Introduction and General

properties.

Co i6 preJent

() chlorophyll b Haemoglobin.
(c) vitamin-l2 (d) vitamin- k.

Ans:

vitain- |2 Ccyanocobalamine)

in can cer
2 Which used epfectively
chemotheropy
(b) ze ise'b salt
(a) cis platin
thase.
(c) both ) and (2) (d) None of
AQs (a) cib- platfin.
Pair of transition
3. hich of the following calculated value
matal i o n , have the same
magne tic mo ment ?
af pin only Fe and
(a) Ti2t and 2t

(d) c t and Ti
and

Ans.
and haing
Gpaired elect
electNs.

6 leat Soluble in water?

4 khich one

A9I
 Ans:

So\ubi lity of A9,5 is lesser than Aq

p. AgF Agc| Nacl , Na Br NaT are colourle

but Ag BY and Ag 1 aye colored because.

(a) Agt polarizas Br an d I and hot able to

po laríze and

has Unpaúred electron.

e) Ag r has crystal defects.
d) All| of these
Ans :(a)

poirs of tansition
lo. hch afthe follouing
metal ion are the etronger oxi di zìng
in aqweous solution.
2+ 2+ 6TiT an d cY
and Cr

t (d vt2 and
Mn3tan d

Mnt
etable tran
Mnt more

CoT s moe ctab|e

In aqueous soltion
Co t
th an

7. Which not an ioteretitial Compound

(a) Tio (b) FegO

Ans: (b) Fego formed by baancing its

valen ces.
8. E° values for te Couples crot/ey2t and
MO/Mt ae
and Volts

Yespectively. Thase Values sug9est toat.

acts veducing agent wWhere a5

acts agent
an
oxidizing
than cr31 stote.
more Gtable
etable than Mot
(c) Mn is more
agent whare as
(d) cr 2+ acto an
oxtdizing
Mn aet reduing agent.
Ans: (a)

Lesser negaive veducion potentia l

reduing 99ent
indicate
reduction Potential
4igher pasiitive
indicates trat stronger OxNdzirg
agent
pair the fint
a. In hich a the
more
foluoigthan
stable secon one
Species i6
a) Mn2+ Mnt
Tit4 Fe2+

Ans (a) Lonfisunation.

Mnt have
d4
conPisuratibn.
Mn3t have
((9. The basi char acter of transitton matal
mono oxo
follow tha order.

(a) vo > CrO > Tio > Feo

Cro > Vo > Feo Tio

(C)Tio > Feoy vo >
(d) Tio> cros Feo.

Ans : (d)

|). i5 tonsported in the con tainers mad.

Mercug
up op
(d) n
(a) No (b) Fe

Ans : Fe

12. 6iver Or naments get Rurnished in air

due to the reaction

( No cd) Hao

Ans.
+Hao
A oO +A95

Capper displaces which of the metal from

their salt Solutions D
(b) Zn S04 (cs FesO4
(a) Ag No

Ans : AgNO
ReFe =-O. 4oV
Znzn =-o.76V
EO = +0.&o V,
Aot/Ag
|4 pick out the Correet order.
(a) electical
conductí vity
) deeiby Hg <Au

(E) Melting point

d) atomic si ze Sc<Ti V.

Ans: b)

|5. Whch of the follesíng 6et f metals

an forrs allag ?
( L - Na
a) cu- Au

Fe - Hg
Ans :
ions in Solution
lb. hhich of the follouing
dispropotfon ation?
nder go 2+ (c) cut
2+
Fe

transiHon SeHes.
klhich elomant
the fint
I7. third ionibation enthal py?
highes t
has d) zn.
(b) Fe
(a) bc

Ans: (d)
éompoun ds
l2. khjch af the follooing
has unpaied electon.?
cAnd
ib coloured
(c) KMno4
(a) cuF2
Ans: (a)
 Among tho SerDes of transition
Metal iono, the one. whare IOnG
have eletronúc onigura tion ib.
44 bt
(a) Ti3t Mo () T; 24

