(1001CJA101021240058) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Advanced)

AIOT
(Academic Session : 2024 - 2025)
20-04-2025

JEE(Main + Advanced) : LEADER TEST SERIES / JOINT PACKAGE COURSE

Test Type : Full Syllabus
ANSWER KEY PAPER-2
PART-1 : PHYSICS
Q. 1 2 3 4 5 6
SECTION-I (i)
A. B,C,D A,C C,D A,C,D A,C A,B,C
Q. 7 8 9 10
SECTION-I (ii)
A. B B A A
Q. 1 2 3 4 5 6
SECTION-II (i)
A. 12.00 100.00 0.25 121.14 to 121.15 201.60 10.08
Q. 7 8 9
SECTION-II (ii)
A. 2 1 8

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6
SECTION-I (i)
A. A,C A,B,C,D A,C,D A,B,D A,B,C A,B,C
Q. 7 8 9 10
SECTION-I (ii)
A. D D C D
Q. 1 2 3 4 5 6
SECTION-II (i)
A. 2.00 4.00 172.41 1.15 101.00 150.55
Q. 7 8 9
SECTION-II (ii)
A. 3 3 7

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6
SECTION-I (i)
A. B,C A,B,C,D A,D B,C B,D A,B,D
Q. 7 8 9 10
SECTION-I (ii)
A. B D D A

Q. 1 2 3 4 5 6
SECTION-II (i)
A. 1.00 2.00 12.00 21.00 4.00 3.00
Q. 7 8 9
SECTION-II (ii)
A. 4 2 90

HINT – SHEET

1001CJA101021240058 HS-1/8
 Target : JEE(Main + Advanced) 2025/20-04-2025/Paper-2
PART-1 : PHYSICS PART-2 : CHEMISTRY
SECTION-II (i) SECTION-I (i)

6. Ans ( 10.08 ) 1. Ans ( A,C )

ρR
F = QE = Q ( )
(1)
(i) BH3 ,T HF
−−−−−−−−−−→
NaOH
−−−−→
6∈0
(ii) H2 O2 , OH

QR
⎛
Q
⎞
Q2 (i) Hg(OAc)2 , H2 O NaOH
= ⎜
⎜
⎟
⎟ = (2) −−−−−−−−−−−→ −−−−→
6∈0 4π
(R
3 − R3
) ⎠
7π∈0 R2 (ii) NaBH4
⎝
3 8

PART-1 : PHYSICS
SECTION-II (ii)
MCP BA
−−−−−→
9. Ans ( 8 ) (3)
CH2 Cl2

For the first question, apply the Boltzmann equation,

(4) + (CH3)3CO – Na+ → No reaction
and
P = σATs4 2. Ans ( A,B,C,D )
where A is the surface area of the planet, and Ts the
temperature at the center. Then
1
P 4
Ts = ( )
4πσR2
For the second question, it is reasonable to assume
that the temperature depends on the distance form the Θ
CH3 MgBr (1eq.) OD /D2 O
center only. Then the definition of k gives for a −−−−−−−−−−→ −−−−−−→
spherical shell of thickness dr
ΔQ 1 dr
k= .
Δt 4πr2 dT
The heat through the shell depends on the power 3. Ans ( A,C,D )
radiated from within the shell. Since the planet is
uniform, this depends on the volume according to
4 3
ΔQ 3
πr r3
Δt
=P 4
3
πR3
=P
R3 4. Ans ( A,B,D )
so that rearrangement yields X = XeOF4, Y = XeO2F2, Z = XeO3
dT =
P
4πkR3
r dr 5. Ans ( A,B,C )
Integrating between the center and the surface, M = Cu
P K4 [F e(CN )6 ]
ΔT = , Cu2+ −−−−−−−−→ Cu2 [F e(CN)6 ] ↓
8πkR
(Brown)
which could be used to find the temperature of the
interior.

