UnitTest - D03 Oct 2023
UnitTest - D03 Oct 2023
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(A) One mole of phosphine (B) Two moles of phosphoric acid
(C) Two moles of phosphine (D) One mole of phosphorus pentoxide
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3. What is the molarity of HCl solution that has a density of 1.17 g/mL at 25°C ?
(A) 36.5 M (B) 18.25 M (C) 42.0 M (D) 32.05 M
4. How many moles of Mg3(PO4)2 consists 0.25 mole oxygen atoms ?
ISD
(A) 2.55 ´ 10–2 (B) 0.0225 (C) 3.125 ´ 10–2 (D) 1.5 ´ 10–2
5. From the following which one has least molecules ?
(A) 0.1 mole CO2 (B) 11.2 L CO2 at STP
(C) 22 g CO2 (D) 22.4 ´ 103 mL CO2 (STP)
6. 13.8 g element consist 4.6 ´ 1022 atoms what is the atomic mass of element ?
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(A) 290 (B) 180 (C) 34.4 (D) 10.4
7. In the reaction :
3+
2Al(s) + 6HCl(aq) ¾¾
® 2Al(aq) + 6C l (aq )+ 3H 2(g)
(A) 6L HCL(aq) is consumed for every 3L H2 produced.
(B) 33.6 mL H2(g) is produced regardless of temperature and pressure for every mole Al that reacts.
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(C) 67.2 L H2(g) at STP is produced for every mole Al that reacts.
(D) 11.2 L H2(g) at STP is produced for every mole HCl(aq) consumed.
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8. The density (in g mL–1) of 3.60 M sulphuric acid solution that is 29 % H2SO4 (Molar mass = 98 g
mol–1) by mass will be
(A) 1.64 (B) 1.88 (C) 1.22 (D) 1.45
9. In the reaction of sodium thiosulphate with I2 in aqueous medium the equivalent weight of sodium
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thiosulphate is equal to
(A) Molar mass of sodium thiosulphate
(B) The average of molar masses of Na2S2O3 and I2
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(A) 1 mole of HCl(g) (B) 2 mole of HCl(g) (C) 0.5 mole of HCl(g) (D) 1.5 mole of HCl(g)
17. 1.0 g of magnesium is burnt with 0.56 g O2 in a closed vessel. Which reactant is left in excess and
how much ? (At. wt. Mg = 24, O = 16)
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(A) Mg, 0.16 g (B) O2, 0.16 g (C) Mg, 0.44 g (D) O2, 0.28 g
18. A hydrocarbon contains 85.7 % C. If 42 mg of the compound contains 3.01 ´ 1020 molecules, the
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molecular formula of the compound will be ......
(A) C3H6 (B) C6H12 (C) C12H24 (D) C2H4
19. The most abundant elements by mass in the body of a healthy human adult are : Oxygen (61.4 %);
Carbon (22.9 %); Hydrogen (10.0 %) and Nitrogen (2.6 %). The weight which a 75 kg person would
gain if all 1H atoms are replaced by 2H atoms is ......
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(A) 15 kg (B) 37.5 kg (C) 7.5 kg (D) 10 kg
20. 1 gram of a carbonate (M2CO3) on treatment with excess HCI produces 0.01186 mole of CO2. The
molar mass of M2CO3 in g mol–1 is...
(A) 1186 (B) 84.3 (C) 118.6 (D) 11.86
21. A mixture of 2.3 g formic acid and 4.5 g oxalic acid is treated with conc. H2SO4. The evolved gaseous
mixture is passed through KOH pellets. Weight (in g) of the remaining product at STP will be
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(B) 18 ml of water
(C) 0.00224 L of water vapours at 1 atm and 273 K
(D) 0.18 g of water
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23. Calculate the number of moles of hydrogen required to produce 20 mole ammonia by Haber’s process ?
(A) 40 (B) 10 (C) 20 (D) 30
24. Weight of sucrose required for 0.1 M 2 L at solution of sucrose is .......
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28. Which of the following elements has the highest ionisation energy
(A) [Ne]3s2 3p1 (B) [Ne]3s2 3p2 (C) [Ne]3s2 3p3 (D) [Ar]3d10 4s24p2
29. Which one of the following has largest size ?
(A) Na (B) Na+ (C) Na– (D) None of these
30. A sudden large jump between the value of second and third ionisation energies of elements would
be associated with which of the following electronic configurations ?
