L iCnemican Kinetics] 2s.* - Inside the Chapter... <0 aR se We 422 43.1 HERE HH ite | | | 44 aaroferd ar aR 4.4.1 Ter wae ah anfairart $4.2 Wem Bite a) abies 443 BH HH He BH afar 45 Tarabre oifutereaat or taze frie 4.6 oiftiimen a a aR Pie 46.1 HTT Hat BE TTA 47 WRT TT TH 48 AA AGS TET UE TH fart carter sition & Gn gin ay st wares re 2 eH Fo wer fra atm F) Sten 2 ei dere at eames gro Seif fai sh wot, (aG = 46) WY cere sifsitean a Taaisit, see ana orgem aes asd wr ar an, sais aor a Healt a ant areal at sod & fed cues opie ar feo arer #1 oo 35 ified fame 8 at og 3 8, sg 6h ay oF ciate at orci ate an Mi ores oe a aera 9 om fifa sr then &, arafine 3, grten Oo am ao gh wets ah oe are, ifr frees Seg cote ot # gem BL ee ator eso} Pe ey a © 7 sifefrard (Slow Reactions) (Ay reenter ar ara ((nstantaneous or fonie Reactions) © Fatiteat Rea o7 ga ate en & & se os ARS ant ees oT Be 8, aroma aAGeNt ayant &| © arate afar’, orem a ¥ HCL NaOH > NeClL+H,0 NaCl, + ABNO 46) > ARC, + NINO, Gat ‘Wary Slow Reactions) © syst ea SF ara oPeaaT a anerRtw afer, (molecular reactions) ua 8) & sittin aA nit eH ett 81 ea qe athens! 8 oP eo we eth ag AR TE aT A GH alg ees (observable) T area Gitnis ad dat & ‘Bere fre herder we, wee eet, a2 BF were graftsftfirad 2m) ®) seer @ tafew oe gen ere testeta at afte CHsCOOH + C:H,0H > CH.COOC.A. + 1.0 Gi) Meg WewTEs wT HTEET 2:02 + 2H.0 + O: Gi) TERT Aee-siteMEs a oT 2NO; + 4NO; +O: ee site a aT a on een 81 © Tarahre aemfrat offre rare st ag ere & fore afbhrarsit & ae at ame, aaa arco at fates srerit Harr a, erat far fafird & wore 8 agent fret arn fara ara 1 © oaftfaran S- sent err feat where ot ae at ren Ee afters a carat ation om in ae HY arn: after an st wae A ene fen on eae e— @ frat ww airerer at aren # ah & an TAL 6 frst ge seme st arem # afer a arith sfitien R —> P#) “al R Sif we Aer sie P scag tl et her BER Rot ere eat aa Rataen dt FE car Pat area Hate ‘ats a ore set cst = caffe = araraieg sfefioen a1 a she der, eating 2 te metre iff tn 35 we Horan frat sen | vel Co Pre ae} wel earerew A ArEMT A oh ai oe @) Are wa S ear sere A aaa A ate By weft we 8) afi R —> PH af «oh aaa we fice oh see Bh ATT (R|, SF Ph FH Ry Te (PLA a ae =n A [errata eH] ALPI=UP12 Ph om: star Nal o tam ar iy errs ctw i we ses |] soem a a A & fea fea om th ‘afer fern a3 Cm) ote Cea) fara oaftraree ote ze atta Anh eaten rer G1 ste an wt Yow eer tr ya > om faa 4.1 (= ) afr & wal Y erga ate ara A aa stem afsting 35 oz orate a7 st cata wart) ' 3 few fea 44 (Ce ) sag & ae A aren aire way Fa siee safefina an sit anata ay aA cata ra 81 © feet iret am afafra o orafeen a1 saat anefirs am secre @1rerabrar a viet foe Ar orm ane a Pe stra Aer Se ra ares (a0 Bw we Es ah oie ewe, ste am aT Starr am aa ara Bi fe atfraner ot gone