HS-2/8 1001CJA101021240058
 All India Open Test/Leader Test Series/Joint Package Course/20-04-2025/Paper-2
6. Ans ( A,B,C ) 8. Ans ( D )
(A) pH = 5 + log 1 = 5 (Buffer solution) ⇒ = M = 80 g mol – 1
and
(B) salt hydrolysis

(C) [ H + ] = √CKa = 10−5 ; pH = 5

(Terminal alkynes responsed
(D) [OH – ] = 2 × 5 × 10 – 6 = 10 – 5, pOH = 5, pH = 9
to tollen's test)
PART-2 : CHEMISTRY
SECTION-I (ii)
10. Ans ( D )
3
7. Ans ( D ) NaN3 (s)
1mole
Na +
(solid) 2
N2
(gas)

Rate of diffusion of methane N2(g) + 3H2 → 2NH3 (g)

1 NH3 + Ca(OCl)Cl → N2 + CaCl2 + H2O

= mole sec−1
16 × 20
PART-2 : CHEMISTRY
Rate of diffusion of hydrocarbon
SECTION-II (i)
20
1. Ans ( 2.00 )
√
−1
= moles sec
M × 40
rCH4 √ Mhyd Acid (A) is ethanoic acid as it is an important
Now, = constitutent of vineagar.
rhyd 16
1
16×20 M
√
40 × M √ M
= ⇒ =
√20
4 16 × 20 × √20 4
M×40

⇒ √M = 2√20

−1
⇒ M = 80 g mol
Also,
0.125 m mol of (A) consumes 0.375 m mol H2 . So,

(A) has three π -bonds

Therefore : molecular formula of A is C6H8

An open chain isomer of A can be

CH2 = CH – CH = CH – CH = CH2

A six membered stable monocyclic isomer of (A)

can be or

Now, since (C) has no chiral carbon. So, x = 0

And (D) has one asymmetric carbon, so y = 2
1001CJA101021240058 HS-3/8
 Target : JEE(Main + Advanced) 2025/20-04-2025/Paper-2
2. Ans ( 4.00 ) PART-2 : CHEMISTRY
Total number (z) of dipeptides which can be made
SECTION-II (ii)
by (C) and (D) are
gly - gly, ala - ala, gly - ala, ala - gly
7. Ans ( 3 )
H3 O+
Hence, z = 4 −−−−→
Step−1

3. Ans ( 172.41 ) I2 /OH −

n1 Cv1 + n2 Cv2 −−−−−→
Cvmix = ( ) Step−3
n1 + n2
5R 5R
( 0.5 × 2
) + (0.5 × 2
)

=
1 KMnO4
5R −−−−−→
Cvmix = Step−4
2
Cpmix = R + Cvmix
5R
=R+

=
7R
2
8. Ans ( 3 )
2 Δ Tb = i.Kb.m
For reversible adiabatic process
2
0.08 = i × 0.5 ×
T1 V1γ−1 = T2 V2γ−1 20
7 0.08 20
300(1)r−1 = t2 (4) 5 × =i
0.5 2
2
300 × 1 = T2 (4) 5 i = 1.6
300 = T2 × 1.74
T2 = (172.41 K) Scm2 2 mole
= 500 × × 0.6
mole 20 L
4. Ans ( 1.15 ) Λm = 30
Scm2
=
3
Scm−1
1000cm 3 100
Λ m = 3 Sm – 1

9. Ans ( 7 )
BaCl2 + Na2 SO4 → BaSO4 ↓ +2NaCl
0.2 M 0.1 M ppt
9 0.04 mole 0.02 mole 0.08 mole
X = O2 γ = = 1.28
7 πNa2 SO4 = i1 C1 RT πNaCl = i2 C2 RT
15 πNa2 SO4 + πNaCl = (i1 C1 + i2 C2 ) . RT
Y = CO2 γ= = 1.15
13 0.02 0.08
=3×( ) + 2( ).R × T

