16 Practice Set-3

PRACTICE SET-3

1. The sulphate of a metal M contains 9.87% of M. This 8. Equal weights of methane and hydrogen are mixed in an
sulphate is isomorphous with ZnSO 4 .7H 2 O . The atomic empty container at 25C. The fraction of the total
weight of M is: pressure exerted by hydrogen is:
a. 40.3 b. 36.3 1 8 1 16
a. b. c. d.
c. 24.3 d. 11.3 2 9 9 17
2. 74.5 g of a metallic chloride contain 35.5 g of chlorine. 9. Ratio of masses of proton and electron is:
The equivalent weight of the metal is: a. Infinite b. 1.8 103
a. 19.5 b. 35.5 c. 1.8 d. None of these
c. 39.0 d. 78.0
10. Splitting of signals is caused by:
3. The packing efficiency of the two-dimensional square unit a. Proton b. Neutron
cell shown below is: c. Positron d. Electron

11. The number of moles of KMnO 4 that will needed to react

with 1 mole of sulphite ion in acidic solution is:
2 3
a. b.
5 5
l 4
a. 39.27% b. 68.02% c. d. 1
5
c. 74.05% d. 78.54%
4. A compound M p X q has cubic close packing (ccp) 12. The number of moles of KMnO 4 that will be needed to
react completely with 1 mole of ferrous oxalate in acidic
arrangement of X. its unit cell structure is shown below.
medium is:
The empirical formula of the compound is:
2 3 4
a. b. c. d. 1
5 5 5
M
X
13. The reaction, 12 H 2 (g)  AgCl(s) H  (aq)  Cl  (aq)  Ag(s)
occurs in which the galvanic cell.
a. Ag | AgCl(s) | KCl(Soln) | AgNO3 | Ag
b. Pt | H 2 (g) | HCl(soln) | AgNO3 (soln) | Ag
a. MX b. MX 2
c. Pt | H 2 (g) | HCl(soln) | AgCl(s)Ag
c. M 2 X d. M 5 X14
d. Pt / H 2 (g) | KCl(soln) | AgCl(s)Ag
5. Which of the following solutions has largest boiling
point? 14. When a lead storage battery is discharged
a. 0.1 M glucose b. 0.1 M NaCl a. SO2 is evolved
c. 0.1 M BaCl2 d. 0.1 M urea b. lead is formed
6. Which of the following solutions have lowest freezing c. lead sulphate is consumed
point d. sulphuric acid is consumed
a. 0.1 M NaCl b. 0.01 M NaCl 15. If a molecule MX 3 has zero dipole moment, the sigma
c. 1.0 M NaCl d. 0.001 M NaCl bonding orbitals used by M (atomic number < 21) are:
7. When an ideal gas undergoes unrestrained expansion, no a. pure p b. sp hybridised
cooling occurs because the molecules
c. sp 2 hybridised d. sp3 hybridised
a. are above the inversion temperature.
b. exert no attractive forces on each other. 16. Among the following the linear molecule is:
c. do work equal to loss in kinetic energy. a. CO2 b. NO2
d. collide without loss of energy. c. SO 2 d. ClO 2
17. The ratio of K p / K c for the reaction CO(g)+ 1
2 O2 (g) b. Temperature is a state function.
c. Change in the state is completely defined when the
 CO2(g) is:

