(0999DJA161103240018) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Advanced)

TEST # 14
(Academic Session : 2024 - 2025)
29-12-2024

JEE(Main + Advanced) : LEADER TEST SERIES / JOINT PACKAGE COURSE

Test Type : Review (Unit Test # 06, 07, 08, 09 & 10)
ANSWER KEY
PART-1 : PHYSICS
Q. 1 2 3 4
SECTION-I (i)
A. C C A A
Q. 5 6 7
SECTION-I (ii)
A. A,C,D A,C,D A,B,C,D
Q. 1 2 3 4
SECTION-II (i)
A. 6.25 1.25 7.00 0.75
Q. 5 6 7 8 9 10
SECTION-II (ii)
A. 3 2 3 9 3 5
PART-2 : CHEMISTRY

Q. 1 2 3 4
SECTION-I (i)
A. D D C C
Q. 5 6 7
SECTION-I (ii)
A. C,D A,D A,B,C
Q. 1 2 3 4
SECTION-II (i)
A. 5.00 8.00 7.40 0.02
Q. 5 6 7 8 9 10
SECTION-II (ii)
A. 9 6 8 5 6 3
PART-3 : MATHEMATICS

Q. 1 2 3 4
SECTION-I (i)
A. B B B B
Q. 5 6 7
SECTION-I (ii)
A. A,B,D A,B,C A,B,C,D
Q. 1 2 3 4
SECTION-II (i)
A. 156.50 1.00 64.00 3.00
Q. 5 6 7 8 9 10
SECTION-II (ii)
A. 75 26 2 2 1 81

HINT – SHEET
PART-1 : PHYSICS 3. Ans ( A )
SECTION-I (i) From screw guage
zero error = + 0.20 mm
2. Ans ( C ) Dia of Chalk = 3.5 – 0.2
1240
K= − 1.5 = 0.5 eV = eEd = 3.3 mm
620
2∈ for vernier calliper
=e× 0d
∈0 zero error = – 0.05 cm
1
d= m Thus it must show = 0.33 – 0.05
4
= 0.28 cm

0999DJA161103240018 HS-1/8
 Target : JEE (Main + Advanced) 2025/29-12-2024
4. Ans ( A ) 6. Ans ( A,C,D )
2π y
Δϕ = Δx & Δx = ( ) × d 13.6z 2 [
1
−
1
] = 204
λ D 2
3λD1
1 (2n)2
y1 = 1 1
d 13.6z 2 [ − ] = 40.8
Now for y2 n2 (2n)2

Δϕ 3 π solving, n = 2, z = 4
Imaxcos2 = Imax × ⇒ Δϕ = + 2nπ
2 4 3
& this can be 4π + or 6π − 6π − π
π
3
π
3 3
7. Ans ( A,B,C,D )
y2 2π
= Δϕ⇒ y2
17D2 λ 13D2 λ In standing wave energy is confined between
⇒ (
D2
× d) = 6d
,
6d
λ
13D2
node & antinode.
∵ y1 = y2 ⇒ = 3D1
6 Node and antinode do not transfer its energy but
finally & D2 = 18 D element between node & antinode transfers its
13
D2 − D1 5D
v= = energy to other element.
Δt 13
PART-1 : PHYSICS PART-1 : PHYSICS
SECTION-I (ii) SECTION-II (i)

5. Ans ( A,C,D ) 1. Ans ( 6.25 )

V0 dv
i20 = = 50√2 A −mv ⋅ = μ(mg + qE0 )
dl
√ R2 + X22 0 l

⇒ i10 = 50 A −m ∫ vdv = μ(mg + qE0 ) ∫ dl

v0 0
mv20
l=
2μ(mg + qE0 )
1(100)
l= = 6.25 m
2 × 4(10 + 2 × 5)
2. Ans ( 1.25 )
N = mg + qE0

and −m dv = μN
dt
dv
−m = μ(mg + qE0 )
Phase difference between v and i is θ = 0° dt
i = i1 + i2 0 t

