Topic 1 - The Particulate Nature of Matter
Topic 1 - The Particulate Nature of Matter
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State the distinguishing properties of solids, liquids and gases
● The three states of matter are solid, liquid and gas
● Melting and freezing take place at the melting point
● Boiling and condensing take place at the boiling point
● They can be represented by the simple model above, particles are represented
by small solid spheres
● solids- particles have a regular arrangement and are close together
● liquids- particles have a random arrangement and are close together
● gases- particles have a random arrangement and are spread apart
Describe the structure of solids, liquids and gases in terms of particle
separation arrangement and types of motion
● Gas: particles have the most energy – shown by the diagram, as the particles are
the most spread apart, motion is more random and frequent
● Liquid: particles have more energy than those in a solid, but less than those in a
gas
● Solid has least energy – particles are not moving/are just vibrating
Describe changes of state in terms of melting, boiling, evaporation, freezing,
condensation and sublimation
● Physical changes – therefore involves the forces between the particles of the
substances, instead of these changes of state being chemical changes
o Evaporation = happens at the surface, molecules have enough energy to
evaporate – i.e. go from liquid to gas
o Freezing = liquid to solid
o Melting = solid to liquid
o Boiling = happens throughout the liquid, liquid to gas
o Condensation = gas to liquid
o Sublimation = solid to gas
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(Extended only) Explain changes of state in terms of the kinetic theory
● Kinetic theory can help to explain melting, boiling, freezing and condensing…
o The amount of energy needed to change state from solid to liquid and
from liquid to gas depends on the strength of the forces between the
particles of the substance.
o The nature of the particles involved depends on the type of bonding and
the structure of the substance.
o The stronger the forces between the particles the higher the melting
point and boiling point of the substance.
o The more kinetic energy (from increased temperature) particles have, the
more movement, which causes a change of state from (s) to (l) to (g)
Describe qualitatively the pressure and temperature of a gas in terms of the
motion of its particles
● The higher the pressure = the more motion of a gas’ particles
● The h igher the temperature = the more motion of a gas’ particles
Show an understanding of the random motion of particles in a suspension
(sometimes known as Brownian motion) as evidence for the kinetic particle
(atoms, molecules or ions) model of matter
● Particles in liquids and gases (known as fluids) move randomly (this is called
Brownian motion)
● This happens because they collide with other moving particles in the fluid
● This is evidence for the kinetic particle model of matter- it shows that there are
individual particles which make up solids/liquids/gases
(Extended only) Describe and explain Brownian motion in terms of random
molecular bombardment
● Particles in liquids and gases move randomly because they are bombarded by
the other moving particles in the fluid. Larger particles can be moved by light,
fast-moving molecules
● Robert Brown observed the random movement of pollen grains within water,
which showed that there were separate particles within the water that were
moving randomly and caused the grain to move (kinetic theory)
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Describe and explain diffusion
● Movement of particles from an area of high concentration to an area of low
concentration
● For this to work, particles must be able to move
o Therefore, diffusion does not occur in solids, since the particles cannot
move from place to place (only vibrate)
o A smell does not travel very fast, because the particles collide with
particles of air, changing direction randomly when they collide, taking
much longer to travel from place to place
(Extended only) Describe and explain dependence of rate of diffusion on
molecular mass
● The smaller the molecular mass, the greater the average speed of the molecules
(but all gases have the same average kinetic energy at the same temperature)
o Therefore, the smaller the molecular mass, the faster the gas diffuses
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1 Kinetic theory explains the properties of matter in terms of the arrangement and movement of
particles.
(a) Nitrogen is a gas at room temperature. Nitrogen molecules, N2, are spread far apart and
move in a random manner at high speed.
[2]
(ii) Compare the movement and arrangement of the molecules in solid nitrogen to those in
nitrogen gas.
[3]
(b) A sealed container contains nitrogen gas. The pressure of the gas is due to the molecules of
the gas hitting the walls of the container.
Use the kinetic theory to explain why the pressure inside the container increases when the
temperature is increased.
[2]
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The following apparatus can be used to measure the rate of diffusion of a gas.
constant
pressure
applied metal foil,
gas escapes
gas syringe gas through small
hole in foil
nitrogen
it 1.00
chlorine
hl 0.63
nitrogen
it 1.05
(c)
c) Explain why nitrogen gas diffuses faster than chlorine gas.