(A) 1s2 2s2 2p6 3s1 (B) 1s2 2s2 2p6 3p1 (C) 1s2 2s2 2p6 3s1 3p2 (D) 1s2 2s2 2p6 3s2
31. The electronic configuration of Gadolinium (atomic number 64) is.....
(A) [xe] 4f 8 5d9 6s2 (B) [xe] 4f 7 5d1 6s2 (C) [xe] 4f 9 5d5 6s2 (D) [xe] 4f 6 5d2 6s2
32. The first ionization potential (eV ) of Be and B respectively are.....
(A) 8.29, 9.32 (B) 9.32, 8.29 (C) 9.32, 9.32 (D) 8.29, 8.29
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33. Which of the following order for ionization energy is correct ?
(A) Be > B > C > N > O (B) B < Be < C < O < N
(C) B < Be < C < N < O (D) B < Be < N < C < O
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34. Which of the following is most electro-negative ?
(A) carbon (B) silicon (C) lead (D) tin
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35. An element has electronic configuration 1s22s22p63s23p4. Predict their period, group and block :
(A) Period = 3rd, block = p, group = 16 (B) Period = 5th, block = s, group = 1
(C) Period = 3rd, block = p, group = 10 (D) Period = 4th, block = d, group = 12
36. The correct order of atomic radii is.....
(A) Na < Mg < Al < Si (B) Si < Al < Mg < Na (C) Na < Al < Si < Mg (D) Al < Si < Mg < Na
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37. The set representing the correct order of first ionisation potential is...
(A) K > Na > Li (B) Be > Mg > Ca (C) B > C > N (D) Ge < Si > C
38. All the s-block elements of the periodic table are placed in the groups ...
(A) IA and IIA (B) IIIA and IVA (C) B sub groups (D) VA and VIIA
39. If an atom has electronic configuration 1s22s2, 2p63s23p63d34s2 It will be placed in
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(A) Second group (B) Third group (C) Fifth group (D) Sixth group
40. The position of the element with electronic configuration 1s22s22p63s23p63d34s2 is placed in the
group ......
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43. According to periodic law of elements the variation in properties of elements is related to their.
(A) Nuclear neutron-proton number ratio (B) Atomic masses
(C) Nuclear masses (D) Atomic number
44. Which of the following sets of ions represents the collections of isoelectronic species ?
(A) K+, Ca2+, Sc3+, Cl– (B) Na+, Mg2+, Al3+, Cl– (C) K+,Cl–, Mg2+, Sc3+ (D) Na+, Ca2+, Sc3+, F–
45. Which of the following ion has the highest value of ionic radius ?
(A) Li + (B) F – (C) O2– (D) B+
46. The formation of the oxide ion (O2–
(g)) require first an exothermic and then an endothermic step as
shown below
O(g) + e– ¾® O(g)
– ; DHo = –142 kJ mol–
O–(g) + e– ¾® O2–
(g) ; DH = 844 kJ mol
o –
This is because
(A) Oxygen is more electronegative.
O(g) + e ¾® O(g) ; DH = –142 kJ mol
O–(g) + e– ¾® O2–
(g) ; DH = 844 kJ mol
o –
This is because
(A) Oxygen is more electronegative.
(B) O–has comparatively larger size than oxygen atom.
(C) O– ion will tend to resists the addition of another electron.
(D) Oxygen has high electron affinity.
47. In which of the following arrangements the order is not according to the property indicated against it ?
(A) Al3+ < Mg2+ < Na+ < F – – increasing ionic size
(B) B < C < N < O – increasing first ion ization enthalpy
(C) I < Br < F < Cl – increasing electron gain enthalpy
(D) Li < Na < K < Rb – increasing metallic radius
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48. Which one of the following sets of ions represents a collection of isoelcctronic species ?
(A) Ba+2, Sr+2, K+, Ca+2 (B) N–3, O–2, F–1, S–2 (C) Li+, Na+, Mg+2, Ca+2 (D) K+, Cl–1, Ca+2, Sc+3
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49. The increasing order of first ionization enthalpies of the elements B, P, S and F (lowest first) is .........
(A) P < S < B < F (B) F < S < P < B (C) B < S < P < F (D) B < P < S < F
50. Identify the correct order of the size of the following :
ISD
(A) Ca2+ < K+ < Ar < S2– < Cl– (B) Ca2+ < K+ < Ar < Cl– < S2–
(C) Ar < Ca2+ < K+ < Cl– < S2– (D) Ca2+ < Ar < K+ < Cl– < S2–
51. Which one of the following constitutes a group of the isoelectronic species ?
(A) CN–1, N2, O 2–2 , O 2–2 (B) N2 , O2–1, NO +, CO
(C) C2–2 , O2–1 , CO, NO (D) NO +, C2–2 , CN–1 , N2
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52. The set representing the correct order of ionic radii is ........
