(0999DJA161103240005) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Advanced)

TEST # 04
(Academic Session : 2024 - 2025)
18-08-2024

JEE(Main+Advanced) : LEADER TEST SERIES / JOINT PACKAGE COURSE

Test Type : Review (Unit Test # 01, 02 & 03)
ANSWER KEY
PART-1 : PHYSICS
Q. 1 2 3 4
SECTION-I (i)
A. D B D D
Q. 5 6 7
SECTION-I (ii)
A. A,C A,C C,D
Q. 8 9 10 11
SECTION-I (iii)
A. D D C A
Q. 1 2 3 4 5 6
SECTION-II
A. 4 1 2 5 2 6

PART-2 : CHEMISTRY
Q. 1 2 3 4
SECTION-I (i)
A. D A A C
Q. 5 6 7
SECTION-I (ii)
A. A,C A,B,C B,C
Q. 8 9 10 11
SECTION-I (iii)
A. D A C C
Q. 1 2 3 4 5 6
SECTION-II
A. 125 7 83 3 4 18

PART-3 : MATHEMATICS
Q. 1 2 3 4
SECTION-I (i)
A. D A D C
Q. 5 6 7
SECTION-I (ii)
A. A,C,D A,B A,D
Q. 8 9 10 11
SECTION-I (iii)
A. D D C B
Q. 1 2 3 4 5 6
SECTION-II
A. 6 6 4 2 9 6

HINT – SHEET
PART-1 : PHYSICS 3. Ans ( D )
SECTION-I (i)
Component in x-y plane = 20 cos 30°
Component on z axis = 20 sin 30°
1. Ans ( D ) so
ds dv
v= = 6t2 + 6t + 2 ⇒ a = = 12t + 6 = 0 → = 20 cos 30∘ cos 60∘ ^i + 20 cos 30∘ sin 60∘ ^j + 20 sin 30∘ k^
A
dt dt ^
1 → ^ ^
A = 5 3i + 15j + 10k
⇒ t = – which is impossible. Therefore √

2
acceleration will not be zero at any time 4. Ans ( D )
– 11 = – 5t + ½ at2

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PART-1 : PHYSICS 10. Ans ( C )
−1
SECTION-I (ii) gravitational potential is α ( ) so any
r
6. Ans ( A,C ) position far away has more potential. Gravitational
field inside a uniform hollow sphere is zero due to
its own mass, but it is non-zero due to other
masses present near by.
11. Ans ( A )
^ ^
→v = 6i + (20 − 4t) j
When rays are moving from air to glass,
time when vy = 0
1.5 (1.4 − 1) (1.5 − 1.4)
= + 20 – 4t = 0
f1 +R +R
1.5
=
0.4 0.1
+ =
0.5 t=5
f1 R R R T = 2 × t = 10 sec
|f1| = 3R 20 − 4t
tan 53 =
6
When rays are moving from glass to air, 4 20 − 4t
=
1 (1 − 1.4) (1.4 − 1.5) 0.5 3 6
= + = t = 3 sec
F2 −R −R R
|f2| = 2R R = vx × T
= 6 × 10 = 60 m
PART-1 : PHYSICS
v2y 20 × 20 400 200
H= = = = = 50m
SECTION-I (iii) 2×a 2×4 8 4
8. Ans ( D )
PART-1 : PHYSICS
SECTION-II

Min force required to move 8 kg block on 1. Ans ( 4 )

surface = µN GMS GMS
aE = and aS = 2
⇒ aS = 4aE
= 0.4 (100) = 40 N r2E (
rE
)
2
so 8 kg block will remain at rest
a8kg = 0
3. Ans ( 2 )
FBD of 2 kg

a2kg = 50 − 10 = 20 m/s2
2 kq2
(iv) friction between 8 kg block & ground will b2 a2 q 2 4 1
tan θ = = = × =2
be static kq1 b q1
2 1 2
a2

so fstatic = 10 N

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4. Ans ( 5 ) 3. Ans ( A )
5–T=0⇒T=5 such type of question is solved by excess
product
50%
2SO3(g) −−→ 2SO2(g) + O2(g)