[2]
(ii) Explain why the nitrogen gas diffuses faster at the higher temperature.
[1]
[Total: 10]
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2 Concentrated ammonia solution gives off ammonia gas. Concentrated hydrochloric acid gives off
hydrogen chloride gas. Ammonia, NH3, and hydrogen chloride, HCl, are both colourless gases.
Ammonia reacts with hydrogen chloride to make the white solid ammonium chloride.
glass tube
After ten minutes a white solid forms in the tube where the gases meet.
(a) (i) Write the chemical equation for the reaction of ammonia with hydrogen chloride.
....................................................................................................................................... [1]
(ii) Name the process by which the ammonia and hydrogen chloride gases move in the tube.
....................................................................................................................................... [1]
(iii) At which point, A, B, C or D, does the white solid form? Explain why the white solid forms
at that point.
explanation .........................................................................................................................
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[3]
Predict how the results of the experiment would be different. Explain your answer.
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....................................................................................................................................... [3]
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(b) Some of the white solid is removed from the tube and dissolved in water.
test ......................................................................................................................................
.............................................................................................................................................
result ...................................................................................................................................
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[3]
test ......................................................................................................................................
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result ...................................................................................................................................
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[3]
(c) The diagram shows the electron arrangement in a molecule of ammonia, showing only outer
shell electrons.
N H
....................................................................................................................................... [1]
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(ii) Hydrazine, N2H4, is another compound of nitrogen and hydrogen.
H H
N N
H H
[3]
(i) Name the linkages found in the polymers of nylon and protein.
....................................................................................................................................... [1]
....................................................................................................................................... [1]
(iii) What is the general name given to the products of hydrolysis of proteins?
....................................................................................................................................... [1]
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(e) Suggest the structure of the monomer used to make the polymer shown.
H O
N C
n
[1]
[Total: 22]
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3 Compound X is a colourless liquid at room temperature.
(a) A sample of pure X was slowly heated from –5.0 °C, which is below its melting point, to 90 °C,
which is above its boiling point. Its temperature is measured every minute and the results are
represented on the graph.
F
90 °C
D
E
temperature
B
t °C C
A
–5 °C
time
(i) Complete the equation for the equilibrium present in the region BC.
....................................................................................................................................... [1]
....................................................................................................................................... [1]
(iv) What would be the difference in the region BC if an impure sample of X had been used?
....................................................................................................................................... [1]
(b) Compound X is a hydrocarbon. It contains 85.7% of carbon. The mass of one mole of X is 84 g.
....................................................................................................................................... [1]
....................................................................................................................................... [1]
PhysicsAndMathsTutor.com [Total: 9]
4 (a) Different gases diffuse at different speeds.
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....................................................................................................................................... [1]
(ii) What property of a gas molecule affects the speed at which it diffuses?
....................................................................................................................................... [1]
(b) Helium is a gas used to fill balloons. It is present in the air in very small quantities. Diffusion can
be used to separate it from the air.
Air at 1000 °C is on one side of a porous barrier. The air which passes through the barrier has
a larger amount of helium in it.
(i) Why does the air on the other side of the barrier contain more helium?
....................................................................................................................................... [1]
.............................................................................................................................................
....................................................................................................................................... [1]
(c) Most helium is obtained from natural gas found in the USA. Natural gas contains methane and
7% helium. One possible way to obtain the helium would be to burn the methane.
....................................................................................................................................... [1]
(ii) Suggest why this would not be a suitable method to obtain the helium.
.............................................................................................................................................
....................................................................................................................................... [1]
(iii) Suggest another method, other than diffusion, by which helium could be separated from
the mixture of gases in natural gas.
....................................................................................................................................... [1]
[Total: 7]
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5 Explain each of the following in terms of the kinetic particle theory.
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(b) A liquid has a fixed volume but takes up the shape of the container. A gas takes up the shape
of the container but it does not have a fixed volume.
liquid gas
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.............................................................................................................................................. [3]
[Total: 6]
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6 The diagram shows a heating curve for a sample of compound X.
D
80 E
temperature / °C
B
15 C
A
time
..................................................................................................................................... [1]
(b) Write an equation for the equilibrium which exists in region BC.
..................................................................................................................................... [2]
..................................................................................................................................... [1]
(d) Explain how the curve shows that a pure sample of compound X was used.