initial and final states are specified.
a. 1 b. RT
d. Work appears at the boundary of the system.
c. (RT)1/ 2 d. (RT) 1/ 2
26. One mole of a non-ideal gas undergoes a change of state
 2NO(g) ; K p / K c
18. For the reaction N2 (g)  O2 (g)  (2.0 atm, 3.0 L, 95 K) 
 (4.0 atm, 5.0 L, 245 K) with
is equal to: a change in internal energy, E  30.0L  atm. The
a. RT b. 0 change in enthalpy ( H) of the process in L-atm is:
c. (RT) 1 d. 1 a. 40.0
19. If the hydrogen ion concentration of a given solution is b. 42.0
5.5  10 3 mol litre 1 , the pH of the solution will be: c. 44.0
a. 2.26 b. 3.40 d. not defined, because pressure is not constant
c. 3.75 d. 2.76 27. The half life periods of four isotopes are given:
I  6.7 years II  8000 years
salt  .
20. Henderson’s equation is pH  pKa  log If the
acid III  5760 years IV  2.35 105 years
acid gets half neutralised the value of pH will be: a. I b. II
[pK a  4.30] c. III d. IV
a. 4.3 b. 2.15 28. How many  and  particles are emitted in the
c. 8.60 d. 7
transformation 238
92 8U 
 92
234
U
21. The rate constant for the reaction, 2N2O5 
 4NO2+O2 a. 1, 1 b. 1, 0
is 3.0  105 s 1. If the rate is 2.40 105 mol L1s 1 , then c. 1, 2 d. 2, 1
the concentration of N 2O5 (in mol L1 ) is: 29. Amongst the following, the most basic compound is:
a. 1.4 b. 1.2 a. benzylamine b. aniline
c. 0.04 d. 0.8 c. acetanilide d. p-nittroaniline

22. If I is the intensity of absorbed light and C is the 30. The hybridisation of carbon atoms in C — C single bond
concentration of AB for the photochemical process. H — C  C — C — CH  CH2 is

AB  hv 
 AB , the rate of formation of
*
AB is a. sp3  sp3 b. sp2  sp3
directly proportional to:
c. sp  sp3 d. sp3  sp
a. C b. I
c. I 2 d. C.I 31. Assign the IUPAC name for the following compound.
Cl
23. Example of intrinsic colloid is:
a. Glue b. Sulphur Cl N=N
c. Fe d. As 2S3
a. (3-chlorophenyl)(4-chlorophenyl) diazene)
24. Colloidal solution of arsenious sulphide can be prepared
b. 3,4-bis(chlorophenyl) diazene
by:
c. (4-chlorophenyl (3-chlorophenyl) diazene
a. Electrodispersion method
d. 3,4-dichloroazobenzene
b. Peptisation
c. Double decomposition 32. What is the IUPAC name of the following compound?
d. Hydrolysis] O