i0 = 50 or −m ∫ dv = μ(mg + qE0 ) ∫ dt
i0 v 0 v0 0
Pav = cos θ = 2500 W
2 mv0
Thus t =
μ(mg + qE0 )
1(10)
= 1.25 s
0.4(1 × 10 + 2 × 5)
V0
z= = 2Ω.
i0
HS-2/8 0999DJA161103240018
 Leader Test Series/Joint Package Course/29-12-2024
3. Ans ( 7.00 ) 6. Ans ( 2 )
2
1 1 R Excess pressure in a bubble of gas in a liquids is
= ( mR2 ) w1 − ( m( ) ) w2
2 2 2
1 1 R R
2 2 Pressure out side the bubble is P0 + rgh
= [ mR2 + m( ) + m( ) ] wf
2 2 2 2 2s
When P0 is atmospheric pressure
w1 w2 r
= −
2 8 Therefore pressure inside the bubble is P0 + ρgh
1 1 1
= ( + + ) × ωf 2s
2 8 4 P0 + ρgh +
R
1 3 4+1+2
= − = wf 10 2 × 8 × 10−2
2 8 8 1.01 × 105 × 103 × 10 × +
100 0.02 × 10−3
1 −2
β = wf = 16 × 10
7 1.01 × 105 + 103 +
1 2 × 10−3
49β = 49 × = 7 1.01 × 105 + 103 + 0.08 × 105
7
4. Ans ( 0.75 ) 1.01 × 105 + 0.01 × 105 + 0.08 × 105
ΔL = LF − Li
1 R 1
2 = 105 (1.01 + 0.01 + 0.08)
= { m ( ) w2 + w1 }
2 2 8
2 2
= 1.1 × 105 = 110 × 103 = 55x × 103
1 R R
= { m( ) + m( ) } W2
2 2 2 So x = 2
2
1
2
R
− { − m( )
2
} w1 7. Ans ( 3 )
3 3
= mR2 { + }
8 8
3
= 10 × 1 ×
4
ΔL
τ= = 0.75
Δt

PART-1 : PHYSICS
SECTION-II (ii)

5. Ans ( 3 ) i1sin237 cos 37 = i2 sin253 cos 53

3
i2 = i1
4
μ0 i1 3 ∘ μ0 3
sin 37 + × i1 sin3 53∘
4R 4R 4
ℓ 1 = 24 km, ℓ 2 = 79.1 cm, e = 0.3D μ0 i1 27 3 64
[ + × ]
79.1 − 3 × 24.1 4R 125 4 125
⇒ 0.3D =
2 μ0 i1 75 μ0 i1
1.8 × =3
0.3D = = 0.9 4R 125 20R
2
D = 3 cm
0999DJA161103240018 HS-3/8
 Target : JEE (Main + Advanced) 2025/29-12-2024
8. Ans ( 9 ) 10. Ans ( 5 )
m1 − m2 2m2 1 m × 4m
V1 = U1 − U (v − 0)2 ⩾ W0
m1 + m2 m1 + m2 2 m + 4m

m1 − m2 − 2m2 1
V1 = U ⇒ 4mv2 ⩾ 5w0
m1 + m2 2

m1 − 3m2 PART-2 : CHEMISTRY

V1 = ( ) U
m1 m2
SECTION-I (i)

1. Ans ( D )

V1 will be maximum when m2 >>> m1

∴ V1 = – 3U

∴ h = 9h

9. Ans ( 3 ) 2. Ans ( D )
Δd

σ=−
⎛
d ⎞ (1) NH3 has higherboiling point than AsH3 and PH3
⎝
Δh ⎠ on account H-bonding. SbH3 has highest boiling
h
point on account of highest molecular weight.
vw = 2Ai = Af(2 + 0.08 × 10 – 2) (2) As the size of element increases, the strength of
M–H bond decreases and thus stability decreases.
Af 2
⇒ = (3) Basicity decreases down the group.
Ai 2 + 0.08 × 10−2
Af − Ai −0.08 × 10−2 −0.08 × 10−2
3. Ans ( C )
= ≈ 1 8RT P
Ai 2 + 0.08 × 10−2 2 Z= πσ 2 √ .
√ 2 πM KT

