EAPS 375 Midterm 2 Study Guide Notes
EAPS 375 Midterm 2 Study Guide Notes
CI numbers include both direct emissions plus land use and other indirect
effects
• Brazil: world leading producer of sugarcane
o Advanced industrial agriculture tech
o Large amount of arable land
o Tropical climate
o Ratooning
o Sugarcane: quite bulky and sugars do not preserve well so sugarcane is typically
moved no more than 40 km to mill
o Planting, fertilizer, chemicalsà harvest/transportà dryingà mash (thermal and
electrical inputs)à fermentationà distiller grains
o Corn stover: trash that remains after harvest t make ethanol
§ Risk of soil degradation if organic material is not returned to field
o 13 billion bussels of corn produced in US
o 27% ethanol + 10% DDGS, 33% livestock feed, 11% human consumption (high
fructose corn syrup, starch, beverages, cereals)
o 1 tonne of corn à 378 I of EtOH and 309 kg DDGS (Dry Distiller Grains with
Solubleà high protein feed that is primarily fed to cattle)
• US Ethanol used as Oxygenate:
o Gasoline needs high octane fuel oxygenates prevent engine knock
o Options include:
§ Tetraethyl lead: banned 1996
§ MTBE Methyl tert-butyl ether
• Soluble in water, groundwater
• Does not readily biodegrade
• Tastes bad in very small concentrations in water
• Mostly banned in US for gasoline (used in Asia)
• Alternatives to corn for ethanol.
o Starch and sugar-based feedstocks:
§ Millet/sorghum:
• High starch
• Grow on marginal land,
• Lower inputs necessary
• GHG reduction (>70%)
§ Cellulosic feedstocks: nonfood based
• High yield + biological carbon sequestration
• Marginal land usage
• EROI up to 30+
§ Switchgrass:
• Marginal land usage
• EROI up to 20
• Biodiesel:
o Regular petroleum diesel (C9-C25 hydrocarbons)
o Biodiesel: fatty acid esters
§ Advantages:
• Works in existing diesel engines
• Solvent properties
• Almost no Sulphur
• Better lubricating properties
• Higher cetane: measure of ignition and combustion quality (50 to
60)
o Ignites more quickly
o High cetane number the less time it takes
o Derives from hydrocarbon n-hexadecane
o High ease of ignition and assigned value of 100
o Depends on density, viscosity, surface tension, time for
fuel to vaporize and mix with air, molecular structure
§ Feedstocks:
• Virgin oils, waste food oils, sewage sludge, second generation
biofuels
• Canola, sunflower, hemp, palm, soya bean
o Food vs. fuel:
§ Price of food, expensive due to increase in biofuels
§ Food prices going up because of energy costs, drought, more varied diets
in many countries with rising wealth
o Direct conversion of CO2 (hydrocarbon):
o Current economy: takeà makeà dispose
§ Crude oil (distillationà aviation fuel (combustion)à CO2+H2Oà
CO2 emission (CO2 capture and storage)
o Circular economy (direct air capture)
§ Hydrogenation, combustion, CO2 capture
• Petroleum pricing:
o Sale of gasoline and diesel
§ Cost of gasoline derived from:
• Crude oil cost
• Refining costs and profits
• Refining costs and profits
• Distribution and marketing costs and profits
• Taxes
§ Gas stations make profits of 2% or less (2-4 cents per gallons sold)
§ 1 gasoline gallon equivalent= 114,000 Btu by defining
§ 1 diesel gallon equivalent= 1.136 GGE
o Mileage standards: corporate Average Fuel Economy Café
§ Average fuel economy during Obama era: 37.4 mpg
§ Proposed trump rule: 29.5 mpg
o Extensive deforestation
• Charcoal:
o Rich people used it for heating, cooking
o smelting important reason for deforestation
o coppiced wood: cut trees at low level: grow back
• sources of energy:
o estimates proportion of energy sources
o proportions of energy mix since 1800
• pre-industrial prime mover energy sources:
o human, animals, wind, water (motive movers)
o waterwheels, windmills, human labor, steam engineers, water turbines, steam
turbines, horses, cattle, people
• Changes in energy mix:
• Global primary energy demands past and future:
o Fossil fuels hit peak in 2030 and then decline
o Renewables increase by 14% in 2030
• Growth in use of coal:
o Prior to late 1700s
o Jet (gemstone)
o China (early mining), Fushun mine, Marco Polo
o Make cokeà iron production
o Mining for surface exposure
