & (1,3) respectively. If the
we‡qvMdj k~b¨ n‡j, mij‡iLvi Dci¯’ GKwU we›`yi ¯’vbv¼ KZ? length of third line is subtracted from summation of length
of first two lines, then the result is zero. What is the co-
ordinate of a point on the line?
awi, †iLvwU ax + by + c = 0 … … … (i) Let, the line is ax + by + c = 0 … … … (i)
∴ + − =0 ∴ + − =0
√ √ √ √ √ √
⇒ 2a + 3b + 2c − a − 3b − c = 0 ⇒ a + c = 0 ⇒ 2a + 3b + 2c − a − 3b − c = 0 ⇒ a + c = 0
(i) bs mgxKiY x = 1 Ges y = 0 n‡j, a + c = 0 nq| In equation (i) if x = 1 and y = 0 then, a + c = 0.
∴ ax + by + c = 0 †iLvi Dci¯’ we›`y (1, 0) [Ans.] ∴(1, 0) is a point on line ax + by + c = 0 [Ans.]

b¤^i eÈb: Mark distribution:

 + − = 0; wbY©‡qi Rb¨ 03 b¤^i| 03 marks for determining, + − = 0;
√ √ √ √ √ √
a + c = 0 ; wbY©‡qi Rb¨ 03 b¤^i| 03 marks for determining, a + c = 0
ax + by + c = 0 †iLvi Dci¯’ we›`y (1, 0); wbY©‡qi Rb¨ 04 04 marks for determining, (1, 0) is a point on line ax +
b¤^i| by + c = 0

D”PZi MwYZ HMath

14 10
x + y − 12x + 16y − 69 = 0 Ges x + y − 9x + Find length of common chord of the circles x + y −
12y − 59 = 0 e„Ë؇qi mvaviY R¨v Gi ˆ`N¨© wbY©q Ki| 12x + 16y − 69 = 0 and x + y − 9x + 12y − 59 = 0 .

awi, S ≡ x + y − 12x + 16y − 69 = 0 … … … (i) Let, S ≡ x + y − 12x + 16y − 69 = 0 … … … (i) Center

e„‡Ëi †K›`ª C (6, −8) Ges e¨vmva©, r = 13 GKK C (6, −8) and radius, r = 13 unit.
S ≡ x + y − 9x + 12y − 59 = 0 … … … (ii) S ≡ x + y − 9x + 12y − 59 = 0 … … … (ii)
√ √
e„‡Ëi †K›`ª C , −6 Ges e¨vmva©, r = GKK = Centre of the circle is C , −6 and radius, r =
10.735 GKK unit = 10.735 unit.

C C = 6− + (−8 + 6) = GKK 9 5
C C = 6− + (−8 + 6) = unit,
2 2
r ~r = 2.26 GKK (cªvq)
r ~r = 2.26 unit (approx.)
r + r = 23.735 (cªvq)
r + r = 23.735 (approx.) ∴ r ~r < C C < r + r
∴ r ~r < C C < r + r
∴ The circles intersect each other
∴ e„ËØq ci¯úi‡K †Q` K‡i|
∴ Equation of common Chord,
∴ mvaviY R¨v‡qi mgxKiY, S − S ⇒ −3x + 4y − 10 = 0
S − S ⇒ −3x + 4y − 10 = 0

⇒ 3x − 4y + 10 = 0 … … … … (iii) ⇒ 3x − 4y + 10 = 0 … … … (iii)
(i) e„‡Ëi †K›`ª C (6, −8) n‡Z (iii) Gi j¤^ `~iZ¡, CD = l = Perpendicular distance of the Centre of circle (i) C (6, −8)
| . ( ) |
= 12 GKK and (iii),
( )
| . ( ) |
∴ mvaviY R¨v‡qi ˆ`N¨©, AB = 2 r − l = CD = l = = 12 unit.
( )

2√13 − 12 = 10 GKK (Ans.) ∴ Length of common chord, AB = 2 r − l =

2√13 − 12 = 10 unit. (Ans.)
b¤^i eÈb:
e„ËØq ci¯úi‡K †Q` K‡i; wbY©‡qi Rb¨ 01 b¤^i| Mark distribution:
3x − 4y + 10 = 0; wbY©‡qi Rb¨ 03 b¤^i| 01 mark for determining, the circles intersect each other
l = 12 GKK; wbY©‡qi Rb¨ 02 b¤^i| 03 marks for determining, 3x − 4y + 10 = 0;
AB = 10 GKK; wbY©‡qi Rb¨ 04 b¤^i| 02 marks for determining, l = 12 unit
[we. `«t GKK bv wjL‡j 01 b¤^i KZ©b Kiv n‡e|] 04 marks for determining, AB = 10 unit
[N. B: 01 mark will be deducted if unit is not written.]

c`v_©weÁvb Phy
15 10
GKwU Av‡jvKiwk¥ −2ı̂ − 5ȷ̂ eivei g~jwe›`y‡Z AvcwZZ nq I xy Z‡j A light ray is incident along −2ı̂ − 5ȷ̂ on the origin and
cÖwZdwjZ nq| AvcwZZ Av‡jvKiwk¥ I cÖwZdwjZ Av‡jvK iwk¥i ga¨eZ©x reflects along the xy-plane. What is the angle between the
†KvY wbY©q Ki| incident ray and reflected ray?

A⃗ = −2ı̂ − 5ȷ̂ A⃗ = −2ı̂ − 5ȷ̂

y –A‡ÿi mv‡_ A⃗ Gi †KvY, θ = cos = 158.2 Angle of A⃗ with y-axis, θ = cos = 158.2
√ √
∴ AvcZb †KvY = 180 − 158.2 = 21.8 ∴ incident angle = 180 − 158.2 = 21.8
∴ cÖwZdwjZ iwk¥i mv‡_ †KvY = 2 × 21.8 = 43.6 [Ans.] ∴ angle with reflected ray = 2 × 21.8 = 43.6 [Ans.]
b¤^i eÈbt Marks Distribution:
θ = 158.2 ; wbY©q Kivi Rb¨ 04 b¤^i| 04 marks for determining, θ = 158.2
AvcZb †KvY = 21.8 ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, incident angle = 21.8
cÖwZdwjZ iwk¥i mv‡_ †KvY = 43.6 ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, angle with reflected ray = 43.6

c`v_©weÁvb Phy
16 10
3 kmh †e‡M cÖevwnZ b`x‡Z GKRb muvZviæ 5 kmh †e‡M muvZvi In a river flowing with 3 kmh velocity, a swimmer
w`‡q wVK wecixZ we›`y †_‡K cvo eivei †¯ªv‡Zi wecix‡Z 1 km `~iZ¡ swims with 5 kmh velocity and traverses 1km along the
AwZµg K‡i| b`xi cÖ¯’ 2 km n‡j, b`xi cÖ‡¯’i mv‡_ muvZviæ KZ †Kv‡Y current from just the opposite point of the other bank. If the
muvZvi w`‡qwQj? width of the river is 2 km, then at what angle with the
width of the river did he swim?
cvo eivei `~iZ¡, x = (u + v cos α) Distance along the bank, x = (u + v cos α)
x = −1 x = −1
⇒ −1 = (3 + 5 cos α) × ⇒ −1 = (3 + 5 cos α) ×
10 cos α + 5 sin α = −6 10 cos α + 5 sin α = −6
⇒ cos α + sin α = − ⇒ cos α + sin α = −
√ √ √ √ √ √

⇒ cos(α − θ) = [θ = cos ] ⇒ cos(α − θ) = [θ = cos ]

√ √ √ √
∴ α = 149.02 ∴ α = 149.02
∴ cÖ‡¯’i mv‡_ = 149.02 − 90 = 59.02 [Ans.] ∴ angle with the width of the river = 149.02 − 90 =
b¤^i eÈbt 59.02 [Ans.]
x = (u + v cos α) ;†jLvi Rb¨ 02 b¤^i| Marks Distribution:

10 cos α + 5 sin α = −6; †jLvi Rb¨ 03 b¤^i| 02 marks for writing, x = (u + v cos α)
α = 149.02 ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for writing, 10 cos α + 5 sin α = −6
cÖ‡¯’i mv‡_ = 59.02 ; wbY©q Kivi Rb¨ 02 b¤^i| 03 marks for determining, α = 149.02
02 marks for determining, angle with the width of the river
= 59.02

c`v_©weÁvb Phy
17 10
wP‡Î ivZzj, AN©¨ I mRx‡ei evmv h_vµ‡g A, B I C Ae¯’v‡b| Zv‡`i g‡a¨ According to the figure, the house of Ratul, Arggha and
†Kvb `yBR‡bi evmvi ga¨eZx© mivmwi c_ m‡e©v”P? Sajib are respectively at A, B and C. Direct distance
between the houses of which two of them will be the
greatest?
awi, ivZz‡ji evmvi Ae¯’vb †f±i, OA⃗ = 3ı̇ − 4ȷ̇ − 3k Let, the position vector of Ratul’s house is
A‡N©¨i evmvi Ae¯’vb †f±i, OB⃗ = 3ı̇ + 4k OA⃗ = 3ı̇ − 4ȷ̇ − 3k ; position vector of Arggha’s house
mRx‡ei evmvi Ae¯’vb †f±i, OC⃗ = 10ȷ̇ is OB⃗ = 3ı̇ + 4k ; position vector of Sajib’s house is

AB⃗ = 4ȷ̇ + 7k, AB⃗ = √65 OC⃗ = 10ȷ̇.