25. Which of the following statements is false? CH3 – C – CH = CH – CH2 – C – COOH

a. Work is a state function. OH
 a. 2-hydroxy-6-oxohept-4-enoic acid 41. Number of oxygen atoms in a acetamide molecule is:
b. 2-hydroxy-6-ketohept-4-enoic acid a. 1 b. 2
c. 5-acetyl-2-hydroxypent-4-enoic acid c. 3 d. 4
d. 2-hydroxy-6-oxoheptanoic acid
42. Urea is:
33. When propyne is treated with aqueous H 2SO 4 in presence a. Monoacidic base b. Diacidic base
of HgSO 4 , the major product is? c. Neutral d. Amphoteric
a. propanal 43. Melting points are normally the highest for
b. propyl hydrogen sulphate a. Tertiary amides b. Secondary amides
c. acetone c. Primary amides d. Amines
d. propanol
44. Amines behave as:
34. Which of the following compounds does not dissolve in a. Lewis acids b. Lewis bases
conc. H 2SO 4 even on warming? c. Aprotic acids d. Amphoteric compounds
a. Ethylene b. Benzene 45. The common acid used in the manufacture of rayon and
c. Hexane d. Aniline plastics is:
35. Chloroform on heating with silver powder gives: a. Methanoic acid b. Ethanoic acid
a. Acetylene b. Methane c. Propanoic acid d. Butanoic acid
c. Ethylene d. Nitroethane 46. Solvays process is used for the manufacture of :
a. NaOH b. (Na2CO3. 10H2O)
36. If methyl bromide and ethyl bromide are mixed in equal
c. K2CO3 d. Na2O2
proportion and mixture is treated with sodium, the number
47. Alkali metals give a __________ when dissolved in liquid
of possible organic products is:
ammonia
a. 1 b. 2 c. 3 d. 4
a. Deep blue solution b. Colourless
37. Ethyl alcohol is industrially prepared from ethylene by: c. Red colour d. None of the Above
a. Permanganate oxidation 48. What are Oxo-Acids?
b. Catalytic reduction a. Acid containing Oxygen
c. Absorbing in H 2SO 4 followed by hydrolysis b. Acid containing Sulphur
d. Fermentation c. Acid containing Carbon
d. None of the Above
38. Propene, CH 3  CH  CH 2 can be converted to 1-propanol
49. In curing cement plasters, water is sprinkled from time to
by oxidation. Which set of reagents among the following is
time. This helps in
ideal to effect the conversion?
a. Converting sand into silicic acid
a. Alkaline KMnO 4
b. Keeping it cool
b. B2 H 6 and alkaline H 2 O 2 c. Developing interlocking needle like crystals of hydrated
c. O3 / Zn dust silicates
d. OsO 4 / CH 4 ,Cl2 d. Hydrating sand and gravel mixed with cement.
50. The substance not likely to contain CaCO3 is
39. Compound which gives acetone on ozonolysis? a. Dolomite b. A marble statue
a. CH 3  CH  CH  CH 3 b. (CH 3 ) 2 C  C(CH 3 ) 2 c. Calcined gypsum d. Sea shells.
c. C6 H 5CH  CH 2 d. CH 3CH  CH 2
Answers and Solutions
40. CH 3 — C — CH 2 — COOC 2 H 5  NaOH
H 2O
 A,
||
O 1. (c) As the given sulphate is isomorphous with
Product ‘A’ in the reaction is: ZnSO 4 .7H 2 O its formula would be MSO 4 .7H 2 O .m is
a. CH 3COOH b. C 2 H 5OH the atomic weight of M, molecular weight of
c. CH3COCH3 d. C2 H5CHO MSO 4 .7H 2 O  m  32  64  126  m  222
 m (c) 0.1 BaCl 2  Ba 2   2Cl  ; 0.3 mole
( BaCl 2 
Hence % of M   100  9.87 (given) or
m  222 particles)
100 m  9.87m  222  9.87 or 90.13m  222  9.87 (d) 0.3 M urea (0.1 mole particles).
222  9.87 Tb will be largest for C and, therefore, boiling point will
or m  24.3 .
90.13 be larges.
2. (c) wt. of metallic chloride = 74.5 6. (c) Tf depends upon concentration because solution is
wt. of chlorine = 35.5 the same. Therefore, 0.1 M NaCl will cause maximum
 wt. of metal  74.5  35.5  39 depression in freezing point and the freezing point of
Equivalent weight of metal: 1.0 M NaCl solution will be lowest.
weight of metal 39
  35.5   35.5  39 7. (b) According to postulates of kinetic theory, there is no
weight of chlorine 35.5
intermolecular attractions or repulsions between the
1 molecules of ideal gases.
3. (d) Contribution of circle from corner of square 
4
 Effective number of circle per square 8. (b) Let x grams of each hydrogen and methane are mixed,
x
Moles of H2 
2
x
Moles of CH 4 
16
1 x
  4  1(at centre)  2 8
4  Mole-fraction of H 2  2 
x x 9
 Area occupied by circle  2πr 2 ; r  radius. 
2 16
Also, diagonal of square 4 r  2 L, where L,  side of
Partial pressure of H 2 8
  mole  fraction of H 2 
square. Total pressure 9
Area occupied by circles
 Packing fraction 
Area of square 9. (b) m p / m e  1837  1.8  103.