at rier wha aH AC site feria 2 em ar re a aca at stan a 4 seae = ara a, sete ep = Limit aro ar amet ay = 3 vred a ora yee or te de Bait eT sea a rrr yes ree afew HH ivefiar Ah r,., BRI aT ach #1 ea: xe ‘i creer 2 at wan ote ure & Me hy TA aT A aera Bowie wa E | sora a aren a er etree fire em ott faite erm & aia fg qe ahh ng eat BT bre, oR a ares bor a ea oar & fen aa Cm) ste (a) # atfirerea (Ry athe sa (P) & a & shen site metre on can Tae see erates safitiera 9 a fine x shire sree sear ce sree are ara sion a sree a am femme Fe forgae srrrre & fis otic at astern aight 1a 8 sae & fo sifitfieer A— Be wal, a3 stir =—SA1_. , A) after A328 fi At irqe tt arty -- SAL Divers aif are fared are A A eet fine ae & at thm Bd thereto & sri BA aT A faepe ah ar teen 1 a ai ah ger aA fer, ap] ic Pee afb 2M, > Hyg thy, 2a aa ssf Ny +3Hay) > 2NE, ee srry athe fare A +n,Bm,C+m,D LAA 1 8} wan a cafe item Soi st ern act th Lala 1 aby 1 aiey aoat Ta, atm, at eat rer offer 3 Brig) + BOR ag) +6H fog) > SBP a9) +31730(0) 5 fert 1 apy ‘At * _ yb 3 v = Mey 1 AW30} 3 3a ata aaa N+ 9 22 & fa Pa AY at BH 10% mor! Ls arat 7g 1 (oY % far art at a Gi) 2% WH a AE aA =wie? = 26 103 moll? st Wa42 afer a+ 2B 5 30% fra fart ana ce WF BT TT 107 mol Cs Br a sat aT A A athe Be fage af at x aa aif WET A+ 2B eee IC A certo grt ai) _ tater we 3 de me fe got @ 2a ygHAL 1a) 1 ge 490) Lio “st ya 3 so 833-107 mol Ls! 1 aby Lae) ty 2 SSB), 1a) 1h 0 ate Pa "Fa “F SBI 210°? = 0652107 a qe pel 10) = 6.6 « 10° mol L's? srefere 21 (Initial Rate) or =o mR Pet afer a wears am aeorm 81 t areet ow faa s2-1-0 5 one onPiaficar om 1 oof eer Td are a da ma aw at or ah oe art Mae TEM ows wh ARS AW aIETT PI 2 Rg Aw 1-08) am fog oe aH ne eet te By ae wr GaP ar Ae 21 ‘204 organi fiver Frm (Law of Mass Action) # rier TE ‘Pian on fret afer a ae, ced am St are fier re abe ees te APRN) Sse Te em Ss after 2A +o; B> mes m0 fet an (Arie? ; val [aL ott By safe x ae y waht gas a, att nea sh a aed #1 at ae re tom t Pe sara x ae y ae seh gra Fea fe ont Bi oh ny at 0,3 Ra at ae r= KAP BP o ~ MAL par a Ss x1arey i) sre emer (ii) wh arse Ar aia (Differemtial Rate Equation) 81 ren € 1K targa feat &, it Se ‘feerafay (Rute Constant) Rem & i ais Gs wise aT ay fram ore #1 ate B=) at cu = oe: am feria ag afitica ang wai gaa: SRR St Azar sare oF mol LB Safes at fe chee ond 9 8 Senge tare) ernamA f= he ait dec a LL 5 15 rE ar fate st yard were afar nA Br 2NO. [4a AFA 200 + OQ, > 20, fie 7A A 4 Bae wr wre 9 tt card fara) suf 8 oPiien a de WE TET eo oF ad 8 ag ofteds at em ga wate gear 41 o adhe A TaRGft A stra ep wat a 2 ord) 2, fred after or aw AB da ofa 3 eh ah 8 oom care sitien a ant Raia ar aa @, PRAY afer a BT sal wa a BL aeicen Be Fare, TR WT ATE OY Te HH TaHeaEA ¥ them 3 da 1 |» CH,COOH + C,H,OH Sees Be Berke get her A rer ait B= vere a) soRel & Sifier ét ttm gal Soha afera A wag or aaex fra aftr & aah aifiareat wt ate sore ore ae a ea afiineng oer 7 9 1 Prraieh aru an an she wRemee e E B garaged ata 2 aie: ate oiProrely at eaMT aT AB we A feat orn & Pred gel cae oT avs ATE er covey, aPRflar aor of) aoRear ar Bt wa dt sepf® (Nature of Medion) eo a aera oh mat arate om gira eat 2 a pat affirm ya Rare A ers se, ofan Ir aif Sin #, aA ays frarwe A aT a tl gaa Rare 4 stares sre 8 sath %, Bee ret Bea stant ek oe ae oPitren it a Ss ee 8) ‘afte wera © ae after teh ah & Rew aa a een B ey teh afipaist ar tn fds fete ter oh onferit a warn on warm + 9 Tere, Se Cly BAT ANA BT ae ag farm & seq gore Ft satiate A orftenreas fat ier RA ar orantoer ax SO &, few otra cay 8 Ar Bore 8 ie Prez ee fer eh #1 Hy+ Ch, Bh 2HCT iit satire ea 8? 82. Ue fin Aw HOB ae aero Fes am KIA] pe aff a fre meee a afin ae #? sarafierm site ae ea 8? 3. sfufiear 20+ Bs 40 10 Sfewe FC TRA 210 mol LG at I CH AAA ae LA fags HR at tame Soa. RP este t rer 30 Fe 0.5 mol 28 ee 0.2 mol LA HEB a sromn fare oft fms eae T TL a5, stra Se 8 chen pre pf eT aT BP ia! 3.5. Affine Nay) Sly > 2NH erence aia.47. 38. 39. \3.1 [s2: Is. [5 lz.s. [s6. 57. yar wr @ feet oftrnren a zene a Ber area Fl Sr aioe a sea; BEAT (inter-related) #1 fefae afutina On fad wed #2 area) safafarn a1 sit fatine safiataren a it genrdal feafeoret satire a ai mania ae are an re ae are Pee | ‘Raj, Board 2011) . ara A+B +208 Aa gaa TT mol Ls! etch eA wang 1? ge feat at sthfinar Br ad Fi AVHO+B @=KIAl ae affine aga UT siifirat, Ferst ore Asha et AC _Cat wae othe CR NR 1S ef a oe She 2103 mol Est ar 2 e = 10? mol L's" St AR] * a = -(0.2-0.5)mol - 30min 2 mol I? min* a a sites 0 ect = not 1° see! 60 ~~, L67 x 10 mol L's? atew fstinar'st aire oa at aan orem tata stew saftey 2a Pratfea ace @, Fre apa stro sot at rere ard # ores fia ari gg atts SAMBA Nog) + 3H) > INH gs FIR AN) 2a) ints) 3 dk & fart afvtinn wi an an sehr ache offreree aH [areata ret wien 13.9. A reer ft ae cafefarer aa Piz ae By TRA ERE (mol a, Pale ota on aT] te Te PARA NA +89 RATA AP) cepa AA cura a: Oh = mol cara ot fare ora wat sf fern on we ¥ a= afifiem sA+)R 9 FTE 7 =KIANBY mot L's"! (ar LaP nol Dy = (nolL)! (a) SRT FT TSA, (b) TT (oy TAH, (a) HATTER ACI ,{ Ald!) ar =2+ 10? mol L's? @ Pret ofatien a fay cia 4 soften aren gel & oriat ar at aftfaen a wife exert #1 eo 3ef ae oars Tar aravee: @ fee an fee ore ot % aren we fren om t1 0 aft ane sfeiaen fatten ge F tic & At aed vite ae 0 a frefm ge ater ti om: saffarn aif Ft fer van sfonfes fen sr ween ¢) fare offre a writes er Fraifes an Prater ag a an weiteor aera val & arial ar att sa safe at a weet Et 0 a sfitear nA + n.B > See et ar ween fe B— am = Kar By