Now,
BC⃗ = −3ı̇ + 10 ȷ̇ − 4k, BC⃗ = √125
AB⃗ = 4ȷ̇ + 7k, AB⃗ = √65
AC⃗ = −3ı̇ + 14ȷ̇ + 3k, AC⃗ = √214
BC⃗ = −3ı̇ + 10 ȷ̇ − 4k, BC⃗ = √125
∴ ivZzj I mRx‡ei Ae¯’v‡bi cv_©K¨ m‡e©v”P |
= −3ı̇ + 14ȷ̇ + 3k, AC⃗ = √214
b¤^i eÈb: ∴ Distance between the houses of Ratul and Sajib will
be the greatest.
OA⃗, OB⃗, OC⃗ ‡ei Kivi Rb¨ 03 b¤^i|
AB⃗ , BC⃗ , AC⃗ ‡ei Kivi Rb¨ 06 b¤^i| Mark distribution:
ivZzj I mRx‡ei Ae¯’v‡bi cv_©K¨ m‡e©v”P wbY©‡qi Kivi Rb¨ 01 b¤^i|
03 marks for determining OA⃗, OB⃗, OC⃗.
06 marks for determining AB⃗ , BC⃗ , AC⃗ .
01 mark for determining distance between the houses of
Ratul and Sajib will be the greatest.

c`v_©weÁvb Phy
18 10

gm„Y †njv‡bv ZjwU wP‡Îi g‡Zv f‚wgi Dci Av‡Q| f‚wgi, w¯’wZ Nl©Y ¸Yv¼ The smooth inclined plane is on the surface as depicted in
0.3| eø‡Ki fi m me©wb¤œ KZ n‡j †njv‡bv ZjwU MwZkxj n‡e? [†njv‡bv the figure. Coefficient of static friction of the surface is 0.3.
Z‡ji fi 150 kg] For what minimum value of mass of block m will the
inclined plane be in motion? [Mass of inclined plane is
150kg]

∴ R = Mg cos θ ∴ R = Mg cos θ
μ = 0.3, θ = 30°, M = 150 kg μ = 0.3, θ = 30°, M = 150 kg
R sin θ ≥ f n‡j, †njv‡bv Zj MwZkxj n‡e| If, R sin θ ≥ f , the inclined plane will be in motion.
R = Mg + Rcos θ R = Mg + Rcos θ
Rsin θ ≥ f Rsin θ ≥ f
⇒ Rsin θ ≥ μ(Mg + Rcos θ) ⇒ R(sin θ − μ cos θ) ≥ μMg ⇒ Rsin θ ≥ μ(Mg + Rcos θ) ⇒ R(sin θ − μ cos θ) ≥ μMg
⇒ mgcos θ(sin θ − μ cos θ) ≥ μ Mg ⇒ mgcos θ(sin θ − μ cos θ) ≥ μ Mg
⇒m≥μ . ( )
⇒m≥μ . ( )

∴ m ≥ 0.3 × ∴ m ≥ 0.3 ×
°( ° . × °) °( ° . × °)
m ≥ 216.33 kg m ≥ 216.33 kg
∴ eø‡Ki fi m me©wb¤œ 216.33 kg ∴ Minimum value of mass of block mœ 216.33 kg
b¤^i eÈbt Marks Distribution:
R sin θ ≥ f n‡j, †njv‡bv Zj MwZkxj n‡e ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, if, R sin θ ≥ f , the inclined
R = Mg + Rcos θ ; wbY©q Kivi Rb¨ 02 b¤^i| plane will be in motion.
02 marks for determining, R = Mg + Rcos θ
m≥μ . ( )
; wbY©q Kivi Rb¨ 04 b¤^i|
04 marks for determining, m ≥ μ . ( )
m ≥ 216.33 kg ; wbY©q Kivi Rb¨ 01 b¤^i|
01 mark for determining, m ≥ 216.33 kg
eø‡Ki fi m me©wb¤œ 216.33 kg ; wbY©q Kivi Rb¨ 01 b¤^i|
01 mark for determining, minimum value of mass of block
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|]
mœ 216.33 kg
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.]

c`v_©weÁvb Phy
19 10
1000 kg f‡ii GKwU i‡KU‡K Djø¤^fv‡e Dr‡ÿcY Ki‡Z n‡e| R¦vjvwb A rocket of 1000 kg mass is to be projected vertically. The
`n‡b Drcbœ M¨v‡mi wbM©gb †eM 800 ms | velocity of ejection of burnt fuel is 800 ms .
(i) Kx nv‡i M¨vm wbM©Z n‡j i‡KUwU wb‡Ri IRb‡K AwZµg K‡i wVK (i) What should be the rate of emission of fuel so that the
Do‡Z mÿg n‡e? rocket will just be able to overcome its weight and take off?
(ii) Kx nv‡i M¨vm wbM©Z n‡j i‡KUwU ïiæ‡Z AwfKl©R Z¡i‡Yi wظY Z¡iY (ii) What should be the rate of emission of fuel so that the
cv‡e? rocket will get twice the acceleration of gravitational
acceleration initially?
(i) i‡KUwU wb‡Ri IRb AwZµg K‡i Do‡Z mÿg n‡e hw` R¦vjvwb `n‡b (i) the rocket will be able to overcome its weight and take
Drcbœ M¨v‡mi wbM©g‡bi d‡j m„ó NvZ i‡K‡Ui IR‡bi mgvb nq; off if the impulse produced by ejection of fuel is equal to
A_©vr u = mg nq| the weight of the rocket
× . i.e. u = mg
∴ = = kgs = 12.25 kgs
× .
∴ R¦vjvwb `n‡bi by¨bZg nvi n‡e 12.25 kgs ∴ = = kgs = 12.25 kgs
∴ Minimum rate of emission of fuel will be 12.25 kgs
(ii) i‡K‡Ui DaŸ©gyLx Z¡iY a n‡j, ma = u − mg
(ii) if the upward acceleration of rocket is ‘a’ , ma =
⇒a= −g⇒ = (a + g)
u − mg
cÖkœvbymv‡i, a = 2g ⇒a= −g⇒ = (a + g)
∴ = × (2g + g) = × 3g ATQ, a = 2g
= × 3 × 9.8 kgs = 36.75 kgs ∴ = × (2g + g) = × 3g
∴ 36.75 kgs nv‡i M¨vm wbM©Z n‡Z n‡e| = × 3 × 9.8 kgs = 36.75 kgs
b¤^i eÈbt
∴ The rate of emission of gas should be 36.75 kgs
u = mg; ‡jLvi Rb¨ 02 b¤^i|
= 12.25 kgs ; wbY©q Kivi Rb¨ 03 b¤^i| Marks Distribution:
02 marks for writing, u = mg
ma = u − mg; wbY©q Kivi Rb¨ 03 b¤^i|
03 marks for determining, = 12.25 kgs
= 36.75 kgs ; wbY©q Kivi Rb¨ 02 b¤^i|
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| m~Î bv 03 marks for determining, ma = u − mg
wj‡L mivmwi gvb emv‡jI m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|] 02 marks for determining, = 36.75 kgs .
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written. Direct input of values without writing
formula is also acceptable.]