5. Ans ( 2 ) 6400 g 6400 g

[E] = ML2T – 2 6400 6400
2 −2 mol
M1 L1 T1 64 32
n = 5( )( ) ( )
M2 L2 T2 100 200
2 −2
1 1
= 5 (2) ( ) ( )
excess
2 2
6. Ans ( 6 ) Moles of SO3 wrt 200 moles of O2 = 400 mol
mass = 400 × 80 = 3200
= 32 kg (theoretical)
100
actual mass of SO3 = 32 × = 64kg
50

To have resultant along north, force towards 4. Ans ( C )

west should be cancelled. Each Na+ ion is closely surrounded by 6 other Cl–
ions
PART-2 : CHEMISTRY
PART-2 : CHEMISTRY
SECTION-I (i)
SECTION-I (ii)
1. Ans ( D )
5. Ans ( A,C )
Thermal stabilits ⇒ LiOH < KOH < RbOH
Bond length ⇒ HF < HCl < HBr < HI
2. Ans ( A ) 6. Ans ( A,B,C )

(A)

(B) Based on B.O and atomic size

(D) HgS > CdS > ZnS : Poor shielding by d and
f-orbital

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7. Ans ( B,C ) PART-2 : CHEMISTRY
By PV = nRT SECTION-II
At “A” 1. Ans ( 125 )
2 × 8 = 2 × R × TA Possible subshells are present in the 8th period:
8 8s 7d 6f 5g 8p
TA =
R
Between A & B , V is constant Total electrons = 5 + 25 + 35 + 45 + 15 = 125
PA P 2. Ans ( 7 )
= B
TA TB SF6, ClF6+ , BeCl2, SO3, P H4+ , OF2, ICl+2
2 P
= B ⇒ PB = 75R 3. Ans ( 83 )
8/R 300
Between A & D ,P is constant Moles of CuCl2 = 10 × 12 × 1
×2×
1
×
1
0.6 0.5 0.4
VA V
= D
TA TD ⇒ 83.33 moles
8 10 10
= ⇒ TD =
8/R TD R Balanced equation :
PART-2 : CHEMISTRY 40%
CuCl2 + 2KCN −−
→ Cu(CN)2 + 2KCl
SECTION-I (iii) 50%
2Cu(CN)2 −−
→ Cu2 (CN)2 + (CN)2 ↑
8. Ans ( D )
60%
NF3 is polar (pyramidal shape) Cu2 (CN)2 + 6KCN −−
→ 2K3 [Cu(CN)4 ]
XeF5+ shape is sq. pyramidal (polar),
bond angle < 90º 4. Ans ( 3 )
ICl2+ shape is bent (polar), Δ G = Δ Gº + RT ln Q
bond angle < 109º28'
Δ Gº = 2 Δ Gfº(NO2) – Δ Gfº (N2O4) = 0
11. Ans ( C )
22
(P) 20 gm of KOH present in 100 gm solution Δ G = 8 × 300 ln( ) = 3360 J
1
100
V= = 98.04 ml 5. Ans ( 4 )
1.02
20/56 1 YA YB
M= × 1000 = 3.64 M = + o
98.04 PT otal PAo PB
(Q) 444 gm CaCl2 in 1 lit. solute
1 1 − YB Y
444 444 = + B
= =4M 99 100 80
111/1 111
(R) 1.204 × 1024 molecules of water = 2 mole 1 4 − 4YB + 5YB
=
2 mole of water at 4°C is 36 gm or 36 ml 99 400

(S) Volume of 0.2 M NaOH solution 400 = 396 + 99YB

0.2 × V = 1 × 10 – 3 mole
4
−3 YB = × 100 ≃ 4%
1 × 10 99
V= × 1000
0.2
V = 5 ml
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6. Ans ( 18 ) 3. Ans ( D )
1mL → 1.8 gm 1000 mL → 1800 gm. f(x) = – 2x3 – 9x2 – 12x + 1
98
Mass of H3PO4 ⇒ × 1800 = 98 × 18 ⇒ f '(x) = – 6x2 – 18x – 12
100
To be decreasing
Molarity =
10 × 1.8 × 98
= 18 M f '(x) < 0, i.e., – 6x2 – 18x – 12 < 0
98 ⇒ x2 + 3x + 2 > 0
PART-3 : MATHEMATICS ⇒ (x + 2)(x + 1) > 0
SECTION-I (i) Therefore either x < – 2 or x > – 1
1. Ans ( D ) ⇒ x ∈ ( – 1, ∞ ) or ( –∞ , – 2)
Expression 4. Ans ( C )
= ( α tan γ + β cot γ )( α cot γ + β tan γ ) (−2)(2x−x2 )
2