...........................................................................................................................................
..................................................................................................................................... [2]
[Total: 6]
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1 (a (i) 6e between two nitrogen atoms; note: can be any combination of dots or crosses [1]
1 lone pair on each nitrogen atom; [1]
(ii) (at higher temperature) molecules move faster / have more energy [1]
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Question Answer Marks
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Question Answer Marks
2(c)(i)
(c)(i) cov 1
2(c)(ii) 3
M1 one shared pair of electrons between each N and H; 1
M2 one shared pair of electrons between the N atoms; 1
M3 one lone pair on each N and no additional electrons anywhere; 1
(d)(i)
d)(i 1
2(d)(ii) proteins are made from more than two monomers; 1
OR
nylon is made from 1 or 2 monomers (only);
2(d)(iii)
(d)(ii acids; 1
2(e) 1
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3 (a (i) (X(s) ↔) X(l) [1]
[Total: 9]
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4 (a (i) (particles) spread to fill total available volume / move from high concentration
to low concentration / moves down a concentration gradient (1) [1]
(b)
b) helium atoms / molecules are lighter than molecules in air or N2 and O2
or helium is less dense than air or N2 and O2.
or helium diffuses (through the porous barrier) faster than air or N2 and
O2. (1) [1]
(ii) faster rate of diffusion / molecules move faster (at high temperatures). (1) [1]
[Total: 7]
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5 (a any three from:
particles have more energy (1)
move faster (1)
collide more frequently (1)
more particles have energy greater than Ea [3]
guidance: more colliding molecules have enough energy to react is worth (2)
(b) particles move in all directions / randomly in both liquids and gases (1)
[Total: 6]
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6 (a liquid; [1]
(d) (in region BC) solid melts / liquid boils (in region DE); [1]
at one / fixed / sharp / single / specific temperature; [1]
[Total: 6]
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1 (a) A small amount of liquid bromine is added to a container which is then sealed.
Br2(l) → Br2(g)
Use the ideas of the Kinetic Theory to explain why, after about an hour, the bromine
molecules have spread uniformly to occupy the whole container.
...........................................................................................................................................
...........................................................................................................................................
..................................................................................................................................... [3]
(b) The diagrams below show simple experiments on the speed of diffusion of gases.
porous pot
allows gas hydrogen
air
molecules porous pot
to diffuse
air air
higher level
large
same level
beaker
coloured
liquid
diagram 1 diagram 2
higher
level
air
carbon dioxide
large beaker
diagram 3
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Complete the following explanations. Diagram 1 has been done for you.
Diagram 1
There is air inside and outside the porous pot so the rate of diffusion of air into the pot is
the same as the rate of diffusion of air out of the pot. The pressure inside and outside the
pot is the same so the coloured liquid is at the same level on each side of the tube.
Diagram 2
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Diagram 3
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[Total: 9]
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2 Cobalt is an element in Period 4 of the Periodic Table.
(a) Use your copy of the Periodic Table to help you complete the table below.
Co
Co2+
[2]
60
(b) Co is a cobalt isotope.
....................................................................................................................................
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.............................................................................................................................. [2]
(ii) Explain why two isotopes of the same element have identical chemical properties.
.............................................................................................................................. [1]
(iii) State one industrial use and one medical use of radioactive isotopes.
[Total: 7]
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3 The following table gives information about six substances.
(a) Which substance could have a macromolecular structure, similar to that of silicon(IV)
oxide?
..................................................................................................................................... [1]
..................................................................................................................................... [1]
..................................................................................................................................... [1]
..................................................................................................................................... [1]
..................................................................................................................................... [1]
..................................................................................................................................... [1]
[Total: 6]
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4 The Kinetic Theory explains the properties of matter in terms of the arrangement and
movement of particles.
(a) Nitrogen is a gas at room temperature. Nitrogen molecules, N2, which are spread far
apart move in a random manner at high speed.
(i) Draw a diagram showing the arrangement of the valency electrons in a nitrogen
molecule.
Use × to represent an electron from a nitrogen atom.
[2]
(ii) How does the movement and arrangement of the molecules in a crystal of nitrogen
differ from those in gaseous nitrogen?
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....................................................................................................................................
............................................................................................................................... [3]
(b) Use the ideas of the Kinetic Theory to explain the following.
