GOC

CLASS 11 - CHEMISTRY

1 The IUPAC name of the compound is: [1]

CH 3−C ¿ OCH 3
H−C ¿∨¿ −CO ¿ CH H −CH 2 CH 3 ¿
3

2 The IUPAC name of the compound is: [1]

3 The IUPAC name of the compound is: [1]

CH 3 CH 2 CH 2 C¿ OCH2 CH3
HCH 3

4 The IUPAC name of the compound is: [1]

H 3 C−C¿ H 5 C2 O
H −C¿∨¿ −C
O ¿ OCH H −CH 3 ¿
3

5 Give IUPAC name/structure of: [1]

1. (CH ​3 ) ​2 (C ​2 H ​5 ) C - (CH ​2 ) ​3 - (CH ​3 ) ​3

2. Ortho - chloro anisole

6 Which of the following represents the correct IUPAC name for the compounds [2]
concerned?

1. 2, 2 - Dimethylpentane or 2 - Dimethylpentane

2. 2, 4, 7 - Trimethyloctane or 2, 5, 7 - Trimethyloctane

3. 2 - Chloro - 4 - methylpentane or 4 - Chloro - 2 - methylpentane

4. But - 3 - yn - 1 - ol or But - 4 - ol - 1 - yne.

7 Write IUPAC name of the following: [2]

1.
 2.

3.

4.

8 Identify the functional groups in the following compounds: [2]

1.

2.

3.

9 Write the IUPAC nameof the compound from its given structure. [2]

10 Give the IUPAC name of the following compound [2]

11 What is the cause of geometrical isomerism in alkenes? [1]

12 Write all structural isomers of molecular formula C ​3 H ​6 O [2]
13 Draw structure of all isomeric alcohols having molecular formula C ​5 H ​12 O. [2]
14 An alkane has a molecular mass of 72. Draw all its possible chain isomers and [2]
write their IUPAC names.
15 Explain why the name butanol is not specific whereas the name butanone [2]
represents a specific compound?
16 Identify the pairs of compounds that represent position isomerism. [2]
CH ​3 —C(CH ​3 ) (OH) - CH ​3

CH ​3 —CH(CH ​3 )—CH ​2 —OH

 CH ​3 —O—CH ​2 —CH ​2 —CH ​3

CH ​3 —O — CH(CH ​3 )—CH ​3

CH ​3 - CH ​2 - CH ​2 - CH ​2 - OH

CH ​3 —CH ​2 —CH(OH)—CH ​3

17 Why is benzylic free radical more stable than allylic free radical? [1]
18 Identify the reagents shown in bold in the following equations as nucleophiles [1]
or electrophiles
−¿+ H2 O ¿

1. CH 3 COOH + HO−¿→ CH COO 3 ¿

2. CH 3 COOH 3 +CN → ( CH 3 )2 C ( CN )( OH )

3. C 6 H 6 +CH 3 CO →C 6 H 5 COCH 3

19 Draw the orbital diagram showing hyperconjugation in ethyl cations. [1]

20 Identify electrophilic centre in the following: CH ​3 CH=O, CH ​3 CN, CH ​3 I [1]
22 Arrange the following compounds in increasing order of acidity [2]
1. CH ​3 CH (Br) CH ​2 COOH

2. CH ​3 CH2CH (Br) COOH

3. CH ​3 CH2C (Br) ​2 COOH

4. CH ​2 BrCH ​2 CH ​2 COOH

23 [2]
Explain why is more stable than and is the least
stable cation.
24 Hyperconjugation involves delocalisation of ___________. [2]
1. electrons of carbon - hydrogen σ bond of an alkyl group directly
attached to an atom of unsaturated system.

2. electrons of carbon - hydrogen σ bond of alkyl group directly attached

to the positively charged carbon atom.

3. π - electrons of carbon - carbon bond

4. lone pair of electrons

25 Arrange the following carbocation in increasing order of their stability. [2]

+ ¿H 3 ¿
+¿ ,C ¿
( CH 3 )3 C
26 Identify the most stable species in the following set of ions giving reasons [2]
+ ¿ Br ¿
3
+¿ HB r ,C ¿

1.
+¿ H 2 Br ,C 2
¿
+¿ H3 , C ¿
C
−¿C I ¿
3
−¿ HC I C ¿

2.
−¿ H 2 CI , C 2
¿
−¿ H 3 ,C ¿
C

27 Explain hyperconjugation effect. How does hyperconjugation effect explain the [3]
stability of alkenes?
28 Arrange the following: [3]

1.
in order of increasing stability.
+¿ ¿
+¿ ,C H =CHCH ¿
+¿ , (C H 3 )3 C 2 2
¿
+¿,C 6 H 5 CH 2 ¿
2. C H 3 CH 2
in order of decreasing stability.

HC=C , CH ​2 = CH −¿¿ ​ , (CH ​3 ) ​2 CH −¿¿ ​ ​

−¿ ¿
−¿ ¿ −¿ ,CH ¿ −¿¿
3. ​ , CH 3 CH 2 ​ , C 6 H 5 CH 2
3

in order of increasing stability.

29 Giving justification, categorise the following molecules/ions as nucleophile or [3]

electrophile:

HS −¿¿ ​ ​ ​ −¿¿ ​ ​
​ , BF 3 , C 2 H 5 O ​ , (CH 3 ) 3 N:,

30 Which of the two structures CH ​3 COOH and CH ​3 COO −¿¿

​ is more stabilized by [3]
resonance? Explain.
31 What are electrophiles and nucleophiles? Explain with examples. [3]