– 4 α β cot22 γ lim
2
=8
x→0 x2
= α 2 + (tan2 γ + cot2 γ ) α β + β 2 ( − 2
)

cos2 2γ
– 4α β PART-3 : MATHEMATICS
sin2 2γ
= α2 + β2 + α β SECTION-I (ii)
2
⎡ sin2 γ cos2 γ 4(cos2 γ − sin2 γ) ⎤ 5. Ans ( A,C,D )
( + ) −
⎣ cos2 γ sin2 γ 4sin2 γcos2 γ ⎦ ƒ(x) =
=α + 2 β2 + α β
π
(sin4 γ + cos4 γ) − (cos4 γ + sin4 γ − 2sin2 γcos2 γ) ⎧
⎪ 1 x ∈ (2nπ, 2nπ + 2
) n ∈ I + ∪ {0}
[ ] ⎪
⎪
⎪
sin2 γ cos2 γ ⎪
⎪
⎪
⎪
⎪
= α + β + 2 α β = ( α + β )2,
2 2 ⎪
⎪
⎪
⎪
⎪
⎪
1+5loge x
3
x = (4n + 1) π
2
n ∈ I + ∪ {0}
⎪
⎪
Which is independent of γ and dependent on ⎪
⎪
⎪
⎪
5loge x π 3π
α,β. ⎨
2
x ∈ (2nπ + 2
, 2nπ + 2
) n ∈ I + ∪ {0}
⎪
⎪
∴ options (D) is correct. ⎪
⎪
⎪
⎪
⎪ 1+5loge x 3π
⎪
⎪
⎪
⎪ 3
x ∈ 2nπ + 2
n ∈ I + ∪ {0}
2. Ans ( A ) ⎪
⎪
⎪
⎪
⎪
⎪

P(x = 4t2 + 3, y = 8t3 – 1)

⎪
⎪ 3π
⎪
⎩
⎪ 1 x ∈ (2nπ + 2
, 2nπ + 2π) n ∈ I + ∪ {0}
let Q(4t12 + 3, 8t13 – 1) ƒ(x) is discontinuous at all positive odd integral
dy
at P , =
dy/dt
= = 3t
24t2 multiple of π
dx dx/dt 8t 2
∴ tangent at P is y – 8t3 + 1 = 3t (x – 4t2 – 3) ƒ(x) is continuous at integral multiple of π
Q will satisfy it 6. Ans ( A,B )
∴ 8t13 – 8t3 = 3t (4t12 – 4t2) x2 + x + 2
2
x2 + x + 2
( ) − (a − 3) ( ) + (a − 4) = 0
8(t1 – t)(t12 + t1t + t2) = 3t. 4(t1 – t) (t1 + t) x2 + x + 1 x2 + x + 1
x2 + x + 2 1 7
2(t12 + t1t + t2) = 3t(t1 + t) y= =1+ ∈ ( 1, ]
2
x +x+1 2
x +x+1 3
2t12 + 2t1t + 2t2 = 3t t1 + 3t2
y2 – (a – 3) y + (a – 4) = 0
2t12 – t1t – t2 = 0
⇒ (y2+3y – 4) – a (y – 1) = 0
(t1 – t) (2t1 + t) = 0 7
t ⇒ (y – 1) (y + 4 – a) = 0 ⇒ 1 < a – 4 <
t1 = − 3
2 19
∴ Q (t2 + 3, – t3 – 1) a ∈ (5, ]
3

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7. Ans ( A,D ) 9. Ans ( D )
2 81
(P) 81sin x + 2
= 30
81sin x
2
Let 81sin x =t
81
t+ = 30
t
t = 27 or t = 3
2
81sin x = 27
2 2
34sin x = 33 & 34sin x = 31
x , 0⩽x<1 √3
⎧
⎪
⎪
⎪
sin x = & sin x = 1
⎪
⎪ 2 2
⎪
⎪
⎪ 1
, 1⩽x<2 π π
⎪
⎪ 2 x= or x =
f (x) = ⎨ 3 6
⎪
⎪
⎪
x−2 , 2⩽x<3 (Q) x + 1 = 3 and y + 2 = 3
⎪
⎪
⎪
⎪
⎪
⎪ 1 x = 2 and y = 1
⎩
⎪
2
, 3⩽x<4
x+y=3
PART-3 : MATHEMATICS
(R) 2 × 2 × 3 = min value
SECTION-I (iii)
min. value = 12
8. Ans ( D )
7 (S) (1 – α ) (1 – β ) = 1 + (sin θ + cos θ )
(P) 2ℓn (2x − 5) = ℓn (2 (2x − ))
2
∴ maximum value = 1 + √2
Let 2x = t
t2 – 12t + 32 = 0 ⇒ t = 4 or t = 8
10. Ans ( C )
∴ x = 2 (rejected) or x = 3 a (cos 3x) + (1 − cos 2x)
(P) lim =1
x→0 x + sin x + cos x
(Q) Take log both sides to base '10'
5x
log10 x (log10 ( ) − 1) = 0
lim a (cos 3x) + (1 − cos 2x) = lim x + sin x + cos x
2 x→0 a→0