(A) Li + > Be 2+ > Na+ > Mg2+ (B) Na+ > Li+ > Mg2+ > Be 2+
(C) Li + > Na+ > Mg2+ > Be 2+ (D) Mg2+ > Be 2+ > Li+ > Na+
53. The correct sequence which shows decreasing order of the ionic radii of the elements is.....
(A) Na+ > F – > Mg+2 > O –2 > Al+3 (B) O–2 > F – > Na+ > Mg+2 > Al+3
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(C) Al+3 > Mg+2 > Na+ > F – > O –2 (D) Na+ > Mg+2 > Al+3 > O –2 > F –1
54. The increasing order of the ionic radii of the given isoelectronic species is :
(A) Cl–, Ca2+, K+, S2– (B) S2–, Cl–, Ca2+, K+ (C) Ca2+, K+, Cl –, S2– (D) K+, S2–, Ca2+, Cl–
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55. Which one of the following represents the correct order of increasing first ionization enthalpy of Ca,
Ba, S, Se and Ar ?
(A) Ca < S < Ba < Se < Ar (B) S < Se < Ca < Ba < Ar
(C) Ba < Ca < Se < S < Ar (D) Ca < Ba < S < Se < Ar
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O(g) + e– ¾® O(g)
– ; D H(–) = –141 kJ mol–1
f
O(g) + e– ¾® O2–
(g) ; D fH
(–) = +780 kJ mol–1
The process of formation of O2– in gas phase is unfavourable even though O2– is isoelectronic with
neon. It is clue to the fact that,
(A) Oxygen is more electronegative.
(B) Addition of electron in oxygen results in larger size of the ion.
(C) Electron repulsion overweights the stability gained by achieving noble gas configuration.
(D) O– has comparatively size that Oxygen atom.
57. The angular momentum of electron in ‘d’ orbials is equal to :
2
(A) 2h (B) h (C) 0 h (D) 6h
3
58. The number of d-electrons in Fe2+ (Z = 26) is not equal to the number ‘p’ of electrons in which one of
the following ?
(A) p-electrons in Cl (Z = 17) (B) d-electrons in Fe (Z = 26)
(C) p-electrons in Ne (Z = 10) (D) s-electrons in Mg (Z = 12)
59. The species Ar, K+ and Ca2+ contain the same number of electrons. In which order do their radii
increase ?
(A) Ca2+ < Ar < K+ (B) Ca2+ < K+ < Ar (C) K+ < Ar < Ca2+ (D) Ar < K+ < Ca2+
60. Which of the following atoms has the highest first ionization energy ?
(A) Sc (B) Rb (C) Na (D) K
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61. In the following reactions, ZnO is respectively acting as a/an ......
(a) ZnO + Na2O ¾® Na2ZnO2
(b) ZnO + CO2 ¾® ZnCO3
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(A) base and acid (B) base and base (C) acid and base (D) acid and base
62. Magnesium reacts with an element (X) to form an ionic compound. If the ground state electronic
configuration of (X) is 1s2 2s2 2p3, the simplest formula for this compound is
ISD
(A) Mg3X2 (B) Mg2X3 (C) Mg2X (D) MgX2
63. Which one of the following elements is unable to form MF63 - ion ?
(A) In (B) Ga (C) B (D) Al
64. The correct order of atomic radii in group 13 elements is
(A) B < Ga < Al < In < Tl (B) B < Al < In < Ga < Tl
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(C) B < Ga < Al < Tl < In (D) B < Al < Ga < In < Tl
65. For the second period elements the correct increasing order of first ionisation enthalpy is :
(A) Li < Be < B < C < O < N < F < Ne (B) Li < Be < B < C < N < O < F < Ne
(C) Li < B < Be < C < O < N < F < Ne (D) Li < B < Be < C < N < O < F < Ne
66. Match the following :
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Oxide Nature
(a) CO (i) Basic
(b) BaO (ii) Neutral
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Assertion (A) : The ionic radii of O2– and Mg2+ are same.
Reason (R) : Both O2– and Mg2+ are iso-electronic species.
In the light of the above statements, choose the correct answer from the options given below.
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(A) Both (A) and (R) are true and (R) is the correct explanation of (A).
(B) Both (A) and (R) are true but (R) is not the correct explanation of (A).
(C) (A) is true but (R) is false.
ISD
(D) (A) is false but (R) is true.
