Unique Set. 01
Unique Set. 01
⇒y = = ⇒y = =
√ √ √ √
× √ √ × × √ √ ×
⇒y = ( )
⇒y = ( )
⇒y = = ⇒y = =
√ √ √ √
y = ⇒y x −x y =m y y = ( )
⇒y x −x y =m y
( )
⇒ 2y y x + 4x y − 2y y x − 2xy = m y y × 2 ⇒ 2y y x + 4x y − 2y y x − 2xy = m y y × 2
⇒ x (x − 1)y + x(2x − 1)y − m y = 0 (Proved) ⇒ x (x − 1)y + x(2x − 1)y − m y = 0 (Proved)
b¤^i eÈbt
p − q = 3; wbY©q Kivi Rb¨ 03 b¤^i| Mark Distribution:
03 marks for determining, p − q = 3
= 0 + 2q t − 2pq; wbY©q Kivi Rb¨ 03 b¤^i|
03 marks for determining, = 0 + 2q t − 2pq
p = 2, q = −1; wbY©q Kivi Rb¨ 04 b¤^i|
04 marks for determining, p = 2, q = −1
⇒ = ⇒ =
⇒ = ⇒ =
. . . .
∴ = =1 [(𝑥, 𝑦) = (1,2)] ∴ = =1 [(𝑥, 𝑦) = (1,2)]
∴ ¯úk©‡Ki mgxKiY, (y − 2) = 1(x − 1) ⇒ 𝑥 − 𝑦 + 1 = 0 ∴ Equation of tangent, (y − 2) = 1(x − 1) ⇒ 𝑥 − 𝑦 + 1 = 0
b¤^i eÈbt
Mark Distribution:
we›`y (1,2); wbY©q Kivi Rb¨ 02 b¤^i|
02 marks for determining, required point (1,2)
= ; wbY©q Kivi Rb¨ 04 b¤^i|
04 marks for determining, =
¯úk©‡Ki mgxKiY, 𝑥 − 𝑦 + 1 = 0 ; wbY©q Kivi Rb¨ 04 b¤^i| 04 marks for determining, equation of tangent,
𝑥−𝑦+1=0
3 ,0 3 ,0
4 ,0 4 ,0
4 4
x= x=
2 + 4 ,0
1 1
x= 2 x=2 x= 2 x=2
x এর ডানসীমা
∴ Ave× As‡ki †ÿÎdj = ∫x এর বামসীমা [Dc‡ii 𝑦(𝑥) − wb‡Pi 𝑦(𝑥)]
𝑑𝑥 ∴ Area of enclosed region = ∫ [upper
= ∫ (2 − ln 𝑥) 𝑑𝑥 = 3.497 eM© GKK y(x) − lower y(x)] dx
= ∫ (2 − ln 𝑥) 𝑑𝑥 = 3.497 sq. unit.
b¤^i eÈbt
x এর ডানসীমা Mark Distribution:
Ave× As‡ki †ÿÎdj = ∫x এর বামসীমা [Dc‡ii 𝑦(𝑥) − wb‡Pi 𝑦(𝑥)] 𝑑𝑥 04 marks for writing, area of enclosed region
; ‡jLvi Rb¨ Kivi Rb¨ 04 b¤^i| =∫ [upper y(x) − lower y(x)] dx
Ave× As‡ki †ÿÎdj = 3.497 eM© GKK; wbY©q Kivi Rb¨ 06 b¤^i| 06 marks for determining, area of enclosed region
[we:`ª: GKK bv wjL‡j ev fzj GKK wjL‡j 01 b¤^র KZ©b Kiv n‡e|] = 3.497 sq. unit.
[N. B: 01 mark will be deducted if unit is not written or
wrong unit is written.]
c`v_©weÁvb Phy
03 [Easy] 10
Bqs Gi wØwPo cixÿvq GKwU wP‡oi mvg‡b 2.0 μm †e‡ai I 1.6 In Young’s double-slit experiment, in front of one slit the
cÖwZmiYv‡¼i A‡åi cvZ e¨eüZ n‡j †K›`ªxq Pig ¯’vbvšÍwiZ nq| A‡åi central maximum shifts if a 2.0 μm width mica sheet with a
cvZ mwi‡q wPo n‡Z c`©vi `~iZ¡ wظY Kiv nq| GLb cvkvcvwk `ywU D¾¡j refractive index of 1.6 is used. When the mica sheet is
cwÆi `~iZ¡ c~‡e© †K›`ªxq Pi‡gi ¯’vbvšÍ‡ii cwigv‡Yi mgvb nq| e¨eüZ removed and the distance of the scree from the slits is
Av‡jvi Zi½‰`N©¨ KZ? doubled, the distance between two consecutive bright
fringes is equal the previous shift of the central maximum.