c`v_©weÁvb Phy
20 10

2 kg f‡ii `ywU e¯‘i A I B Gi wPÎvbyhvqx msN‡l©i c~‡e© †e‡Mi gvb Two objects A & B of mass 2kg collided according to the
v = 30 ms , v = 20 ms | msN‡l©i c‡i A e¯‘i †eM figure. Before the collision, v = 30 ms , v = 20 ms .
25 ms | msN‡l©i ci B Gi †e‡Mi gvb wbY©q Ki| If velocity of A after the collision is 25 ms , then
determine the value of velocity of B after the collision.
v ⃗ = −30 cos 30° ı̂ + 30 sin 30° ȷ̂ = −15√3ı̂ + 15ȷ̂ v ⃗ = −30 cos 30° ı̂ + 30 sin 30° ȷ̂ = −15√3ı̂ + 15ȷ̂
v ⃗ = 20 cos 45° ı̂ + 20 sin 45° ȷ̂ = 10√2ı̂ + 10√2ȷ̂ v ⃗ = 20 cos 45° ı̂ + 20 sin 45° ȷ̂
v ⃗ = 25 cos 150° ı̂ + 25 sin 150° ȷ̂ = 10√2ı̂ + 10√2ȷ̂
= −12.5√3ı̂ + 12.5ȷ̂ v ⃗ = 25 cos 150° ı̂ + 25 sin 150° ȷ̂
fi‡e‡Mi msiÿYkxjZvi bxwZ Abymv‡i, m v ⃗ + m v ⃗ = m v ⃗ + = −12.5√3ı̂ + 12.5ȷ̂
m v ⃗′ According to the law of conservation of momentum,
⇒ −15√3ı̂ + 15ȷ̂ + 10√2ı̂ + 10√2ȷ̂ = 12.5ȷ̂ − 12.5√3ı̂ + m v ⃗ + m v ⃗ = m v ⃗ + m v ⃗′
v ⃗′ ⇒ −15√3ı̂ + 15ȷ̂ + 10√2ı̂ + 10√2ȷ̂ = 12.5ȷ̂ − 12.5√3ı̂ +
v ⃗ = 9.812ı̂ + 16.642ȷ̂ ∴ v ⃗ = 19.319 ms v ⃗′
b¤^i eÈbt v ⃗ = 9.812ı̂ + 16.642ȷ̂ ∴ v ⃗ = 19.319 ms
v ⃗ = −15√3ı̂ + 15ȷ̂ ; wbY©q Kivi Rb¨ 02 b¤^i| Marks Distribution:
v ⃗ = 10√2ı̂ + 10√2ȷ̂ ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, v ⃗ = −15√3ı̂ + 15ȷ̂
v ⃗ = −12.5√3ı̂ + 12.5ȷ̂ ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, v ⃗ = 10√2ı̂ + 10√2ȷ̂
02 marks for determining, v ⃗ = −12.5√3ı̂ + 12.5ȷ̂
m v ⃗ + m v ⃗ = m v ⃗ + m v ⃗′ ; m~Î ‡jLvi Rb¨ 02 b¤^i|
02 marks for writing formula,
v ⃗ = 19.319 ms ; wbY©q Kivi Rb¨ 02 b¤^i| m v ⃗ + m v ⃗ = m v ⃗ + m v ⃗′
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| m~Î bv 02 marks for determining, v ⃗ = 19.319 ms
wj‡L mivmwi gvb emv‡jI m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|] [Note: 01 mark will be deducted if unit is not written or
wrong unit is written. Direct input of values without writing
formula is also acceptable.]

c`v_©weÁvb Phy
21 10

cÖwZ m †ÿÎd‡j fi 50 gm n‡j fi‡K›`ªMvgx j¤^ A‡ÿi mv‡c‡ÿ If mass in per m area is 50 gm then determine the moment
cvZwUi RoZvi åvgK wbY©q Ki| [AB = BC = CD = DA, BD = of inertia of the disc with respect to the axis perpendicular
5m] to its center of mass. [AB = BC = CD = DA, BD = 5m]
2.5m e¨vmv‡a©i e„ËvKvi cv‡Zi RoZvi åvgK = × M × r moment of inertia of the circular disc with 2.5 m radius
= ×M×r
= × 0.05 × π × 2.5 × 2.5 = 3.0679 kgm
= × 0.05 × π × 2.5 × 2.5 = 3.0679 kgm
e‡M©i evûi ˆ`N©¨ = m
√
length of side of the square = m
eM©vKvi cv‡Zi RoZvi åvgK = × M × (2 × l ) √
moment of inertia of the square plate = × M × (2 × l )
= × 0.05 × × = 1.302 kgm
√ √
wP‡Îi RoZvi åvgK = (3.0679 − 1.302) = 1.7659 kgm = × 0.05 × × = 1.302 kgm
√ √
[Ans.] moment of inertia of the object in the figure =
b¤^i eÈbt (3.0679 − 1.302) = 1.7659 kgm [Ans.]
2.5m e¨vmv‡a©i e„ËvKvi cv‡Zi RoZvi åvgK = 3.0679 kgm ; wbY©q Marks Distribution:
Kivi Rb¨ 04 b¤^i| 04 marks for determining, moment of inertia of the circular
eM©vKvi cv‡Zi RoZvi åvgK = 1.302 kgm ; wbY©q Kivi Rb¨ 04 disc with 2.5 m radius = 3.0679 kgm
b¤^i| 04 marks for determining, moment of inertia of the square
plate = 1.302 kgm
wP‡Îi RoZvi åvgK = 1.7659 kgm ; wbY©q Kivi Rb¨ 02 b¤^i|
02 marks for determining, moment of inertia of the object
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|]
in the figure = 1.7659 kgm
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.]

c`v_©weÁvb Phy
22 10

2 m ˆ`‡N©¨i GKwU myZv Øviv hy³ 500 g f‡ii ee‡K Djø‡¤^i mv‡_ 60 ° A bob of mass 500 g suspended from a 2 m long string is
†Kv‡Y bZ K‡i †Q‡o w`‡j, Gi cybivq Djø¤^ Ae¯’v‡b Avm‡Z KZ mgq released aligning it at 60 ° with the vertical. What is the
jvM‡e? time to return to the vertical position?

θ = 60 − θ θ = 60 − θ
E =E E =E
⇒ mg(l − l cos 60°) = mg(l − l cos θ ) + mv ⇒ mg(l − l cos 60°) = mg(l − l cos θ ) + mv
⇒ v = 2gl(cos θ − cos 60°) ⇒ v = 2gl(cos θ − cos 60°)
⇒ v = 2gl [cos(60° − θ) − cos 60°] ⇒ v = 2gl [cos(60° − θ) − cos 60°]
⇒ w l = 2gl cos(60° − θ) − ⇒ w l = 2gl cos(60° − θ) −

⇒w= cos(60° − θ) − ⇒w= cos(60° − θ) −

⇒ = cos(60° − θ) − ⇒ = cos(60° − θ) −
° °
∴t=∫ ∴t=∫
( ° ) ( ° )

=∫ ∴ t = 0.7546 s =∫ ∴ t = 0.7546 s

[lower limit = 0.0001 a‡i] [Considering lower limit = 0.0001]

b¤^i eÈbt Marks Distribution:
mg(l − l cos 60°) = mg(l − l cos θ ) + mv ; ‡jLvi Rb¨ 03 marks for writing, mg(l − l cos 60°) = mg(l −
03 b¤^i| l cos θ ) + mv

w= cos(60° − θ) − ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, w = cos(60° − θ) −

° °
t=∫ ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, t = ∫
( ° ) ( ° )

t = 0.7546 s ; wbY©q Kivi Rb¨ 03 b¤^i| 03 mark for determining, t = 0.7546 s

[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|] [Note: 01 mark will be deducted if unit is not written or
wrong unit is written.]

c`v_©weÁvb Phy
23 10

1 kg f‡ii GKwU cv_‡ii UzKiv‡K 10 m j¤^v GKwU myZvq †e‡a wP‡Îi A piece of stone of 1 kg is tied with a 10m long thread and
g‡Zv K‡i Avbyf‚wgK e„ËvKvi c‡_ †Nviv‡bv n‡”Q| myZvwU m‡e©v”P 12 N fvi rotated in the horizontal plane like as the figure. The thread
mn¨ Ki‡Z cv‡i| my‡Zv bv wQ‡o m‡e©v”P KZ †e‡M cv_iwU‡K †Nviv‡bv m¤¢e? can bear maximum 12N force. At what maximum velocity
the stone can be rotated without tearing off the thread?
AB = l AB = l
= T sin θ … (i) = T sin θ … (i)
mg = T cos θ … (ii) mg = T cos θ … (ii)
(i) I (ii) n‡Z, sin θ + cos θ = + From (i) & (ii), sin θ + cos θ = +

=1− ⇒v= 1− =1− ⇒v= 1−

× × . × × .
= 1− ( )
= 6.32 ms = 1− ( )
= 6.32 ms

b¤^i eÈbt Marks Distribution:

= T sin θ; ‡jLvi Rb¨ 02 b¤^i| 02 marks for writing, = T sin θ
mg = T cos θ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, mg = T cos θ

v= 1− ; wbY©q Kivi Rb¨ 04 b¤^i| 04 marks for determining, v = 1−

v = 6.32 ms ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, v = 6.32 ms

[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| m~Î bv [Note: 01 mark will be deducted if unit is not written or
wrong unit is written. Direct input of values without writing
wj‡L mivmwi gvb emv‡jI m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|]
formula is also acceptable.]