72. The first ionization enthalpies of Be, B, N and O follow the order ..........
(A) O < N < B < Be (B) Be < B < N < O (C) B < Be < N < O (D) B < Be < O < N
73. Outermost electronic configurations of four elements A, B, C, D are given below :
(A) 3s2 (B) 3s2 3p1 (C) 3s2 3p3 (D) 3s2 3p4
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The correct order of first ionization enthalpy for them is :
(A) (A) < (B) < (C) < (D) (B) (B) < (A) < (D) < (C)
(C) (B) < (D) < (A) < (C) (D) (B) < (A) < (C) < (D)
74. It is observed that characteristic X-ray spectra of elements show regularity. When frequency to the
power “n” i.e. of X-rays emitted is plotted against atomic number “Z”, following graph is obtained.
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(C) 3
1 Z
(D)
2
Section B
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• Write the answer of the following questions. [Each carries 2 Marks] [24]
NO2
HO
75. HNO3
H2SO4
In the above reaction, 3.9 g of benzene on nitration gives 4.92 g of nitrobenzene. The percentage
yield of nitrobenzene in the above reaction is ...... %. (Round off to the Nearest Integer). (Given
atomic mass : C : 12.0 u, H : 1.0u, O : 16.0 u, N : 14.0 u)
O
O
C
Cl
76. + C6H 5NHC6H 5 ® C6H5–C–N–(C6H5)2
0.140 g 0.388 g 0.210 g
Consider the above reaction. The percentage yield of amide product is ...... . (Round off to the
Nearest Integer). (Given : Atomic mass : C : 12.0 u, H : 1.0 u, N : 14.0 u, O : 16.0 u, Cl : 35.5 u)
77. Complete combustion of 3 g of ethane gives x ´ 1022 molecules of water. The value of x is ..........
(Round off to the Nearest Integer).
[Use : NA = 6.023 × 1023; Atomic masses in u : C : 12.0 ; O : 16.0 ; H : 1.0]
COOH COOH
78. FeBr3
+ Br2 + HBr
Br
Consider the above reaction where 6.1 g of benzoic acid is used to get 7.8 g of m-bromo benzoic acid.
The percentage yield of the product is ....... (Round off to the Nearest integer)
[Given : Atomic masses : C = 12.0u, H : 1.0u, O : 16.0 u, Br = 80.0 u]
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79. What mass of 95% pure CaCO3 will be required to neutralise 50 mL of 0.5 M HCl solution according
to the following reaction ?
CaCO3(s) + 2HCl(aq) ® CaCl2(aq) + CO2(g) + 2H2O(l)
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[Calculate upto second place of decimal point]
(A) 3.65 g (B) 9.50 g (C) 1.25 g (D) 1.32 g
ISD
80. If a rocket runs on a fuel (C15 H30) and liquid oxygen, the weight of oxygen required and CO2
released for every litre of fuel respectively are : (Given : density of the fuel is 0.756 g/mL)
(A) 1188 g and 1296 g (B) 2376 g and 2592 g (C) 2592 g and 2376 g (D) 3429 g and 3142 g
81. A 0.166 g sample of an organic compound was digested with cone. H2SO4 and then distilled with
NaOH. The ammonia gas evolved was passed through 50.0 mL of 0.5 N H2SO4. The used acid
required 30.0 mL of 0.25 N NaOH for complete neutralization. The mass percentage of nitrogen in
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the organic compound is .........
82. Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason
(R)
Assertion (A) : At 10°C, the density of a 5 M solution of KCl [atomic masses of K and Cl are 39 &
35.5 g mol–1]. The solution is cooled to –21°C. The molality of the solution will remain
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unchanged.
Reason (R) : The molality of a solution does not change with temperature as mass remains
unaffected with temperature.
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In the light of the above statements, choose the correct answer from the options given below :
(A) Both (A) and (R) are true and (R) is the correct explanation of (A)
(B) Both (A) and (R) are true but (R) is not the correct explanation of (A)
(C) (A) is true but (R) is false
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84. 56.0 L of nitrogen gas is mixed with excess of hydrogen gas and it is found that 20 L of ammonia
gas is produced. The volume of unused nitrogen gas is found to be .......... L.
85. The normality of H2SO4 in the solution obtained on mixing 100 mL of 0.1 M H2SO4 with 50 mL of
0.1 M NaOH is ......... ´ 10–1 N. (Nearest Integer)
CH3 CHO
86.
5g (92 %)
In the above reaction, 5 g of toluene is converted into benzaldehyde with 92% yield. The amount of
benzaldehyde produced is ........... ´ 10–2 g. (Nearest integer).
House Of Wisdom
Chapters : 1,3 Std 11 : Chemistry
Unit Test
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Section B
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• Write the answer of the following questions. [Each carries 2 Marks] [24]
75.
77.
78.
80.
82.
83.
84.
86.