2πr 2 2πr 2 π 10. (a) Splitting of signals is caused by protons attached to

  2   0.785
L2 8r 4 adjacent carbon provided these are not equivalent to the
 % Packing efficiency absorbing proton.
= 78.5 %.
11. (a) The balanced chemical reaction is:
4. (b) Contribution of atom from the edge centre is ¼. 2MnO 4  5SO 32  6H  
 2Mn 2  5SCO 24  3H 2 O
Therefore, number of
 5 moles SO32 reacts with 2 mole of KMnO4
1
M   4 (from edge centre)  1 (from body centre)  2  1 mole of SO32 require 2
moles of KMnO 4 .
4 5

1 1 12. (b) The balanced redox reaction is:

Number of X   8 (from corners)   6 (from
8 2 3MnO 4  5 FeC 2 O 4  24H  
 3Mn 2  5Fe 3
corners) = 4
10CO2  12H2O
 Empirical formula  M 2 X 4  MX 2
 5 moles FeC2 O 4 require 3 mole of KMnO4
5. (c) Tb will depend upon the number of particles given by
3
the solution in the solution (concentration is same).
 1 mole of FeC2 O 4 will require mole of KMnO 4 .
5
(a) 0.1 M glucose (0.1 mole particles)
13. (c) In a galavanic cell, oxidation occurs in the left hand
(b) 0.1 M NaCl ( NaCl   Na   Cl  ; 0.2 mole
electrode chamber and reduction in right hand electrode
particles) chamber. In the following combination of cell.
Pt | H 2 (g) | HCl(soln) || AgCl(s) | Ag(s)
 The cell reactions are: 24. (c) Arsenious sulphide can be prepared by double
At anode  H   e
2 H 2 (g) 
1 decomposition.
At cathode AgCl(s)  e  
 Ag  Cl  As 2O3  3H 2S 
 As 2S3  3H 2 O

Net: 1
2  H   Ag(s)  Cl
H 2 (g)  AgCl(s)  25. (a) Work is not a state-function, it depends on path
followed.
14. (d) In a lead storage battery, sulphuric acid is consumed
as: Pb  PbO 2  2H 2SO 4   2PbSO 4  2H 2 O 26. (c) H  U  (pV)  30  2(5  3)  5(4  2)  44 L atm.

15. (c) For non-polar MX 3 , it must have triangular planar 27. (d) Longer the half life period, more will be the stability
of the element.
arrangement, i.e., there should be sp 2 hybridisation
around M. 28. (c) 238
92 U 
 92
234
U  x 24He  y 01e
238  234  4x  0
16. (a) CO2 is a linear molecule because of sp hybridisation
or 4x  4 or x  1
around carbon atom.
n  92  92  2x  y
17. (d) Kp  Kc (RT) ,
92  92  2  1  y
 1 1
Here n  2   1     or y2
 2  2
Kp 29. (a)
  (RT )1/ 2 
—CH 2 — NH
Kc 2

benzyla min e
n
18. (d) Kp  Kc (RT)
Lone pair is not involved in resonance, most basic. In all
Kp other cases, lone-pair of nitrogen is involved in resonance,
Here n  2  (1  1)  0  1
Kc less basis.
19. (a) [H  ]  5.5  103 mole/litre 30. (d) H — C  C— C H  CH 2
 3   2
pH   log [H ]; pH   log [5.5  10 ]; pH  2.26 sp sp

[Salt] 31. (a) This compound is named as the derivative of

20. (a) pH  pK a  log
[Acid] ‘diazene’.
1 32. (a) The principal functional group is –COOH. The parent
pH  4.3  log 2  4.3  log 1; pH  4.3  0  4.3 hydride is ‘heptane’.
1
2 33. (c) Alkynes undergo Markownikoff’s addition of water in
1
21. (d) The unit of rate constant (t ) indicating that the presence of
H 2SO 4 / HgSO 4
decomposition reaction following first order kinetics.
 Rate  k[N 2O5 ] CH 3 — C  C — H  H 2SO 4 
HgSO 4