(i) A sealed container contains nitrogen gas. The pressure of a gas is due to the
molecules of the gas hitting the walls of the container.
Explain why the pressure inside the container increases when the temperature is
increased.
....................................................................................................................................
.............................................................................................................................. [2]
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(ii) The following apparatus can be used to measure the rate of diffusion of a gas.
constant
pressure
applied metal foil
gas escapes
gas syringe gas through small
hole in foil
nitrogen 25 1.00
chlorine 25 0.63
nitrogen 50 1.05
....................................................................................................................................
.............................................................................................................................. [2]
.............................................................................................................................. [1]
[Total: 10]
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5 Three of the halogens in Group VII are:
chlorine
bromine
iodine
(a)
a) How does their colour change down the Group?
[1]
(ii) How does their physical state (solid, liquid or gas) change down the Group?
[1]
colour
(b) Describe how you could distinguish between aqueous potassium bromide and aqueous
potassium iodide.
test
(c) 0.015 moles of iodine react with 0.045 moles of chlorine to form 0.030 moles of a single
product. Complete the equation.
I2 + Cl2 [2]
[2]
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6 Strontium and sul ut they have
different properties.
melting point / oC 87 -8
(a) The formulae of the chlorides are similar because both elements have a valency of 2.
Explain why Group II and Group VI elements both have a valency of 2.
[2]
(b) Draw a diagram showing the arrangement of the valency electrons in one covalent
molecule of sulphur chloride.
Use x to represent an electron from a sulphur atom.
Use o to represent an electron from a chlorine atom.
[3]
[1]
[1]
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1 (a explanation of evaporation e.g. particles (or molecules) with a lot of energy leave the
liquid / bromine particles break free from each other / forces or bonds between
bromine molecules broken / molecules (in liquid) have weak forces holding them
together / weak intermolecular forces / Van der Waals forces between molecules
(don’t have to be stated as weak) / (weak intermolecular forces alone scores this
mark);
allow: particles (or molecules) of bromine escape from liquid [1]
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2 (a 27p 32n 27e [1]
27p 32n 25e [1]
(b) (i) same proton number / same number of protons / same atomic number [1]
different nucleon number / different number of neutrons / different mass number [1]
(iii) industrial detection of leaks / thickness of paper etc. / nuclear fuel for generating
electricity / nuclear weapons / radiographs of welds / measuring wear / sterilising food [1]
not: carbon dating
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3 (a E [1]
(c) A [1]
(d) F [1]
(e) C [1]
[Total: 6]
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4 (a) (i) 6e between two nitrogen atoms (can be any combination of dots or crosses) [1]
1 lone pair on each nitrogen atom [1]
(ii) (1) nitrogen has smaller Mr / lighter molecules / lower density [1]
nitrogen molecules / particles move faster (than chlorine molecules) [1]
(2) at higher temperature nitrogen molecules or particles (not atoms) move faster /
have more energy [1]
[Total: 10]
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5 (a (i) darker or actual colours [1]
chlorine yellow, yellow/green
bromine orange, brown, brownish red
iodine black grey, purple
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6 (a) Group II metals will lose 2e [1]
Group VI elements will gain 2e [1]
(c)
c) Ions cannot move in solid or can move in liquid [1]
TOTAL = 7
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1 Acid-base reactions are examples of proton
(i) In terms of proton transfer, explain what is meant by the term weak
.............................................................................................................................................
base.
....................................................................................................................................... [2]
(ii) Given aqueous solutions of both bases, describe how you could show that sodium
hydroxide is the stronger base. How could you ensure a ‘fair’ comparison between the two
solutions?
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(i) Complete the equation for the reaction between sulfuric acid and ethylamine. Name the
salt formed.
(ii) Amines and their salts have similar chemical properties to ammonia and ammonium salts.
Suggest a reagent that could be used to displace the weak base, ethylamine, from its salt
ethylammonium chloride.
....................................................................................................................................... [1]
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(c) Gases diffuse, which means that they move to occupy the total available volume.
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....................................................................................................................................... [2]
(ii) When the colourless gases hydrogen bromide and ethylamine come into contact, a white
solid is formed.
The following apparatus can be used to compare the rates of diffusion of the two gases
ethylamine and hydrogen bromide.
A B C
Predict at which position, A, B or C, the white solid will form. Explain your choice.
.............................................................................................................................................