c`v_©weÁvb Phy
24 10
1kg f‡ii GKwU KYv x-Aÿ eivei Pj‡Q| Gi wefekw³i mgxKiY A particle of 1 kg mass is moving along x-axis. The
V(x) = x − x J| KYvwUi †gvU hvwš¿K kw³ 2J n‡j, KYvwUi equation of its potential energy is V(x) = x − x J. If
me©wb¤œ MwZ‡eM wbY©q Ki| [†hLv‡b, 0 ≤ x ≤ 1.5] the total mechanical energy of the particle is 2J, then what
is the minimum velocity of the particle? [Where, 0 ≤ x ≤
1.5]
[me©wb¤œ MwZ‡e‡Mi Rb¨ wefekw³ m‡e©v”P n‡e|] [For minimum velocity, potential energy will be maximum]
m‡e©v”P wef‡ei Rb¨, =0 For maximum potential, =0
⇒ x − x = 0 ⇒ x(x − 1) = 0 ⇒ x − x = 0 ⇒ x(x − 1) = 0
∴ x = 0,1 ∴ x = 0,1
= 2x − 1 = 2x − 1

x = 0 n‡j, = −1 < 0 x=0, = −1 < 0

x = 1 n‡j, =1>0 x=1, =1>0

∴ x = 0 Gi Rb¨ wefekw³ m‡e©v”P n‡e| ∴ For x = 0, Potential energy will be maximum.
V(0) = 0 V(0) = 0
∴E +0=2 ∴E +0=2
∴ mv =2⇒v =4 ∴ mv =2⇒v =4
⇒v = 2 ms (Ans.) ⇒v = 2 ms (Ans.)
b¤^i eÈbt Marks Distribution:
x = 0,1 ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, x = 0,1
m‡e©v”P wefekw³ V(0) = 0 ; wbY©q Kivi Rb¨ 04 b¤^i| 04 marks for determining, maximum potential energy,
V(0) = 0
v = 2 ms ; wbY©q Kivi Rb¨ 04 b¤^i|
04 marks for determining, v = 2 ms
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|]
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.]

c`v_©weÁvb Phy
25 10

wPÎvbyhvqx, m f‡ii e¯‘wU m f‡ii e¯‘wU‡K av°v w`‡q Df‡q kã According to the figure, the object with m mass collided with
K‡i GK‡Î Pj‡Z jvMj| h = 0.2m n‡j KZUzKz kw³ kãkw³‡Z the object with m mass and then they started moving together
iæcvšÍwiZ n‡e? as a combined body with sound. If h = 0.2m, then how much
energy will be converted into sound energy?
m u + m u = (m + m )v m u + m u = (m + m )v
⇒ 1.4 + 2.1 = 3. v ∴ v = 2 ms ⇒ 1.4 + 2.1 = 3. v ∴ v = 2 ms
msN‡l©i Av‡M †gvU kw³, E = m u + m u = 9 J Total energy before the collision, E = m u + m u = 9 J
msN‡l©i ci †gvU kw³, E = (m + m ). v + m gh = Total energy after the collision, E = (m + m ). v +
6 + 1. g. h = 7.96J m gh = 6 + 1. g. h = 7.96J
∴ kã kw³‡Z iæcvšÍwiZ n‡e = (9 − 7.96) = 1.04 J [Ans.] ∴ Converted into sound energy = (9 − 7.96) = 1.04 J [Ans.]
b¤^i eÈbt Marks Distribution:
v = 2 ms ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, v = 2 ms
E = 9 J ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, E = 9 J
03 marks for determining, E = 7.96J
E = 7.96J ; wbY©q Kivi Rb¨ 03 b¤^i|
02 marks for determining, converted energy = 1.04 J
kw³ iæcvšÍwiZ n‡e = 1.04 J ; wbY©q Kivi Rb¨ 02 b¤^i|
[Note: 01 mark will be deducted if unit is not written or wrong
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|] unit is written.]

c`v_©weÁvb Phy
26 10

1kg f‡ii GKwU w¯’i e¯‘ 20m `~iZ¡ †_‡K 10 ms Z¡i‡Y hvÎv ïiæ A stationary object of mass 1kg starts travelling from a
K‡i 3kg f‡ii e¯‘‡K AvNvZ K‡i GK‡Î Pj‡Z _v‡K, hv GKwU w¯úªs Gi distance of 20m with an acceleration of 10ms and strikes
mv‡_ hy³| w¯úªswUi m‡e©v”P ms‡KvPb 0.1 cm n‡j, w¯úªswUi ej aªæeK wbY©q an object of 3kg mass which is attached to a spring.
Ki| Determine the force constant if the maximum contraction of
the spring is 0.1 cm.

v = √2as = √2 × 20 × 10 = 20ms v = √2as = √2 × 20 × 10 = 20ms

fi†e‡Mi msiÿYkxjZvi bxwZ Abyhvqx, m u + 0 = (m + According to the conservation law of momentum,
m )v ⇒ 1 × 20 = 4v ∴ v = 5ms m u + 0 = (m + m )v ⇒ 1 × 20 = 4v ∴ v =
kw³i msiÿYkxjZvi bxwZ Abyhvqx, 5ms According to the conservation law of energy,
mv′ = kx ⇒ ×4×5 = × kx mv′ = kx ⇒ ×4×5 = × kx
⇒ k = 10 Nm ⇒ k = 10 Nm
b¤^i eÈbt Marks Distribution:
v = 20ms ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, v = 20ms
v = 5ms ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, v = 5ms
04 marks for determining, k = 10 Nm
k = 10 Nm ; wbY©q Kivi Rb¨ 04 b¤^i|
[Note: 01 mark will be deducted if unit is not written or
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| m~Î bv
wrong unit is written.]
wj‡L mivmwi gvb emv‡jI m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|]

c`v_©weÁvb Phy
27 10
†gvU‡ii `ÿZv 90% hv †µb‡K Pvjbv Ki‡Q| †µ‡bi `ÿZv 50%| hw` A motor of 90% efficiency is running a crane. The
†gvU‡ii ÿgZv 3.98 kW nq, Z‡e †µbwU 746 N IR‡bi e¯‘‡K KZ Mo efficiency of the crane is 50%. If the power of the motor is
†e‡M Dc‡i DVv‡Z cvi‡e? 3.98 kW, then with what average velocity the crane will be
able to lift an object of 746 N weight?
†gvU‡ii Kvh©Ki ÿgZv p = (0.9 × 3.98 × 10 )W = 3582 W Effective power of the motor, p = (0.9 × 3.98 ×
†µ‡bi Kvh©Kix ÿgZv p = 0.5p = (0.5 × 3582)W 10 )W = 3582 W
= 1791 W Effective power of the crane, p = 0.5p = (0.5 ×
Gevi, p = Fv ∴ v = = 2.4 ms (Ans.) 3582)W
= 1791 W
b¤^i eÈbt
Now, p = Fv ∴ v = = 2.4 ms (Ans.)
†gvU‡ii Kvh©Ki ÿgZv p = 3582 W ; wbY©q Kivi Rb¨ 03 b¤^i|
Marks Distribution:
†µ‡bi Kvh©Kix ÿgZv p = 1791 W ; wbY©q Kivi Rb¨ 03 b¤^i|
03 marks for determining, effective power of the motor,
v = 2.4 ms ; wbY©q Kivi Rb¨ 04 b¤^i|
p = 3582 W
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|]
03 marks for determining, effective power of the crane,
p = 1791 W
04 marks for determining, v = 2.4 ms
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.]

imvqb Chem
28 10

[A, B cÖPwjZ †gŠ‡ji cÖZxK bq] [A, B are not conventional symbol of elements]
A I B Øviv MwVZ †hŠMmg~‡ni Av`©ªwe‡kølY †KŠkj eY©bv Ki| Describe the mechanism of hydrolysis of compounds formed
by A and B.
A → P (dmdivm); B → Cl (†K¬vwib) A → P (Phosphorus); B → Cl (Chlorine)
Compound formed by A and B → PCl , PCl
A I B Øviv MwVZ †hŠM → PCl , PCl Hydrolysis of PCl : PCl + 3H O → H PO + 3HCl
PCl Gi Av`©ªwe‡kølYt PCl + 3H O → H PO + 3HCl

Hydrolysis of PCl : PCl + H O → POCl + 2HCl

PCl Gi Av`ª©we‡kølYt PCl + H O → POCl + 2HCl

PCl + 3H O → H PO + 3HCl
PCl + 3H O → H PO + 3HCl ∴ PCl + 4H O → H PO + 5HCl
∴ PCl + 4H O → H PO + 5HCl Marks Distribution:
b¤^i eÈbt 02 marks for writing the compounds formed by A and
A I B Øviv MwVZ †hŠMmg~n PCl , PCl ;‡jLvi Rb¨ 02 b¤^i| B are PCl , PCl .
A I B Øviv MwVZ †hŠMmg~‡ni Av`©ªwe‡kølY †KŠkj eY©bv Kivi Rb¨ (04× 02) = 08 marks for describing the mechanism of
hydrolysis of compounds formed by A and B.
(04×02) = 08 b¤^i|

imvqb Chem
29 10
mwbœ‡ek msL¨v mgvb n‡jI [Ni(CO) ] Ges [Ni(CN) ] G †K›`ªxq Though the coordination number of [Ni(CO) ] and
cigvYyi msKiY wfbœ-e¨vL¨v Ki| [Ni(CN) ] is same, the hybridization of their central atom
is different-Explain.
Dfq †ÿ‡Î mwbœ‡ek msL¨v 4| Coordination number in both cases is 4.
[Ni(CO) ]: [Ni(CO) ]:
Ni → [Ar] 3d 4s 4p Ni → [Ar] 3d 4s 4p

kw³kvjx wjM¨vÛ CO Gi cÖfv‡e: Due to the effect of strong ligand CO:

kw³kvjx wjM¨v‡Ûi cÖfv‡e 4s G Dcw¯’Z B‡jKUªb †Rvo 3d AiweUv‡j Due to the effect of strong ligand, the electron pair present
cybweb©¨¯Í nq Ges 1 wU s I 3 wU p AiweUvj CO KZ©„K `vbK…Z e †Rvo in 4s gets rearranged in 3d orbital and one s and three p
MÖnY K‡i [Ni(CO) ] MVb K‡i| orbitals accept e pair donated by CO and forms [Ni(CO) ].
∴ [Ni(CO) ] †K›`ªxq cigvYy Ni sp msKwiZ| ∴The central atom of [Ni(CO) ], Ni is sp hybridized.
[Ni(CN) ] :
[Ni(CN) ] :
Ni → [Ar]3d 4s 4p
Ni → [Ar]3d 4s 4p