7 0.8 0.8
Z = SO2 γ = = 1.16 = (0.075 + 0.2)RT
6

5. Ans ( 101.00 ) = 0.275 × 0.0821 atm × 300

G = NaHCO3, D = NH3 = 6.99
= 7 atm

HS-4/8 1001CJA101021240058
 All India Open Test/Leader Test Series/Joint Package Course/20-04-2025/Paper-2
PART-3 : MATHEMATICS 3. Ans ( A,D )
SECTION-I (i) (a) Tn3 + Tn = Tn+1 − Tn

1. Ans ( B,C ) ∑
100
(Tn3 + Tn + 1) = T101 − T1 + 100 = T101 + 99
n=1
xf(y) < yf (x) ∀ 0 < x < y < 1
f(y) f(x) Tn+1
(c) Tn2 + 2 =
⇒ < ∀x < y Tn
y x
f(x) 100 100 Tn+1 T
⇒ g(x) = is decreasing ∏ (Tn2 + 2) = ∏n=1 = 101 = T101
x n=1 Tn T1
⇒ g ′ (x) < 0 ⇒ xf ′ (x) < f(x) 100 Tn+1
(d) ∏
n=1
( − Tn2 ) =2100
f(x) Tn
f ′ (x) <
⇒
x
∀ x, 0 < x < 1
4. Ans ( B,C )
′
Hence, f (x) < g(x)∀ x, 0 < x < 1
Hence, f '(x) is less than minimum value of g(x)
which is g (1)
∴ f ′ (x) < f(1)
1 1
′ ′
x f (x) < f(x) ⇒ ∫ x f (x) dx < ∫ f(x) dx
0 0

(3x – y) (x + 3y) = 0
1 −x
⇒ f(1) < 2 ∫ f(x) dx y = 3x, y =
0
3

2. Ans ( A,B,C,D ) (a) m1 + m2 = 3 −

1
3
=
8
3
c∣ ∣ −b ∣ 1
|z1 z2 | = ∣∣ = 1, |z1 + z2 | = ∣ ∣ = 1 (b) am1 + m2 = 3 (− ) + 3 = 2
a ∣ ∣ a ∣ 3

⇒ (z1 + z2 ) × (z¯1 + ¯z2 ) = 1

(c) y = 2x + 4
−12 4
1 1 A ≡ (4, 12), B = ( , )
⇒ (z1 + z2 ) ( + ) = 1 7 7
z1 z2 1 √ 144 + 16 160 80
Area (ΔAOB) = × 16 + 144 × √ = =
2 49 2×7 7
(z1 + z2 )2 = z1 z2
⇒
2
5. Ans ( B,D )
−b c (A2 − 2I)B = 0 ⇒ A2 = 2I and
⇒ ( ) = ⇒ b2 = ac
a a
A
θ 2π B = adj A = |A|. = − √2A{∴ |A| = − 2√2}
|z1 + z2 | = |z1 ||1 + eiθ | = 2 cos = 1 ⇒ θ = 2
2 3 AB = A (adj A) = |A|. I
θ
P Q = |z2 − z1 | = |z1 || eiθ − 1| = 2 sin tr. (AB) = 3|A| = −6√2
2
π √
and det. (A − √ 2B) = det. (A + 2A) = det. (3A)
= 2 sin = 3
3 = 27(−2√2) = −54√2

1001CJA101021240058 HS-5/8
 Target : JEE(Main + Advanced) 2025/20-04-2025/Paper-2
6. Ans ( A,B,D ) 8. Ans ( D )
a, b and c are in G.P.
x3 – 3 x + λ = 0 let root = α , β , γ x2 +f
⎡
x+d
, x<0
⎢
∴ α + β + γ = 0, αβ + βγ + γα = −3, αβγ = −λ x2 + f ⎢
f (x) = lim = ⎢
⎢ f
, x=0
n→∞ 2ex (ex )n + x + d ⎢
⎢ 2+d
α2 + β 2 + γ 2 = 6, (α, β, γ ∈ I)
⎢
∴
⎣
0 , x>0
∴ Possibilities are For f(x) to be continuous
f f
= =0 ⇒ f=0
d 2+d
f(x) = || x – 4| – 2| – 1
∴ h(x) = x3 − 3x + 4