Mn
7+ (d) Tít4,V 3t Mnt

Ans : (a)

tranition metal ions

has
klhich of
highest
tte
folsuing
mag netic moment
2+
e) u2+ (b) Ni 2+ 2+ d Fe

Ans:

21. gives Ha gas wrth Ho.s04 and Hci

but rot HNO becauGe.

acte an
Oxidizing agent o han
eact witth HNO

HNO i6 earer acid than H9so4 and

Hcl
chamical Seres Zn iS abore
(c) In ele ctro
hydngen
reduced in pre ferne. o
NOS
fon.
hydrorium
Ars: D
+4 HNO Zn(NO,) t 2 Nog +2to
22. The value for Mn/ Mn couple much
more positive thon that for cyt /crt becawe
(a) larger thívd ion)za tfon eneray ot Mn
(b)
difftcult
Mnt ion
to

due to
remove electron fron
it6 more electronjc Stablity
more Stable than cy2t due to
more hydrotion ener poses
Volue than Mn couple.
Al are cOrre ct .

Ans . (d)

lhich o the
I.P?
folleuing eement has maximum

cd) er.

Ans: Mn.

i5 highly corosive?
hhich op the follaing
a) Fede (b) pbcla CC) Hg2cle do Hg cla
Ans: ()
Corrosi ye nature of metal i on c 5 RP

+o.8b

the
given metal ions.
higher amg
25. Nich of the folouing Compound orms.
mobt Stabla complex compound ?
(b) Ni2+ (C) Fet
(a) Mn2+

Ans:
 which fof te
about cy2t (z=24) flbuingand Mnbt etate ment

(z-25)
are orrect

(a) cy 2t
vedei cing agent
(b) Mp>t
oxidizing agent

(C) Poth cYT and Mn enhibi t configuration

d) Al D ttase
Ans.(d)

27. Match list -I (aloys) wrth Let -I (constitu enh)

and Belect the correc t anBer.

Ljst -I
i6t-I
Gher man silver P. Cu,Sn

BrasS Q.

Monel metal R.

S.
3
CU Zn.
Bronze
3
2 G)
4 (P)
Ans: (A)
coloured
transtion elemente fom
28.
aenerag presence of unpaired electons
salts de to the
will be
which of the folloing Compound
Solid state 9
coloured n
(b) zn Fa <)CUFa dA9,50
(a) cu2cla

ion í6 theated uith KI, a white.

When
pás precipitate ie formed
(a) ua Ia (b) cuIa (c) d) cuI

An: (a)
 Out
of and Cucla cu co i5 more.
btable dua to
(a) cut more hydration enthalpy.
Cy tl ib more etable 2dlo con ouration

(c) Cu2t i more hydration ethalpr.

(d) |esser hydration anthalpy.
Ans : (c)

dimar
A compound of Tyon xists

in etate. which ib hydroscopic and

vapour brown acidic
dissolves in wwater
giving
Golution the compoond i6.
() Fe °4 (c) Feclz d za Feo,
(a) Fe s°4
Ans:. (c)

Fecl t 3 te0 Fe oH t 3 Hc)

Brown.
in vapor State.
Fe cl exists Feacdo

mìxture o
D2. Ltho pone
(b) Znb t BasO4
) Z 504 + Baso4
(d) zno + Baso4.
(C) Zn co Ba b0

Ans ( b )
wite pigment
Lithopone
that
The par af Compounds
Can

33.

to gethar ib Sncla
(b) Hg cla
a) Fe da Sncla
cd) Fe cl> kI
Fe cl2 Gn cla
C)
Ans: (C)
 For t four SuctegGiVe transition elementb.

Cr Mn, Fe and Co -tthe sta bi lity of +

in whch
Oxidation state be hore.
of the order 2

(a) cr > M > co> Fe o) Mn > Fe cr>co

(d) co > Mn > Fe >cr.