What is the wavelength of the light used?
Aåcv‡Zi d‡j m„ó c_ cv_©K¨ (𝜇 − 1)𝑡 Path difference created due to using mica sheet (𝜇 − 1)𝑡
( ) ( )
†K›`ªxq Pi‡gi ¯’vbvšÍi = shift of the central maximum =
( ) ( ) ( ) ( )
`ywU D¾¡j cwÆi `~iZ¡ = = = distance between two bright fringes = = =
( ) ( . )× × ( ) ( . )× ×
⇒ =λ⇒ =λ ⇒ =λ⇒ =λ
∴ λ = 6000Å ∴ λ = 6000Å
c`v_©weÁvb Phy
04 [Medium] 10
2mm cÖ¯’‡”Q‡`i cwievnx Zv‡ii mv‡_ GKwU d‡Uv B‡jKwUªK †Kvl hy³| A conductive wire with a cross-sectional area of 2mm is
1.5A Zwor cÖevn cvIqv hvq hLb †Kv‡l 300 nm Gi UV iwk¥ AvcwZZ connected to a photo electric cell. A current of 1.5 A flows
nq| hw` cwievnx e Gi †eM d‡Uv e Gi †e‡Mi 0.0005% nq, Z‡e when UV light of 300nm wavelength is incident on the cell.
cwievnxi cÖwZ GKK AvqZ‡b e msL¨v KZ? [m~Pb Zi½‰`N©¨ 320 𝑛𝑚] If the velocity of conduction electrons is 0.0005% of the
velocity of photoelectrons, then what is the electron number
in per unit volume of the conductor? [The threshold
wavelength is 320nm]
= + mv = + mv
c`v_©weÁvb Phy
05 [Medium] 10
2 km `xN© weªR GKwU 600 kg wbðj f‡ii Mvwo me©wb¤œ KZ mg‡q What is the minimum time for a rest mass of 600 kg car to
AwZµg Ki‡Z cvi‡e hw` weªRwUi m‡e©v”P aviYÿgZv 9800N nq? cross a 2 km long bridge if the bridge’s maximum load
capacity is 9800N?
m= ⇒ = [GLv‡b, 𝑚 = = 1000 𝑘𝑔] m= ⇒ = [Here, 𝑚 = = 1000 𝑘𝑔]
mwVKfv‡e gvb emv‡bvi Rb¨ 03 b¤^i| 03 marks for putting the values correctly.
𝐿 = 230.035 𝑚 ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, 𝐿 = 230.035 𝑚
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| m~Î bv [Note: 01 mark will be deducted if unit is not written or
wj‡L mivmwi gvb emv‡jI m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|] wrong unit is written. Direct input of values without writing
formula is also acceptable.]
imvqb Chem
01 10
wZb Kve©bwewkó A †hŠM 2,4-DNPH Gi mv‡_ wewµqvq Aa:‡ÿc †`q, Compound ‘A’ which consists of three carbons gives off
wKš‘ U‡jb weKvi‡Ki mv‡_ wewµqv K‡i bv| A †hЇM NH − NH †hvM precipitate in the reaction with 2,4-DNPH, but does not give
Ki‡j,180 𝐶 ZvcgvÎvq ‡mvwWqvg B‡_v·vB‡Wi Dcw¯’wZ‡Z B †hŠM Drcbœ reaction with Tollen’s reagent. When NH − NH is added to
nq| C †hЇMi mv‡_ †mvWv jvBg †hvM K‡i DËß Ki‡jI B †hŠM Drcbœ compound ‘A’, in presence of sodium ethoxide, compound ‘B’
nq| C †hŠM SOCl Gi mv‡_ wewµqv K‡i D †hŠM Drcbœ K‡i| A, B, is produced at 180 𝐶 temperature. When soda lime is added
to compound ‘C’ and then heated, compound ‘B’ is also
C I D †hŠMmg~n kbv³ Ki Ges mswkøó wewµqv¸‡jv wjL|
produced. Compound ‘C’ produces compound ‘D’ if reacts
with SOCl . Identify compounds A, B, C & D and write the
reactions concerned with it.