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....................................................................................................................................... [3]
[Total: 14]
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2 The halogens are a collection of diatomic non-metals in Group VII.
(a)
a) Define the term diatomic.
.............................................................................................................................. [1]
.............................................................................................................................. [1]
.............................................................................................................................. [1]
(b) The halogens react with other non-metals to form covalent compounds.
Draw a diagram which shows the arrangement of the valency electrons in one molecule
of the covalent compound arsenic trifluoride.
The electron distribution of an arsenic atom is 2 + 8 + 18 + 5.
[3]
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(c) Photochromic glass is used in sunglasses. In bright light, the glass darkens reducing
the amount of light reaching the eye. When the light is less bright, the glass becomes
colourless increasing the amount of light reaching the eye.
Photochromic glass contains very small amounts of the halides silver(I) chloride and
copper(I) chloride.
The reaction between these two chlorides is photochemical.
...........................................................................................................................................
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..................................................................................................................................... [3]
[Total: 11]
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3 Selenium and sulfur are in Group VI. They have similar properties.
(a) One of the main uses of selenium is in photoelectric cells. These cells can change light
into electrical energy.
(i) Name a process which can change light into chemical energy.
....................................................................................................................................
(ii) Name a device which can change chemical energy into electrical energy.
.............................................................................................................................. [2]
(i) Selenium forms an ionic compound with potassium. Draw a diagram which shows
the formula of this ionic compound, the charges on the ions and the arrangement of
the valency electrons around the negative ion.
Use o to represent an electron from an atom of potassium.
Use x to represent an electron from an atom of selenium.
[3]
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(ii) Draw a diagram showing the arrangement of the valency electrons in one molecule
of the covalent compound selenium chloride.
Use x to represent an electron from an atom of selenium.
Use o to represent an electron from an atom of chlorine.
[3]
(iii) Predict two differences in the physical properties of these two compounds.
....................................................................................................................................
.............................................................................................................................. [2]
What type of reagent is the selenide ion in this reaction? Give a reason for your choice.
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..................................................................................................................................... [3]
[Total: 13]
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4 Chlorine reacts with phosphorus to form phosphorus trichloride.
(a) Draw a diagram showing the arrangement of the valency electrons in one molecule of
the covalent compound, phosphorus trichloride.
Use x to represent an electron from a phosphorus atom.
Use o to represent an electron from a chlorine atom.
[2]
(ii) Describe how you could show that phosphorus acid, H3PO3, is a weaker acid than
hydrochloric acid.
....................................................................................................................................
....................................................................................................................................
.............................................................................................................................. [3]
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(iii) Two salts of phosphorus acid are its sodium salt, which is soluble in water, and its
calcium salt which is insoluble in water. Suggest a method of preparation for each of
these salts from aqueous phosphorus acid. Specify any other reagent needed and
briefly outline the method.
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.............................................................................................................................. [2]
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[Total: 10]
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5 Ethanoic acid is a colourless liquid at room temperature. It has the typical acid properties
and forms compounds called ethanoates.
(a) A pure sample of ethanoic acid is slowly heated from 0oC to 150oC and its temperature
is measured every minute. The results are represented on the graph below.
D
E
temperature
B
C
A
time
[1]
(ii) What would be the difference in the region B to C if an impure sample had been
used?
[1]
(iii) Sketch on the graph how the line would continue if the acid was heated to a higher
temperature. [1]
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(iv) Complete the following table that compares the separation and movement of the
molecules in regions C to D with those in E to F.
C to D E to F
separation (distance
between particles)
[5]
(b) Complete the word equations for the reactions of ethanoic acid.
(c) Write the symbol equation for the reaction between ethanoic acid and sodium
hydroxide.