Required area
5 5
531
=∫ h(x) dx = ∫ (x3 − 3x + 4) dx =
2 2 4

And

No of solution = 4

PART-3 : MATHEMATICS
9. Ans ( D )
A P (A ∩ BE )
SECTION-I (ii) P( ) = , where A = sum is 4.
BE P (BE )
7. Ans ( B ) And P (BE ) = P (B2) + P (B4)+. . . . . . . . . = 14 + 161 + 641 +. . . . . . . . . ∞
a, b and c are in A.P. 1
4 1 4 1
= = . =
1− 1 4 3 3
∴ √ ac < b 4

x2 +f P (A ∩ BE ) = P (A ∩ B2 ) + P (A ∩ B4 )
⎡
x+d
, x<0
⎢
n A A
−(ex ) + x2 + f ⎢
⎢
−1+f = P (B2 )P ( ) + P (B4 )P ( )
f (x) = n→∞
lim = ⎢
, x=0 B2 B4
2ex (ex )n + x + d
⎢
⎢ 2+d
⎢
⎢
1 3 1 1 (4.3.62 + 1) 433
⎣
−1
, x>0 = ( )+ ( ) = =
2ex 4 36 16 6 4
16.6 4
16.64
433 433
For f(x) to be continuous Hence P ( A ) = .3 = ≅
1
BE 16.6 4 32.216 16
f −1 + f −1
d
=
2 + d
=
2 10. Ans ( A )
n(S) = 6 × 6 × 6 = 63 = 216
∴ 2f + d = 0 ⇒ 2f + d + 1 = 1
Now greatest number is 4, so atleast one of the dice
shows up 4.
∴ n(A) = 43 − 33 = 37

Hence P (A) = 37
216
HS-6/8 1001CJA101021240058
 All India Open Test/Leader Test Series/Joint Package Course/20-04-2025/Paper-2
PART-3 : MATHEMATICS 3. Ans ( 12.00 )
SECTION-II (i) Put x = cos θ
1. Ans ( 1.00 ) 1 − x2 = sin2 θ. ⇒ √x2 − 1 = i sin θ
2 1 1 10 10
a, c, b are in H.P, ⇒ = +
x + √x2 − 1) + (x − √x2 − 1)
c a b (