Ans: (6)

oxide is not
S5. which one
amphoteríc
Rolocing
(a) CrO2 ( craO2 (d) Moo
Ans (d) basic.
order i5 lare coect
coina ge metale?
veg ar ding
(a) Densiy Cu <Ag < y

(b) MP
(C) BP

ca) LE
all a r are Lorrect.

and Base may rea ct w)to.

37.
oxides.
folouang
(c)ZNo
(a) cao
Ans : c)

Zno an amphoteic.
 Some Tmportont Transition

elementb
38. klhen Nacl or kc heated with con
and bolid " We Det
vopours.
(a) chromic Cb emoc hoñde
sulphate.
(e) chromy chlosde mous ehlonde
(d) comous

Ans: (c)

+ 4 Nacl +b Hoso4

+4 Na HSo4 t3He0,

29.
dichromate dianion.
(a)4 Cr-o bonda are equvalent
(b) bonds are qiva lent
Cr-o bonds are cquvalent
Cr-o bond s are non- eúvalent.

40. An aposion tale place whan on Hgs04 is

added to KMnO4
formad
ohich
follbeing
(b) Mnog (c) MnSO4

2MnO4 + HaO4 keso4 t Mn207 + Hao

4. hlhen tused uorto KoH in presence af

the product formed is
(a) purple colour KMnO4 G green olour keMng.
d) purple olour KMno
 NaoH solution gives.

(a) crO4 b) cr oH) .

Ane : (a)

CrO + NooH
NazcrO4
4>. khen on acid eo\ution OX alic aid at &oc
15 itrated i t t KMOO4 Solutfion the ftrot feuo
drope of kMneg are de cotoured slowly but
decolourDbation OcUArs fost later
be Cause
Concentration of Cop. formed
(o) of increae
Mnt oS auto catalyst
one t the producte
(c) boto Mnt and K+ jons act ab auto catalyt

toe reacti bn at the ater

catalyses
Stages. Ans :b)

KMnOA t Heeo4 + Haeo4

4 Ho

prefered to for
44. K reO7
Vo lumetic analysis pimay
standard because.

hygosopic while
(a) Nae CrgO7
not
uwhile. Nancr e07 ot

i5 Pue while Naecre0, ib impure

None of these. Ans : (b)

45. The. OX0 anionb whi ch ontain5 all qivalent
M-o bonde are.

I) cro () Mno4
(a) | only (b) I , I , (0

d) I only
Ans : (C)

Ab. The pro duet of oxidaton of Mno4

in al kallne maciug i6.
(c) Fe04 d Feo
Ans:

2 MnQ4 I + H9o To + Mnog

+20H

47. The colour due to

d-d taneitfon (b) LM charge transfer

(a) transiton
charge tran fer
(c) o transition transition

Ans:

48. The stnete at Cro ion

( tetahedral
a) square planer
d) Pyr amidal.
(c) tigonal bipyramidal
Ans. (b)
bond rocY
49. klhat the ongle

crao, jon. cd) l2b

(c) lo4
(a) loo. 28
Ans d
50. When one 1) is used oith
chomite
Sodiuy carbonate io Rree excesG of air and
ater a yelous
the product io diesolved in watera
olution of compeund (B) i6 obtained After
theatment of this yellouw oolution uoit
bulphunc aid compound (e) can be crystallized
from the Bolution when compound C) is treated
with kcl orange crystalo f compound (o
rystalli ze out Identity A to D

olutian
4 Fecrot + 8 Nan co t 702
(4) + 2e93 t 8Og
8 Nas cro

2 NacYot + Haso4 Nascr

Nascraoy tNagSo4
(B) +teo

NascraO7 + ke ’kecrs 0 t 2Nac.

(P)

No. af. moles veduced by one.

mole af nt ion i.

(n) (o)

Ans: a)

(n-factor =b) (n factor=2)

mole t (crao mole of ent

mole of (crao = l mole ot

 CrO 5 an anhy dicde of
(a) potassium dicromate (b) chromic acid
(c) po tassun chomate d) chomyl chonde
Ans: (b)
53. Mn+ Can be into Mn
converted by entíng
usito
a) 50g (b clo. (J pbo2 d) Gnde

Pboa ehrong oxidizing agent oxidizay.