[2]
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Question Answer Marks Guidance
M2 does not accept (protons) readily A ‘hydrogen ion’ or ‘H+’ for proton
OR less able to accept protons (than strong bases); 2 I accepts fewer / less protons
(a)(ii) M1 same concentration of both bases;
M3 the higher pH is the stronger base; 3 A suitable colours of both weak strong
bases e.g. ethylamine is (greeny)blue,
NaOH is darker blue / purple
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Question Answer Marks Guidance
(b)(ii) sodium hydroxide / calcium hydroxide / NaOH / Ca(OH)2 ; 1 any Group 1 or Group 2 hydroxide or
oxide
(c)(i) Any two from:
(particles move in) random motion;
(particles) move from a region of high concentration to low concentration; 2 A down a concentration gradient
6(c)(ii)
(c
M2 it has a lower (relative) molecular mass (than HBr); A ethylamine is less dense
A ethylamine is a lighter molecule but
M3 ethylamine diffuses faster (than HBr); I ‘ethylamine is lighter’
3 I ethylamine is a smaller molecule
A ethylamine molecules or particles
move faster
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2 (a (i) two atoms per molecule [1]
(ii) 7e in outer shell or level / same number of outer electrons / need to gain one electron [1]
(iv)
halogen solid, liquid or gas colour
at room temperature
[Total: 11]
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3 (a (i) photosynthesis or a photochemical reaction [1]
not an example, question requires a process
not devices which convert light into electricity
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4 (a 3 bp and 1nbp around phosphorus [1]
1 bp and 3nbp around each chlorine [1]
precipitation/filter/decant/centrifuge
rec
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5 (a)(i) boiling [1]
TOTAL = 12
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1 In which changes do the particles move further apart?
W X
gas liquid solid
Y Z
X Y Z
A X to Y B Y to Z C Z to X D Z to Y
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5 The changes that occur when a substance changes state are shown below.
W X
solid liquid gas
Z Y
Which two processes must happen to spread the sugar evenly in the tea?
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7 A sugar cube is dropped into a hot cup of tea.
8 A crystal of purple potassium manganate(VII) was added to each of the beakers shown in the
diagram.
crystal of potassium
manganate(VII)
One beaker contained hot water and the other beaker contained cold water.
In both beakers the purple colour of the potassium manganate(VII) spreads out.
esult
result explanation
A colour spreads faster in cold water particles move faster at a higher temperature
B colour spreads faster in cold water particles move slower at a higher temperature
C colour spreads faster in hot water particles move faster at a higher temperature
D colour spreads faster in hot water particles move slower at a higher temperature
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9 Which statement is an example of diffusion?
10 A few drops of perfume were spilt on the floor. A few minutes later the perfume could be smelt a
few metres away.
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11 The diagram shows the result of dropping a purple crystal into water.
water purple
after five hours solution
purple
crystal
chemical
diffusing dissolving
reaction
A
B
C
D
12 Two gas jars each contain a different gas. The gas jars are connected and the cover slips are
removed.
cover slips
A chemical reaction
B condensation
C diffusion
D evaporation
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13 A liquid is heated until it boils.
thermometer
test-tube
25 cm3 liquid
spirit burner
ethanol
Which result shows that the liquid in the test-tube is pure water?
14 An attempt was made to compress a gas and a solid using the apparatus shown.
piston
gas solid
Which substance would be compressed and what is the reason for this?
substance reason
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15 A gas jar of bromine vapour and a gas jar of air are set up as shown in diagram 1.
The glass slide is removed. Diagram 2 shows the appearance of the gas jars after one hour.
air
mixture of air
glass slide and bromine
bromine
vapour
diagram 1 diagram 2
Which statement explains why the bromine and air mix together?
Which row describes the water particles in the air above the cup compared with the water
particles in the cup?
A
B
C
D
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17 What are the processes W, X, Y and Z in the following diagram?
W X
solid liquid gas
Y Z
18 ‘Particles moving very slowly from an area of high concentration to an area of low
concentration.’
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19 Which diagram shows the process of diffusion?
key
A
different
atoms
20 In which substance are the particles close together and slowly moving past each other?
A air
B ice
C steam
D water
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21 The diagrams show the arrangement of particles in three different physical states of substance X.
W X
gas liquid solid
Y Z
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23 Aqueous lead(II) nitrate and aqueous potassium iodide are added to a dish containing water, as
shown.
yellow precipitate
A diffusion
B distillation
C fermentation
D filtration
24 The diagram shows how the molecules in the exhaust gases diffuse into the air.
molecules in air
molecules in
exhaust gases
A The molecules fall to the ground because they are heavier than air molecules.
B The molecules go back together as they cool.
C The molecules spread further into the air.
D The molecules stay where they are.
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1 D
2 B
3 B
4 A
5 B
6 B
7 C
8 C
9 D
10 D
11 D
12 C
13 C
14 B
15 D
16 B
17 C
18 C
19 C
20 D
21 D
22 D
23 A
24 C
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