∴
ΔA
=−
0.08 × 10 −2
=2
Δd 4. Ans ( C )
A 2 d

Δd
⇒ = – 0.02 × 10 – 2
d

0.02 × 10−2 1
∴ σ= =
0.12×10 −2
3
2

1
⇒ =3
σ

HS-4/8 0999DJA161103240018
 Leader Test Series/Joint Package Course/29-12-2024
PART-2 : CHEMISTRY 2. Ans ( 8.00 )
SECTION-I (ii)

5. Ans ( C,D ) Monochloro products =

6. Ans ( A,D )
3. Ans ( 7.40 )
Na2CO3 + HCl → NaHCO3 + HCl
0.1M
[H + ] = √Ka1 Ka2 = √16 × 10−16 = 4 × 10−8
Fe+ : [Ar]3d7
Unpaired electron = 3 pH = 8 – log4 = 8 – 0.6 = 7.4
Paramagnetic 4. Ans ( 0.02 )
7. Ans ( A,B,C ) HCO−3 ⇌ H + + CO2− 3 , Ka2 = 8 × 10
−10

+2
x(s) → x (0.001 M) + 2e¯ (anode) 0.1 M 4 × 10 – 8 M
y+2 (0.1 M) + 2e¯ → y (s) (cathode) −10
( 4 × 10−8 ) [CO2−
3 ]
8 × 10 =
_____________________________ 0.1
⇒ [CO2− ] = 2 × 10 –3 M
0.06 x+2 3
Ecell = E°cell − log
2 y +2 PART-2 : CHEMISTRY
Ecell = E°cell + 0.06
SECTION-II (ii)
(A) Cd and Ni E°cell = + 0.4 – 0.24 ; Ecell = 0.22
(B) Cd and Fe E°cell = – 0.04 ; Ecell = 0.02 5. Ans ( 9 )
(C) Ni and Pb E°cell = 0.11 ; Ecell = 0.17 n=3
−2 × 13.6 × (1)2
(D) Ni and Fe E°cell = – 0.2 ; Ecell = – 0.14 P.E. = – 2 × T.E. =
(3)2
since in (A) (B) (C) Ecell is positive hence answer
is (A) (B) (C). 6. Ans ( 6 )
Be and Mg compounds do not show flame
PART-2 : CHEMISTRY colouration test.
SECTION-II (i) 7. Ans ( 8 )
1. Ans ( 5.00 )
(P) CH3COOH (Q) CH3CH2OH
(R) CH3CH2Br (S) CH3CHO

(T) (U)

(V) (W)
(Q),(R),(S),(T),(V) can give yellow ppt when
react with NaOI
Total number of π-bonds present in product P is 8
0999DJA161103240018 HS-5/8
 Target : JEE (Main + Advanced) 2025/29-12-2024
8. Ans ( 5 ) x + yy ′ + 2y ′ (
−x2 − xy 2
) = 0 (by using (1))
i, iii, v, vi, viii 2y
9. Ans ( 6 ) x + y ′ (y −
−x2 − y 2
) =0
x 2y
log = log k + 1 logp
m n y 2 − x2
1
= tan45° = 1 x + y′ ( ) =0
n 2y
log k = 0.3010 y′(x2 – y2) = 2xy
⇒k=2
x 1 ⇒ g(x) = 2x
then = KP n = 2 × (3)1 = 6
m
10. Ans ( 3 ) 3. Ans ( B )
2
NH4NO2, (NH4)2Cr2O7, NH4MnO4 |adj(adjA)| = |adjA|