Family of lines
= (cos θ + i sin θ)10 + (cos θ − i sin θ)10
x y 1 x y 1 1 1
+ + =0⇒ + + ( + )=0
a b c a b 2 a b = 2 cos 10θ = 2 f10 (x) = λfk (x)
1 1 1 1
⇒ (x + ) + (y + ) = 0
a 2 b 2 ∴ λ = 2; k = 10 ⇒ λ + k = 12.
−1 −1
⇒ centre of ellipse ≡ ( ,
4. Ans ( 21.00 )
)
2 2
1
AC : x2 + y 2 + 2px + 2qy − 8p + = 0 f6 (cos x) = cos 6 x
2
1 1
⇒ p = : q = ; radius of AC = 2 we know,
2 2
∴ ℓ (major axis) = 2a = 4
(cos x + i sin x)6 = cos 6 x + i sin 6x
⇒ We know, harmonic mean of segment of focal
Equating real part both sides :
chord is equal to semi latus rectum.
cos 6x = 6C0 cos6 x − 6C2 cos4 xsin2 x + 6C4 cos2 xsin4 x − 6C6 sin6 x
2.(1 × 2) 4
semi latus rectum = =
(1 + 2) 3 f6 (cos x) = cos 6 x = cos6 x – 15 cos4 x (1 – cos2x) + 15
2. Ans ( 2.00 )
cos2 x (1 – cos2x)2 – (1 – cos2x)3
a,c, b are in H.P, ⇒ 2 = 1 + 1
c a b
∴ f6 (x) = x6 – 15 x4 (1 – x2) + 15 x2 (1 – x2)2 – (1 – x2)3
Family of lines :
x y 1 x y 1 1 1 ∴ p = 32 ; q = – 48; r = 18, s = –1.
+ + =0⇒ + + ( + )=0
a b c a b 2 a b
1 1 1 1 ∴ 7 (p + q + r –s) = 7 (32 – 48 + 18 + 1) = 7 × 3 = 21
⇒ (x + ) + (y + ) = 0
a 2 b 2
−1 −1 5. Ans ( 4.00 )
⇒ centre of ellipse ≡ ( , )
2 2 Equation of family of planes containing the line of
1
AC : x2 + y 2 + px + 2qy − 8p + = 0
2 intersection of P1 and P2 is given by P1 + λ P2 = 0
1 1
⇒ p = : q = ; radius of AC = 2
2 2 ⇒ (1 + λ ) x + (1 – 2 λ ) y + (2 + λ ) z – 3 – 4 λ = 0
∴ l (major axis) = 2a = 4
… … .(1)
⇒ We know, harmonic mean of segment of focal
Projection of length of line segment AB is greatest,
chord is equal to semi latus rectum.
then AB must be parallel to plane (1)
Semi latus rectum
∴ drs of AB = 2, – 1,3.
2.(1 × 2) 4
= =
(1 + 2) 3 2 (1 + λ ) – 1 (1 – 2 λ ) + 3 (2 + λ ) = 0 ⇒ λ = – 1
8
∴ latus rectum, L = = 2.67 P3 : 3y + z + 1 = 0. ⇒ a = 0, b = 3, c = 1
3 ∴

[L] = [2.67] = 2
1001CJA101021240058 HS-7/8
 Target : JEE(Main + Advanced) 2025/20-04-2025/Paper-2
6. Ans ( 3.00 ) 9. Ans ( 90 )
Projection of length of line segment is least if AB
is perpendicular to plane (1).
1+λ 1 − 2λ 2+λ
= = ⇒λ=1
2 −1 3
∴ Equation of plane P4 is
2x − y + 3z = 7. ⇒ a = 2, b = −1, c = 3
∞
n n−2
= n∫ (−(sin x) + (n − 1)(1 − sin2 x)(sin x) )e−x dx
PART-3 : MATHEMATICS 0

SECTION-II (ii) n(n − 1)

= In−2
7. Ans ( 4 ) n2 + 1

1 1 1 1 1 I10 10 × 9
[ + + + +. . . . ∞] 101 = 101 × = 90.
5 3 6 10 15 I8 102 + 1
2 1 1 1 1
[ + + + +. . . . ∞]
5 6 12 20 30
2 (3 − 2) (4 − 3) (5 − 4)
[ + + +. . . . ∞]
5 6 12 20
2 1 k
× = ⇒k=4
5 2 20

8. Ans ( 2 )
a c sin(200∘ )
− =d ............. (1)
cos(200∘ ) cos(200∘ )
b d sin(200∘ )
+ =c ................ (2)
cos(200∘ ) cos(200∘ )
a = d cos(200°) + c sin(200°) ................ (3)
b = c cos(200°) – d sin(200°) ................ (4)
∴ a2 + b2 = c2 + d2
∴ (a2 + b2 + c2 + d2) = 2 (c2 + d2)
ac = dc cos (200°) + c2 sin (200°)

bd = cd cos (200°) – d2 sin (200°)

Also ___________________________

ac – bd = (c2 + d2) sin (200°)

a2 + b 2 + c2 + d 2 2(c2 + d 2 )
So = = 2 cos ec (200∘ )
ac − bd (c2 + d 2 ) sin(200∘ )

∴ p=2

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