Due to the effect of strong ligand CN :

kw³kvjx wjM¨vÛ CN Gi cÖfv‡e:

Due to the effect of strong ligand, the electrons present in

kw³kvjx wjM¨v‡Ûi cÖfv‡e 3d AiweUv‡ji B‡jKUªbmg~n cybweb©¨¯Í nq
3d gets rearranged orbital and one s and two p orbitals
Ges 1 wU duvKv d AiweUvj, 1 wU s Ges 2 wU p AiweUvj CN KZ…©K
accept lone pair e donated by CN and forms
`vbK…Z gy³‡Rvo e MÖnY K‡i [Ni(CN) ] MVb K‡i| [Ni(CN) ] .
∴ [Ni(CN) ] †K›`ªxq cigvYy Ni dsp msKwiZ| ∴The central atom of [Ni(CN) ] , Ni is dsp
b¤^i eÈbt Marks Distribution:
Ni Gi mvaviY B‡j±ªb web¨vm †jLvi Rb¨ 02 b¤^i| 02 marks for writing the general electron configuration of
kw³kvjx CO wjM¨v‡Ûi cÖfv‡e, Ni cybwe©b¨¯Í nq †`Lv‡bvi Rb¨ 02 b¤^i| Ni.
[Ni(CO) ] †K›`ªxq cigvYy Ni sp msKwiZ; †jLvi Rb¨ 01 b¤^i| 02 marks for showing the rearranged configuration for the
Ni Gi mvaviY B‡j±ªb web¨vm †jLvi Rb¨ 02 b¤^i| effect of strong ligand CO.
kw³kvjx CN wjM¨v‡Ûi cÖfv‡e, cybwe©b¨¯Í nq †`Lv‡bvi Rb¨ 02 b¤^i| 01 mark for writing the central atom hybridization of
[Ni(CO) ] is sp .
[Ni(CN) ] †K›`ªxq cigvYy Ni dsp msKwiZ; †jLvi Rb¨ 01
02 marks for writing the general electron configuration of
b¤^i|
Ni .
02 marks for showing the rearranged configuration for the
effect of strong ligand CN .
01 mark for writing the central atom hybridization of
[Ni(CN) ] is dsp .

imvqb Chem
30 10
jNy H SO `ªe‡Y 2.7 g bgybv meyR wfwUªIj †hvM K‡i 150 mL `ªeY A 150 mL solution is prepared by adding 2.7 g of sample
cÖ¯Z
‘ Kiv n‡jv| G `ªe‡Yi 25mL †K RvwiZ Ki‡Z green vitriol in diluted H SO solution. For oxidizing 25mL
20 mL 0.016 M KMnO `ªeY cÖ‡qvRb nq| bgybv meyR wfwUªI‡ji of this solution, 20 mL 0.016 M KMnO solution is required.
weï×Zvi kZKiv cwigvY wbY©q Ki| Determine the percentage of purity of the sample green
vitriol solution.
awi, 25 mL G weï× meyR wfwUªI‡ji †gvjmsL¨v = n = n Let, the mole number in pure green vitriol is 25 mL = n =
2KMnO + 10FeSO + 8H SO ⎯⎯ 5Fe (SO ) + n
K SO + 2MnSO + 8H O 2KMnO + 10FeSO + 8H SO ⎯⎯ 5Fe (SO ) +
(ne) = (ne) K SO + 2MnSO + 8H O
∴n × 1 = 5 × 20 × 10 × 0.016 (ne) = (ne)
∴n = n = 1.6 × 10 ∴n × 1 = 5 × 20 × 10 × 0.016
∴ 25 mL G weï× meyR wfwUªIj = (1.6 × 10 × 277.85) g = ∴n = n = 1.6 × 10
0.445 g ∴ Pure green vitriol in 25 mL = (1.6 × 10 × 277.85) g =
∴ 150 mL G weï× meyR wfwUªIj = × 0.445 g = 2.67 g 0.445 g
. ∴ Pure green vitriol in 150 mL = × 0.445 g = 2.67 g
∴ weï×Zv = × 100% = 98.89%
. .
b¤^i eÈbt ∴ Purity = × 100% = 98.89%
.
2KMnO + 10FeSO + 8H SO ⎯⎯ 5Fe (SO ) + Marks distribution:
K SO + 2MnSO + 8H O ‡jLvi Rb¨ 02 b¤^i| 02 marks for writing 2KMnO + 10FeSO +
n = n = 1.6 × 10 wbY©‡qi Rb¨ 03 b¤^i| 8H SO ⎯⎯ 5Fe (SO ) + K SO + 2MnSO + 8H O
150 mL G weï× meyR wfwUªIj = 2.67 g wbY©‡qi Rb¨ 03 b¤^i| 03 marks for determining n = n = 1.6 × 10
weï×Zv = 98.89% wbY©‡qi Rb¨ 02 b¤^i| 03 marks for determining Pure green vitriol in 150 mL =
[we: `ª: GKK bv wjL‡j ev fzj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| 2.67 g
m~Î bv ewm‡q mivmwi gvb emv‡j I m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|] 02 marks for determining Purity = 98.89%
[N. B: 01 mark will be deducted if unit is not written or
wrong unit is written or for not determining in nanometer
unit. Direct input of values without writing the formula is
also acceptable.]

imvqb Chem
31 10
(i) Na avZz‡K †K‡ivwm‡bi g‡a¨ msiÿY Kiv nq †Kb? (i) Why is Na metal preserved in kerosene?
(ii) Li avZz‡K †K‡ivwm‡bi cwie‡Z© c¨vivwdb †gvg w`‡q Rwo‡q ivLv nq (ii) Why is Li metal wrapped in paraffin wax instead of
†Kb? preserving in kerosene?
(iii) NCl MwVZ bv n‡jI N O MwVZ nq †Kb? (iii) Why is N O formed, although NCl is not formed?
(i) Na AZ¨šÍ mwµq avZz| Bnv cvwbi mv‡_ wewµqv K‡i H M¨vm Drcbœ (i) Na is a very reactive metal. It reacts with water to
K‡i Ges Av¸b a‡i hvq| evqyi O Gi mv‡_I wewµqv K‡i †d‡j| ZvB produce H gas and catches fire. It also reacts with O of the
GwU‡K †K‡ivwm‡bi g‡a¨ msiÿY Kiv nq| air. So, it is preserved in kerosene.
2Na + 2H O → 2NaOH + H 2Na + 2H O → 2NaOH + H
Na + O → Na O Na + O → Na O
Na O + CO → Na CO Na O + CO → Na CO
(ii) wjw_qvg evqyi Dcv`v‡bi mv‡_ wewµqv K‡i| GwU‡K †K‡ivwm‡b ivLv (ii) Li reacts with the components of air. When it is kept in
n‡j GwU †f‡m D‡V Ges evqyi ms¯ú‡k© P‡j Av‡m| KviY GwU AZ¨šÍ kerosene, it floats and comes in contact with air. Because it
nvjKv avZz| ZvB G‡K †K‡ivwm‡bi cwie‡Z© c¨vivwdb †gv‡g Rwo‡q ivLv is a very light metal. So, it is wrapped in paraffin wax
nq| instead of preserving in kerosene.
Li + O → Li O Li + O → Li O
(iii) N → 1s 2s 2p 2p 2p (iii) N → 1s 2s 2p 2p 2p
N Gi me©‡kl kw³¯Í‡i d AiweUvj _vKv m¤¢e bq| ZvB N m‡e©v”P 3wU In the last energy level of N, no d-orbital is possible. So N
we‡Rvo B‡jKUªb wewkó AiweUvj MVb Ki‡Z cv‡i| ZvB NCl MVb m¤¢e can produce orbital having a maximum of 3 unpaired
electrons. Hence formation of NCl is not possible. But in
bq| wKš‘ Zxeª Zwor FYvZ¥K O Gi Dcw¯’wZ‡Z N Gi me©‡kl kw³¯Í‡ii
the presence of highly electronegative O, N donates the
B‡jKUªb †Rvo `vb K‡i d‡j N O MwVZ nq| ZvB NCl MwVZ bv
electron pair of its outermost energy level and produces
n‡jI N O MwVZ nq|
N O . So N O is formed, although NCl is not formed.
b¤^i eÈbt
Marks distribution:
(i)Na AZ¨šÍ mwµq avZz, cvwbi mv‡_ wewµqv K‡i H M¨vm Drcbœ K‡i (i) 01 mark for writing, Na is a very reactive metal, it reacts
Ges Av¸b a‡i hvq ; †jLvi Rb¨ 01 b¤^i| with water to produce H gas and catches fire.
wewµqv mwVKfv‡e †jLvi Rb¨ 02 b¤^i| 02 marks for writing three reactions correctly.
(ii) wjw_qvg AZ¨šÍ nvjKv avZz, GwU‡K †K‡ivwm‡b ivLv n‡j GwU †f‡m (ii) 01 mark for writing, Lithium is very light, when it is
D‡V Ges evqyi ms¯ú‡k© P‡j Av‡m; †jLvi Rb¨ 01 b¤^i| kept in kerosene, it floats and comes in contact with air.
wewµqvwU †jLvi Rb¨ 01 b¤^i| 01 mark for writing the reaction.
(iii) N Gi B‡j±ªb web¨vm †jLvi Rb¨ 01 b¤^i| (iii) 01 mark for writing the electronic configuration of N.
N m‡e©v”P 3wU we‡Rvo B‡jKUªb wewkó AiweUvj MVb Ki‡Z cv‡i, ZvB 02 marks for writing, N can produce orbital having
NCl MVb m¤¢e bq; †jLvi Rb¨ 02 b¤^i| maximum 3 unpaired electrons.
Zxeª Zwor FYvZ¥K O Gi Dcw¯’wZ‡Z N Gi me©‡kl kw³¯Í‡ii B‡jKUªb 02 marks for writing, due to the presence of highly
†Rvo `vb K‡i, N O MwVZ nq; †jLvi Rb¨ 02 b¤^i| electronegative O, N donates the electron pair of its
outermost energy level and produces N O .