Rate 2.40  10 5  OH  O
 [N 2 O5 ]    0.80 M  |  ||
k 3  105  CH 3 — C  CH 2  
 CH 3 — C — CH 3
unstableenol acetone
22. (d) Rate will be directly proportional to both
concentration and intensity, i.e., rate of formation of 34. (c) Ethylene absorbs H 2SO 4 forming CH3 —CH2OSO3H
AB  C.I. and dissolve.
23. (a) On shaking with the dispersion medium, colloids Benzene with warm H 2SO 4 , undergo sulphonation, and
directly form the colloidal sol. Hence they are called dissolve.
intrinsic colloids. i.e., glue. Hexane, a hydrophobic molecule, does not react with
H 2SO 4 , remains insoluble.
 Aniline, with H 2SO 4 , forms anilinium sulphate salt and does not have to form bond with O of other amide and have
dissolve. least B.P
35. (a) CHCl3  6 Ag  Cl3 CH 
 HC  CH  6AgCl 44. (b) In amines nitrogen has a lone pair of e  . It can donate
36. (c) (i) 2 CH 3 Br  2Na 
 CH 3CH 3 (Ethane) a election pair. So, amines behave as a Lewis base.

(ii) 2 CH 3CH 2 Br  2Na 

 C 4 H10 (Butane) 45. (b) Ethanoic acid is used in the manufacture of resin and
plastics.
(iii) CH 3 Br  C 2 H 5 Br  2Na 
 C 3 H 8 (Propane)
46. (b) (Na2CO3. 10H2O)
37. (c) CH 2  CH 2 
H 2SO 4
 CH 3  CH 2  HSO 4 
Hydrolysis
 The Solvay process or ammonia soda process is used for
CH 3CH 2  OH  H 2SO 4 the manufacture of sodium carbonate
38. (b) Hydroboration oxidation (Industrial preparation of (Na2CO3. 10H2O).
alcohol). 47. (a) Deep blue solution
1 When an alkali metal is dissolved in liquid ammonia, it
3CH 3CH  CH 2  B2 H 6 Dry
(CH 3 CH 2 CH 3 ) 3 B results in the formation of a deep blue coloured solution.
2 ether

(CH 3CH 2 CH 3 ) 3 B 

H 2O2
 3CH 3CH 2 CH 2  OH The ammoniated electrons absorb energy corresponding to
a red region of visible light. Therefore, the transmitted
39. (b) (CH 3 ) 2 C  C(CH 3 ) 2 
O3
 2CH 3  CO  CH 3
light is blue in colour.
48. (a) Acid containing Oxygen
40. (c) Ketonic hydrolysis:
An oxyacid, oxoacid, or ternary acid is an acid that
CH 3  CO  CH 2 COOC 2 H 5 
NaOH
H 2O

contains oxygen. Specifically, it is a compound that
CH 3COCH 3  C 2 H 5OH  CO 2 contains hydrogen, oxygen, and at least one other element,
with at least one hydrogen atom bond to oxygen that can
41. (a) Formula of Acetamide is CH 3CONH 2 which consist
dissociate to produce the H+ cation and the anion of the
single oxygen atom. acid. e.g., carbonic acid, H2CO3 (OC(OH)2; sulphuric
acid, H2SO4 (O2S(OH)2).
42. (a) Urea behaves as a monoacidic base and react with
nitric acid and form sparingly soluble nitrate. 49. (c) Developing interlocking needle like crystals of
hydrated silicates
43. (c) The higher boiling points of amide is because of Water develops interlocking needle ¬like crystals of
Intermolecular hydrogen bonding. hydrated silicates. The reactions involved are the
—H — N — C  O — —H — N — C  O — hydration of calcium aluminates and calcium silicates
| | | |
H R H R which change into their colloidal gels.
—H — N — C  O — At the same time, some calcium hydroxide and aluminium
| | hydroxides are formed as precipitates due to hydrolysis.
H R
Calcium hydroxide binds the particles of calcium silicate
Due to intermolecular hydrogen bonding they have high together while aluminium hydroxide fills the interstices
boiling point than amine and amongst amide the order of rendering the mass impervious
Boiling point are: 50. (c) Calcined gypsum
Primary > Secondary > Tertiary The composition of gypsum is CaSO4 ·2H2O. It does not
This is because of alkyl group by which the carbonyl have CaCO3
oxygen do not form the hydrogen bond (other molecule) so
primary amide have high boiling point and tertiary Amides 