PART-3 : MATHEMATICS ∣ ∣2
= ∣2√3∣ = 12
SECTION-I (i)
4. Ans ( B )
1. Ans ( B ) Required probability =
3C

9C
1
⋅
4C

8C
1
⋅
2C

7C
1
⋅ 3! =
2
7
1 1 1

PART-3 : MATHEMATICS
SECTION-I (ii)

5. Ans ( A,B,D )
Equation of normal is y = mx – 2m – m3
It passes through the point (9, 6) then
6 = 9m – 2m – m3
AB = √ 26 ⇒ m3 – 7m + 6 = 0
r2 = CM2 + AM2 ⇒ (m – 1)(m – 2)(m + 3) = 0
2 2
13 13 ⇒ m = 1, 2, – 3
= (2 × √ ) + (
√
)
2 2
65 Equations of normals are
r2 =
2 y – x + 3 = 0,
2. Ans ( B ) y + 3x – 33 = 0
x2 + y2 + 2gx + 2fy + c = 0
& y – 2x + 12 = 0
It touches the x-axis at origin
⇒ c=0 6. Ans ( A,B,C )
⇒ g2 − c = 0
√
aij = (i2 + j2 – ij)(j – i)
⇒ g=0 aji = (j2 + i2 – ji)(i – j) = – aij
x2 + y2 + 2fy = 0 ... (1) ⇒ A is skew symmetric
Differentiate w.r.t. x
⇒ Tr(A) = 0 ⇒ |A| = 0

HS-6/8 0999DJA161103240018
 Leader Test Series/Joint Package Course/29-12-2024
7. Ans ( A,B,C,D ) 3. Ans ( 64.00 )
2 Equating of line L1 and L2 can be obtained in
∣ α−β ∣ ∣ α−β ∣
Given ∣ ∣ = 1 ∣ ∣ = 12
∣ ¯ ∣
1 − αβ ∣ ¯
1 − αβ ∣ symmetric form
x y− b z
L1 : = =
0 −b c
x−a y z
L2 : = =
a 0 c
∣ x y−b z∣
∣ ∣

Equation of plane p : ∣
∣
0 −b
∣
c∣ = 0
∣ ∣

αα¯ − αβ¯ − βα¯ + ββ¯ = (1 − αβ) ¯

¯ (1 − αβ )
x y z
∣ a 0 c∣

⇒ − − +1 = 0
a b c
α2 ∣∣ − αβ¯ − βα¯ + |β| = 1 − αβ¯ − αβ ¯ ¯
∣
2 ¯ + ααββ
∣
Lines L1 and L2 in vector form
^ ^ ^
| α |2+| β |2=1+| α |2| β |2 L1 : ¯r = bj + λ(−bj + ck)
^ ^
L2 : ¯r = aj + μ(ai + ck)
1 – | α |2+| α |2| β |2 – ( β )2 = 0
Shortest Distance =
(1 – | α |2) – | β |2(1 – | α |2) = 0
1 1 1
(1 – | α |2)(1 – | β |2) = 0 + + = 64
a2 b2 c2
Image of A(1, 0, 0) in the plane x − y − z + 1 = 0
| α |2 = 1 or | β |2 = 1 −1 4 4
is (
3
, , ) its
3 3
distance from M is 3.
|α| = 1 or |β| = 1 4. Ans ( 3.00 )
α = ei θ or β = ei θ Equating of line L1 and L2 can be obtained in
symmetric form
PART-3 : MATHEMATICS x y− b z
L1 : 0
=
−b
=
c
SECTION-II (i) x−a y z
L2 : = =
1. Ans ( 156.50 ) a 0 c
∣
∣
x y−b z∣
∣