imvqb Chem
32 10
(a) PbI †hŠMwU eY©hy³ nq †Kb? (a) Why is the compound PbI coloured?
(b) HF I H O Df‡q nvB‡Wªv‡Rb eÜb MVb Ki‡jI ù‚Ubvs‡K wfbœZv (b) Why does the boiling point of both HF and H O differ
†`Lvq †Kb? inspite of forming hydrogen bonds?
(a) PbI †hŠ‡M I Avq‡bi †cvjvivqb N‡U| †cvjvivwqZ Ae¯’vq eY© (a) Polarization of I ion takes place in PbI compound. The
m„wói g~j KviY n‡jv- A¨vbvq‡bi AvKvi e„w×i mv‡_ †cvjvivqb †hgb main reason for the formation of color in the polarized state
mn‡R N‡U, †Zgwb A¨vbvq‡bi c~Y© AiweUvj †_‡K K¨vUvq‡bi Lvwj Kiv is that-as polarization occurs easily with the increase in the
AiweUv‡j B‡jKUª‡bi ÿwYK ¯’vbvšÍi mn‡R N‡U _v‡K| ZLb cÖ‡qvRbxq size of the anion, the instantaneous transfer of electrons
Kg kw³ `„k¨gvb Av‡jv †_‡K †kvwlZ nq Ges Aewkó Av‡jvi e‡Y© †hŠMwU from the full-filled orbitals of the anions to the vacated
eY©hy³ nq| ZvB PbI †mvbvjx njy` eY©hy³| orbitals of the cations occurs easily. The required small
(b) HF AYy‡Z Zwor FYvZ¥KZvi cv_©K¨ m‡e©v”P (1.9) n‡jI PvR© energy is then absorbed from the visible light and the
c„_KxKiY Kg| Gi AYyi `y cÖv‡šÍ GKwU δ Ges GKwU δ PvR© m„wói compound is colored by the color of the remaining light. So
d‡j cÖwZ WvB‡cvj `yB cv‡k `yBwU H-eÜb MVb K‡i| PbI is golden yellow in color.
wKš‘, H O AYy‡Z `yBwU H-cÖv‡šÍ `yBwU δ Ges O- cÖv‡šÍ 2δ m„wó nq| (b) Though the electronegativity difference is highest (1.9)
in HF molecule, charge dissociation is less. Due to the
d‡j PviwU AvswkK PvR© ( `yBwU δ , `yBwU δ ) e¨envi K‡i cÖwZwU H O
formation of δ and δ charge at the two ends of its
WvB‡cvj cvk^©eZ©x Aci PviwU WvB‡cv‡ji wecixZ PvR©hy³ cÖv‡šÍi m‡½
molecule, H- bonds are formed on either side of each dipole.
PviwU H-eÜb MV‡bi cÖeYZv †`Lvq|
But, in H O molecule, two δ is formed at the two H-
d‡j, H O AYy¸‡jvi g‡a¨ Kvh©Ki AvK©lY e‡ji ZxeªZv †ewk _v‡K| ZvB
terminal and 2δ at the O-terminal. As a result, using four
wecyj msL¨K H O AYyi ms‡hv‡M weivU AvYweK ¸”Q m„wó nq| G Kvi‡Y
partial charges (two δ ,two δ ), each H O dipole tends to
cvwbi ù‚UbvsK (100 C) HF Gi ù‚UbvsK (19.5 C) A‡cÿv A‡bK form four H-bonds with the other four adjacent dipoles.
†ewk| As a result, the intensity of the effective force of attraction
b¤^i eÈbt among H O molecules is more. Therefore, large molecular
(a) PbI †hŠ‡M I Avq‡bi †cvjvivqb N‡U; †jLvi Rb¨ 01 b¤^i| clusters are formed by the association of a large number of
†cvjvivwqZ Ae¯’vq eY© m„wói g~j KviY- A¨vbvq‡bi AvKvi e„w×i mv‡_, H O molecules. Because of this, the boiling point of water
A¨vbvq‡bi c~Y© AiweUvj †_‡K K¨vUvq‡bi Lvwj Kiv AiweUv‡j B‡jKUª‡bi (100 C) is much higher than the boiling point of
ÿwYK ¯’vbvšÍi mn‡R N‡U; †jLvi Rb¨ 02 b¤^i| HF (19.5 C).
PbI †mvbvjx njy` eY©hy³; †jLvi Rb¨ 01 b¤^i| Marks distribution:
(b) HF AYyi `y cÖv‡šÍ GKwU δ Ges GKwU δ PvR© m„wói d‡j cÖwZ (a) 01 mark for writing, polarization of I ion takes place in
WvB‡cvj `y cv‡k `yBwU H- eÜb MVb K‡i; †jLvi Rb¨ 02 b¤^i| PbI compound.
cÖwZwU H O WvB‡cvj cvk^©eZ©x Aci PviwU WvB‡cv‡ji wecixZ PvR©hy³ 02 marks for writing, the formation of color in the polarized
cÖv‡šÍi m‡½ PviwU H-eÜb MV‡bi cÖeYZv †`Lvq; †jLvi Rb¨ 02 b¤^i| state is that- with the increase in the size of the anion, the
cvwbi ù‚UbvsK (100 C) HF Gi ù‚UbvsK (19.5 C) A‡cÿv A‡bK instantaneous transfer of electrons from the full-filled
†ewk; †jLvi Rb¨ 02 b¤^i| orbitals of the anions to the vacated orbitals of the cations
occurs easily.
01 mark for writing, PbI is golden yellow in color.
(b) 02 marks for writing, due to the formation of δ and δ
charge at the two ends of HF molecule, H- bonds are formed
on either side of each dipole.
02 marks for writing, each H O dipole tends to form four H-
bonds with the other four adjacent dipoles.
02 marks for writing the boiling point of water (100 C) is
much higher than the boiling point of HF (19.5 C)

imvqb Chem
33 10
0.693 kg cwigvY `¯Ívi mv‡_ AwZwi³ mvjwdDwiK Gwm‡Wi wewµqvq How many ballons of volume 5 dm can be inflated by the
Drcbœ nvB‡Wªv‡Rb M¨vm Øviv 5 dm AvqZ‡bi KZwU †ejyb fwZ© Kiv Hydrogen gas produced when 0.693 kg Zinc reacts with
hv‡e? [†ejy‡bi wfZ‡ii Pvc 780 mm(Hg) I ZvcgvÎv 27 C] excess Sulphuric acid? [Pressure inside the balloon is
780 mm(Hg) and temperature is 27 C]
Zn + H SO → ZnSO + H Zn + H SO → ZnSO + H
. .
. × . ×
∴ 0.693 kg Zn Gi wewµqvq Drcbœ n‡e
.
= ∴ Reaction of 0.693kg Zn produces =
.
10.59 mol H M¨vm 10.59 mol H gas
awi, GKwU †ejyb fwZ© Ki‡Z n mol H M¨vm cÖ‡qvRb| Let, to inflate one balloon n mol H gas is required.
× ×
PV = nRT ⇒ n = = = 0.208 mol PV = nRT ⇒ n = = = 0.208 mol
. × . ×
∴ GKwU †ejyb fwZ© Ki‡Z 0.208 mol H M¨vm cÖ‡qvRb ∴ To inflate one balloon, 0.208 mol H gas is required.
. .
∴ †ejyb fwZ© Kiv hv‡e = = 50.91 ≈ 50 wU ∴ No. of balloons can be inflated = = 50.91 ≈ 50
. .
[Note: 51 wU †ejyb c~Y© n‡e bv| ZvB DËi 50 wU| [Note: 51 balloons can't be inflated. So, answer is 50.]
b¤^i eÈb: Mark distribution:
wewµqv: Zn + H SO → ZnSO + H ; ‡jLvi Rb¨ 02 b¤^i| 02 marks for writing the reaction, Zn + H SO →
. .