NO2 NO2
CH − CO − CH + H N − NH NO2 → CH − CO − CH + H N − NH NO2 →
njy` Kgjv Aa:‡ÿc njy` Kgjv Aa:‡ÿc
NO2 NO2
𝐶𝐻 − 𝐶 = 𝑁 − NH NO2 + 𝐻 𝑂 𝐶𝐻 − 𝐶 = 𝑁 − NH NO2 + 𝐻 𝑂
| |
(হলুদnjy
কমলা অধঃে
` Kgjv প)
Aa:‡ÿc ( njy` Kgjv Aa:‡ÿc.)
imvqb Chem
02 10
Am¤ú„³ ‘A’ †hЇMi cÖfveKxq wWnvB‡Wªv‡R‡bk‡bi gva¨‡g ‘B’ †hŠM Compound ‘B’ is produced from the catalytic
Drcbœ nq| ‘B’ †hŠM cvwbi mv‡_ wewµqv K‡i ‘C’ †hŠM Drcbœ K‡i hv dehydrogenation of unsaturated compound ‘A’. Compound
U‡jb weKvi‡Ki mv‡_ wewµqv K‡i `c©b MVb K‡i| D‡jøL¨ ‘A’ †hŠMwU ‘B’ reacts with water and produce compound ‘C’ which
mswkøó †kÖwYi ÿz`ªZg m`m¨| Dchy³ wewµqvmn A, B, C †hŠMmg~n kbv³ reacts with Tollen’s reagent and forms mirror. Note that,
Ki| compound ‘A’ is the smallest member of the concerned
class. Identify compounds A,B, C with suitable reactions.
,∆ ,∆
CH = CH ⎯⎯⎯ CH ≡ CH + H CH = CH ⎯⎯⎯ CH ≡ CH + H
% , % ,
CH ≡ CH + H O ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ CH CHO CH ≡ CH + H O ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ CH CHO
% , ° % , °
CH CHO + [Ag(NH ) ]OH → CH COONH + Ag + CH CHO + [Ag(NH ) ]OH → CH COONH + Ag + NH +
NH + H O H O
A → CH = CH A → CH = CH
B → CH ≡ CH B → CH ≡ CH
C → CH CHO C → CH CHO
imvqb Chem
03 10
wb‡Pi wewµqvmg~n wjL| Write down the following reactions.
(i) †nj‡fvjnvW© †Rwj‡bvw¯‹ wewµqv
(i) Hell-Volhard Zelinsky reaction
(ii) KwjÝ weKvi‡Ki mvnv‡h¨ cªvBgvwi A¨vj‡Kvn‡ji RviY
(iii) U‡jb weKviK cix¶v (ii) Oxidation of primary alcohol with Collins reagent
(iv) †iv‡RÛgyÛ weRviY
(iii) Tollen reagent test
(i) CH COOH + X ⎯⎯⎯ CH − COOH + HX (i) CH COOH + X ⎯⎯⎯ CH − COOH + HX
| |
( ) ( )
(ii) CH − CH OH ⎯⎯⎯⎯⎯⎯⎯ CH CHO + H O (ii) CH − CH OH ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ CH CHO + H O
াবক
∆ ∆
(iii) R − CHO + [Ag(NH ) ]OH ⎯ R − COONH + (iii) R − CHO + [Ag(NH ) ]OH ⎯ R − COONH + Ag ↓
Ag ↓ +NH + H O +NH + H O
. .
(iv) R − COCl ⎯⎯⎯⎯⎯⎯⎯⎯ R − CHO (iv) R − COCl ⎯⎯⎯⎯⎯⎯⎯⎯ R − CHO
∆ ∆
imvqb Chem
04 10
(𝑎) U‡jb weKvi‡Ki mv‡_ wewµqvi gva¨‡g †`LvI †h, Møy‡KvR GKwU (a) Show with the reaction of Tollens’ reagent that, glucose
weRviK wPwb| is a reducing sugar.
(𝑏) Kx N‡U ivmvqwbK wewµqvmn wjLt
(𝑖) ¶vi‡Ki Dcw¯’wZ‡Z †K¬v‡ivdig Ges Gwm‡Uvb wewµqv Ki‡j| (b) Write with chemical reaction what happens:
(𝑖𝑖) jNy †mvwWqvg nvB‡Wªv·vB‡Wi Dcw¯’wZ‡Z `yB AYy A¨vwmUvjwWnvBW
(i) If chloroform & acetone is reacted in presence of base.
ci¯ú‡ii g‡a¨ wewµqv Ki‡j|
(ii) If Two molecules of acetaldehyde react with each other in
presence of dilute sodium hydroxide solution.
(𝑎) Mø‡y Kv‡Ri Rjxq `ªe‡Y K‡qK †dvuUv U‡jb weKviK †hvM Ki‡j U‡jb (a) When few drops of Tollens’ reagent is added to the
weKviK weRvwiZ n‡q †Uó wUD‡ei Mv‡q avZe wmjfvi `c©Y m„wó nq| aqueous solution of glucose then the Tollens’ reagent
reduces and forms metallic silver mirror on the wall of test
CH OH (CHOH) CHO + tube.