x = 1 or x = 4 (Q) ƒ(x) = (a – 7) log3x + (b – 2)ex + sinx for

Hence, sum = 5 function to be bounded a = 7; b = 2
(R) α = 2log2(log35) = log3 5 (R) ƒ(x) = x2 + px + 10; for ƒ(x) to be even p = 0
β α = 9 ⇒ β log3 5 = 9
1 α2 1 α α 1 log3 5 1 − cos(1 − cos x) m
(β ) = (β ) = (9)
5 5 5 lim = then m + n = 9
x→0 x4 n
1 log3 9 25
= (5) = =5 (S) Point is are x = 2,3
3 5
(S) √
6 + √6 + √6+. . . ∞ = 3

log 3 (3) = (2)

√

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11. Ans ( B ) PART-3 : MATHEMATICS
tn( π2 +h)
( e − 1) SECTION-II
π
(P) f ( + h) = lim = −1 1. Ans ( 6 )
2 h→0 tn( π2 +h)
( e + 1)
∵ (x, 1), (y, 2), (z, 1), (2, 3) ∈ A×B
tn( π2 −h)
π e −1
f( − h) = lim =1
2 h→0 tn( π2 −h) ⇒ A = {x, y, z, 2}
( e + 1)
B = {1, 2, 3}
Jump = 2
Number of onto map = 4C2.3! = 36
2. Ans ( 6 )
(Q) lim
x→∞
P(x) → ∞ and lim P(x) → ∞ .
x→(−∞)

P(0) = – 1 and P(x) is even this P(1) = P( – 1) = 1

π & P(2) = P( – 2) = – 1.
⎧
⎪
x ; 0<x< 4
⎪
⎪
⎪
⎪
Hence, from IVT minimum no. of zeroes are 6.
(R) f (x) = ⎨ b ; x=0
⎪
⎪
⎪
⎪
⎩
⎪
sin x ; − π4 < x < 0 3. Ans ( 4 )
Required limit is
ƒ(0) = ƒ(0 + h) = ƒ(0 – h) ⇒ b = 0
d −1 ∣
(h (x))∣
π dx ∣
x=1
⎧
⎪
x ; 0⩽x< 4
f (x) = ⎨
⎩ π
∵ ƒ – 1(x) = x – 1; g – 1(x) = x3 + x + 1
⎪
sin x ; − 4
<x<0

Also h(x) = g(ƒ(x))

ƒ'(0+) = ƒ'(0 – ) = 1
–1 –1 –1 3
⇒ h (x) = ƒ (g (x)) = x + x
1 − cos 9x 81
(S) ℓ= =
⇒
d −1
(h (x)) = 3x2 + 1
(ex − 1) 2 2
dx

ℓ
[ ] = [4.5] = 4
9

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4. Ans ( 2 )
∞ ∞
1 k
∑ ∑

n=1
2n k=1 2k

1 2 3
S= + + +. . . .
2 22 23

S 1 2 1 1 1
= + +. . . . = + + +. . . . .
2 22 23 2 22 23

S
=1⇒S=2
2
∞
1 1 1
2∑ = 2 ( + 2 +. . . . . .) = 2
n=1
2n 2 2

5. Ans ( 9 )

6. Ans ( 6 )
ƒ(x + y) = ƒ(x) + ƒ(y) + x2y + xy2
f (x) + f (h) + x2 h + xh2 − f (x)
f' (x) = lim
h→0 h
f (h)
= x2 + lim
h→0 h

ƒ'(x) = x2 + 2
x3
f (x) = + 2x + c
3

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