0.693 kg Zn Gi wewµqvq Drcbœ n‡e = 10.59 mol H M¨vm; ZnSO + H

wbY©‡qi Rb¨ 02 b¤^i| 02 marks for determining, the reaction of 0.693 kg Zn
GKwU †ejyb fwZ© Ki‡Z 0.208 mol H M¨vm cÖ‡qvRb; wbY©‡qi Rb¨ 03 produces = 10.59 mol H gas.
b¤^i| 03 marks for determining, to inflate one balloon,
†ejyb fwZ© Kiv hv‡e = 50.91 ≈ 50 wU; wbY©‡qi Rb¨ 03 b¤^i| 0.208 mol H gas is required.
[we: `ª: GKK bv wjL‡j ev fzj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| 03 marks for determining the no. of balloons can be inflated
m~Î bv ewm‡q mivmwi gvb emv‡j I m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|] = 50.91 ≈ 50
[N.B: 01 mark will be deducted if unit is not written or
wrong unit is written. Direct input of values without writing
the formula is also acceptable.]

imvqb Chem
34 10
75 mL 0.035 M 125 mL 0.003 M 75 mL 0.035 M 125 mL 0.003 M
A B solution MN solution A B solution MN solution

hw` AN Gi K = 9 × 10 nq, Z‡e cvÎ `ywUi `ªeY‡K wgwkÖZ If K of AN is 9 × 10 , then will there be any
Ki‡j †Kv‡bv Aa:†ÿc co‡e wK-bv e¨vL¨v Ki| precipitation when the solution of the two containers are
mixed together? Explain it.
A B ⇌ 3A + 2B A B ⇌ 3A + 2B
wgkÖ‡Y A Gi NbgvÎv: concentration of A in the mixture :
× × . × × .
S = = = 0.039 M S = = = 0.039 M
MN ⇌ M + 2N MN ⇌ M + 2N
wgkÖ‡Y N Gi NbgvÎv : concentration of N in the mixture :
× × . × × .
S = = = 3.75 × 10 M S = = = 3.75 × 10 M

∴ AN Gi K = [A ][N ] = 0.039 × (3.75 × ∴ K of AN = [A ][N ] = 0.039 × (3.75 × 10 ) =

10 ) = 5.48 × 10 5.48 × 10
K >K K >K
∴ wgwkÖZ `ªe‡Y †Kv‡bv Aa:‡ÿc co‡e bv| ∴ There will be no precipitation in the mixture.
b¤^i eÈbt Marks distribution:
A B ⇌ 3A + 2B †jLvi Rb¨ 01 b¤^i| 01 mark for writing A B ⇌ 3A + 2B
A Gi NbgvÎv = 0.039 M wbY©‡qi Rb¨ 02 b¤^i| 02 marks for determining the concentration of A =
0.039 M
MN ⇌ M + 2N †jLvi Rb¨ 01 b¤^i|
01 mark for writing MN ⇌ M + 2N
N Gi NbgvÎv = 3.75 × 10 M wbY©‡qi Rb¨ 02 b¤^i|
02 marks for determining the concentration of N =
K = 5.48 × 10 wbY©‡qi Rb¨ 03 b¤^i|
3.75 × 10 M
wgwkÖZ `ªe‡Y †Kv‡bv Aa:‡ÿc co‡e bv GUv †jLvi Rb¨ 01 b¤^i| 03 marks for determining K = 5.48 × 10
[we: `ª: GKK bv wjL‡j ev fzj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| 01 mark for writing there will be no precipitation in the
m~Î bv ewm‡q mivmwi gvb emv‡j I m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|] mixture.
[N. B: 01 mark will be deducted if unit is not written or
wrong unit is written or for not determining in nanometer
unit. Direct input of values without writing the formula is
also acceptable.]

imvqb Chem
35 10
wbw`©ó ZvcgvÎvq 100 mL 2.5 × 10 M FeCl Gi Rjxq `ªe‡Y If 50 mL 0.5M NaOH is mixed with the aqueous solution of
50 mL 0.5M NaOH `ªeY †hvM Ki‡j 1.5 × 10 g Fe(OH) 100 mL 2.5 × 10 M FeCl at a fixed temperature, green
Gi meyR e‡Y©i Aat‡ÿc c‡o| H ZvcgvÎvq Fe(OH) Gi `ªve¨Zv colored precipitate of 1.5 × 10 g Fe(OH) will be formed.
¸Ydj KZ? What will be the solubility product of Fe(OH) at that
temperature?
Fe Av‡M wQj 2.5 × 10 mol Previous amount of Fe = 2.5 × 10 mol
. × . ×
Aatwÿß Fe(OH) = mol = 1.67 × 10 mol Precipitated Fe(OH) = mol = 1.67 × 10 mol
. × . ×
∴ `ªexf~Z Av‡Q (2.5 − 1.67) × 10 mol Fe(OH) = ∴ Dissolved in the solution = (2.5 − 1.67) ×
8.3 × 10 mol Fe(OH) 10 mol Fe(OH) = 8.3 × 10 mol Fe(OH)
. × . ×
∴ `ªe‡Y [Fe ]= M = 5.53 × 10 M ∴ In solution [Fe ] = M = 5.53 × 10 M
. .

. × × . × . × × . ×
[OH ] = − M = 0.167 M [OH ] = − M = 0.167 M

∴ K (Fe(OH) ) = 5.53 × 10 × (0.167) = ∴ K (Fe(OH) ) = 5.53 × 10 × (0.167) =

1.54 × 10 1.54 × 10
b¤^i eÈb: Mark distribution:
`ªe‡Y [Fe ] = 5.53 × 10 M wbY©‡qi Rb¨ 03 b¤^i| 03 marks for determining [Fe ] = 5.53 × 10 M
[OH ] = 0.167 M wbY©‡qi Rb¨ 03 b¤^i| 03 marks for determining [OH ] = 0.167 M
K (Fe(OH) ) = 1.54 × 10 wbY©‡qi Rb¨ 04 b¤^i| 04 marks for determining K (Fe(OH) ) = 1.54 × 10
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| m~Î [Note: 01 mark will be deducted if unit is not written or
bv wj‡L mivmwi gvb emv‡jI M«nY‡hvM¨ n‡e|] wrong unit is written. Direct input of values without writing
the formula is also acceptable.]

imvqb Chem
36 10
Rjxq `ªe‡Y Zn I Fe Avq‡bi kbv³Ki‡Y `ywU mvaviY weKvi‡Ki bvg Write the name of two common reagents which can
wjL I wewµqvmg~n †`LvI| identify Zn and Fe ions in aqueous solution and
show the reactions.

b¤^i eÈbt Marks Distribution:

Identify of Zn and Fe ions in aqueous solution-
Rjxq `ªe‡Y Zn I Fe Avq‡bi kbv³Ki‡Y- (02×02) = 04 marks for writing the name of two
`ywU K‡i mvaviY weKvi‡Ki bvg ‡jLvi Rb¨; (02×02) = 04 b¤^i| common reagents
`ywU K‡i wewµqv; ‡jLvi Rb¨ (1.5×04) = 06 b¤^i| (1.5×04) = 06 marks for writing two reactions.

imvqb Chem
37 10
(a) Li Gi Z…Zxq AvqbxKiY kw³ †ei Ki| (a) Determine the 3rd ionization energy of Li.
(b) nvB‡Wªv‡Rb cvigvYweK eY©vwji dzb&W wmwi‡Ri wØZxq jvBb Gi Zi½‰`N©¨ (b) Determine the wavelength of the 2nd line of Pfund
wbY©q Ki| series of the atomic spectrum of Hydrogen.