Mnt to Mo +

54. de
The
set of compoundo having Co louY
to
harge transer spectra ib (ave.
I. KMnO4

Ans: I , D,

S5. the laooratorg manganese Salts

to
are
oRidizing permanganate bg
(a0 con. Ptassum hydroxide
(c) pero XOdi sulphate b sodium Carbonate

2Mn+ 59203 4
+|bHt
 Lanthanoido and ito properties and
Actioiee and fto Proper +ies.
bb. The colour o lan thanoid ion i5 due to
(a) Pf traneitions porty filed orli tnls
talb
b)- transitions in comp letelg Alled f-
P-orbitols
(c) Dot cd) None
a)

( ) The maximum Odation etate Shown by Np is

(a) tb (6)+7 d) t4.
Ans ()
58. The Gorrect Order of jonic radii of y,
Lat and Eu3+

<l a y t () La >eu >y*

(a) Eu

Ans. (b

Contraetion
greater from element
Sq. Actinoid
than
Lanthanoid contracthon.hy?
to element
electons are more effectivey shielding
Prom nucleaY charge
(o) 5 electont provide. poor shielding frong
element in senes.
element to

Actinoids are. last of the peñodic

table
and (b)
d) Both (a)
Ans . D)
60. hich of the element has lowest
third jonizo tion ener sy.
(a) Ce (bsm (C) td
Ans:

electronic conturatim
half filed
Zr belongs to transiion Seòes
bl. Athough
tian sition Seies even ton
and H to b
Show similar physical and chemical properttes
oencue.
have simiilar atomic rodius.
( poto have eletronic con figuration
(c) Poth belorgs to amne Øoup af the peiodic
table
d- bloE
(d) Bth belong to

Ans: (a)

correct?
(og. Which of tre
less
flauing
basic than LuOH)
(a) La oH)
Lonthanide 5eies ionic
(6) In
ionb deceaas.
elemen t of transitjon
(c) La i6 aetuaig an

Beies.
(d 4tomk radus and H are Same

becoe Lanthanide Contractfon

Ans: (a)
b2. 1he chemísry of Lan thanoids
dominated by ito +a oxidation Gtote which o
the
follouing i6 inorreet .?
(a) Becawe of the large Siza of tha Ln() ions
its compoundo are.
predo min anty ionic
in choracter.
(b) The lonic (I) decveae in general
wlth incYeasing atomíc num ber.

C) Ln compounde
) are
genera lg colourles
bosic in nature,
Ln ) hy droxides OAe
maing
An)
folouing pairs t lantanoide.
Ore colour less.?
and
(a) Ey
Ly3+ and Ce Tm

and Lust
(C)
Ce3t
d) La3+ Lu3+ and

Ans : Ca)

4) con ftguration

Cebt f ) and
are Colourles cìnce tho
in the UV Yegibn ietead ap yisible
absorb

region.
Gtatemento.
Conoider folluwingleast baeic omong
|: La (Ot)>
Lanthani des.
hydroxicas of
 and H4 41 poases almost tho ame
TOnic radii

Ce4+ (an
an oxdi zing Agent:

wihich f the aoove. iblae false?

Ans (I ony)

i5 ìm por tont member

bb. CeHum (2= 5a)
lanthanides. Which of te follooing Gtatement
the
cerum i6 inorreet ?
aout
ceñum
(a) Te conmmon oXica tion etate ot
+ and
are
goo analyical reagent
(o) Ce +4
cerium i5 not
stute of
(c) The
in bolutfons.
Known
agen t

cerium
(I) acts
an
oxidi zig
(d)
Ans :

oXOmefal anion
Name the which
metale
trangition
sevies f tre. oxidation 5tate
exhibito the
the
metal number oX)hamY
datton group
to
qual +5
) Vanadate
CY
hromate
+7 7
Mn
permangonate