o Used in place of wood for heating industry
• Growth of coal in UK
o Wood running out, surface exposures exhauster, deeper mines led to water
flooding
o Waterà pumping is expensive and complicated
• Industrial revolution:
o First steam engine:
§ Boiler steam pushes piston upà boiler valve closes, water valve opensà
water cools pistonà steam condensesà pressure dropsà air pressure
pushes piston back
§ Yields 3750 watts, 5 hp
§ Heavy inefficiency, placed near mines
§ Long application, less complicated
§ Deficiencies:
• Cylinder cools and must be reheated, energy lost
• Only proves pull on condensation stroke
§ Improvements:
• Separate condenser and steam jacket
• Better cylinders for improved machining
• Sun and planet gear, converted reciprocating to circular motion
• Double acting engine
o Much more efficient, less coal, cheaper
o Large and immobile
o Power limited by low pressures
§ Watt engine:
• Much more efficient
• Took royalty of 1/3 of value of coal saved over Newcomen engine
• Watt First system with condenser in 1776 cycled by:
o Drawing steam into cylinder beneath pistonà piston
moves upà piston travel steam valve closes, and
condenser valve opensà pressurized steam, in cylinder is
drawn into cold considerà water
o Atmospheric pressure pushes cylinder back down
o Bottom of piston travel steam valve opens and condenser
valve shuts, pressurized steam moves into piston cylinder
that is hot
o Constructed 496 engines, 11,200 total hp and fraction of
120,000 hp from water wheels and 24,000 from
Newcomen engines
• Growth of steam power:
o After 1800: metal machining improves
o Better cylinders and stronger boilersà higher pressures
§ High pressures allowed for increased power within smaller engine
§ Allowed for transportation
o Made much smaller for same power
o Smallerà cheaper, did not need as much water, and could run faster
o 1850: Corliss engine: improved efficiency and powerà more controlled and
faster speeds
§ Textile manufacturing and steel rolling
o Steam did allow for movement of power but wind and water still important
o Largest steam engines were limited and cannot compete with internal
combustion engines (poor mass, power ratios)
• Societal implications of steam power
o Steel rails, railways, freed from rivers
o Move more freight by water
o Centralization of industry
• Use of coal:
o Population in UK 1907: 40,000,000
o Over 1 million employed in coal industry in UK
o 250 million tonnes produced in UK in 1900
• Problems with steam engines:
o Not much Powerful, efficient, power dense, clean
o Improvements continued over time period from 100 kW to 3 MW
o Efficiency improved by 2.5 to 25%
o Turbines and combustion engines became less practical with development of
electricidal motorsà inefficient because less efficient, piston moves back and
forth, and power provided only when being pushed by steam, so momentum is
lost
§ Rotary motion needed, requires lot of extra machinery and friction to
turn the reciprocating motion into rotary motion
• Steam turbines:
o Powered by steam, gas, water
o Generation of electrical power
o Coal (38.5%) globally in 2018 for electrical power
o Largest power turbine: 700 MW, 1.9 GW Arabelle systems (nuclear)
o Operation:
§ Higher pressures and temperatures
§ Steam enthalpy larger, more energy generated
§ Higher pressure and tempà higher efficiency
§ Supercritical H20: 374 °C, 218 atm (3200 psi)
§ Efficiency: actual work output/ net fuel energy input
• Cogeneration to improve efficiency
o Combined heat and power (CHP)
o Generate electrical
o Use remaining heat for heating, chilling
o Reduces energy inputs by 35%
o Losses for 100 GJ of fuel energyà 10 GJ
• Gas turbines:
o Compressor
o Combustion system: T>2000 F
o Turbines run compressor
o High Tà higher efficiency
o Attempts to 2600 F, material issues and cooling problems
• Improving efficiency for CCP
o Exhaust fluids still hot
o Don’t waste heat energy in exhaust
o Gas turbine exhaust makes steam to run steam engine
o Both generate power, efficiency approaching 60%
o Bottoming cycle:
§ Use residual heat
§ District heating, greenhouses
§ Cogeneration reach 95%
• Coal fired power generation:
o Fuel preparation
o Crushed coal
o Pulverized coal, burns hot like gas
• Efficiencies in power generation:
o Heat rate: amount of heat produced by fuel per amount of electricity produced
o US total: 756 MMst
o Exports from US: 116 MMst
o Powder river basin 16 mines: 43%
§ Lower Sulphur content
§ Costly to transport
• Average cost of coal: 2017: $32
• Average cost of shipping: $20
o Most of coal exports are metallurgical coal: 60%
o 40% for thermal or steam coal for power generation
• Moving coal:
o Trains (70%), trucks, water, other
o Conveyor systems, coal slurry pipelines
o Coal barge on Ohio river and coal ship in Great lakes
• Stranded resources
o Carbon bubble and unburnable carbon
o Limit of CO2 in atmosphere to remain at 2 °C
o Valuations of companies depend on this resource that may never be recovered
o Bubble arises because combined proven oil, gas, and coal reserves on books of
fossil fuels companies will produce far more than this amount of CO2 when
consumed
• Diversion on electrical power
o Most coal used for electrical generation
• Electrical grid:
o Faraday discovered electromagnetic induction
o Relationship between magnetism and electricity
o Current produced from motion of conducting loop through magnetic field
o In generator, wire coils rotate through magnetic fields produced by permanent
or electromagnets
o Cannot fully understand how coal is used without understanding what mainly
used forà electrical generation
o 38.5% produced by thermal coal fired power plants
• DC vs. AC:
o direct current, alternating current
o frequency:
§ NA: 60 Hz=frequency
§ Europe: 50 Hz=frequency
o AC: can easily step up to higher voltage
§ Lower resistive losses
§ Not effective for long transmission
§ Higher losses: 250 km for AC
§ Break even $$ 600 km
§ Interconnects easier for DC
§ Fewer wires required
§ Semiconductor transformers allow boosting to HVDC
o DC: high losses, limited transmission, need many powers plants
• Electrical grid components:
o Generation, transmission, distribution
• Distribution of energy sources for generation:
o Coal, gas, nuclear, hydro, wind, solar, geothermal, biomass
o US coal consumption decreased since 2008 (natural gas increasing)
o 75% of US decrease of CO2 in last decade
• Electricity and economy:
o Electricity usage appears to be good indicator of real time indicator of economic
activity
• Footprint of bitcoin:
o Annual usage equal to 204 TWh, power use of Thailand
o Releases 114 Mt CO2 (emission of Czech Republic)
o 1 bitcoin transaction: 2,800,000 VISA transactions
o US data center consumption is greater than all of UK
o Information and communications in US> 2% CO2 emissions
o Will require 20.9% projected electricity demand by 2030
• Formation of coal:
o Most coal formed from conversion of woody materials by heat and pressure
o Starts in water saturated bogs, anoxic conditions
o Volatiles (Water, methane), carbon richer
o Rank= measure of quality of coal (carbon content)
o Coal in sedimentary basins
o Most coal formed during carboniferous period
o Surface mining: produces 100 Mmst per year thermal coal
o Underground mining: produces 14.5 MMst/year
o Global coal reserves:
§ World recoverable reserves:
• 1.1 trillion short tons, 1 trillion tce
• USA global reserve: 22%
• Russia: 15%
• Australia, China, India
§ Comparing coal reserves to other sources of energy:
• 47.4% reserves
• 79.8% resources
• 16.9 billion tonnes energy produced
• Global coal consumption (2018): 3772 Mtoe
• Global decline in coal consumption, except for Asia Pacific
countries
• China consumes 50.5% of global total, India 12%, USA 8.4% (top 3)
• Japan shut down nuclear plants, coal may increase
• India consumption grew by 8.7% in 2018
§ Global coal movements:
• Australia (250 Mtoe), Indonesia (220 Mtoe), Russia (136 Mtoe),
USA (66 Mtoe)
o Global coal usage for electricity generation:
§ 60% electricity
§ Steel 20%
§ Cement 4%
o Coal responsible for 45% of global emissions
o Carbon capture technology:
§ Cab trap and store carbon emissions
• Power plant emissions injected into absorber
• Solvent collects CO2
• Heat is used to separate solve from CO2
• CO2 stores beneath North Sea