(a) Li Gi cÖ_g Kÿc‡_i e Gi kw³ E = × (a) Energy of e in the 1st orbit of Li , E =

×( . ) × . × × . × ×
= ( . )
× =
× ×( . ) × . × × . ×
−1.962 × 10 J (cÖvq) = ( . )
× =
×

∴ AvqbxKiY kw³ = +1.962 × 10 J atom −1.962 × 10 J (approx.)

weKí: ∴ Ionization energy = +1.962 × 10 J atom
Alternative:
AvqbxKiY kw³ = R − × hc ×
Ionization energy = R − × hc ×
= 1.09678 × 10 m × − × 6.626 × 10 Js × 3 ×
= 1.09678 × 10 m × − × 6.626 ×
10 ms ×
= 1.962 × 10 J atom (Ans. ) 10 Js × 3 × 10 ms ×
b¤^i eÈb: = 1.962 × 10 J atom (Ans. )
Mark distribution:
E = × m~‡Îi Rb¨ 02 b¤^i|
02 marks for writing the formula, E = ×
ev, AvqbxKiY kw³ = R − × hc × m~‡Îi Rb¨ 02 b¤^i|
Or, 02 marks for writing the formula, Ionization energy
AvqbxKiY kw³ = 1.962 × 10 J atom wbY©‡qi Rb¨ 03 b¤^i|
=R − × hc ×
[we.`ªt hyw³ msMZ †h‡Kv‡bv wbqg MÖnY‡hvM¨ n‡e| GKK bv wjL‡j ev fzj GKK
wjL‡j 01 b¤^i KvUv hv‡e| m~Î bv wj‡L mivmwi gvb emv‡jI m~‡Îi Rb¨ 03 marks for determining ionization energy=
eivÏK…Z b¤^i cv‡e|] 1.962 × 10 J atom
(b) wiWev‡M©i mgxKiY g‡Z, [N.B: Any logical method also acceptable. 01 mark will
be deducted if unit is not written or wrong unit is
=R − = 1.097 × 10 m −
written. The mark allocated for the formula will be
∴ = 1.097 × 10 × − m provided even if the correct value is put directly without
writing the formula.]
[∵ n = 5 , n = 5 + 2 = 7] = 2.149 × 10 m
(b) According to Rydberg’s equation,
∴ λ = 4.653 × 10 m (Ans. )
b¤^i eÈbt =R − = 1.097 × 10 m −

=R − m~‡Îi Rb¨ 01 b¤^i| ∴ = 1.097 × 10 × − m [∵ n = 5 , n =

n Ges n Gi gvb mwVKfv‡e emv‡bvi Rb¨ (01×02) = 02 b¤^i| 5 + 2 = 7] = 2.149 × 10 m
λ = 4.653 × 10 m wbY©‡qi Rb¨ 02 b¤^i| ∴ λ = 4.653 × 10 m (Ans. )
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| m~Î bv Mark distribution:
wj‡L mivmwi gvb emv‡jI M«nY‡hvM¨ n‡e|] 01 marks for writing the formula, = R −
(01×02) = 02 marks for putting the values of n and n
correctly.
02 marks for determining, λ = 4.653 × 10 m
 [Note: 01 mark will be deducted if unit is not written or
wrong unit is written. Direct input of values without
writing the formula is also acceptable.]

imvqb Chem
38 10
2.5 g bgybv CaCO †K 50 mL 2M HCl `ªe‡Y m¤ú~Y©iƒ‡c `ªexf‚Z K‡i cÖvß In order to completely neutralize the solution obtained
`ªeY‡K c~Y© cÖkwgZ Ki‡Z cÖ_‡g 20 mL 10% NaOH Ges cieZx©‡Z by dissolving 2.5 g sample CaCO in 50 mL 2M HCl
10 mL 0.5M NaOH `ªeY cÖ‡qvRb n‡jv| CaCO bgybvi weï×Zv wbY©q solution, initially 20 mL 10% NaOH and later on
Ki| 10 mL 0.5M NaOH is required. Determine the purity of
CaCO sample.
CaCO + 2HCl → CaCl + CO + H O CaCO + 2HCl → CaCl + CO + H O
NaOH + HCl → NaCl + H O NaOH + HCl → NaCl + H O
(ne) = (ne) + (ne) + (ne) (ne) = (ne) + (ne) + (ne)
⇒ 2 × 50 × 10 =2× + 10 × 10 × 0.5 + ⇒ 2 × 50 × 10 =2× + 10 × 10 × 0.5 +
× ×
20 × 10 × 20 × 10 ×
∴ W = 2.25 g ∴ W = 2.25 g
. .
∴ CaCO Gi weï×Zv = × 100% = 90% ∴ Purity of CaCO = × 100% = 90%
. .
b¤^i eÈbt Marks distribution:
CaCO + 2HCl → CaCl + CO + H O ‡jLvi Rb¨ 01 b¤^i| 01 mark for writing CaCO + 2HCl → CaCl + CO +
NaOH + HCl → NaCl + H O ‡jLvi Rb¨ 01 b¤^i| H O
W = 2.25 g wbY©‡qi Rb¨ 05 b¤^i| 01 mark for writing NaOH + HCl → NaCl + H O
CaCO Gi weï×Zv = 98.89% wbY©‡qi Rb¨ 03 b¤^i| 05 marks for determining W = 2.25 g; 05 marks.
[we: `ª: GKK bv wjL‡j ev fzj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| 03 marks for determining Purity of CaCO = 90%
m~Î bv ewm‡q mivmwi gvb emv‡j I m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|] [N. B: 01 mark will be deducted if unit is not written or
wrong unit is written or for not determining in
nanometer unit. Direct input of values without writing
the formula is also acceptable.]

imvqb Chem
39 10
Av‡qvwWwgwZK wewµqv Avqb-B‡jKUªb c×wZ‡Z mgZv Ki| [†mvwWqvg Balance the iodimetric reaction by ion electron method.
_v‡qvmvj‡dU I Av‡qvwWb e¨envi K‡i] [using Sodium Thiosulphate and Iodine]
RviY Aa© wewµq: 2S O → S O + 2e … … … (ii) Oxidation half reaction: 2S O → S O +
weRviY Aa© wewµqv: I + 2e → 2I … … … (i) 2e … … … (ii)
(i) + (ii) ⇒ I + 2S O → 2I + S O Reduction half reaction: I + 2e → 2I … … … (i)
`k©K Avqb Na †hvM K‡i, 2Na S O + I → Na S O + 2NaI (i) + (ii) ⇒ I + 2S O → 2I + S O
b¤^i eÈbt Adding spectator ion Na , 2Na S O + I →
RviY Aa©-wewµqv; ‡jLvi Rb¨ 03 b¤^i| Na S O + 2NaI
Marks distribution :
weRviY Aa©-wewµqv; ‡jLvi Rb¨ 03 b¤^i|
03 marks for writing: oxidation half-reaction.
K¼vj wewµqv †jLvi Rb¨ 04 b¤^i|
03 marks for writing: reduction half-reaction.
[we: `ª: RviY-weRviY Aa©-wewµqv Qvov mivmwi mgZv wewµqv †jLvi Rb¨ 02
04 marks for balancing the reaction by ion electron
b¤^i|]
method.
 [N.B : 02 marks for writing directly balanced reaction
without oxidation-reduction half reaction]

imvqb Chem
40 10
20g cwigvY Na CO I NaHCO Gi wgkÖ‡Y 45% NaHCO Amount of 20g mixture of Na CO and NaHCO contains
we`¨gvb| wgkÖYwU‡K AwZwi³ nvB‡Wªv‡K¬vwiK Gwm‡W `ªexf‚Z Ki‡j 37 C 45% NaHCO . What volume of gas will be produced if
I 760mm (Hg) Pv‡c KZ AvqZb M¨vm Drcbœ n‡e? excess HCl is dissolved in the mixture at 37 C and 760
mm (Hg) pressure?
NaHCO Gi cwigvY = 20 × 45% = 9g Amount of NaHCO = 20 × 45% = 9g
NaHCO + HCl → NaCl + CO + H O NaHCO + HCl → NaCl + CO + H O

∴ 9g †_‡K mol CO Drcbœ nq ∴ From 9g, mol CO is produced

Na CO + 2HCl → 2NaCl + CO + H O Na CO + 2HCl → 2NaCl + CO + H O

∴ 11g †_‡K mol CO Drcbœ nq ∴ From 11g, mol CO is produced

∴ †gvU CO = + mol = 0.211 mol ∴ Total, CO = + mol = 0.211 mol

∴ PV = nRT ⇒ 1 × V = 0.211 × 0.0821 × 310 ⇒ V = ∴ PV = nRT ⇒ 1 × V = 0.211 × 0.0821 × 310 ⇒ V =
5.3701 L = 5370 mL 5.3701 L = 5370 mL
b¤^i e›Ubt Mark distribution:
wgkÖ‡Y NaHCO Gi cwigvY = 9g ; wbY©‡qi Rb¨ 02 b¤^i| 02 marks for determining the amount of NaHCO in
NaHCO + HCl → NaCl + CO + H O; wewµqv ‡jLvi Rb¨ 01 mixture = 9g.
01 marks for writing the reaction: NaHCO + HCl →
b¤^i|
Na CO + 2HCl → 2NaCl + CO + H O; wewµqv ‡jLvi Rb¨ NaCl + CO + H O

01 b¤^i| 01 marks for writing the reaction: Na CO + 2HCl →

†gvU CO = 0.211 mol; wbY©‡qi Rb¨ 03 b¤^i| 2NaCl + CO + H O
†gvU CO M¨v‡mi AvqZb, V = 5370 mL; wbY©‡qi Rb¨ 03 b¤^i|
03 marks for determining the total CO = 0.211 mol.
[we: `ª: GKK bv wjL‡j ev fzj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|
03 marks for determining the total volume of CO gas, V
m~Î bv ewm‡q mivmwi gvb emv‡j I m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|]
= 5370 mL
[N.B: 01 mark will be deducted if unit is not written or
wrong unit is written. Direct input of values without
writing the formula is also acceptable.]