Carnot Cycle and Heat Engine Notes
Heat Engine
A heat engine is a device that converts heat energy into mechanical work by undergoing a cyclic
process. It operates between two thermal reservoirs:
1. Hot Reservoir (source): Supplies heat at a high temperature T_H.
2. Cold Reservoir (sink): Absorbs residual heat at a lower temperature T_C.
Key Components of a Heat Engine:
1. Working Substance: A fluid or gas undergoing cyclic transformations.
2. Heat Source: Provides thermal energy.
3. Heat Sink: Receives unused heat.
4. Piston/Cylinder: Converts thermal energy into mechanical work.
Efficiency of a Heat Engine:
The efficiency (eta) is given by:
eta = W/Q_H = (Q_H - Q_C) / Q_H = 1 - Q_C/Q_H
Carnot Cycle
The Carnot Cycle is an idealized thermodynamic cycle proposed by Sadi Carnot. It represents the
most efficient cycle for a heat engine operating between two temperatures T_H and T_C.
Stages of the Carnot Cycle:
1. Isothermal Expansion (A to B): The gas expands at T_H, absorbing heat Q_H.
2. Adiabatic Expansion (B to C): The gas expands without heat exchange, and temperature drops to
T_C.
3. Isothermal Compression (C to D): The gas is compressed at T_C, rejecting heat Q_C.
4. Adiabatic Compression (D to A): The gas is compressed without heat exchange, and temperature
rises to T_H.
Efficiency of the Carnot Cycle:
The efficiency is given by:
eta = 1 - T_C/T_H
Derivation of Carnot Cycle Efficiency
1. Work Done in an Isothermal Process:
During isothermal expansion and compression:
W_AB = Q_H = nRT_H ln(V_B/V_A)
W_CD = Q_C = nRT_C ln(V_D/V_C)
2. Relationship Between Adiabatic Processes:
T_H * V_B^(gamma-1) = T_C * V_C^(gamma-1)
T_C * V_D^(gamma-1) = T_H * V_A^(gamma-1)
3. Net Work Done:
W_net = Q_H - Q_C
Substitute Q_H and Q_C:
W_net = nRT_H ln(V_B/V_A) - nRT_C ln(V_D/V_C)
4. Efficiency of Carnot Cycle:
Efficiency eta = W_net/Q_H = (Q_H - Q_C)/Q_H = 1 - Q_C/Q_H
Since Q_C/Q_H = T_C/T_H:
eta = 1 - T_C/T_H