Total natural number formed Equation of plane p : ∣

∣
0 −b
∣
c∣ = 0
∣ ∣

∣ a 0 c∣
= 4 + 16 + 64 + 256 = 340 x y z
⇒ − − +1 = 0
a b c
Total natural number not exceeding 8531 Lines L1 and L2 in vector form
^
= 4 (1 digit) + 16 (2 digit) + 64 (3 digit) + L1 : ¯r = bj^ + λ(−bj^ + ck)
^
229 (4 digit) = 313 L2 : ¯r = aj^ + μ(ai + ck)
2. Ans ( 1.00 )
Total 4 digit (different) number = 24 Shortest Distance =
number according to given condition 1 1 1
+ + = 64
1 1 1 1 a2 b2 c2
= 4! ( 1−
+ − + )
1! 2! 3! 4! Image of A(1, 0, 0) in the plane x − y − z + 1 = 0

Required probabilty = 9 = 3 = 9 is (
−1 4 4
, , ) its distance from M is 3.
24 8 3 3 3

0999DJA161103240018 HS-7/8
 Target : JEE (Main + Advanced) 2025/29-12-2024
PART-3 : MATHEMATICS 7. Ans ( 2 )
SECTION-II (ii)
(tany + ysec2y)dy = ex(sinx + cosx)dx
ytany = exsinx + C
5. Ans ( 75 ) (0,0) gives C = 0
ytany = exsinx
π tan π = ex1 sin x1
⇒ sin x1 = 0 ⇒ x1 = 2π
x1
=2
π
The eq. of circle is 8. Ans ( 2 )
x2 + y2 – 2x – 4y – 20 = 0 The chord joining α and β is
Centre (1, 2) radius = 1 + 4 + 20 = 5
√ x cos[(α + β)/2]
+
y sin[(α + β)/2]
Using eq. of tangents at (x1, y1) of a b

x2 + y2 + 2gx + 2fy + c = 0 is = cos( α −2 β )

xx1 + yy1 + g(x + x1) + f(y + y1) + c = 0 π 1

= cos () =

Eq. of tangent at (1, 7) is 4 √2

α+β
x . 1 + y . 7 – (x+1) – 2(y+7) – 20 = 0 If =θ
2
⇒ y–7=0 then the equation of the chord is
x
Similarly eq. of tangent at (4, – 2) is cos θ + sin θ = 1
(a/√25)
4x – 2y – (x + 4) – 2 (y – 2) – 20 = 0 Hence, the chord touches the ellipse
⇒ 3x – 4y – 20 = 0 .....(2) x2 y2
2
+ 2
=1
For pt C, solving (1) and (2), we get (a/√2) (b/√2)
2 y 2
x
x = 16, y = 7 or 2 + 2 = 1
∴ C(16, 7) a b 2
Therefore, k = 2
Now, clearly ar (quad ABCD) = 2 Ar (rt Δ ABC)
9. Ans ( 1 )
= 2 × 1 × AB × BC = AB × BC
2
where AB = radius of circle = 5
and BC = length of tangent from C to circle
= 162 + 72 − 32 − 28 − 20 = 225 = 15
10. Ans ( 81 )
√ √

∴ ar (quad ABCD) = 5 × 15 = 75 sq. units x−1 y−0 z−1

6. Ans ( 26 )
∣ ∣
∣ ∣
∣ ∣
∣
1−1 2 1−1∣=0
∣ ∣
3 /2 ∣ 1−0 0−1 1+2∣
Total area = ∫ (1 + 4x − x2 ) dx ⇒ 3x – z – 2 = 0
0 →a = αi^ + βj^ + γk || to 3x – z – 2 = 0
x3 ∣
3/2
39 ⇒ 3α − 8 = 0 .....(1)
= x + 2x2 − =
→a ⊥i^ + 2j^ + 3k
∣
3 ∣0 8
& 39 1 3 3
=
. . m ⇒ α + 2β + 38 = 0 ..... (2)
16 2 2 2
13 →a (^i + ^j + 2k) = 0
⇒ 3m = ⇒ 12m = 26
2 ⇒ α + β + 28 = 2 ..... (3)
on solving 1, 2 & 3
α = 1, β = –5, 8 = 3
So (α – β + 8) =
HS-8/8 0999DJA161103240018