েকাজ
imvqb Chem
05 10
GKwU †hЇMi bgybv `ªe‡Y eªvwWi weKviK †hvM Ki‡j njy` Aat‡¶c c‡o| A sample compound gives yellow precipitate in reaction with
Z‡e D³ †hŠM †dnwjs `ªe‡Yi mv‡_ wewµqv K‡i bv| wK¬‡gbmb weRvi‡Y Brady’s reagent. But the compound does not react with
GwU n-†c‡›Ub Drcbœ K‡i Ges n¨v‡jvdig wewµqvq Ask †bq| | bgybv Fehling's solution. It produces n-pentane in Clemmensen
†hŠMwUi IUPAC c×wZ‡Z bvg, ms‡KZ Ges Zxeª Rvi‡Y cÖvß cÖavb reduction and takes part in Haloform reaction. Write down the
Drcv`mg~n wjL| name in IUPAC method, the formula and the major products
obtained from the strong oxidation of the sample compound.
†h‡nZy eªvwWi weKvi‡K njy` Aat‡¶c → A¨vjwWnvBW/wK‡Uvb Since yellow precipitate with Brady’s reagent →
†h‡nZy, †dnwjs `ªe‡Yi mv‡_ K‡i bv → wK‡Uvb aldehyde/ketone
†h‡nZy wK¬‡gbm‡b †c‡›Ub nq → C-5 msL¨v wewkó wK‡Uvb| Since, it does not give reaction with Fehling's solution →
ketone
|| ||
m¤¢ve¨ CH − C − CH − CH − CH , CH − CH − C − Since, pentane in Clemmensen reaction → 5-C ketone
CH − CH || ||
Gi g‡a¨ cª_gwU n¨v‡jvdig wewµqv †`q| Probable, CH − C − CH − CH − CH , CH − CH − C −
CH − CH
||
So, CH − C − CH − CH − CH ; †c›Uvb-2-Ib The first one gives haloform reaction.
[ ] ||
𝐶𝐻 𝐶𝑂𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 + 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 So, CH − C − CH − CH − CH ; name: Pentan-2-one.
[ ]
𝐶𝐻 𝐶𝑂𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 + 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻
b¤^i eÈbt
†dnwjs `ªe‡Yi mv‡_ K‡i bv → wK‡Uvb ‡jLvi Rb¨ 01 b¤^i| Mark distribution:
wK¬‡gbm‡b †c‡›Ub nq → C-5 msL¨v wewkó wK‡Uvb ‡jLvi Rb¨ 01 b¤^i| 01 mark for writing it does not give reaction with Fehling’s
solution → ketone.
||
01 mark for writing pentane in Clemenson reaction → 5-C
CH − C − CH − CH − CH ‡hŠMwU n¨v‡jvdig wewµqv †`q
ketone.
‡jLvi Rb¨ 02 b¤^i|
†hЇMi ms‡KZ ‡jLvi Rb¨ 02 b¤^i| ||
02 marks for writing CH − C − CH − CH − CH gives
†hЇMi IUPAC bvg ‡jLvi Rb¨ 02 b¤^i|
haloform reaction.
bgybv †hŠMwUi Zxeª Rvi‡Y cÖvß cÖavb Drcv`mg~n
02 marks for writing the structural formula.
𝐶𝐻 𝐶𝑂𝑂𝐻, 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 ‡jLvi Rb¨ 02 b¤^i|
02 marks for writing the name of compound in IUPAC
method.
02 marks for writing the major products obtained
𝐶𝐻 𝐶𝑂𝑂𝐻, 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 from the strong oxidation of the
sample compound.
imvqb Chem
06 10
Zxeª Rvi‡Ki Dcw¯’wZ‡Z 2,5-WvBwg_vBj †n·vb-3-Ib †hŠMwUi RviY Show the compounds formed in the oxidation reaction of
wewµqvq Drcbœ †hŠMmg~n †`LvI I 𝐼𝑈𝑃𝐴𝐶 bvg wjL| 2,5-dimethylhexane-3-one in presence of strong oxidant
and write the IUPAC names.
| || | | || |
CH − CH − C − CH − CH − CH CH − CH − C − CH − CH − CH
, ডাইিমথাইলেহ ান ওন ,
| || | [ ] | | || | [ ] |
CH − CH − C − CH − CH − CH ⎯ CH − CH − CH − CH − C − CH − CH − CH ⎯ CH − CH −
| |
COOH + CH − CH − COOH COOH + CH − CH − COOH
∴ The compounds produced are: 2-methyl propanoic acid.
∴ Drcbœ †hŠMmg~n n‡jv : 2-wg_vBj †cÖvcv‡bvwqK GwmW|
Mark distribution:
(03 ×02) = 06 marks for writing the name of compound in
b¤^i eÈbt IUPAC method.
†hЇMi IUPAC bvg ‡jLvi Rb¨ (03×02) = 06 b¤^i| 04 marks for writing reaction.
wewµqv ‡jLvi Rb¨ 04 b¤^i|