Chemical equilibrium approaches from both
S
The chemical reactions which takes place in both Such equilibrium is established in physical reactions. forward & backward direction
directions are called reversible reactions It is dynamic in nature. Chemical equilibrium is dynamic in nature.
Equilibrium is the end state of a reversible reaction.
C
Gaseous Equilibrium is established only in a closed container.
I
Here vapour pressure is constant at a constant temp for given. For a general reversible reaction
At equilibrium, the rate of forward and backward aA + bB cC+ dD
reactions are equal.
S
[C] [D]
C d
At equilibrium, the concentration of reactants & Kc =
Established only at a constant temparature [A]a [B]b
products becomes constant.
Y
o
Ice-water equilibrium established at 0 C (at1atm)
At any time during the reaction aA+bB cc+dD
H
Established only in a Saturated solution the ratio [C]C [D]d is known as concentration quotient, Qc.
[A]a [B]b
eg: Saturated sugar solution.
P
Sugar (dissolved) Sugar (undissolved) At equilibrium Qc = Kc
Equilibrium
forward
product
H
equilibrium
Rate Here solubility depends upon pressure (Henry’s law)
Conc 1. Value of K does not depends upon initial concentration of
eg: Soda water reactants and products.
reactant
A
backward
CO (dissolved) CO (undissolved) 2. Value of K does not depends upon the direction from which
Time Time equilibrium is attained.
L L
Q. For the equilibrium A B, the variation of the rate of the forward (a) & Q. Which of the given statements does not elucidate the equilibrium state Q In the given reaction: A+2B 2C, 2 moles each of A & B present in 10 L
A
reverse (b) reaction with time is given by precisely? of solution combine to form 1 mole of C. Calculate Kc for the reaction.
(A) The equilibrium can be approached from either direction.
(B) The equilibrium can be attained only if the system is an isolated system. (A) 1.5 (B) 6.67 (C) 0.15 (D) 2.3
(C) The free energy change at constant pressure and temperature is zero.
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(D) It is dynamic in nature.
AIIMS
CHEMICAL EQUILIBRIUM
Applications of K & Q
• Value of K depends only on temperature.
According to Le-chatelier's principle, if a system at equilibrium is
• If K for the reaction aA + bB cC+dD is K, then subjected to a change in concentration, temperature or pressure,
K for the reaction cC+dD aA+ bB will be K1 If they are in solid or liquid phase(or aqueous), K can be represented as Kc. the equilibrium will shifts automatically in one direction which will
nullify the effect of the change.
If they are in gaseous phase, K can be represented as Kp
• If K for the reaction aA + bB cC+dD is K, then
For a general reaction 1. Conc. of reactant increases shift towards forward reaction.
K for the reaction naA+ nbB ncC + ndD will be (K)n
aA + bB cC + dD 2. Conc. of product decreases shift towards forward reaction.
• During the addition of two reactions having equilibrium [C] [D] PCc PDd 3. Conc. of reactant decreases shift towards backward reaction.
constants K & K2, then the net Constant K = K x K Kc =
C d
& Kp =
[A]a [B]b PAa PBb 4. Conc. of product increases shift towards backward reaction.
• During the subtraction of a reaction having constant K from a 5. Pressure increases shift towards lesser number of gaseous moles
reaction having constant K , then the net constant K = K /K Kp = Kc (RT) n g ng = np - nR 6. Pressure decreases shift towards higher number of gaseous moles
• If Q<K, the reaction will proceed in forward direction 7. No. of gaseous moles of reactants & products are equal, pressure has no effect.
• If Q>K, the reaction will proceed in backward direction Unit of Kc = (mol/L)
ng 8. If temperature increases shift towards endothermic
9. If temperature decreases shift towards exothermic
• If Q=K, the system is in equilibrium. Unit of Kp = (atm)
ng
10. Catalyst helps to attain eqm state easily.
• If K >103, the reaction is almost complete in forward direction. If ng= 0, equilibrium constant has no unit After the establishment of eqm, catalyst has no effect.
• If K <10-3, the reaction is in backward direction. 11. Addition of inert gas at constant volume, no effect.
In heterogeneous equilibrium, concentration of pure solid &
• If K is in b/w 10³ & 10-3, almost same reaction takes place pure liquid is taken as one
12. Addition of inert gas at constant pressure
higher number of gaseous moles
shift towards
in both forward and backward direction
eg : CaCO3(s) CaO (s) + CO2 (g)
Kp = PCo 2
Q At a given temperature, the equilibrium constants for the reactions,
1 Q Which one of the following conditions will favour maximum formation
NO(g) + O2(g) NO2 (g) & 2NO2 (g) 2NO(g) +O 2 (g) Q of the product in the reaction A2(g)+ B2(g) X2(g) . rH = -XkJ/mol?
2
NEET 2018
are K1 and K2 respectively. If K1 is 4 x 10-3 . then K2 will be (A) Low temperature and high pressure (B) High temperature and high pressure
JEE 2020
JIPMER
(A) 8x10- 3 (B) 16x10- 3 (C) 6.25x104 (D) 6.25x106 (C) Low temperature and low pressure (D) High temperature and low pressure
